Absstract of: CN122235793A
0001 本发明公开了一种具有多级尖锥结构的制氢电极及其制备方法和应用,属于电解水制氢电极技术领域;本发明制氢电极的制备方法包括以下步骤:将导电基底作为阴极进行分段电沉积工艺,得到具有多级尖锥结构的制氢电极;所述分段电沉积工艺包括三步:第一步,将导电基底放入电镀液电沉积,不采用磁场辅助,第二步,将导电基底从电镀液中取出,空气中静置,第三步,将导电基底重新放入电镀液电沉积,不采用磁场辅助;所述第三步的电流密度和第一步的电流密度之比大于等于1:1,所述电镀液包括电镀添加剂。本发明制备的制氢电极具有多级尖锥结构,用于电解水制氢具有高活性和高稳定性;同时制备工艺简单,成本低。
Absstract of: CN122241649A
0001 本公开提供了一种电解槽寿命的预测方法、系统、电子设备及存储介质,包括:基于寿命预测模型对电解槽各电流的历史电压值进行归一化处理,并将归一化处理后的时间序号作为自变量以及历史电压值作为因变量;根据对自变量和因变量进行线性回归拟合得到的电压变化趋势直线方程和预设电压失效阈值获取当前电压达到预设电压失效阈值所需时间与当前时间的时间差值,将时间差值作为电解槽的剩余使用寿命。本公开通过电解槽电压变化趋势直线方程结合预设电压失效阈值获取电解槽的当前电压达到预设电压失效阈值的所需时间与当前时间的时间差值,将时间差值作为电解槽的剩余使用寿命,实现了对电解槽寿命的精准预测,降低了意外停机风险,延长了使用寿命。
Absstract of: CN122235774A
本发明提供一种基于太阳能的海水直接电解制氢效率动态评估方法,涉及数据处理技术领域,该方法采集海水流动速度瞬时值构建海水动态流态指标,并对光伏组件输出电流、电压进行连续采样与时间对齐以获得电解槽输入功率;基于电解槽几何结构进行固定空间映射划分,计算各固定位置区域的基准反应电流密度;通过流态‑电流密度响应函数模型生成区域传质响应系数,对电流密度进行修正得到流态耦合电流密度,并据此计算有效电解电荷量和制氢效率;当效率连续偏离预设阈值时调整光伏组件输出功率并匹配调节电解槽工作电流,实现制氢效率的连续动态评估。
Absstract of: CN122235761A
本申请公开了一种FeCo/MWCNT复合电催化剂及其制备方法与应用,主要应用于电催化水分解反应中的析氧反应(OER);采用简便的溶剂热法制备前驱体,并经碳化构筑了FeCo/MWCNT复合催化剂;碳化过程促进了FeCo合金的形成,同时在多壁碳纳米管(MWCNT)的链接作用下获得了具有高电子导通性与结构稳定性的复合体系;OER性能提升主要源于FeCo合金对活性中心电子结构的优化,以及MWCNT提供的高效电子传输通道,二者产生显著的协同催化效应;本申请不仅丰富了MOF衍生物在催化领域的应用,也为非贵金属高OER活性催化剂的设计与制备提供了新的思路和可行路径。
Absstract of: CN122231049A
本发明公开了一种高电流密度下的碱性水制氢电解槽,涉及制氢电解槽技术领域,包括设备固定座和开设在设备固定座内部的放置槽,所述设备固定座的内部成排设置有单元电解槽,所述设备固定座的两端均安装有用于固定单元电解槽的锁紧丝杆,所述设备固定座的下端且位于单元电解槽的底端设置有清洁组件,所述清洁组件包括驱动电机;本发明可以将单元电解槽下方的异物进行清洁,单元电解槽的下方没有积存杂物提高了单元电解槽的电解效率,不会堵塞电解液流道,降低能耗,可以避免各个单元电解槽之间的间距发生较大的变化,单元电解槽间距一致不会发生变形、短路,确保电解效率与设备稳定性,单元电解槽底端的位置变化后可以被活动夹持块矫正。
Absstract of: CN122233453A
0001 本发明公开了一种Ir<0.82>Sn<0.18>O<2>多孔纳米片及其制备方法和应用,所述方法包括以下步骤:(1)将氯化铱、水合氯化锡、硝酸钠和水合柠檬酸溶于乙醇与去离子水的混合溶剂中,搅拌均匀,得到前驱体混合溶液;(2)将前驱体混合溶液离心分离,收集沉淀后干燥,得到前驱体粉末;(3)将前驱体粉末在空气气氛下进行煅烧处理,自然冷却后得到煅烧产物;(4)将煅烧产物用去离子水和乙醇交替洗涤,干燥后得到Ir<0.82>Sn<0.18>O<2>多孔纳米片。本发明操作简便、重复性好,通过Sn的掺杂在降低贵金属Ir负载量的同时,利用Ir与Sn之间的协同效应有效提升了材料的催化活性和运行稳定性。
