Absstract of: US20260265934A1
A water electrolyzer includes an anode formed by a sulfur-doped (Ni,Fe)OOH (S—(Ni,Fe)OOH) electrode. The water electrolyzer also includes a cathode formed by NiMoN nanowire arrays supported on Ni foam.
Absstract of: US20260264061A1
The present invention relates to a process for converting a gas comprising NH3 in the presence of a cold plasma, preferably a plasma generated by dielectric barrier discharge (DBD), and of a catalyst comprising a support comprising alumina, nickel, and at least one promoter comprising iron. The invention also relates to such a catalyst, and to the use thereof for producing high value-added molecules like hydrogen (H2).
Absstract of: WO2026185409A1
The invention relates to a method for standby of an electrolysis system (400, 600). The electrolysis system comprises an electrolysis unit (1) and an oxygen gas separator (2) for separating oxygen gas and electrolyte, and the electrolysis unit (1) is connected to a power connection point (4) for an energy supply (E) for electrolysis in the electrolysis unit (1). The method comprises: lowering the hydrogen content (g(H2)) in the oxygen gas separator (2) in response to a signal for interrupting the electrolysis if a first threshold value (c1(H2), cMi_1(H2)) of a hydrogen gas content in the oxygen gas separator is exceeded, if a first threshold value of an oxygen gas content (c1(O2), cMi_1(O2)) in the oxygen gas separator is not met, if a predetermined first time (t1) is reached, if a first threshold value (r1, rMi_1) for a ratio (c(H2)/c(O2)) of hydrogen gas content to oxygen gas content is exceeded, and/or if a first threshold value (1/r1, 1/rMi_1) for a ratio (c(O2)/c(H2)) of oxygen gas content to hydrogen gas content is not met; and subsequently interrupting the electrolysis of the electrolysis unit (1). The invention also relates to a control device and to an electrolysis system.
Absstract of: WO2026185334A1
In a process for the reduction of iron oxides comprising a DRI-process, wherein the DRI- process comprises processing iron, in particular iron ore, by H2 and CO in a process chamber in order to reduce the iron oxide to sponge iron, wherein the CO for use in the DRI-process is formed from CO2, at least a part of, in particular at least 90%, preferably 100% of the CO2 being obtained from a DAC process, whereby at least a part, in particular at least 90%, preferably 100% of carbon originating from the CO2 is stored permanently in the sponge iron.
Absstract of: US20260265926A1
A hydrogen-powered autonomous mobile vehicle includes a mixing valve, a hydrogen storage device, a fuel cell, and an electrolyzer. The mixing valve has a first gas intake port coupled to the hydrogen storage device, a second gas intake port, and an outlet port coupled to the fuel cell, and includes a gas intake pipe coupled to the electrolyzer. The fuel cell is configured to perform a first redox reaction based on hydrogen supplied by the hydrogen storage device to generate electric energy and water. The electrolyzer is configured to receive the water and perform a water electrolysis reaction to generate hydrogen. The mixing valve is configured such that the hydrogen supplied by the hydrogen storage device and the hydrogen generated by the water electrolysis reaction converge and are delivered to the fuel cell. The fuel cell is configured to perform a second redox reaction based on the converged hydrogen.
Absstract of: US20260265932A1
0000 An electrolysis apparatus is presented. Anode and cathode catalysts or carbon electrodes are submerged in saltwater in a basin with the goal of extracting hydrogen gas, which is a renewable source of energy. The basin is metallic and includes rubber on the outside of the basin to handle high temperatures. A battery connected to the basin serves as a power supply and provides direct electric current to cause the breakdown of the element via electricity to produce hydrogen gas and direct the hydrogen gas to other items as a source of electricity.
Absstract of: WO2026184800A1
The present invention first relates to a method for coating a polymer electrolyte membrane (01), in particular for a water electrolysis cell, with a recombination catalyst layer (02). The recombination catalyst layer (02) is used to catalyze a recombination reaction of oxygen and hydrogen and is intended to prevent the formation of an explosive mixture, in particular in the water electrolysis cell. In one step of the method, the polymer electrolyte membrane (01) is provided. In addition, an aqueous solution of a platinum salt is provided. The aqueous solution of the platinum salt is mixed into a dispersion of a perfluorosulfonic acid, as a result of which platinum cations (04) of the platinum salt are bound to anions (05) of the perfluorosulfonic acid and platinum-containing particles form in the dispersion. The dispersion containing the platinum-containing particles is applied to the membrane (01) and heated, as a result of which water is evaporated and a laminate-type coating is produced on the membrane (01), said coating providing the recombination catalyst layer (02). The invention further relates to a polymer electrolyte membrane (01) coated according to said method, in particular for a water electrolysis cell.
Absstract of: WO2026186535A1
The present invention pertains to an anion conductive film-catalyst layer assembly comprising a porous substrate, an anion conductive film that is disposed at least in pores of the porous substrate and that contains a water-insoluble polymer having an unsubstituted polyethylene-oxy structure, and a catalyst layer that is disposed in contact with at least one surface of the anion conductive film and that contains an oxygen generation catalyst or a hydrogen generation catalyst for use in water electrolysis. The average value (Tave), the maximum value (Tmax), and the minimum value (Tmin) of the thickness of the catalyst layer satisfy formula 1: 1/2Tmax < Tave and formula 2: 2Tmin > Tave. The present invention also pertains to: a method for producing the anion conductive film-catalyst layer assembly; and a water electrolysis cell.
Absstract of: US20260269283A1
Gas pressure equalisation systems, and method of operation, for an electro-synthetic or electro-energy liquid-gas cell or cell stack. The gas pressure equalisation systems includes a first pressure equalisation tank for partially containing a first liquid and a first gas. The first gas is positioned above a liquid first level. A first gas conduit is provided for the transfer of the first gas between the cell or cell stack and the first pressure equalisation tank. In another aspect, a second pressure equalisation tank may be additionally provided for partially containing a second liquid and a second gas positioned above a liquid second level. A second gas conduit is then provided for the transfer of the second gas between the cell or cell stack and the second pressure equalisation tank.
Absstract of: US20260265924A1
An electrolysis system contains: at least one electrolysis cell; a cathode-side water circuit having a hydrogen separator; an anode-side water circuit having an oxygen separator; an equalization connection which leads, coming from a cathode-side water connection, to the anode-side water circuit via a pump and an ion exchanger via a node point and an operating line; and an idle line which branches off upstream of the control line and leads to the cathode-side gas connection.
Absstract of: US20260265612A1
The present invention relates to a process for converting a feedstock comprising at least one biomass fraction into hydrocarbons, said process comprising a step a) of pretreating the feedstock, a step b) of electrolysis of water into oxygen and hydrogen allowing the production of a stream of hydrogen and of a stream of oxygen, in which the water is at least partly obtained from a Fischer-Tropsch synthesis step e), a step c) of gasification of the feedstock pretreated in step a), in the presence of all or part of the oxygen stream obtained from the water electrolysis step b) so as to obtain a gaseous effluent comprising a synthesis gas, an optional step d) of conditioning the gaseous effluent comprising a synthesis gas obtained from step c) and a step e) of Fischer-Tropsch synthesis of the gaseous effluent obtained from step c) or optionally from step d) in the presence of all or part of the hydrogen obtained from the water electrolysis step b) so as to produce a stream comprising synthetic liquid hydrocarbons and at least one gaseous effluent.
Absstract of: US20260265923A1
A process for producing hydrogen includes a) providing a starting mixture containing bromine, water and a sulfur containing compound, b) reacting the starting mixture provided in a) so as to produce a reaction mixture effluent comprising sulfuric acid and hydrogen bromide, c) separating the reaction mixture effluent obtained in b) into hydrogen bromide enriched compositions and into sulfuric acid enriched compositions the hydrogen bromide enriched composition contains at most 1,000 ppm of sulfuric acid, c) comprises at least two distillation steps, d) subjecting a portion of the hydrogen bromide enriched composition to an electrolysis so as to obtain hydrogen and a bromine containing composition, the electrolysis cell is operated at an operational temperature of at least 70° C., and e) recycling a portion of the bromine containing composition obtained in d) back to a).
Absstract of: US20260265080A1
A low Pt-loaded MXene-carbon nanotube aerogel film and its preparation method are provided. The method includes adding an H2PtCl6 solution to a MXene nanosheet colloidal suspension to obtain a Pt@MXene nanosheet suspension, mixing the Pt@MXene nanosheet suspension with a carbon nanotube suspension to obtain a mixed suspension under ultrasonic treatment, and cooling a metal plate in liquid nitrogen in advance, placing the mixed suspension on a surface of the metal plate for rapid freezing, and freeze-drying to obtain a low Pt-loaded MXene-carbon nanotube aerogel film material with a vertical porous structure.
Absstract of: US20260265051A1
In a method for producing low-carbon hydrogen from ammonia and a plant implementing the method, liquid ammonia feedstock is heated and superheated in a heat-reclaiming module coil and supplied into an ammonia cracking reactor, the resulting nitrogen-hydrogen mixture is cooled in an air cooler, and hydrogen is recovered. The liquid ammonia fuel is heated and evaporated, the gaseous ammonia fuel is superheated and mixed with tail gases resulting from the hydrogen recovery, and the resulting fuel gas, together with hot air, is supplied to the ammonia cracking reactor. The ammonia feedstock and the ammonia fuel are evaporated and superheated in respective recuperative heat exchangers. An outlet for the flue gases of the ammonia cracking reactor is connected to the heat-reclaiming module. Extraction of distilled water from the flue gases as a by-product becomes possible by cooling the exiting flue gases to approx. +60° C. in the heat-reclaiming module.
Absstract of: US20260265940A1
A feedwater preparation system in a water electrolyser is adapted to produce hydrogen and oxygen in one or more pressurised electrolyser stacks using alkaline water and comprises a product gas conditioning system that has a safety valve out-blow material stream pipe which is connected to a feedwater vessel, and/or has a depressurisation stream pipe from a gas cleaning vessel which is connected to the feedwater vessel.
Absstract of: AU2025224758A1
A system for producing energy and methane includes a waste-to-energy unit configured to produce energy and a flue gas by combusting waste and an oxidizing agent having oxygen and a carbon dioxide (CO2) separation unit configured to separate CO2 from the flue gas to provide separated CO2. The system also includes a bio-methanation unit configured to generate methane (CH4), heat, and water using the separated CO2 received from the CO2 separation unit and received hydrogen (H2) gas. The system further includes an electrolyzer coupled to a source of water (H2O) and an electric power source supplying electricity and configured to split the H2O to generate the oxygen used in the oxidizing agent and the H2 gas used in the bio-methanation unit.
Absstract of: AU2025230555A1
The present invention relates to boiling water reactors arranged to receive a synthesis gas for producing raw gas products, such as a raw methanol product, particularly for transient operation, such as where the synthesis gas is at least partly provided by producing hydrogen by electrolysis of water or steam. Embodiments of the invention include a boiling water reactor, a method of revamping an existing boiling water reactor, and a process for producing raw gas product, such as raw methanol product, utilizing the boiling water reactor.
Absstract of: US20260265925A1
A system and method of making hydrogen from water. A reaction vessel is provided with an outer shell, a central shaft, and concentric inner tubes separated by annular spaces. Water is delivered to the annular spaces by a water pump through an inlet defined in the reaction vessel. The water courses along a tortuous flow path. That path begins at an inner annular space around a central shaft. It ends at an outer annular space. The water emerges from the reaction vessel through an outlet associated with a manifold. A vibratory stimulus is applied to the reaction vessel and water. Water molecules are dissociated into hydrogen molecules and oxygen atoms. These reaction products are delivered through the manifold along an effluent flow path to a receiving pressure vessel before deployment to a sub-assembly for harnessing clean energy.
Absstract of: AU2025262338A1
Methods and systems for synthesis using an underwater electric arc. Such methods and systems form an electrical arc between an anode and a cathode positioned under water or within an aqueous mist and introduce an added material into the vicinity of the electrical arc. The formation of the electrical arc in the vicinity of the added material facilitates synthesis of chemical products from the added material. Such synthesized chemical products include ammonia, hydrogen, cyanide, and hydrogen cyanide.
Absstract of: WO2026185353A1
The present invention discloses an electrolysis device. The electrolysis device according to the present invention incorporates a reactor, a hydrogen gas-liquid separator, an oxygen gas-liquid separator and a cleaning component, the cleaning component is connected to the reactor, the hydrogen gas-liquid separator and/or the oxygen gas-liquid separator, and is configured to store a cleaning agent for pickling, and is configured to provide the cleaning agent to the electrolysis device during pickling, such that a pickling operation may be performed efficiently, to improve production efficiency.
Absstract of: WO2026185352A2
The invention discloses a cleaning agent for pickling, an electrolysis device and a method for pickling. The cleaning agent contains a chelating agent, which may effectively remove metal deposits produced by corrosion on surfaces of components of the electrolysis device, improve pickling efficiency and quality, and thus improve an overall production performance of hydrogen. The electrolysis device according to the invention incorporates a reactor, a hydrogen gas-liquid separator, an oxygen gas-liquid separator and a cleaning component, the cleaning component is connected to the reactor, the hydrogen gas-liquid separator and/or the oxygen gas-liquid separator, and is configured to store the cleaning agent for pickling, and is configured to provide the cleaning agent to the electrolysis device during pickling, such that a pickling operation may be performed efficiently, to improve production efficiency. In the method for pickling according to the invention, a concentration of metal ions in the cleaning agent is monitored, which not only may ensure that the cleaning agent is used in an effective range, but also may end a pickling process in time, thereby avoiding excessive consumption of the cleaning agent, saving a pickling time, while ensuring a pickling effect.
Absstract of: US20260265939A1
The present invention relates to an electrolyser system (10) comprising at least one electrolyser (20), the electrolyser (20) comprising at least one steam inlet (41) and at least one off-gas outlet (38; 39), and a turbocharger (62) for compressing off-gas from the electrolyser (20). The turbocharger (62) comprises a drive fluid inlet, a drive fluid outlet, a compression fluid inlet, a compressed fluid outlet, a compressor (13) and a turbine (12). The turbine (12) is configured to drive the compressor (13). The drive fluid outlet of the turbocharger (62) is fluidically connected to the at least one steam inlet (41) of the electrolyser (20). The at least one off-gas outlet (38; 39) of the electrolyser (20) is fluidically connected to the compression fluid inlet of the turbocharger (62). The system (10) can further can comprise a steam source fluidically connected to the drive fluid inlet of the turbocharger (62) for powering the turbine (12) using pressurised steam.