Absstract of: CN122235740A
0001 本申请公开了一种制氢系统和制氢系统的控制方法,涉及制氢技术领域,其中,制氢系统包括电解槽、气液分离器、脱杂气器、换热器、气水分离器以及干燥器,电解槽具有出口;气液分离器具有混合物入口和排气口,混合物入口连通出口;脱杂气器具有进气端和出气端,进气端连通排气口;且排气口排出的气体未经换热而进入脱杂气器内;换热器具有散热流道,散热流道的一端连通出气端;气水分离器具有第一通气口和第二通气口,第一通气口与散热流道的另一端连通;干燥器连通第二通气口。本申请提供的制氢系统可以使得制氢的流程缩短,设备数量减少。
Absstract of: CN122235764A
本发明属于纳米材料制备及应用技术领域,公开了一种磷掺杂镍钴硫化物纳米管催化剂及其制备方法与应用。该方法包括:以金属镍盐、钴盐、尿素为原料,以水为溶剂,经水热反应制备镍钴氢氧化物纳米棒前驱体,再通过水热合成镍钴硫化物纳米管,最后经磷化制得具有中空结构的磷掺杂镍钴硫化物纳米管催化剂。通过磷掺杂有效优化了镍钴硫化物的电子结构,提升了催化性能。所制备的催化剂在析氢和硫氧化反应中具有出色的催化活性。在两电极硫离子氧化耦合制氢电解池中,需要0.373 V电压输出10 mA cm‑2的电流密度,实现了节能制氢及高附加值单质硫的目标。此外,本发明制备方法简便、条件易控,原料低成本环保,可广泛应用于电解水制氢与硫氧化反应等领域。
Absstract of: CN122230499A
本申请提供了一种具有吸附纯化与钯膜纯化的高纯氢气制备装置,本申请中所有部件集成于一体化刚性机柜内,消除了外部级联高压管路,减少泄漏点,提升系统刚性和安全性,便于通过防爆与压力容器认证;通过“气液分离器‑吸附纯化单元‑高温钯膜”的三段式结构,吸附单元采用分子筛+钯触媒复合填充,兼具深度脱水和催化脱氧功能,为钯膜提供干燥、无氧的前置保护环境,显著延长其使用寿命;稳压隔离管段的设置能够形成“压力稳定隔离带”,有效吸收切换产生的压力波动,防止钯膜因压力交变而受损;集成保护回路,在异常停机或气源中断时迅速抽空钯膜腔体,物理阻断空气接触,彻底杜绝高温氧化风险。
Absstract of: CN122234793A
本发明属于太阳能捕获与光催化水制氢应用领域,公开了仿生环肽‑卟啉光催化制氢光敏剂、制备方法及应用。所述光敏剂由具有分子限域结构的环形多肽(CP)与卟啉(TPP)光敏单元通过共价键偶联,制备卟啉‑环肽(TPP‑CP)复合光敏材料,然后在卟啉‑环肽复合光敏材料周围引入具有亲水‑疏水两性的聚二甲基丙烯酰胺(PDMA),利用分子间相互作用构建柔性限域微环境,从而在分子尺度上模拟天然光捕获体系中蛋白质‑色素的空间构型及其多级微环境调控机制。该光敏剂(TPP‑CP/PDMA)能够有效抑制卟啉光敏单元间π‑π堆叠,降低非辐射弛豫,促进光生电荷分离与传递,从而实现高效光催化产氢。
Absstract of: CN122231302A
0001 本发明涉及新型纳米材料及控制合成领域,公开了一种高熵合金及其制备方法与应用,包括以下步骤:制备ZIF‑67空心球、制备Co/NC前体、制备高熵合金前体、制备高熵合金。本发明以ZIF‑67衍生的氮掺杂碳为载体的Co金属颗粒为前体,通过电置换反应成功引入Ni、Fe、Cu、Pt金属,制备出NiCoFeCuPt高熵合金纳米颗粒、NiCoFeCu合金纳米颗粒、NiCoFe合金纳米颗粒;本发明的高熵合金在酸性和碱性条件下均表现出高效且稳定的HER催化性能。
Absstract of: CN122235748A
本发明公开一种能够大幅降低阴离子交换膜电解槽氧中氢浓度的双极板和集流板结构,所述双极板/集流板上为构成公用管道所开的通孔的内壁面经过绝缘处理,或者采用绝缘体与导电的双极板/集流板组成复合结构,从而阻断通孔内壁面与电解液的直接接触,本发明能够大幅降低阴离子交换膜电解槽运行过程中的氧中氢浓度,从而提升阴离子交换膜电解槽运行安全性。本发明具有结构简单、成本低的特点,并与现有阴离子交换膜电解槽装配、生产过程高度适配,具有显著工程应用价值。
Absstract of: CN122230611A
0001 本发明公开了一种基于温度梯度分区催化的氨裂解制氢装置及制氢方法,属于氨制氢技术领域。该装置包括依次流体连通的进料汽化系统、分区裂解系统、纯化系统及回热器。所述分区裂解系统内部沿径向由内向外依次设置有同轴嵌套的低温催化区、中温催化区和高温催化区;其最外围设有加热装置,热量向内径向传递,在内部形成由外向内递减的温度场,使各催化区的温度与所填充催化剂的活性温度区间精准匹配。本发明变传热劣势为催化驱动力,激活了中心床层,消除了反应死区,使全床层催化剂均能充分参与裂解反应,有效提升了高流速下的氨转化率与系统综合能效。
Absstract of: CN122230750A
本发明公开一种光催化制氢用Au@WO3:Yb,Er/CdS复合催化剂的制备方法,属于光催化材料技术领域。本发明所述方法首先将Yb2O3,Er2O3制成的稀土硝酸盐、氯金酸、(NH4)6H2W12O40·xH2O混合成为前驱体溶液Ⅰ,将其滴加到聚苯乙烯蛋白石模板上煅烧后得到Au@WO3:Yb,Er反蛋白石材料,将其加入到由CdCl2·2.5H2O和Na2S·9H2O制成的前驱体溶液Ⅱ中,搅拌,洗涤,干燥得到Au@WO3:Yb,Er/CdS复合催化剂;该催化剂集合了单一Au@WO3:Yb,Er和单一CdS的优点,在Au、WO3:Yb,Er和CdS协同作用下,抑制了载流子复合,提高了光吸收率,提高了析氢产率。
Absstract of: AU2024389236A1
An electrolyzer stack (17) wherein each of the electrode compartments (5, 6) is delimited by the ion-transporting separator (15) and a bipolar plate (14) as well as a gasket (25) that is surrounding the electrode compartments (5, 6). An electrolyte manifold (27) extends along the stack (17) and through an opening (20) in each of the bipolar plates (14). The electrolyte manifold (27) is formed by multiple serially connected flow restrictors (28), of which one flow restrictor (28) is provided per cell (1) and inserted between neighbouring gaskets (25) and comprises a flow canal (30) having a canal inlet (30 A) and a canal outlet (30B), wherein the canal inlet (30 A) is provided in the throughput opening and fluid-flow connected to the electrolyte manifold (27) and the canal outlet (30B) is fluid-flow connected to one of the cells (1) for supply of electrolyte from the electrolyte manifold (27) to the respective cell (1). The canal is narrow and long for reducing shunt currents and for providing a pressure drop larger, for example at least 10 times higher, than a pressure drop along the electrolyte manifold (27).