Absstract of: US20260265938A1
To provide a fluorinated polymer, from which such a polymer membrane can be produced that when a laminate having a polymer membrane that contains a fluorinated polymer having groups convertible to ion exchange groups sandwiched between transfer base materials is subjected to hot pressing and then the transfer base materials are peeled from the laminate, few pinholes are formed in the polymer membrane. To provide an electrolyte membrane using the fluorinated polymer, a membrane electrode assembly and a water electrolyzer. The fluorinated polymer of the present disclosure is a fluorinated polymer having units based on tetrafluoroethylene and having groups convertible to ion exchange groups, wherein no endothermic peak is observed within a range of 300 to 350° C. measured by differential scanning calorimetry.
Absstract of: US20260264059A1
An ammonia decomposition catalyst including a composite oxide forming a perovskite structure with at least barium, zirconium, and ruthenium. Also included is a honeycomb structure including the ammonia decomposition catalyst and an internal combustion engine including the ammonia decomposition catalyst. The ammonia decomposition catalyst exhibits excellent initial activity even at low temperatures and excellent heat resistance in terms of ammonia decomposition activity.
Absstract of: WO2026184298A1
A device and method for hydrogen production via microwave resonant plasma torch-assisted ammonia cracking. The device comprises: a microwave unit (1), configured to generate microwaves; and a reaction unit (2), connected to the microwave unit (1). The reaction unit (2) comprises a resonant torch (21). The resonant torch (21) comprises a housing (211), wherein the housing (211) has a closed end and an open end, a resonant cavity (212) is formed between the closed end and the open end, the outer wall of the housing (211) is provided with a gas inlet communicated with the resonant cavity (212), and the gas inlet is configured to be communicated with an external ammonia gas source. A central electrode (213) passes through the resonant cavity (212). Microwaves are fed from the closed end into the resonant cavity (212) to establish microwave resonance therein, and a plasma region is formed around the tip of the central electrode (213) close to the open end, so that ammonia gas flowing in from the gas inlet undergoes a cracking reaction when passing through the plasma region, so as to generate cracked gas containing hydrogen gas.
Absstract of: US20260269280A1
A part includes comprising a metal substrate and a layer of amorphous carbon-based material having sp2 hybridised bonds and sp3 hybridised bonds. The layer has a first content of sp3 hybridised bonds on the substrate side, anda second content of sp3 hybridised bonds on the side of an external surface of the layer,the first content being greater than the second content.An average content within the layer of sp3 hybridised bonds is between 5% and 65%and in that the content of sp3 hybridised bonds evolves continuously within the layer.
Absstract of: WO2026185069A1
The invention relates to a hydrogen-production plant (10), comprising: a plurality of electrolysis devices (11) which are designed to generate hydrogen from water with the aid of electrical current, wherein oxygen is produced during the generation of the hydrogen; a water circuit (13) which is designed to supply water to the electrolysis devices and to remove water and oxygen from the same, wherein the water circuit (13) has a water storage container (17) from which water can be supplied to the electrolysis devices, wherein the water circuit (13) has a pump (16) which is designed to convey the water from the water storage container (17) towards the electrolysis devices, wherein the water circuit (13) has an oxygen separator (18) which is designed to separate oxygen from the water discharged by the electrolysis devices upstream of the water storage container (17). The oxygen separator (18) has at least one first, horizontally extending separation tube (19) to which water and oxygen can be supplied from the electrolysis devices, wherein from a first end (19a) of the respective first, horizontally extending separation tube (19), water can be conducted towards the water storage container (17), and wherein, from a second end (19b) of the respective first, horizontally extending separating tube (19), oxygen can be conducted towards an oxygen outlet (20).
Absstract of: WO2025093133A1
The invention relates to an electrochemical cell assembly, comprising a stack of cell units, wherein each cell unit has a periphery and a central portion surrounded by the periphery, the periphery has a first flange portion (90-1) and an opposite second flange portion (90-2), the flange portions of adjacent cell units overlie one another and are separated by a gap (88-1, 88-2), wherein between two adjacent cell units, there is provided a fluid flow path comprising an inner flow path between the central portions of adjacent cell units and an outer flow through said gaps, and a flow restriction device (112) comprising at least one flow restriction member (114-1, 114-2), said flow restriction device being configured to reduce or prevent fluid flow along the outer flow path.
Absstract of: WO2025056228A1
The present invention relates to a process for producing hydrogen from an ammonia-containing gas with a supported catalyst in the form of a ruthenium-endowed support body, and to the use of such a ruthenium-containing supported catalyst in a process for producing hydrogen. The process comprises the providing of a supported catalyst in the form of a ruthenium-endowed support body, wherein the support body comprises a refractory oxide as support material, is cylindrical and has at least three mutually spaced-apart channels that extend fully through the support body, where one of the channels extends along a central longitudinal axis.
Absstract of: WO2025040149A1
Disclosed in the present invention is a composite membrane for a water electrolysis cell. The composite membrane contains non-woven fabric and polymer resin, the polymer resin being present in one or two sides of the non-woven fabric and partially or completely permeating into the non-woven fabric structure, the non-woven fabric accounting for 20-95% of the weight of the composite membrane, the thickness of the non-woven fabric being 0.20-2.00 mm, the gram weight thereof being 100-400 g/m2, and the density thereof being 0.20-0.50 g/cm3. The composite membrane for a water electrolysis cell of the present invention has the characteristics of high air impermeability, low resistance and high service durability in alkali liquor environments.
Absstract of: WO2025093091A1
An alkaline electrolyzer comprising a stack (17) of electrolytic cells (1) for producing hydrogen gas (8). Each of the cathode compartments (5) comprises a cathode gas outlet (23A) into a cathode electrolyte return conduit (28), the downstream end (41) of which is connected to a hydrogen purifier (33) configured for providing purified hydrogen gas by removing oxygen from the gas received from the cathode electrolyte return conduit (28). A cathode gas recirculation system (38) connects a downstream end of the hydrogen purifier (32, 33) to an upstream end (40) of the cathode electrolyte return conduit (28) for supplying purified hydrogen gas to the cathode electrolyte return conduit (28). Each of the anode compartments (6) comprises an anode gas outlet (23B) into an anode electrolyte return conduit (28), the downstream end (41) of which is connected to an oxygen purifier (33) which removes hydrogen from the gas coming from the anode electrolyte return conduit (28). An anode gas recirculation system (38) connects a downstream end (41) of the oxygen purifier (33) to an upstream end (40) of the anode electrolyte return conduit (28) for supplying purified oxygen gas to the anode electrolyte return conduit (28). Hereby the electrolyzer can be operated at part load, for example below 10% of the nominal load.
Absstract of: WO2025093132A1
The invention relates to an electrochemical cell assembly (10), comprising a base plate, an end plate (26), a stack (12) comprising a plurality of cell units (14) stacked upon one another, said stack (12) being arranged between said base plate and said end plate, and an electrically conductive power transmission device (38) comprising a connector (40) that is located on a side of the end plate that is facing away from the stack, the power transmission device spanning the end plate and being electrically connected to the stack, wherein the power transmission device is attached to the end plate by a fastening device (42) at a portion of the power transmission device that is located between an electrical connection to the stack and the connector.
Absstract of: EP4803666A1
The present invention relates to a hydrogen production system (1). The system (1) comprises an electrolyser (10), equipped with an internal tank (101), adapted to produce hydrogen from the electrolysis of water, and a water distribution pipe (62) adapted to connect the internal tank (101) of the electrolyser (10) to a water source (50).Advantageously, the system also comprises an electrolyte tank (20) adapted to contain a quantity of electrolyte equal to or greater than the quantity of electrolyte contained by the internal tank (101) of the electrolyser (10), and a waste tank (30) adapted to contain a quantity of fluid greater than the quantity of electrolyte contained by the internal tank (101) of the electrolyser (10). Furthermore, the system comprises an electrolyte distribution pipe (63) adapted to connect the internal tank (101) of the electrolyser (10) to the electrolyte tank (20), a drain pipe (64) adapted to connect the internal tank (101) of the electrolyser (10) to the waste tank (30), and a water control valve (71) adapted to regulate the flow of fluid in the water distribution pipe (62), an electrolyte control valve (72) adapted to regulate the flow of fluid in the electrolyte distribution pipe (63), and a control valve (73) adapted to regulate the flow of fluid in the drain pipe (64). Finally, the system comprises a control unit (40) connected to the electrolyser (10) and the valves (71-73) to control its operation. In particular, the electrolyser (10) measures a
Absstract of: TW202503118A
The present invention refers to an electrolyzer (1) for the production of hydrogen from an alkaline electrolyte. The electrolyzer (1) comprises a first header (11) and a second header (12) between which a plurality of elementary cells (20) and a plurality of bipolar plates (5, 5', 5") are stacked. Each bipolar plate (5) separates two adjacent elementary cells. According to the invention, each of said bipolar plates (5, 5',5") comprises two plate-form components (5A, 5B) coupled together and configured so as to define one or more inner cavities (66) for the circulation of a cooling fluid. Furthermore, each bipolar plate (5, 5', 5") comprises an inlet section (SI) and an outlet section (SV) respectively for the inlet and outlet of said cooling fluid in said one or more inner cavities (66).
Absstract of: EP4803659A1
0001 A gas conduit (58) is constructed and arranged to feed a gas (42) into an active area (50) of an electrolysis cell (12) within a stack (14) in sufficient quantity to function as an electrical insulator and reduce an electric current at an entry (52) of the active area (50) and thereby more closely balance the current at the entry (52) of the active area (50) with the current at an exit (54) of the active area (50). Also, an electrolysis-mixed stack configuration (10) is provided having a plurality of electrolytic cells (12) forming an electrolysis stack (14), a pump (20) in fluid communication with a hydrogen-side phase separator (22) in fluid communication with a heat exchanger (24) in fluid communication with a hydrogen-side recycle blower (26); where the electrolysis stack (14) is shared with an oxygen-side (16) having a pump (20) in fluid communication with an oxygen-side phase separator (32) in fluid communication with the heat exchanger (24) in fluid communication with the oxygen-side recycle blower (36); wherein hydrogen (42) is generated.
Absstract of: EP4804378A1
0001 The invention is about a method for controlling an electrolysis system (1) comprising a transformer unit (2), rectifier units (3) operating in parallel, and electrolysis module rows (4) with hydrogen and oxygen sides (5, 6) connected at DC sides (7) of the rectifier units (3), the method comprising: - detecting a Fault Ride Through event; and - adjusting the ramp-up rate of a DC current considering a current position of control valves (8) on the hydrogen and oxygen sides (5, 6).
Absstract of: EP4803660A1
A gas inlet conduit (58) is constructed and arranged to feed a gas (42) into an active area (50) of an electrolysis cell (12) within a stack (14) in sufficient quantity to function as an electrical insulator and reduce an electric current at an entry (52) of the active area (50) and thereby more closely balance the current at the entry (52) of the active area (50) with the current at an exit (54) of the active area (50). Also, an electrolysis-separated stack configuration (10) is provided having a plurality of electrolytic cells (12) forming an electrolysis stack (14), a hydrogen-side pump (20) in fluid communication with a hydrogen-side phase separator (22) in fluid communication with a hydrogen-side heat exchanger (24) in fluid communication with a hydrogen-side recycle blower (26); where the electrolysis stack (14) is shared with an oxygen-side pump (30) in fluid communication with an oxygen-side phase separator (32) in fluid communication with an oxygen-side heat exchanger (34) in fluid communication with the oxygen-side recycle blower (36); wherein hydrogen (42) is generated.
Absstract of: EP4803822A1
0001 Die vorliegende Erfindung betrifft eine Vorrichtung zur Wärmeerzeugung sowie ein dazugehöriges Verfahren und ein Computerprogramm, wobei durch eine Einlassöffnung ein Wasserstoff (H<2>)-Gasgemisch in mindestens einen Reaktionsraum geleitet wird, wobei der Reaktionsraum in Verbindung mit einem Impulszünder steht, welcher eine Initialzündung des Gasgemisches im Reaktionsraumes erzeugt, der dabei entstehende Wasserdampf wird über mindestens eine Auslassöffnung aus dem Reaktionsraum in ein Dampfrohr geführt, in dem der Wasserdampf kondensiert, wobei das Dampfrohr derart ausgebildet ist, dass es eine Kurve bildet und parallel zum Reaktionsraum zurückgeführt wird, wodurch das darin gebildete Wasser zur Aufrechterhaltung der Reaktion im Reaktionsraum und/oder zur Wiederverwendung in einem Elektrolyseprozess verwendet werden kann.
Absstract of: EP4803667A1
An electrolyzer, a method for manufacturing the electrolyzer, and an electrolyzer module are provided, relating to the field of electrolyzers. The electrolyzer includes: a frame defining an inner cavity and including a top frame, a bottom frame, a first frame, and a second frame; a bipolar plate connected to the frame and dividing the inner cavity into an anode chamber and a cathode chamber; a first collection frame, located within the anode chamber and fixed to an end of the bipolar plate near the top frame, and defining a first cavity together with the bipolar plate; an anode mesh, located on a side of the first collection frame away from the bipolar plate; a second collection frame, located within the cathode chamber and fixed to an end of the bipolar plate near the top frame, and defining a second cavity together with the bipolar plate; a cathode mesh, located on a side of the second collection frame away from the bipolar plate. The first frame and the second frame each have a hollow chamber. One of the first frame and the second frame has a first discharge port formed on an inner wall facing the anode chamber, and the other of the first frame and the second frame has a second discharge port formed on an inner wall facing the cathode chamber, the first discharge port being in communication with the first cavity, and the second discharge port being in communication with the second cavity. This is at least advantageous in improving electrolysis efficiency of the electrolyze
Absstract of: CA3201278A1
The present invention regards a method for converting carbon dioxide into carbon monoxide in high-temperature, dry, solid oxide electrolysis providing increased lifetime of SOECs and SOEC stacks by addressing the problem of coking, while simultaneously ensuring highest possible CO production from each cell or stack.
Absstract of: US20250059653A1
0000 Microorganisms and bioprocesses are provided that convert gaseous C1 containing substrates, such as syngas, producer gas, and renewable H<2 >combined with CO<2>, into nutritional and other useful bioproducts.