Absstract of: DE102024137556A1
Die Erfindung betrifft ein Kühlfeld (1) für ein stapelförmig aufgebautes elektrochemisches System (10), insbesondere einen Elektrolyseur, und weist mindestens einen Kühlmitteleinlass (2) und mindestens einem im Vergleich hierzu größeren Kühlmittelauslass (3), insbesondere jeweils zwei derartige Ein- und Auslässe (2, 3), auf, wobei zwischen dem Kühlmitteleinlass (2) und dem Kühlmittelauslass (3) ein Einlassbereich (4), ein Hauptströmungsfeld (7) und ein Auslassbereich (9) gebildet sind, wobei das Hauptströmungsfeld (7) einen mittigen Einschnürungsbereich (8) aufweist, und wobei im mittigen Einschnürungsbereich (8) Kanäle (13) gebildet sind, welche in dem betreffenden Bereich parallel zueinander verlaufen, wogegen zwischen dem Einschnürungsbereich (8) und den Übergängen (14, 15) zum Einlassbereich (4) beziehungsweise Auslassbereich (9) mehrere mindestens einfach abgeknickte Kanalabschnitte (16, 17) vorliegen, und wobei auf der Seite des Kühlmitteleinlasses (2) eine Rippenstruktur (18) und auf der Seite des Kühlmittelauslasses (3) eine Pinstruktur des jeweiligen Ein- beziehungsweise Auslassbereichs (2, 3), jeweils unter Wahrung eines Abstandes zu den genannten Kanalabschnitten (16, 17), dem Hauptströmungsfeld (7) benachbart ist.
Absstract of: AU2026204236A1
A system (1) for generating hydrogen gas comprises a reaction vessel (101) containing an aqueous solution (102) and a cathode (105) and an anode (107) each positioned at least partly in the reaction vessel (101). The system (1) comprises first and second ultrasonic transducers (215-220) which emit ultrasonic waves in the direction of the cathode (105) and the anode (107) respectively. Each ultrasonic transducer (215-220) is driven by a respective transducer driver (202) to optimise the operation of the system (1) for generating hydrogen gas by sonoelectrolysis. un u n
Absstract of: US20260168622A1
0000 A distributed hydrogen energy system adds onto existing infrastructure of a localized renewable energy microgrid and utilizes excess generated energy to power an electrolyzer to produce hydrogen gas on site that is compressed and stored in a stationary pressure vessel. The stored hydrogen gas can be used directly within the local renewable energy microgrid wherein the stored hydrogen gas is converted to energy through use of one or more fuel cells or can be used in the context of a distributed energy system wherein the stored hydrogen gas is shared as part of a larger distribution network via pipeline or via one or more portable pressure vessels.
Absstract of: WO2026123931A1
Disclosed in the present application are a flow battery device for recovering Li+ and a recovery method. In the present invention, a waste LiFePO4 solid wrapped by a porous PTFE filter membrane is placed on one side of a positive electrode electrolyte of a flow battery, such that the positive electrode electrolyte in an oxidized state can penetrate through the filter membrane to be in full contact and react with LiFePO4. The electrolyte of the positive electrode oxidizes LiFePO4 into Li+ and FePO4 by means of an oxidation reaction, and the generated Li+ enters the electrolyte and penetrates through the membrane to reach one side of the negative electrode in the form of a supporting electrolyte; in addition, the membrane material has strong selectivity for Li+, ensuring that the other ions cannot penetrate through the membrane. The electrode surface of the negative electrode of the flow battery is coated with a hydrogen evolution catalyst to perform a hydrogen evolution reaction and recover hydrogen, thereby achieving the dual purpose of recovering Li+ and producing hydrogen by means of electrolysis. A new LiFePO4 electrode material is re-obtained by means of calcination, etc., from the FePO4 produced at the positive electrode and the Li+ product obtained at the negative electrode, and is used in a lithium-ion battery.
Absstract of: WO2026123932A1
The present invention provides a device for the preparation of p-benzoquinone by means of electrocatalytic oxidation of hydroquinone coupled with cathode hydrogen production by means of water electrolysis, and the use thereof. The hybrid water electrolysis system comprises an electrolyte, a separator, a membrane electrode, and an electrode plate having flow channels. In the present invention, an anodic oxygen evolution reaction (OER) in water electrolysis is replaced by the oxidation of hydroquinone, which can significantly reduce the voltage of the system. The electrocatalytic oxidation of hydroquinone to produce p-benzoquinone may be carried out under the condition of 0.7 V (vs. RHE), and compared with 1.8 V for OER, the electrical energy consumption of the system is reduced by nearly two-thirds. In the present invention, by means of selecting or synthesizing a catalyst, selecting a suitable ion exchange membrane, controlling the system voltage, etc., the system voltage for the electrocatalytic oxidation of hydroquinone coupled with hydrogen production by means of water electrolysis is successfully reduced, and the obtained product is single p-benzoquinone with a higher economic value and can be separated and obtained simply by means of filtration.