Absstract of: WO2025045641A1
The present invention refers to an electrolyser (1) for the production of hydrogen from an alkaline electrolyte. The electrolyser (1) comprises a first header (2) and a second header (3) between which a plurality of elementary cells (4) and a plurality of bipolar plates (5) are stacked. Each bipolar plate (5) separates two adjacent elementary cells. The electrolyser (1) further comprises a plurality of clamping elements (20) that mechanically connect said headers (2, 3). Each of the elementary cells (4) comprises a frame (6) defining a chamber (6A), having an anodic section and a cathodic section, in which an anodic electrode (7) and a cathodic electrode (8) are at least in part housed. Each of the elementary cells (4) further comprise a separator element (10) that separates the anodic section from the cathodic section. According to the invention, each of the frames (6) comprises first through holes (61) and each of the bipolar plates (5) comprises second through holes (51), wherein each of said first through holes (61) of one frame (6) is mutually aligned with a corresponding first through holes (61) of each of the another frames (6) and with one of said second through holes (51) of each bipolar plate (5), wherein each one of said clamping means (20) extends through said through holes (51, 61) mutually aligned.
Absstract of: WO2026180519A1
Process and plant for the production of a product gas containing nitrogen and hydrogen from ammonia, the process comprising the steps of: i) pre-cracking an ammonia feed stream to a pre-cracked process gas containing hydrogen, nitrogen, ammonia by contact with a first ammonia cracking catalyst; ii-1) non-catalytic partial oxidation of the pre-cracked process gas with an oxygen containing gas to a process gas containing nitrogen, water, nitrogen oxides and residual amounts of ammonia; ii-2) cracking of at least a part of the residual amounts of ammonia to hydrogen and nitrogen in the process gas by contact with a second ammonia cracking catalyst and simultaneously reducing the amounts of nitrogen oxides to nitrogen and water by reaction with at least a portion of the hydrogen formed during at least the pre-cracking of the ammonia feed stream, thereby producing said product gas containing nitrogen and hydrogen; iii) withdrawing the product gas. The product gas is purified downstream to a hydrogen product.
Absstract of: WO2026182019A1
The present invention provides an electrolytic hydrogen supply device to be attached to at least one side of goggles. A hydrogen supply device according to the present invention comprises: an electrolytic cell in which a pair of positive and negative electrodes are disposed in the vertical direction and which is capable of storing electrolytic water; and an electrolytic cell receiving section which has a recess that opens from the bottom toward the outside of the side of the goggles, and which is configured to insert and fix the electrolytic cell in the recess from the outside toward the inside to the bottom. The electrolytic cell has a pair of front and rear sealing members in the inward and outward directions for sealing the inner wall of the electrolytic cell receiving section and the outer wall of the electrolytic cell, and has, above the electrolytic cell, a reserve tank space formed in a gap between the outer wall of the electrolytic cell and the inner wall of the electrolytic cell receiving section between the front and rear sealing members, and a first gas film that allows a gas containing hydrogen and water vapor in the electrolytic cell to pass through and be released into the reserve tank space.
Absstract of: US20260258558A1
0000 A method to generate hydrogen gas comprises circulating an electrolyte through an electrolyte circuit including an electrochemical cell comprising an anode and a cathode, wherein hydroxide ions in the electrolyte are oxidized at the anode to produce oxygen gas and water in the electrolyte is reduced at the cathode to produce hydrogen gas. The method further includes introducing an inert gas into the electrolyte circuit to dilute a gas phase of the electrolyte circuit.
Absstract of: WO2026181397A1
A water electrolysis apparatus (100) comprises: a catalyst (52) that is disposed outside an oxygen gas-liquid separator (4) and reduces hydrogen mixed into oxygen; and an oxygen circulation line (6) in which a blower (61) is disposed and which returns oxygen that has passed through the catalyst (52) to the oxygen gas-liquid separator (4).
Absstract of: WO2026182942A1
A solar-driven opto-electrolysis hydrogen production system configured to convert light and water into hydrogen is disclosed. The system includes a solar radiation collection assembly, an optical transmission network, and one or more opto-electrolysis light rods positioned within a reactor containing water. Each light rod includes an inner optical core, a cladding, and a porous layer comprising photocatalytic centers configured to generate hydrogen upon illumination. The inner optical core contains spectral conversion additives that modify incident solar radiation such that emitted wavelengths overlap an absorption band of the photocatalytic centers. In certain embodiments, the porous layer comprises a monolithic porous structure formed around the cladding with pore characteristics selected to permit diffusion of water and removal of evolved hydrogen. A plurality of light rods may be arranged in an array to enable scalable hydrogen production.
Absstract of: WO2026181447A1
A hydrogen generation apparatus (1a) comprising a plurality of cell stacks (10) that, through electrolysis of water, generate hydrogen and oxygen as a byproduct, and a control device that controls the cell stacks (10) and controls circulation of hydrogen, wherein: the plurality of cell stacks (10) are divided into at least one firstly-started cell stack (10a) that is started firstly among the plurality of cell stacks (10) and at least one subsequently-started cell stack (10b), (10c) that is started subsequently to the firstly-started cell stack (10a); and the control device (11) is configured to be able to supply, to the subsequently-started cell stack (10b), (10c), hydrogen generated by the firstly-started cell stack (10a) when starting the subsequently-started cell stack (10b), (10c) after the firstly-started cell stack (10a) is started.
Absstract of: US20260257925A1
The present invention relates to a method of physical and energetic utilization of silicon components that are obtained in electrical scrap recycling. In order to create a recycling method which is effective in terms of time, plant technology and energy, it is proposed that a silicon component be dissolved in an alkali under the process pressure (p) and a first suspension temperature in the range from 50° C. to equal to or greater than the boiling point of the alkali at the process pressure p. After the silicon has been dissolved, the resultant suspension is filtered for separation of meta-, di- and oligosilicate, and the second suspension temperature is maintained during the filtration within the temperature range specified from 50 to less than the boiling point of the alkali.
Absstract of: US20260258513A1
0000 The present invention discloses a systematic carbon emissions reduction method for whole process of steel production and casting, comprising the steps of: injecting hydrogen into a blast furnace, wherein the hydrogen is sourced from a nuclear-based hydrogen production system, a water electrolysis hydrogen production system, and a coke oven gas-steam reforming hydrogen production system; wherein electrical energy consumed by the water electrolysis hydrogen production system is sourced from gas-fired power generation, steam residual pressure power generation, solar power generation, wind power generation, and nuclear power generation; wherein combustible gases used for the gas-fired power generation are coke oven gas, blast furnace gas, and converter gas; wherein steam for the steam residual pressure power generation is sourced from a sintering waste heat boiler; wherein steam for the coke oven gas-steam reforming hydrogen production is low-pressure steam exhausted from the residual pressure power generation; producing end products comprising cast steel sections and casting materials including high-carbon ductile cast iron profiles with a carbon content of 2-4% and a silicon content of 2-4%, and high-carbon ductile cast steel profiles with a carbon content of 1-2% and a silicon content of 1-1.9%; and recycling scrap from the end products into a converter or an electric arc furnace for smelting.
Absstract of: US20260257913A1
Proposed is a system for generation of blue hydrogen through natural gas reforming, carbon dioxide capture, carbon resource utilization, and reaction product storage. The system includes a natural gas storage container for storing liquefied natural gas including shale gas, a hydrocarbon reformer in which a gas mixture containing hydrogen and carbon dioxide is produced, a hydrogen filling station in which hydrogen is received and stored, a reactor in which carbon dioxide produced is received and reacted with a basic alkali mixed solution to capture carbon dioxide and in which a reaction product is collected and a carbon dioxide reaction product and a waste solution are separated from the reaction product, a carbon resource storage container storing the carbon dioxide product, and a hydrogen generator in which the carbon dioxide reaction product is used to product hydrogen, and the produced hydrogen is delivered to the hydrogen filling station.
Absstract of: US20260261119A1
0000 An electrolysis system includes a renewable power generation plant, an electrolysis plant, a transformer station and an AC bus bar. The renewable power generation plant is connected to the public electricity grid at a point of connection via the AC bus bar and includes a power plant controller and a self-controlled converter that is connected to the AC bus bar. The electrolysis plant includes an electrolysis active power controller and a converter arrangement that is connected to the AC bus bar. The electrolysis active power controller is configured for controlling active power of the electrolysis plant at the AC bus bar and the power plant controller is configured for controlling reactive power at the point of connection. A method for operating an electrolysis system is also provided.
Absstract of: US20260257990A1
An amidinium-functionalized compound, characterized in that the compound has a structure according to General Formula I or General Formula II wherein ⋅R5 and R9 are any substituent different from hydrogen; ⋅R1 to R4 are independently selected from the group consisting of an alkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an alkaryl group, an aryl group and a heteroaryl group, or any of R1 and R3, R1 and R4, R1 and R2, R3 and R4, R2 and R3, or R2 and R4 represent the necessary atoms to form a five- to eight-membered non-aromatic ring; ⋅R6 to R8 are independently selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an alkaryl group, an aryl or heteroaryl group, a halogen group, an ether group, a nitro group, an amine group, or any of R5 and R6, R6 and R7, R7 and R8, or R8 and R9 represent the necessary atoms to form a five- to eight-membered ring; X— is an anion; and wherein ⋅at least one of R1 to R9 comprises a polymerizable group or comprises the necessary atoms to link the amidinium group to a polymer.
Absstract of: WO2026182306A1
The present invention provides a system for synthesizing ammonia using a chemical compressor having a hydrogen storage alloy embedded therein, and a method for synthesizing ammonia using the ammonia synthesis system. The system for synthesizing ammonia comprises: a water electrolysis stack that generates hydrogen; a chemical compressor that stores and discharges hydrogen supplied from the water electrolysis stack; and an ammonia synthesis unit that receives hydrogen from the chemical compressor and synthesizes ammonia, wherein the chemical compressor includes: a hydrogen storage unit having the hydrogen storage alloy embedded therein; a cooling unit that cools the hydrogen storage unit; a heating unit that heats the hydrogen storage unit; and a control unit that controls operations of the cooling unit and the heating unit, wherein the heating unit includes a plurality of different heating sources independently controllable from one another, and the control unit controls the cooling unit to cool the hydrogen storage alloy of the hydrogen storage unit when hydrogen is stored in the hydrogen storage unit, and controls at least one of the plurality of heating sources of the heating unit to heat the hydrogen storage alloy when hydrogen is discharged from the hydrogen storage unit.
Absstract of: EP4800057A1
0001 The present invention relates to a reinforced composite polymer electrolyte membrane having assured mechanical, structural, and thermal stability.
Absstract of: EP4800782A1
The present invention relates to a method for the preparation of a cathode for alkaline water electrolysis of water particularly useful in the reaction of hydrogen evolution comprising nickel, iron and/or cobalt oxide and a noble metal based on the self-combustion of a precursor mixture deposited or coated on the surface of an electrode carrier. The invention also relates to an electrode obtainable according to said method and to its use as cathode in water electrolysis, in particular in alkaline water electrolysis.
Absstract of: WO2025090834A1
Disclosed herein are systems and methods for tandem hydrogen (H2) production and carbon dioxide (CO2) capture. For example, described herein are methods comprising tandem H2 production and CO2 capture and conversion to a carbonate mineral. In some examples, the method is an electrochemical method. In some examples, the method comprises dissolving CO2 in water and applying an electrochemical potential sufficient to drive the H2 evolution reaction, thereby producing H2 and CO3 2-. In some examples, the methods further comprise contacting the CO3 2- with a cation to thereby form an insoluble carbonate compound.
Absstract of: WO2025087865A1
The present invention relates to a guard bed reactor for silicon removal, a solid oxide electrode system for producing hydrogen comprising a guard bed reactor for silicon removal, a method of operating the system to produce hydrogen and a use of the guard bed reactor for silicon removal for depleting a stream of steam from volatile silica species.
Absstract of: WO2025087866A1
The invention relates to a method of operating a solid oxide electrolysis cell (SOEC) stack for producing hydrogen, and a system for carrying out the method, said SOEC stack comprising at least one solid oxide electrolysis cell (SOEC), said at least one SOEC comprising an electrolyte layer interposed between a fuel-side and an oxy-side, the method comprising transient operation, in which the transient operation comprises: - operating the SOEC stack under open-circuit voltage (OCV); - providing a feed gas comprising ammonia; - supplying at least a portion of said feed gas comprising ammonia to a guard bed reactor, said guard bed reactor comprising a catalyst active in the cracking of ammonia to nitrogen and hydrogen; and withdrawing from said guard bed reactor a forming gas comprising nitrogen and hydrogen; - supplying at least a portion of the forming gas comprising nitrogen and hydrogen to the fuel-side of the at least one of the solid oxide electrolysis cells (SOECs) of the SOEC stack; and withdrawing from said at least one of the SOECs of the SOEC stack, a first fuel-side exit gas.
Absstract of: EP4800161A1
Provided is a technique for suppressing occurrence of cracking in a solid electrolyte layer. A solid oxide electrolysis cell includes an air electrode containing a complex oxide having a perovskite structure, a fuel electrode, and a solid electrolyte layer disposed between the air electrode and the fuel electrode. In an interface region of the fuel electrode, which region extends 5 µm from the interface between the fuel electrode and the solid electrolyte layer, the Al content is 1 ppm or greater and 100 ppm or less.
Absstract of: EP4545476A1
Process (2) for the production of an enhanced fuel gas (4) containing at least hydrogen gas from a fuel stream, in particular from an ammonia fuel stream (6). Said process comprises the following steps:- providing the fuel stream (6) (S100);- providing a condensable medium (8), preferably water steam (8), to a cracker unit (10);- at least one step of performing an endothermic cracking reaction of the fuel stream (6) in the cracker unit comprising at least one catalyst suitable for cracking said fuelstream (6), so as to produce an at least partially cracked fuel stream as said enhanced fuel gas (4) (S300); and- condensing at least partially said condensable medium (8) to provide said heat for the endothermic cracking reaction of the fuel stream (6).
Absstract of: WO2025088418A1
Electrochemical device (1), preferably of the electrolyser type for hydrogen production, characterised by comprising: - at least one support frame (2), with a substantially laminar development, which is provided with at least one seat (3) for an electrochemical module (10), said support frame (2) comprising a first face (12') and a second face (12") which are opposite to each other, at least one electrochemical module (10) which is mounted in said at least one seat (3) and which comprises a separation membrane interposed between two electrodes, respectively between an anode and a cathode, at least one bipolar plate (20) for applying/transferring electrical energy to the electrodes of said at least one electrochemical module (10), said bipolar plate (20) comprising a first surface (21') and a second surface (21") which are opposite to each other, said bipolar plate (20) being superimposed on said support frame (2) and being configured so that the first surface (21') of said bipolar plate (20) rests, at least in part, on a first face (12') of said support frame (2).
Absstract of: EP4800162A2
The hydrogen production system comprises a solid oxide electrolysis cell (SOEC) that electrolyzes steam, a steam discharge line through which the steam discharged from the hydrogen electrode of the SOEC passes, a main heat exchanger that generates the steam by heating supply water through heat exchange between the supply water and the steam passing through the steam discharge line, a combustor that combusts a part of hydrogen contained in steam discharged from a hydrogen electrode, a superheater that exchanges heat between the steam generated in the main heat exchanger and the combustion gas generated in the combustor, a gas discharge line through which an exhaust gas discharged from an oxygen electrode of the SOEC passes, a steam bleeding line that allows the steam discharge line and the combustor to communicate with each other, and an exhaust gas bleeding line that allows the gas discharge line and the combustor to communicate with each other.
Absstract of: EP4799916A2
The present invention relates to an apparatus and method for producing, storing, and transferring hydrogen. According to the present invention, in order to address the problems of conventional systems and methods for producing, storing, and transferring marine green hydrogen, which are configured with a fixed structure in a small-scale offshore wind power generator on a coast or in a shallow sea area with a shallow depth of water, and thus, have low efficiency due to the difficulty in mass production of hydrogen, and a large storage space is occupied when the produced hydrogen is converted into a compressed gas form, and when the produced hydrogen is converted into ammonia, additional energy is required to extract the hydrogen again and there is a risk of environmental pollution and casualty in the event of an outflow accident, provided is a marine platform for producing, storing, and transferring marine green hydrogen, which is configured such that marine green hydrogen is produced through a floating marine structure configured to produce marine green hydrogen using electricity produced using renewable energy from the ocean, and simultaneously, the produced marine green hydrogen is stored, transferred, and offloaded through a single offshore platform (FPSO), thereby being possible to easily construct a large-scale production facility capable of producing, storing, and transferring marine green hydrogen without greenhouse gas emission on the basis of eco-friendly energy.
Absstract of: EP4800156A1
Provided is a membrane-electrode assembly for a water electrolysis cell, including: a polymer electrolyte membrane having an active area and an inactive area surrounding the active area; a hydrogen generation electrode positioned on a first surface of the active area of the polymer electrolyte membrane; an oxygen generation electrode positioned on a second surface of the active area of the polymer electrolyte membrane; a first subgasket disposed on a first surface of the inactive area of the polymer electrolyte membrane and surrounding the hydrogen generation electrode; and a second subgasket disposed on a second surface of the inactive area of the polymer electrolyte membrane and surrounding the oxygen generation electrode, wherein the first subgasket has a first window accommodating the hydrogen generation electrode, and a first water supply path surrounding the first window and exposing the inactive area of the polymer electrolyte membrane.
Absstract of: EP4800158A1
The various embodiments of the present invention disclose a pressurized alkaline electrolyser stack, comprising: a stack core (100a) comprising a plurality of electrolysis cells (200), wherein each electrolysis cell (200) comprises an anode chamber comprising an anode, a cathode chamber comprising a cathode, a diaphragm (206) separating the anode chamber and the cathode chamber, at least one cell frame (201) and at least one gasket (202). The stack core (100a) is configured to have a first stack core length L1 and a first gasket stress σ1 at a first design temperature T1 and a second stack core length L2 and a second gasket stress σ2 at a second design temperature T2. The first design temperature T1 is at least 80 degrees Celsius and the second design temperature T2 is less than 30 degrees Celsius. A stack core length difference dL = L1-L2 is between 0 to 20 millimeters, and a gasket stress difference dσ =σ1-σ2 is between 0 to 20 MPa.
Absstract of: EP4800157A1
0001 Method of operating an electrolysis system (2) wherein the method comprising the step of: (S100) providing a control signal (S5) to a product valve (18b) on the oxygen-side (V) of the electrolysis system (2) to keep the product valve (18b) open in order to buffer oxygen provided by the electrolysis system (2) in a buffer tank (14b) on the oxygen-side (V) in normal operation of the electrolysis system (2).
Absstract of: EP4800000A1
The invention relates to an methanol plant comprising: a CO2-rich feed, a hydrogen-rich feed, a boiler feed water stream, a CO2-electrolysis section arranged to electrolyse at least a portion of the CO2-rich feed to output a mixed stream, a heat exchange section arranged to heat exchange at least a portion of the first mixed stream so as to output a cooled mixed stream and a steam stream, a methanol synthesis loop arranged to receive at least a portion of the cooled mixed stream and at least a portion of the hydrogen-rich feed and to output a raw methanol stream, a purge gas stream, and a flash gas stream, and a methanol upgrading section, wherein the steam stream is arranged to provide heat energy for one or more components of the methanol upgrading section. At least a portion of the purge gas stream is arranged to be recycled to the CO2-rich feed, and/or at least a portion of the flash gas stream is arranged to be recycled to at least one of: the mixed stream and the cooled mixed stream. The invention also relates to a method for converting CO2 to methanol.
Absstract of: US2020032688A1
0001 Systems for abatement of pollutants in an exhaust gas stream of an internal combustion engine including a hydrogen injection article configured to introduce hydrogen upstream of a catalytic article are effective for the abatement of carbon monoxide and/or hydrocarbons and/or nitrogen oxides. The introduction of hydrogen may be intermittent and/or during a cold-start period.
Absstract of: SE2500030A1
Uppfinningen avser förfarande och arrangemang för att producera ammoniak från väte samt luftens kväve. Uppfinningen kännetecknas av att i en förbränningsmotor för ammoniak förbränns ammoniak stökiometriskt med syret i den omgivningsluft som tillförs motorn varefter bildad het avgas med vattenånga reagerar med järnet i avgassystemet och bildar rost i en endoterm reaktion varvid väte frigörs samtidigt som ammoniak bildas i en exoterm reaktion i motorns avgassystem som består av järn och utgör ett cirkulärt energilager.
Absstract of: NZ808750A
The invention relates to a new kind of electrocatalyst to be incorporated as part of the electrodes, anode and cathode, in water electrolysers aimed for hydrogen production through the electrochemical splitting of water into oxygen and hydrogen. The electrocatalyst is characterized by a layered and porous structure that provides a high performance towards the oxygen evolution reaction in the absence of added ionomer. The object of the invention is framed in the field of energy.
Absstract of: WO2025051317A1
The invention relates to a fluid-conducting plate arrangement (3) of an electrochemical system (1), comprising a compression plate (4) which has an inner side (6), facing a stack of electrochemical cells, and an outer side (5) and is passed through by a plurality of through-openings to which a plurality of coolant passages (8, 9), namely a coolant inlet (8) and a coolant outlet (9), are to be assigned, wherein each coolant passage (8, 9) has a branch (12) which opens towards the inner side (6) and is formed by the compression plate (4) together with an insert plate (10) inserted into it on the outer side, such that the compression plate (4) has two separate passage portions (13, 14) and the insert plate (10) has a collecting portion (18) which adjoins the two passage portions (13, 14).
Absstract of: WO2025049352A2
This discloses a surfaced plasmon resonance catalyst device and a chemical reaction systems using the catalyst device. The catalyst device includes metal nanoparticles formed over a supporting body with ligands that are interposed between the supporting body and many of the metal nanoparticles. Many of the ligands are bonded to a surface of the supporting body on one hand and are also bonded to at least part of the metal nanoparticles on the other hand. One chemical reaction system includes a flow reactor that accommodates the catalyst device for use in ammonia cracking.
Absstract of: NZ804904A
The present invention describes an improved catalytic reactor system with an improved catalyst that transforms CO2 and low carbon H2 into low-carbon syngas with greater than an 80% CO2 conversion efficiency, resulting in the reduction of plant capital and operating costs compared to processes described in the current art. The inside surface of the adiabatic catalytic reactors is lined with an insulating, non-reactive surface which does not react with the syngas and effect catalyst performance. The improved catalyst is robust, has a high CO2 conversion efficiency, and exhibits little or no degradation in performance over long periods of operation. The low-carbon syngas is used to produce low-carbon fuels (e.g., diesel fuel, jet fuel, gasoline, kerosene, others), chemicals, and other products resulting in a significant reduction in greenhouse gas emissions compared to fossil fuel derived products.
Absstract of: US20260250871A1
0000 An electro-energy or electro-synthetic cell, including a cathode, an anode and an electrode separator positioned between the cathode and the anode. A liquid electrolyte inlet supplies a liquid electrolyte to the cell, and a liquid electrolyte outlet removes the liquid electrolyte from the cell. The liquid electrolyte outlet includes an overflow weir over or through which excess liquid electrolyte flows out of the cell. In another form, one or more drippers are included as part of the liquid electrolyte inlet and/or the liquid electrolyte outlet and drip chambers are positioned below the drippers. In another form, one or more porous capillary structures are located in liquid pathways in the cell, for example in a liquid pathway provided by an overflow weir or adjacent a dripper. In another form, one or more restrictors are utilised that create a pressure drop in the liquid electrolyte passing through the restrictor.
Absstract of: WO2026174667A1
The present invention belongs to the technical field of photoelectrocatalysis. Specifically disclosed are a composite photoelectrocatalytic material, and a preparation method therefor and a use thereof. According to the present invention, first, a Bi-containing solution is used as an electrolyte for electrodeposition, a V-containing precursor solution is coated, and then annealing treatment is performed to obtain a BiVO4 matrix material; then, the BiVO4 matrix material is used as a working electrode, a Ni-containing solution is used as an electrolyte, and photo-assisted electrodeposition is performed to obtain NiO/BiVO4; and then a solution containing Ni5P4 nanoparticles is coated on the NiO/BiVO4 to obtain the composite photoelectrocatalytic material. The composite photoelectrocatalytic material obtained according to the present invention has a built-in electric field, and has high catalytic activity and excellent catalytic performance; the Ni5P4 greatly improves the yield and selectivity of H2O2; and the preparation method also has the characteristics of simple operation, time saving, and low energy consumption.
Absstract of: US20260249262A1
0000 An ammonia decomposition reactor having a function of preheating ammonia gas, including a heat exchanger body and a reactor body enveloped externally by the heat exchanger body. A heat-exchange tube on the heat exchanger body is provided in a heat-exchange shell, one end is in communication with an ammonia gas heat-exchange inlet, and the other end is in communication with an ammonia gas heat-exchange outlet. A heat medium inlet and A heat medium outlet are individually connected to the heat-exchange shell. A catalyst tube is provided in a reaction shell. An ammonia gas heat-exchange outlet on the heat exchanger body is in communicated with an ammonia gas inlet on the reactor body, an ammonia gas inlet is communicated with an ammonia-gas-decomposition-gas outlet by a catalyst tube, and the ammonia-gas-decomposition-gas outlet is communicated with a heat medium inlet on the heat exchanger body.
Absstract of: WO2011139804A2
Compositions and methods for a hybrid biological and chemical process that captures and converts carbon dioxide and/or other forms of inorganic carbon and/or CI carbon sources including but not limited to carbon monoxide, methane, methanol, formate, or formic acid, and/or mixtures containing CI chemicals including but not limited to various syngas compositions, into organic chemicals including biofuels or other valuable biomass, chemical, industrial, or pharmaceutical products are provided. The present invention, in certain embodiments, fixes inorganic carbon or CI carbon sources into longer carbon chain organic chemicals by utilizing microorganisms capable of performing the oxyhydrogen reaction and the autotrophic fixation of CO2 in one or more steps of the process.
Absstract of: US20260250851A1
The present invention relates to a catalysis promoter dissolved in an electrolyte of a water electrolysis device using an alkaline electrolyte and promoting the catalytic activity of an oxygen evolution electrode.
Absstract of: US20260249278A1
0000 The present disclosure discloses a noble metal oxide cluster catalyst anchored on cobalt-based nanosheets and a preparation method thereof. The preparation method includes mixing a cobalt acetate solution, a metal salt solution, ammonium metavanadate, and acetylene black uniformly, stirring at a temperature in a range of 50 °C to 100 °C, and filtering to collect a sample; and subjecting the sample to vacuum drying, pyrolyzing the sample under air atmosphere, to obtain the noble metal oxide cluster catalyst anchored on cobalt-based nanosheets.
Absstract of: WO2025040912A1
The disclosure provides a process of preparing an ion-conducting membrane comprising a sulphonated hydrocarbon ionomer having an ion-exchange capacity I2 meq/g, the process comprising the steps of: a) providing a sulphonated hydrocarbon ionomer having an ion- exchange capacity I1 meq/g; b) casting an ion-conducting membrane from a mixture of the sulphonated hydrocarbon ionomer provided in step a) and a solvent; c) applying a treatment to the ion-conducting membrane prepared in step b) which reduces the ion-exchange capacity from I1 meq/g to an ion-exchange capacity I2 meq/g, wherein I2 is less than I1.
Absstract of: AU2025262351A1
A hydrogen generation device with a breathing detection function. The hydrogen generation device comprises an electrolytic cell, a gas pipe, a sensor, a valve switch and a controller, wherein the electrolytic cell is used for electrolyzing water to generate a hydrogen-containing gas; the gas pipe is in communication with the electrolytic cell and has a gas outlet, and the gas pipe is used for receiving the hydrogen-containing gas and outputting the hydrogen-containing gas through the gas outlet; the sensor is used for sensing the breathing of a user to generate a breathing signal; the valve switch is arranged in the gas pipe; and the controller is electrically connected to the valve switch and the sensor, and the controller opens the valve switch on the basis of an inspiration signal, and closes the valve switch on the basis of an expiration signal. Therefore, the present invention provides the hydrogen-containing gas, and does not provide the hydrogen-containing gas in an expiration state, such that not only can excessive pressure in a breathing tube be prevented, but also the hydrogen-containing gas can be prevented from rapidly flowing to a user when the user inhales again, thereby improving the practicability and the usage experience.