Absstract of: WO2026123413A1
The present invention relates to the technical field of water electrolysis. Disclosed are a catalyst for seawater electrolysis, and a preparation method therefor and a use thereof. A MOFs-based electrocatalyst having excellent chloride ion corrosion resistance, stability and high controllability is synthesized by means of sulfuration treatment, and is used for an OER reaction of seawater electrolysis. The catalyst has excellent structural stability, chlorine corrosion resistance, more surface active sites, and high catalytic activity. Upon an electrochemical test of the catalyst, only Ni3S4 is restructured to form S-O anions, while NiFe-MOF does not undergo significant oxidation and structural changes, indicating that the NiFe-MOF has good structural stability. In addition, the S-O anions are preferentially adsorbed onto Fe3+ at a heterogeneous interface, thereby modulating the electronic structure of nearby Ni2+, and thus optimizing the adsorption and desorption ability of Ni2+ toward OER reaction intermediates.
Absstract of: WO2026128841A2
A method and system of generating electrical power or hydrogen from thermal energy is disclosed. The method includes adding heat to (or removing heat from) a salinity gradient generator configured to generate a more concentrated and a less concentrated saline solution. The method further includes drawing the more concentrated saline solution and the less concentrated saline solution from the salinity gradient generator and feeding the more concentrated saline solution and the less concentrated saline solution into a power generator. Feeding the saline solutions into the power generator causes the power generator to receive the saline solutions and generate power by performing a controlled mixing of the more concentrated saline solution and the less concentrated saline solution. The method further includes drawing, from the power generator, a combined saline solution comprising the mixed saline solutions and feeding the combined saline solution to the salinity gradient generator.
Absstract of: US20260166526A1
One embodiment of the present invention provides a metal composite catalyst for ammonia decomposition and hydrogen production, comprising: a composite metal oxide support; and metal nanoparticles dispersed on a surface or inside pores of the composite metal oxide; wherein the composite metal oxide support is derived from a layered double hydroxide comprising nickel and at least two types of metals different from nickel, the metal nanoparticles are reduced from the composite metal oxide support, and a weight content of nickel metal, measured by ICP analysis, is 45 wt % or more.
Absstract of: WO2026123439A1
A kilowatt-scale reaction device for water-electrolysis-based hydrogen production coupled with oxidation, comprising a power supply system, a reactor system, a raw material supply system, a cooling system, and a gas detection system. The reactor system comprises integrated condensation reactors (2) connected to each other and a static mixer (3). The raw material supply system comprises raw material tanks (4). The raw material tanks (4) are communicated with the static mixer (3). The cooling system comprises a mixer cold trap (8) and a reactor cold trap (9). The mixer cold trap (8) is communicated with the static mixer (3). The reactor cold trap (9) is communicated with the integrated condensation reactors (2). A reaction system operates safely and stably, enabling co-production of high-purity hydrogen at a cathode while achieving electrocatalytic oxidation of various biomass molecules, thereby expanding the reaction scale.
Nº publicación: US20260171475A1 18/06/2026
Applicant:
DE NORA PERMELEC LTD [JP]
NATIONAL UNIV CORPORATION YOKOHAMA NATIONAL UNIV [JP]
DE NORA PERMELEC LTD
NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY
Absstract of: US20260171475A1
An anode for electrolysis in which electrolysis performance is less likely to deteriorate even when electric power having a large output fluctuation, such as renewable energy, is used as a power source and in which excellent catalytic activity is stably maintained for a long period of time is provided. The anode for electrolysis 10 includes a conductive substrate 2 in which at least a surface of the conductive substrate 2 is formed of nickel or a nickel-based alloy; and a first layer 4 formed on the surface of the conductive substrate 2, the first layer 4 being capable of functioning as a catalyst layer containing a lithium-containing nickel cobalt oxide represented by a composition formula LixNiyCozO4 (0.05≤x≤1.0, 1.0≤y≤2.0, 1.0≤z≤2.0, and x+y+z=2 to 3).