Absstract of: AU2025234540A1
A method for control of the individual catholyte and anolyte flows through a multitude of electrolyser stacks is provided wherein: a. each electrolyser stack (2) is adapted to perform electrolysis of water, and b. all electrolyser stacks (2) are served with an electric current and that, c. all electrolyser stacks (2) are served with anolyte flow (26), and d. all electrolyser stacks (2) are served with catholyte flow (27). It is preferred that e. differential pressure signals (28.1) at each electrolyser stack (2) is provided and, f. that catholyte control signals (43) and anolyte control signals (42) to each of a catholyte stack inflow valve actuator (44) and an anolyte stack inflow valve actuator (45) are provided for the regulation of each of an anolyte stack inflow valve (56) and a catholyte stack inflow valve (57). An electrolyser system is also provided.
Absstract of: US20260250859A1
0000 An electrolysis system includes a plurality of electrolysis devices connected to a power supply line, the electrolysis devices having an electrical energy supply unit and an electrolysis module coupled to the power supply unit. The energy supply units of the electrolysis devices include a transformer and a rectifier unit. The transformer has a primary winding and a secondary winding connected to an AC voltage side of the rectifier unit. The primary winding of the transformer of at least a first of the electrolysis devices is configured to be adjustable in stages, and the rectifier unit of that electrolysis device is configured to be operated in an uncontrolled manner. The rectifier unit of the energy supply unit of at least a second of the electrolysis devices is configured to be operated in a controlled manner depending on the electrical energy that can be provided by the energy source.
Absstract of: US20260250856A1
The present disclosure relates to an electrode for use as an anode or cathode for electrolysis of a liquid flowing along a flow direction. An electrolysis arrangement includes at least one such electrode and a method for performing electrolysis using the electrolysis arrangement. The electrolysis arrangement includes a cylindrical housing and a plurality of elongated electrodes each extending along a longitudinal direction parallel to the central axis. The plurality of electrodes is arranged in a concentric pattern around the central axis inside the cylindrical housing. The electrolysis arrangement also includes fluid actuating means for causing a rotational flow of a fluid around said central axis inside said inner volume of said cylindrical housing.
Absstract of: US20260250131A1
0000 Page 12 A method for producing a compound comprising at least one of hydrogen or oxygen comprises providing water and a first substance, producing a mixture comprising the water and bubbles comprising the first substance, decreasing a diameter of bubbles comprising the first substance, decomposing a part of the water, and composing a compound at least from the decomposed water and the first substance, and the compound comprising at least one of hydrogen or oxygen. An apparatus is configured for producing a compound comprising at least one of hydrogen or oxygen.
Absstract of: TW202543915A
To provide a reactor capable of suppressing damage to a housing caused by heat. A reactor 10 comprises: a housing 1 including an introduction port 2 for introducing ammonia and a combustible gas, and an outlet 3 for causing the generated gas to flow out; a first catalyst part 13 disposed inside the housing 1 and including a first catalyst for generating heat by burning the combustible gas introduced from the introduction port 2; and a second catalyst part 21 disposed between the first catalyst part 13 and the outlet 3, including a second catalyst heated by heat generated in the first catalyst part 13, and generating hydrogen from ammonia.
Absstract of: US20260250866A1
0000 Process of manufacturing an electrocatalyst for alkaline water electrolysis including: (i) producing an aqueous electrolyte including suspended graphene and graphite nanoplatelet structures having thickness of <100 nm in an electrochemical cell including a negative graphitic electrode, a positive graphitic electrode, an aqueous electrolyte including ions in a solvent, the ions including cations, including sulphate ions, and anions, wherein current passes through the cell to obtain exfoliated graphene and graphite nanoplatelet structures in the aqueous electrolyte in an amount of more than 5 g/l. (ii) Composing an electroplating bath including the suspended graphene and graphite nanoplatelet structures in an amount of more than 2 g/l, the electroplating bath including an aqueous solution of nickel sulphate and the aqueous electrolyte of step (i). (iii) Electrodepositing from the electroplating bath a combined layer of Ni or Ni-alloy and graphene and graphite particles on a carrier to form electrocatalyst.
Absstract of: DE102025107067A1
Die Erfindung betrifft ein Verfahren zur Aufbereitung von Rohwasser (1) für die Nutzung als Edukt-Wasser in einem Elektrolyseprozess, bei dem salzbeladenes Rohwasser (1) bereitgestellt und eine thermische Entsalzung des Rohwassers (1) durchgeführt wird, wobei Wärme (QIN) dem Rohwasser (1) zugeführt und dieses verdampft wird, wobei salzfreies Wasser (H2O) abgezogen wird, das als Edukt-Wasser (9) bereitgestellt und einem Elektrolyseprozess zugeführt wird, bei dem Wasserstoff (H2) als Produktgas erzeugt wird, wobei der erzeugte Wasserstoff (H2) verladen wird, indem der Wasserstoff (H2) einem exothermen Verladeprozess unterzogen wird, aus dem Wärme (QOUT) freigesetzt wird, wobei freigesetzte Wärme (QOUT) übertragen und als Heizwärme (QIN) dem Rohwasser (1) zugeführt und zur Verdampfung genutzt wird.Die Erfindung betrifft weiterhin ein Wasseraufbereitungssystem (11) zur Durchführung des Verfahrens.
Absstract of: US20260250853A1
0000 A hydrogen production system of the present disclosure includes a plurality of electrolyzers which produce hydrogen by electrolyzing a raw material, a plurality of power converters which convert three-phase AC power into DC power and supply the DC power to the plurality of electrolyzers, and a control device which controls the plurality of power converters. Each electrolyzer is connected to a different one of the power converters. The control device is configured to individually control a current or a voltage supplied from the plurality of power converters to each electrolyzer by individually controlling the plurality of power converters, and to control the current or the voltage supplied from the power converter to a measured electrolyzer based on a detection value detected by at least one detection unit of an inlet gas state detection unit, an outlet gas state detection unit, and a power supply physical quantity detection unit.
Absstract of: US20260250854A1
0000 A hydrogen production system of the present disclosure includes an electrolytic device, a plurality of electrical power conversion devices that convert three-phase AC power to DC power and supply the DC power to the electrolytic device, and a control device that controls the electrical power conversion devices. The electrolytic device is connected with the plurality of electrical power conversion devices connected in parallel with each other. The control device is configured to correct, when electrical power supply from some of the plurality of electrical power conversion devices to the electrolytic device is stopped, at least one of voltage and current of the electrical power conversion device that is continuing electrical power supply to the electrolytic device so that a later hydrogen production amount of the electrolytic device approaches a predetermined target amount.
Absstract of: WO2026176299A1
The present application relates to an advanced process for the decoupled production of hydrogen and carbon monoxide from hydrocarbons and carbon dioxide. This process combines the catalytic decomposition of hydrocarbons with the gasification of a solid carbon intermediate to separately produce and store hydrogen and carbon monoxide. From an industrial perspective, this process allows for an easy and highly flexible subsequent mixture of the two products that is critical for downstream processes.
Absstract of: WO2026176213A1
The present invention relates to a system for generating energy by means of hydrogen gas (HHO) for domestic and industrial use, wherein the system is used as an energy source in different applications, such as heating, cooking, boilers and industrial motors or similar. The system comprises a set of units and devices that includes a multipolar cell and several interconnected components, such as pressure valves, a pressurised pump and a gas mixer, which allow HHO to be produced, controlled, and blended with other fuels, optimising energy efficiency and reducing carbon emissions.
Absstract of: WO2026177750A2
An integrated energy system (IES) including a power plant is discussed herein. In some examples, the IES may include a power plant configured to generate steam, a Low-Temperature Methane Steam Reforming plant configured to receive at least a portion of the steam from the power plant to react with Methane within the Low-Temperature Methane Steam Reforming plant to produce Hydrogen, first Carbon Monoxide, and Carbon Dioxide, a first separation unit configured to separate the Hydrogen, the first Carbon Monoxide, and the Carbon Dioxide, a Solid Oxide Electrolysis Stack configured to receive at least a portion of the Carbon Dioxide and to produce second Carbon Monoxide and Oxygen, a second separation unit configured to separate the Carbon Dioxide from the second Carbon Monoxide, and a methanol synthesis reactor configured to receive at least a portion of the Hydrogen and at least a portion of the second Carbon Monoxide to produce Methanol.
Absstract of: WO2026175483A1
The present disclosure provides a converter system (100) for powering a plurality of hydrogen electrolyzers that are electrically coupled together to form at least one electrolyzer string (200). The converter system (100) includes a main power supply unit (10) configured to provide bulk power to the at least one electrolyzer string (200) such that a main current flows through the at least one electrolyzer string (200); an auxiliary power supply unit (20) comprising at least one DC/DC converter (21), which is electrically coupled with the at least one electrolyzer string (200) to inject or extract an adjustable current to or from the at least one electrolyzer string (200); and a control system (30) configured to control at least one of the main power supply unit (10) and the auxiliary power supply unit (20) for operating the converter system (100).
Absstract of: WO2026176844A1
Provided is an electrode laminate for an alkaline water electrolysis cell in which a short circuit due to breakage of a diaphragm is unlikely to occur while having a zero gap structure. The electrode laminate for an alkaline water electrolysis cell comprises: an anode that serves as an oxygen generation electrode; a cathode that serves as a hydrogen generation electrode; and a diaphragm that is interposed between the anode and the cathode and has hydroxide ion conductivity. The electrode laminate has a zero gap structure in which the anode, the diaphragm, and the cathode are laminated so as to be in contact with each other. The anode includes an anode stress relaxation layer, which is deformable by stress, on a surface that is in contact with the diaphragm, and/or the cathode includes a cathode stress relaxation layer, which is deformable by stress, on a surface that is in contact with the diaphragm.
Absstract of: WO2026175484A1
A converter system (100) for powering a plurality of hydrogen electrolyzers is provided. The plurality of hydrogen electrolyzers are electrically coupled together to form at least two electrolyzer strings (210, 220). The converter system (100) comprises: a main power supply unit (10) comprising a main converter that provides bulk power to the at least two electrolyzer strings (210, 220) such that a main current flows through each of the at least two electrolyzer strings; an auxiliary power supply unit (20) comprising at least one DC/DC converter, which is electrically coupled with one electrolyzer string from the at least two electrolyzer strings to inject or extract an adjustable current to or from the one electrolyzer string; and a control system (30) configured to control at least one of the main power supply unit (10) and the auxiliary power supply unit (20) for operating the converter system (100).
Absstract of: US20260250126A1
A method for converting hydrogen sulfide (H2S) to hydrogen (H2) and sulfur(S) includes contact a H2S-containing feed gas stream with a molybdenum disulfide (MoS2) catalyst at a temperature of about 500 to about 1000° C., thereby converting at least a portion of the H2S to H2 and S and producing a spent catalyst in-situ and a residue gas stream leaving the reactor. A method for preparing the MoS2 catalyst in the form of a flower-like nanosheet microsphere. A method for preparing the MoS2 catalyst in the form of a nanosheet.
Absstract of: WO2026175476A1
A method (200) for handling a waste heat generated by at least one component of a wind turbine generator is presented. The method (200) comprises: - determining (210) that an inflow of thermal energy to at least one electrolyzer (121) is needed to control the at least one electrolyzer (121) to operate in a specific electrolyzer state; and - transferring (220) a turbine thermal energy TEturbine associated with at least a part of the waste heat from the wind turbine generator (101) to the at least one electrolyzer (121), by transferring the turbine thermal energy TEturbine from a turbine temperature controlling arrangement (310) to at least one electrolyzer temperature controlling arrangement (320) of the at least one electrolyzer (121) via a connection (322, 330, 340) between the turbine temperature controlling arrangement (310) and the at least one electrolyzer temperature controlling arrangement (320), respectively.
Absstract of: US20260254396A1
0000 An energy supply system is specified for coupling to a wind power station that is used in island mode and that operates an electrolysis facility for the production of green hydrogen with wind energy. The novel energy supply system has a solar energy source, with a photovoltaic module and/or a solar thermal collector, which is configured to supply the electrolysis facility, in particular a containment and water-carrying lines of electrolysis units of the electrolysis facility, with thermal energy in the event of the absence of wind energy. There is also described a corresponding method for coupling solar energy to a wind power station that is operated in island mode.
Absstract of: US20260250857A1
An electrolysis device for producing hydrogen through electrochemical reaction from an aqueous alkali solution is disclosed. The electrolysis device includes an anodic half cell and a cathodic half cell. The anodic half cell and the cathodic half cell are separated via a membrane and the alkali solution can flow through the cathodic half cell. The anodic half cell includes an anodic electrode and the cathodic half cell includes a cathodic electrode. The anodic electrode, the cathodic electrode and the membrane form a membrane-electrode unit. In normal operation of the electrolysis device, an initial fill quantity of the alkali solution in the cathodic half cell can be changed only by diffusion processes through the membrane-electrode unit and/or through electrochemical reaction of the alkali solution in the membrane-electrode unit.
Absstract of: WO2025190563A1
The invention relates to a process for obtaining hydrogen from water, in which an oxidation unit is supplied with a pumpable suspension of zinc particles in alkaline solution, zinc is oxidized electrochemically or thermally to zinc oxide in the oxidation unit (3) with release of hydrogen, the suspension leaving the oxidation unit (3) is fed to a reduction unit (4), and zinc oxides formed in the course of oxidation in the reduction unit (4) are electrochemically reduced to zinc with release of oxygen, and then the suspension leaving the reduction unit (4) is fed back to the at least one oxidation unit (3).
Absstract of: WO2025081243A1
Disclosed herein is an electrochemical cell comprising a porous tubular support adapted to conduct electricity, a bore of the support defining an inner channel configured to receive a flow of a first fluid therethrough; a tubular outer electrode; an electrolyte comprising a porous membrane, the porous membrane separating the porous tubular support and the tubular outer electrode; current collectors for enabling an electrical current to flow through the cell; and a housing for the electrochemical cell, a space between the housing and the tubular outer electrode defining an outer channel configured to receive a flow of a second fluid therethrough.
Absstract of: EP4796521A1
0001 A method for producing methane according the present disclosure includes: producing methane from a raw material gas containing ammonia and carbon dioxide in the presence of a catalyst containing a carrier and a transition metal.
Absstract of: WO2025036406A1
An SOEC module and an SOEC water electrolysis hydrogen production device based on a multi-stack-core module. Said device comprises a steam generator, a mixer, an air heater and a plurality of SOEC modules; each SOEC module comprises a heat preservation shell provided with a hot air module inlet, a hydrogen-containing mixed steam module inlet, an oxygen-rich air module outlet and a product crude hydrogen module outlet, and a plurality of electrolytic cell stack cores arranged in the heat preservation shell; and each electrolytic cell stack core comprises a hot air single-stack inlet, a hydrogen-containing mixed steam single-stack inlet, an oxygen-rich air single-stack outlet and a product crude hydrogen single-stack outlet.
Absstract of: GB2634782A
A method for manufacturing a catalyst coating 200 for a recipient component of a PEM electrolyser and a blended catalyst. The method comprising the steps of: processing a pre-used catalyst-coated donor component 202, to recover a quantity of a catalyst 203; converting the catalyst recovered from the donor component into a powder, thus producing a low-ECSA (electrochemical active surface area) recycled catalyst powder; and blending the recycled catalyst powder 203 with a quantity of high-ECSA unrecycled catalyst powder 204 to form a blended catalyst powder 205. ECSA represents a value for the active surface area of the catalyst and is related to the BET (Brunauer-Emmett-Teller) value.
Absstract of: US2025171652A1
0000 Methods of continuously dispersing catalyst inks for use in coating processes are described. The catalyst ink is continuously mixed in a high shear mixing unit, and the mixed ink is sonicated in a sonication unit. Part of the sonicated catalyst ink is returned to the high shear mixing unit. The method provides continuous mixing and sonicating of the catalyst ink. The mixed and sonicated ink can then be applied to a substrate in a defined pattern.
Absstract of: WO2025082916A1
The invention relates to a unit (200) for producing hydrogen that comprises: - a stack (102) of solid oxide cells, - an air circuit (110), and a fuel circuit (120) passing through the stack (102); characterised in that the unit (200) is equipped with a stopping system comprising: - an inlet (202) and an outlet (204) for neutral gas, for circulating a predetermined neutral gas in the stack; - an inlet (206) and an outlet (208) for safety gas, for circulating a safety gas in the stack (102); and - a control module (210) for switching the stack (102) from the production configuration to the stopped configuration. The invention also relates to a method for controlling such a unit.
Absstract of: WO2025082675A1
The invention relates to a hydrogen-production plant comprising at least a first production line, comprising at least a first electrolysis device with a plurality of first electrolysis modules and comprising a first compressor device with a plurality of first compressor modules, and comprising a controller, comprising at least a schedule-creating module and a control module, wherein the schedule-creating module is designed for creating an activation schedule at least for the first electrolysis modules and for the first compressor modules on the basis of respective performance characteristics of the respective first electrolysis modules, respective performance characteristics of the respective first compressor modules and at least one predetermined optimization criterion, and wherein the control module is designed for activating the first compressor modules and the first electrolysis modules on the basis of the activation schedule created.
Absstract of: EP4796672A1
0001 Es wird ein Verfahren zur Herstellung von Wasserstoff unter Verwendung einer Elektrolyseanordnung (1000) mit einer Elektrolysevorrichtung (100) und einer Verdichtervorrichtung (500) vorgeschlagen, wobei der Elektrolysevorrichtung (100) ein Elektrolysewasser enthaltender Wasserstoffstrom (101) entnommen und zumindest zu einem Teil als Verdichtereinsatzstrom einer Verdichtung zugeführt wird. Hierbei ist vorgesehen, dass der Verdichtereinsatzstrom zumindest einen Teil des Elektrolysewasser des Wasserstoffstroms (101) umfasst und die Verdichtung unter Verwendung eines Turboverdichters (550) durchgeführt wird. Eine entsprechende Elektrolyseanordnung (1000) wird ebenfalls vorgeschlagen.
Absstract of: EP4796673A1
L'invention concerne un système destiné à assurer le fonctionnement sans interruption d'un électrolyseur de production d'hydrogène avec un compresseur à haute pression, comprenant un équipement de production d'hydrogène (1), un équipement de compression (4) de l'hydrogène dans des stockages à haute pression (5, 6), un réservoir tampon (3) de volume réduit, positionné entre l'équipement de production d'hydrogène (1) et l'équipement de compression (4), et un module de contrôle (7) configuré pour piloter le courant électrique alimentant l'équipement de production d'hydrogène (1) de manière à ce qu'il corresponde au débit de compression autorisé.
Absstract of: EP4541945A1
The invention relates to Device for electrochemical reversible dihydrogen storage (1), said device comprising: a sealed chamber (2) intended to receive an electrolytic media (3) and gaseous dihydrogen (4), connection means (5) suitable for connecting the seal chamber to a gas circuit (6) and at least one first electrode (7), and at least one second electrode (8), arranged within the sealed chamber. The at least one second electrode is suitable to oxidize dissolved gaseous dihydrogen, in the electrolytic media, and form protons and to reduce protons and form gaseous dihydrogen according to formula 1: H2 ↔ 2H+ + 2e-, formula 1. The at least one first electrode comprises at least one redox couple My/Mx, insoluble in the electrolytic media, said at least one redox couple being arranged to exhibit at least two oxidation states and being suitable to be reduced from an oxidized state My to a reduced state Mx, and conversely, according to formula 2: My + pe- ↔ Mx, formula 2, wherein x and y are oxidation number. An absolute potential difference |ΔE| between a redox potential of the couple H+/H2, for a predetermined electrolytic media and a predetermined pressure range of gaseous dihydrogen, and a redox potential of the at least one couple My/Mx is lower than or equal to 0.6 V.
Absstract of: WO2022002904A1
A separator for alkaline electrolysis comprising a porous support (10) and a first (20b) and second (30b) porous layer provided on respectively one side and the other side of the porous support, characterized in that the porous support has a thickness (d1) of 150 µm or less and the total thickness (d2) of the separator is less than 250 µm. Also a method is disclosed wherewith such a separator may be prepared.
Absstract of: WO2025165987A1
Methods and systems for hydrogen production from inert sodium salts are described herein. In an example method, steam is generated by a nuclear reactor power plant system. The steam is applied to sodium formate to facilitate one or more thermal and/or hydrothermal decomposition processes, thereby generating hydrogen. In the example method, sodium formate is generated by combining sodium hydroxide generated by an electrolysis process with sodium carbonate and/or sodium bicarbonate generated by a carbon capture process. Embodiments can be used to supply hydrogen storage facilities and/or for energy production.
Absstract of: WO2025053532A1
The present invention relates to a membrane electrode assembly manufacturing method comprising the steps of: (S1) forming a first catalyst layer on the other surface of a separation membrane having a first carrier film attached to one surface thereof; (S2) attaching a second carrier film to the other surface of the separation membrane on which the first catalyst layer is formed; (S3) removing the first carrier film attached to one surface of the separation membrane; and (S4) forming a second catalyst layer on one surface of the separation membrane from which the first carrier film is removed, wherein the second carrier film includes a first area corresponding to the first catalyst layer on the other surface of the separation membrane, and a second area, which is the remaining area that excludes the first area, and the second area of the second carrier film is coated with an adhesive on a surface facing the other surface of the separation membrane on which the first catalyst layer is formed.
Absstract of: GB2632092A
A method of producing hydrogen is described. The method comprises conducting a thermochemical reaction by contacting an active reagent and a basic aqueous solution, for example the hydrolysis of zinc in sodium hydroxide solution, which causes water from the basic aqueous solution to react with the active reagent and to produce hydrogen and a basic aqueous solution comprising an oxidised product. The method further comprises disposing the basic aqueous solution comprising the oxidised product in an electrochemical cell comprising an anode and a cathode, such that at least a portion of the cathode contacts the solution; and conducting an electrochemical reaction by applying a voltage across the anode and the cathode to produce hydrogen, oxygen and the active reagent. The active reagent comprises a metal or metal ion in a first oxidation state and the oxidised product comprises the metal or metal ion in a second oxidation state which is higher than the first oxidation state. Both the electrochemical and thermochemical reactions can be operated continuously.
Absstract of: WO2025071002A1
The present invention relates to a biogas-based electrochemical hydrogen extraction and separation system comprising a solid oxide fuel cell and a solid oxide water electrolysis cell, and a method for operating same. Specifically, the biogas-based electrochemical hydrogen extraction and separation system comprising a solid oxide fuel cell and a solid oxide water electrolysis cell is characterized by comprising: a fuel supply part for supplying biogas as fuel; a first reaction part for reforming the biogas supplied through the fuel supply part so as to generate a first reformed gas; a second reaction part for secondarily reforming the first reformed gas so as to generate a second reformed gas; a third reaction part for receiving the second reformed gas generated in the second reaction part and generating electricity; a fourth reaction part for receiving unreacted gas generated in the third reaction part and using the unreacted gas as fuel, and receiving steam generated in the third reaction part and generating hydrogen; and a power converter which receives the electricity generated in the third reaction part and supplies the electricity to the first reaction part and the fourth reaction part.
Absstract of: TR2026010714A2
Bu buluş; fotoelektrokimyasal hidrojen üretimi alanında, ulaşım sektörü, mobil uygulamalar ve yerleşik uygulamalarda kullanılabilecek hidrojen yakıtının üretimi amacıyla, bizmut vanadatın (BiVO?) fotoelektrokimyasal aktivitesinin artırılması için elektrokimyasal büyütme sırasında kobalt (Co) ve krom (Cr) ile birlikte katkılanması sonucu elde edilen Co ve Cr katkılı BiVO? yarı iletkeni ile ilgilidir.
Absstract of: US20260242957A1
0000 Herein discussed is an electrochemical reactor comprising a first electrode, wherein the first electrode is liquid when the reactor is in operation; a second electrode having a metallic phase and a ceramic phase, wherein the metallic phase is electronically conductive and wherein the ceramic phase is ionically conductive; and a membrane, wherein the membrane is positioned between the first and second electrodes and is in contact with the first and second electrodes, wherein the membrane is mixed conducting. Also discussed herein is a method of producing hydrogen or carbon monoxide comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode, wherein the anode is liquid when the reactor is in operation and wherein the membrane is mixed conducting; (b) introducing a feedstock to the anode; (c) introducing a stream to the cathode, wherein the stream comprises water or carbon dioxide.
Absstract of: WO2026172325A1
The invention relates to an electrolyser for producing dihydrogen via a water electrolysis reaction in a basic medium, the electrolyser comprising a block (20) comprising: - N electrolysis cells (10) connected to one another between two electrode plates, i.e. an anode plate and a cathode plate, - a circuit for flow of fluid arranged to deliver water to the block of cells, and - a power supply (32) intended to deliver a current to the block of cells with a view to generating a water electrolysis reaction. The electrolyser also comprises: - a voltage generator (34) configured, when it is active, to apply a backup voltage (Ts) across the electrode plates of the block of cells and - a control means configured to activate the voltage generator (34) when it detects the power supply (32) has been interrupted.
Absstract of: US20260242965A1
An electrochemical cell stack includes a plurality of cells separated from one another by bipolar plates. Each cell is formed from two half-cells between which a membrane is arranged. The support frame describes a stepped shape with two adjacent cross-section regions. An edge of the membrane lies in a step formed by the cross-section regions and the porous transport layer of a half-cell extends into the step. The support frame includes at least one sealing arrangement and an electrically insulating sealing material. The sealing arrangement includes three sealing regions each having at least one sealing lip. A first sealing region and a second sealing region are assigned to the narrower of the two cross-section regions facing the membrane. A third sealing region on a side of the support frame facing away from the step and borders an opening of the support frame.
Absstract of: WO2026173620A2
The reverse water-gas shift (RWGS) reaction, which is used to convert H2 and CO2 into syngas (H2+CO) is performed using nonstoichiometric metal oxides. The RWGS reaction is performed in two separate steps, achieving both high conversion and high energy efficiency. The reaction may be performed in a single reactor or in multiple reactors arranged in series or parallel. This could be powered either by heat generated by distributed energy sources, concentrated solar thermal (CST) heat, heat from traditional energy generation sources, and/or waste electrical power.
Absstract of: AU2025229653A1
The invention relates to a method for controlling an electrolyzing plant (10), comprising: providing electric energy from an electric power network (32) with a network AC voltage; rectifying the network AC voltage by a rectifying device (50, 52, 54, 56, 58, 60, 62, 64); supplying water to the electrolyzing device (34, 36); providing an AC filter current flow by an active filter device (100), wherein the AC filter current flow is controlled such that it conforms to network regulations of the electric power network; measuring the network AC voltage by using a voltage sensor (128) which provides a respective voltage sensor signal; comparing the voltage sensor signal with a first reference voltage value providing a comparing result; depending on the comparing result, causing the active filter device (100) to emit electric energy to or to receive electric energy from the electric power network.
Absstract of: AU2025221792A1
The invention relates to a method for operating an electrolyzer (1) comprising an anode chamber (3) and a cathode chamber (5), in which water (H2O) is supplied as a reactant and hydrogen (H2) and oxygen (O2) are generated as product gases. On the anode side, the oxygen product gas, which also contains hydrogen as a foreign gas, is generated in a product flow out of the anode chamber (3) and is introduced into a horizontal anode-side collecting line (7) having a surrounding wall (11) and is removed via the collecting line (7), wherein water (H2O) is sprayed onto an inner surface of the surrounding wall (11) of the collecting line (7) so that the surrounding wall (11) is wetted with water and the inner surface is inerted. The invention additionally relates to an electrolyzer (1), in particular for carrying out the method.
Absstract of: US20260242313A1
0000 A methanol plant and a process for the production of methanol is provided. A hydrogen recovery section receives off-gas stream from the methanol synthesis section and outputs a hydrogen-rich stream, which is recycled upstream the methanol synthesis section.
Absstract of: KR102625221B1
The present invention relates to an offshore platform capable of overcoming the intermittency of renewable energy and producing, storing, and supplying carbon-neutral fuels. According to the present invention, the offshore platform comprises: a main body located at sea; a hydrogen production unit disposed in the main body to produce and store hydrogen by electrolyzing seawater through a water electrolysis device; an ammonia production unit disposed in the main body and producing and storing ammonia by synthesizing the hydrogen flowing from the hydrogen production unit through a first synthesis device and nitrogen in the air; a carbon dioxide storage unit disposed in the main body and storing carbon dioxide flowing in from a ship; and a methanol production unit disposed in the main body to produce and store methanol by synthesizing the carbon dioxide flowing in from the carbon dioxide storage unit and the hydrogen flowing in from the hydrogen production unit through a second synthesis device.
Absstract of: WO2026171830A1
The present invention relates to a method (100) for regenerating an electrolysis system (200). The method (100) comprises: - introducing (101) a hydrogen-containing regeneration fluid into a cathode chamber (203) of the electrolysis system (200), - reversing (103) an electrical polarity of a cathode (205) and anode (209) of the electrolysis system (200) compared to a normal operation for electrolysis, so that hydrogen present in the cathode chamber (203) is oxidized, and hydrogen is formed in an anode chamber (207) of the electrolysis system (200), and - flushing out (105) the cathode chamber (203).
Absstract of: WO2026171654A1
An ammonia plant and a method for controlling the same at partial load, wherein the make-up gas for the synthesis of ammonia is produced from renewable power, wherein the plant includes an electrolysis section for the generation of hydrogen and a hydrogen storage, wherein a standby of the water electrolysis section is controlled by the amount of said renewable power and a standby of the ammonia synthesis loop is controlled by the amount of hydrogen contained in said hydrogen storage, and/or by the amount of renewable power available to the water electrolysis section.
Absstract of: WO2026173104A1
Provided is a method for decomposing water so as to obtain a hydrogen gas and an oxygen gas, the method including: a step (A) for electrolyzing an alkali metal hydroxide aqueous solution containing halide ions so as to generate a hydrogen gas at a cathode and to generate halic acid ions at an anode; and a step (B) for thermally decomposing at least some of a compound selected from the group consisting of the halic acid ions generated in step (A) and halic acid salts generated from at least some of the halic acid ions.
Absstract of: WO2026170256A1
The present disclosure relates to a method for providing thermal energy to a direct air capture system and a carbon capture system. The method for providing thermal energy to a direct air capture system comprises the steps of electrolysing H2O to split H2O into hydrogen and oxygen to produce a first waste heat; transferring the first waste heat to a first working fluid; passing the first working fluid through the direct air capture system to heat the sorbent; desorbing CO2 from the sorbent during heating; and evacuating the CO2 from the direct air capture system. The carbon capture system comprises a direct air capture system having a sorbent; an electrolyser adapted for electrolysing H2O and producing a first waste heat; a first fluid circuit; and a first fluid circuit pump connected to the first fluid circuit for pumping a first working fluid around the first fluid circuit.
Absstract of: WO2026171707A1
A process for the production of e-methanol, including the steps of: producing a stream of hydrogen (311) from water electrolysis (302); converting said stream of hydrogen (311) and a CO2 containing stream (313) in a methanol converter of a methanol synthesis loop (300) producing a stream of crude methanol (314) and optionally a stream of purge gas (50); purifying said stream of crude methanol in a methanol distillation section (301) producing a stream of light ends (33) and a stream of fusel oil (80); the process includes the step of producing a POX effluent (106) by performing a partial oxidation (POX) process to one or more of the following POX feed streams: said stream of light ends (33); said stream of fusel oil (80); said stream of purge gas (50); the invention further discloses a plant for production of e-methanol, a method for controlling a methanol plant and a method for revamping a methanol plant.
Absstract of: WO2026171584A1
A modular ammonia production plant with separate hydrogen compression is disclosed. The ammonia production plant comprises at least - a hydrogen production module comprising a hydrogen-containing substance inlet and a hydrogen outlet, - a nitrogen production module comprising an air inlet and a nitrogen outlet, - a hydrogen compression module comprising a primary hydrogen compressor and a nitrogen compression module comprising a nitrogen compressor or a joint compression module comprising a primary hydrogen compressor and a nitrogen compressor, the primary hydrogen compressor comprising a hydrogen inlet configured to be fluidly coupled to the hydrogen outlet of the hydrogen production module and a pressurized hydrogen outlet and the nitrogen compressor comprising a nitrogen inlet fluidly coupled to the nitrogen outlet of the nitrogen production module and a pressurized nitrogen outlet, - a merging station comprising a hydrogen inlet configured to be fluidly coupled to the pressurized hydrogen outlet of the primary hydrogen compressor, a nitrogen inlet configured to be fluidly coupled to the pressurized nitrogen outlet of the nitrogen compressor and a syngas outlet, the syngas containing hydrogen and nitrogen in a molar ratio 3:1, and - an ammonia synthesis module comprising: - an ammonia synthesis reactor comprising an inlet configured to be fluidly coupled to the syngas outlet of the merging station, and an ammonia-rich gas outlet; wherein the primary hydrogen compressor is
Absstract of: WO2026172460A1
Provided is an electrolytic cell that is used in a hydrogen production device for producing hydrogen from a conductive fluid which contains water, said electrolytic cell comprising: an ion exchange membrane which has a first main surface and a second main surface that is positioned oppositely from the first main surface in the thickness direction; an anode section which is disposed in contact with the first main surface and to which the conductive fluid is supplied; and a cathode section which is disposed in contact with the second main surface and which produces hydrogen from the water contained in the conductive fluid. The anode section and the cathode section each include: a separator which has a plate-shaped central section that is conductive and a plate-shaped outer peripheral section which surrounds the central section; and an electrode which is disposed between the central section and the ion exchange membrane so as to face the central section. Formed in the outer peripheral section of at least one of the anode section and the cathode section are: an opening through which the conductive fluid is supplied or which discharges the hydrogen; and a flow path which connects the opening and the central section. In the central section, a plurality of grooves connected to the flow path are formed with spacing therebetween in width direction. At least one recess is formed in an electrode facing surface, which is a surface of the central section that is positioned between the plu
Absstract of: WO2026172458A1
This electrolytic cell is used in a hydrogen production device for producing hydrogen from a conductive fluid containing water. The electrolytic cell comprises an ion exchange membrane, a cathode, and an anode. Each of the cathode and the anode includes: a separator unit that includes a separator part including a central section and an outer peripheral section surrounding the outer periphery of the central section, and a spacer part sandwiched between the ion exchange membrane and the outer peripheral section; and an electrode that has an outer periphery surrounded by the spacer part. An exhaust opening is formed in the outer peripheral section included in the cathode. A supply opening and a discharge opening are formed in the outer peripheral section included in the anode. A first gap is formed between the outer peripheral surface of the electrode included in the cathode and the inner peripheral surface of the spacer part included in the cathode, or a second gap is formed between the outer peripheral surface of the electrode included in the anode and the inner peripheral surface of the spacer part included in the anode.
Absstract of: AU2025345105A1
An electrolytic hydrogen production system coupled with capturing carbon dioxide from flue gas. The system comprises an absorption device (1), an electrolytic hydrogen production device (2), a first gas-liquid separation device (3) and a second gas-liquid separation device (4). The electrolytic hydrogen production device (2) comprises an anode chamber (21), an intermediate chamber (22) and a cathode chamber (23), which are separated by anion exchange membranes (24). In addition, the present invention further relates to a method for using the electrolytic hydrogen production system coupled with capturing carbon dioxide from flue gas. The method comprises: absorbing carbon dioxide from flue gas by using the absorption device (1); allowing the obtained absorption liquid to enter the anode chamber (21), so as to obtain a carbon-dioxide-containing gas-liquid mixture; allowing the gas-liquid mixture to enter the first gas-liquid separation device (3) to undergo separation, so as to obtain carbon dioxide and a first separation liquid; allowing the first separation liquid to enter the intermediate chamber (22), so as to realize the regeneration of the absorbent under the action of ion exchange; and returning the regenerated absorbent to the absorption device (1) again to continue the absorption of carbon dioxide.
Absstract of: US20260242314A1
0000 Process for the preparation of methanol comprising the steps of (a) preparing a hydrogen feedstock by electrolysis (b) providing a carbon oxide feedstock in periods of operating the electrolysis in step (a) (c) mixing at least part of the hydrogen feed and carbon oxide source consisting of carbon monoxide and/or carbon dioxide feed to obtain a methanol synthesis gas; (d) adjusting the molar content of hydrogen, carbon monoxide and/or carbon dioxide from step (c) to a module M of (H2−CO2)/(CO2+CO) to between 1.9 and 2.2 (e) converting the methanol synthesis gas in one or more boiling water reactors to methanol; in periods without operating the electrolysis in step (a) (f) interrupting the converting of the methanol synthesis gas in the one or more boiling water reactors by heat exchange with boiling water, wherein in step (f) the one or more boiling water reactors are heated by one or more auxiliary heaters to maintain boiling of the water in the one or more boiling water reactors.
Absstract of: US20260243230A1
0000 The invention relates to a system for generating energy in open water, in which an offshore wind turbine is releasably connected to a marine vehicle, which includes a transformer device for converting into lower and/or higher electrical voltage, an electrolysis device for generating hydrogen, and a tank for storing the hydrogen. The invention advantageously provides for dynamic changes between the operating modes of storage and transmission, redundancy and maintainability.
Absstract of: US20260242246A1
The present disclosure is directed to a geothermal hydrogen production and compression system, wherein the system comprises an impure water intake to receive water from a impure water source, at least one geothermal well having a well inlet to receive the impure water from the impure water intake in to the geothermal well and one or more well outlets adapted to return heated impure water from the geothermal well, one or more well outlets being adapted to direct the heated impure water from the geothermal well through a steam engine providing a mechanical output, a purification plant comprising one or more purification chambers for separating impurities from the heated impure water expelled from the steam engine to produce at least some fresh water, one or more discharge outlets to discharge one or more products of the purification plant wherein the fresh water is directed to an electrolyser for electrolysis to produce hydrogen gas, where the hydrogen gas is passed through a hydrogen compressor coupled to the mechanical output and pressurised in a storage apparatus.
Absstract of: US20260242958A1
0000 A ceramic reversible cell including any one or more selected from the group consisting of a perovskite-type metal oxide, a hydrate of the perovskite-type metal oxide and a hydride of the perovskite-type metal oxide, in which the any one or more selected from the group consisting of the perovskite-type metal oxide, the hydrate of the perovskite-type metal oxide, and the hydride of the perovskite-type metal oxide include A (A being any one or more selected from the group consisting of Ba, Sr and Ca), B (B being any one or more selected from the group consisting of Zr, Sn, Ce, Ti and Hf), and M (M being any one or more selected from the group consisting of In, Fe, Cr and Mn) as main metal atoms, and satisfy the predetermined formula and include hydride ions when brought into an equilibrium state by contact with dry hydrogen having a water content of 20 ppm or less in a volume ratio at 500° C. to 900° C.
Absstract of: WO2026172459A1
This electrolysis cell is used in a hydrogen production device for producing hydrogen from a conductive fluid containing water. This electrolysis cell comprises an ion exchange membrane, a cathode part, and an anode part. Each of the cathode part and the anode part includes: a separator unit that includes a separator part including a central part and an outer peripheral part surrounding the outer periphery of the central part, and a spacer part sandwiched between the ion exchange membrane and the outer peripheral part; and an electrode having an outer periphery surrounded by the spacer part. An exhaust port is formed in the outer peripheral part included in the cathode part. A supply port and a discharge port are formed in the outer peripheral part included in the anode part. A first gap is formed between an outer peripheral surface of the electrode included in the cathode part and an inner peripheral surface of the spacer part included in the cathode part. A second gap is formed between an outer peripheral surface of the electrode included in the anode part and an inner peripheral surface of the spacer part included in the anode part. The sum of the widths of the first gaps is greater than the sum of the widths of the second gaps.
Absstract of: WO2026172575A1
This electrolysis cell is used in a hydrogen production device for producing hydrogen from a conductive fluid containing water. The electrolysis cell comprises: an ion exchange membrane; an anode unit to which a conductive fluid is supplied; and a cathode unit that produces hydrogen from water contained in the conductive fluid. The anode unit includes: a separator including a conductive central section and an outer peripheral section; and an electrode disposed between the central section and the ion exchange membrane so as to face the central section. The outer peripheral section has formed therein: a first opening; and a plurality of supply flow paths which connect the first opening and the central section and through which the conductive fluid that was discharged from the first opening flows. The plurality of supply flow paths include: a first flow path having the shortest distance from the first opening to the point of connection with the central section; and a second flow path having the longest distance from the first opening to the point of connection with the central section. A first flow path length difference, which is the difference between the flow path length of the first flow path and the flow path length of the second flow path, is smaller than a first distance difference, which is the difference between the distance from the first opening to the point of connection of the first flow path with the central section and the distance from the first opening to the po
Absstract of: WO2026172118A1
Over the past decade, the importance of green hydrogen production has grown exponentially as the world increasingly seeks to reduce its dependence on fossil fuels. Green hydrogen is hydrogen produced using renewable energy sources, such as solar and wind power, and thus offers a carbon-free alternative to conventional fossil-fuel-based hydrogen production. Alkaline electrolyzers play a central role in green hydrogen production. This technology is one of the oldest and most mature methods of hydrogen production via electrolysis. Alkaline electrolyzers split water into hydrogen and oxygen in a liquid alkaline medium, typically a solution of potassium hydroxide (KOH) or sodium hydroxide (NaOH). The invention relates to the capture of carbon dioxide using am apparatus integrated with such an alkaline electrolyzer.
Absstract of: WO2026173101A1
The present invention relates to a method comprising: a step (A) for electrolyzing an alkali metal hydroxide aqueous solution which contains halide ions and which has a concentration of not less than 1 mol/L to produce hydrogen gas with a cathode and produce halogen acid ions with an anode; a step (B) for pyrolyzing at least some of a compound selected from the group consisting halogen acid ions produced in step (A) and a halogen acid salt produced from at least some of the halogen acid ions; and a step (C) for collecting, as an oxidizing agent, at least some of the halogen acid ions that were not pyrolyzed in the step (B).
Absstract of: WO2026173012A1
Provided is a water electrolysis system enabling mounting of a plurality of electrolytic cells while suppressing deterioration in maintainability. The present invention provides a water electrolysis system comprising a water piping base, a product piping base, and an electrolytic cell unit. The electrolytic cell unit includes an electrolytic cell, a water piping part, a product piping part, and a support. The support is configured to unitize the electrolytic cell, the water piping part, and the product piping part. The water piping part is configured to be connected to the water piping base at a first connection part to constitute water piping through which water to be introduced into the electrolytic cell can circulate. The product piping part is configured to be connected to the product piping base at a second connection part to constitute product piping through which a fluid containing the product discharged from the electrolytic cell can circulate. The electrolytic cell unit is configured to be removable from the water electrolysis system.
Absstract of: DE102025105819A1
Multifunktionselement (12c) für eine aus mehreren Zellstapelelementen (12) bestehende Elektrolysezelle (13) einer Elektrolysevorrichtung (10), bestehend aus einem Polymerschaum (22) und aus von dem Polymerschaum (22) auf-genommenen Metallpartikeln (24).
Absstract of: WO2026172697A1
The present invention provides a hydrogen gas production method and a hydrogen gas production device that make it possible to reduce the production cost of hydrogen gas and to efficiently produce hydrogen gas at a lower cost than in the past. Provided is a hydrogen gas production method that includes a decomposition step A for introducing ammonia into a decomposition tower (12) of an ammonia decomposition unit (10) to obtain a decomposed gas and a purification step B for separating residual ammonia and nitrogen gas from the decomposed gas at a purification unit (20A) to obtain purified hydrogen gas. The hydrogen gas production method is characterized by also including an ammonia heating step C for mixing off-gas that includes the residual ammonia and nitrogen gas separated from the decomposed gas at the purification step B with air, combusting the off-gas at a combustor (31) of an ammonia heating unit (30), and using the combustion heat of the combusted off-gas to heat the ammonia before the ammonia is introduced into the decomposition tower (12).
Absstract of: AU2026210694A1
A hydrogen station 10 includes a water electrolysis device 12 that produces hydrogen gas by an electrolytic reaction consuming power supplied from a commercial power network 90, a compressor 14 that compresses the hydrogen gas produced by the water electrolysis device 12, an accumulator 16 that accumulates the hydrogen gas compressed by the compressor 14, a dispenser 18 that fills a fuel cell vehicle 92 with the hydrogen gas accumulated in the accumulator 16, and a control device 20 that controls a power consumption amount of the water electrolysis device 12 on the basis of a command for adjusting supply and demand of power of the commercial power network 90. ul u l
Absstract of: EP4793410A2
0001 To provide a membrane electrode assembly which is excellent in strength and is capable of reducing the electrolysis voltage when applied to a water electrolysis apparatus, and such a water electrolysis apparatus. 0002 The membrane electrode assembly of the present invention is a membrane electrode assembly for use in a water electrolysis apparatus, comprising an anode having a catalyst layer, a cathode having a catalyst layer, and a polymer electrolyte membrane disposed between the anode and the cathode, wherein the polymer electrolyte membrane comprises a fluorinated polymer having ion exchange groups, and a woven fabric, the aperture ratio of the woven fabric is at least 50%, the denier number of warp yarns and the denier number of weft yarns, constituting the woven fabric, are each independently at least 2, a relation of Y≦240X-170 is satisfied, where the membrane thickness of the polymer electrolyte membrane is Y µm, and the ion exchange capacity of the fluorinated polymer is X meq/g dry resin, the membrane thickness Y of the polymer electrolyte membrane is at least 20 µm and at most 150 µm, and the density of the warp yarns and weft yarns constituting the woven fabric is at least 19.7 yarns/cm (50 yarns/inch).
Absstract of: WO2025048510A1
The present invention relates to a separator in which an anode catalyst layer is coated on one surface of a porous substrate, and an electrochemical cell comprising same, the separator allowing ions to smoothly move through pores of the porous substrate and exhibiting low overpotential due to having the anode catalyst layer coated on one surface thereof.
Absstract of: WO2025076572A1
The invention relates to an electrolytic reaction system (1) for producing process gases in the form of gaseous hydrogen and oxygen, comprising at least three electrode assemblies (2), each of which comprise a plurality of hollow cylindrical electrodes that are arranged coaxially to one another and are positioned one inside the other. At least three electrode assemblies (2) are uniformly distributed about a common central vertical axis (4), and a hollow cylindrical container wall (5) for receiving an electrolyte is provided for each electrode assembly (2). A cover element (7) is supported on the upper end face (6) of each of the container walls (5), and the cover element (7) has through-openings (8) which run in the vertical direction and which are designed to discharge process gases produced within the container walls (5). A collecting hood (9) is provided on the cover element (7) in order to combine process gases exiting the individual through-openings (8). An electromagnetic coil (10) which is designed in the form of a ring and comprises a central air core (11) is received by the cover element (7) or is mounted on the cover element (7) and is aligned such that the central vertical axis (4) of the at least three electrode assemblies (2) passes through the central air core (11).
Absstract of: EP4741052A1
The present disclosure relates to an oxygen evolution reaction(OER) oxide catalyst for anion exchange membrane(MEM) water electrolysis doped with various metal atoms using a coprecipitation method, and a preparation method thereof.
Absstract of: KR20260124681A
본 발명은 원자력 발전소의 출력제어와 연계된 수소 생산 시스템 및 그 제어 방법에 관한 것이다. 시스템은 전력계통 운영자로부터 원전 출력제어 정보를 획득하고, 원자력 발전소의 발전 전력과 소내 소비전력에 기초하여 수전해 장치에 공급 가능한 전환가능전력을 산정하며, 계통 접속점에서 측정되는 순송전 전력이 목표 송전 전력을 추종하도록 복수의 전해 스택군의 소비전력을 제어한다. 복수의 전해 스택군은 빠른 부하 추종을 담당하는 저온 전해 스택군과 원전 2차계통의 증기를 이용하는 고온 전해 스택군을 포함할 수 있다. 고온 전해 스택군은 감발 전력이 없는 동안 원전 추기증기로 핫 스탠바이 상태를 유지하고, 감발 전력이 발생하면 열적 정지 없이 전해전력을 공급받을 수 있다. 감발 전력의 고주파 변동 성분은 저온 전해 스택군에, 저주파 지속 성분은 고온 전해 스택군에 배분될 수 있고, 부하전환 중 전체 수전해 소비전력이 목표값을 유지하도록 중첩 제어될 수 있다. 이에 따라 원전의 안정운전, 계통 출력제어 이행, 수소 생산효율 및 고온 전해 스택의 열적 안정성을 함께 향상시킬 수 있다.
Absstract of: EP4792933A1
0001 A purpose of the present invention is to provide an ammonia decomposition catalyst device with which a conversion of ammonia (NH<3>) can be improved. An ammonia decomposition catalyst device 100 for producing hydrogen (H<2>) through decomposition of ammonia (NH<3>) has a gas-flow upstream-side region 100a and a gas-flow downstream-side region 100b, in which a base density of the gas-flow downstream-side region 100b is a higher than that of the gas-flow upstream-side region 100a.
Absstract of: US20250243139A1
An integrated energy system including a power plant is discussed herein. In some examples, the integrated energy system may include at least one nuclear reactor and electrical power generation system configured to generate steam and electricity, a water treatment plant configured to produce Sodium Hydroxide (NaOH) from salt water, a Sodium Formate (HCOONa) production plant configured to receive the Sodium Hydroxide (NaOH) to produce Sodium Formate (HCOONa), a Thermal Decomposition reactor configured to receive the Sodium Formate (HCOONa) and configured to receive at least a first portion of the steam or at least a second portion of the electricity from the power plant to indirectly heat the Thermal Decomposition reactor to produce Hydrogen (H2), Carbon Dioxide (CO2), and Carbon Monoxide (CO) from the Sodium Formate (HCOONa), and a Methanol (CH3OH) reaction chamber configured to receive the Hydrogen (H2), the Carbon Dioxide (CO2), and the Carbon Monoxide (CO) to produce Methanol (CH3OH).
Absstract of: WO2025078333A1
The present invention relates to an electrode (100) for electrolysis of electrolyte, said electrode comprising: first porous layer (102) permeable to electrolyte and gases produced by the decomposition of electrolyte; a second porous layer (104) permeable to electrolyte and gases produced by the decomposition of electrolyte, said second porous layer (104) being arranged adjacent to the first porous layer (102), wherein the first porous layer (102) comprises Nickel.
Absstract of: EP4793391A1
0001 According to the present invention, an uncoated austenitic steel sheet for an alkaline water electrolysis separator is provided, comprising, by wt%: C: more than 0% and 0.04% or less, Si: more than 0% and 0.4% or less, Mn: more than 0% and 0.5% or less, Cr: more than 0% and 2.0% or less, Ni: 33% to 40%, Co: more than 0% and 4.0% or less, the balance of Fe and other inevitable impurities, wherein a value of the following Formula (1) is 0.83 or less, a surface roughness Ra value is 0.07 µm to 0.25 µm, and corrosion resistance is excellent in an alkaline environment. 9.0 − 0.2495 × Ni + 0.9 × Cr − 0.005 × Co
(wherein Ni, Cr and Co represent the content (wt%) of each element).
Absstract of: WO2025033904A1
The present invention relates to an electrode and a method for manufacturing same, the electrode comprising: a nickel-containing metal substrate; a first sol-gel coating layer formed on at least one surface of the metal substrate; and a second sol-gel coating layer formed on the first sol-gel layer, wherein the first sol-gel coating layer and the second sol-gel coating layer each independently include nickel and iron. According to the present invention, the provided electrode for anion exchange membrane water electrolysis can implement improved electrochemical performance and has excellent durability.
Absstract of: JP2026132816A
0001 【課題】水の分解による水素の生成に用いることのできる有用な光触媒を提供すること。 【解決手段】本発明は、下記一般式(1)で表す化合物と、遷移金属錯体化合物とを含んでなる光触媒である。下記一般式(1)中、各Rは、それぞれ独立に、鎖中にヘテロ原子を含んでもよい炭素数1~30の炭素鎖等であり、各R<1>は、それぞれ独立に、カルバゾリル基等であり、pは、1~10の整数であり、各mは、それぞれ独立に0~2の整数であり、各nは、それぞれ独立に0~2の整数である。 【選択図】なし
Absstract of: WO2025033986A1
The present invention relates to a method for preparing a nickel-based phosphide catalyst for an oxygen evolution reaction of an alkaline water electrolysis anode using sodium hypophosphite (NaH2PO2) substitution and pyrolysis.
Absstract of: WO2025027031A1
The invention provides a process for producing hydrogen by thermal reforming of ammonia in an apparatus comprising an ammonia cracking reactor with a catalyst chamber and a staged combustion unit, wherein the catalyst chamber of the ammonia cracking reactor is heated indirectly by heat exchange with the hot flue gases from the staged combustion unit, comprising the steps of: a) incomplete combustion of a fuel comprising ammonia in the first stage of the staged combustion unit to generate a flue gas stream of elevated temperature T1 in the range of 750 to 2000°C, preferably in the range of 1200 to 2000°C; b) complete combustion of the fuel comprising ammonia in the second stage of the staged combustion unit to generate a flue gas stream of a temperature T3 that is less than T1; c) exchanging heat from the flue gas provided in step b) with the ammonia cracking reactor to raise the temperature in the catalyst chamber to a catalytic cracking temperature T2 in the range of 400 to 1000°C, more preferably in the range of 600 to 800°C; d) subjecting an ammonia stream in the heated ammonia cracking reactor of step c) to a catalytic ammonia-cracking step to yield a thermally cracked stream comprising hydrogen, and e) separating the thermally cracked stream into a reject gas stream and an enriched hydrogen stream and withdrawing the enriched hydrogen stream, wherein T3 is at least 50°C above T2 up to a maximum of 1600°C, and wherein T3 is at least 50°C below T1, and wherein the f
Absstract of: WO2025032310A1
The present invention relates to a methanation method comprising providing an electrolyser system, the electrolyser system (20) comprising an electrolyser (10) that has at least one electrolyser cell (11), at least one fuel input (14) through which fuel enters the electrolyser (10) and at least one offgas output (46) from which offgas exits the electrolyser (10), the method further comprising supplying fuel to the at least one fuel inlet, the fuel comprising at least water and either or both carbon dioxide and carbon monoxide, operating the electrolyser system (20) by powering the electrolyser cell (11) with electricity to electrolyse the fuel in the at least one electrolyser cell (11) such that a part of the water splits into hydrogen and oxygen, wherein the electrolyser (10) is operated at a temperature at or in excess of 150 degrees C, and methanation occurs to the carbon dioxide and/or carbon monoxide in the electrolyser (10). The gas mixture can be released from the at least one offgas output (46) and then passed through a gas separation process to separate at least the methane from the gas mixture. The present invention also relates to an electrolyser system (20) configured to operate using the above method. The electrolyser system (20) comprises a fuel fluid flow path connecting a fuel inlet and a fuel outlet. The method may comprise providing to the fuel inlet a fuel gas containing water and a source of carbon selected from one or more of CO and CO2, operating the ele
Absstract of: CN122577325A
本发明公开了一种制氢系统及其供电控制方法,涉及新能源技术领域。制氢系统包括电解槽、空气加热器、水蒸气发生器、混合器、氢气冷旁通、主电源和备用电源,电解槽的供电输入端分别与主电源和备用电源连接,空气加热器的出气口与电解槽的阴极室进气口相连通,氢气冷旁通的氢气出口与混合器的第一进气口相连通,水蒸气发生器的蒸汽出口与混合器的第二进气口相连通,混合器的出气口与电解槽的阳极室进气口相连通;在控制电解槽的电解槽出口温度和电解槽电压分别达到并稳定在目标出口温度和目标电压后,开启主电源,使电解槽开始产氢,并获取电解槽的产氢量,以基于产氢量使用主电源或使用主电源和备用电源共同为制氢系统供电,直至电解槽终止产氢。
Absstract of: CN122564629A
本发明公开了一种镍钴钼复合电催化剂、制备方法及其应用。该方法采用了简单的两步电沉积的方法,通过在泡沫镍上先后沉积钴和钼,形成复合结构,引入钼后,该催化剂表现出比商业催化剂(Pt/C)更低的过电位,在1 M KOH电解液中达到10 mA cm‑²电流密度仅需20 mV的过电位;并且在10 mA cm‑²电流密度下经过100小时的稳定性测试,电流衰减率仅为0.3%,在碱性电解水析氢反应中的具有优异的性能。本发明提供了一种价格低廉,简单且易制备的电解水析氢催化剂制备方法,为设计高效稳定的电催化析氢催化剂提供了新策略。
Absstract of: JP2026527456A
0001 アンモニアから水素リッチガスを生成するための水素生成装置であって、内壁と、内部容積を画定する外壁とを備える第一のチャンバであって、前記第一のチャンバは、前記内壁と前記外壁との間に配置されたアンモニア分解触媒を含み、前記第一のチャンバは、1つ以上のアンモニアガス入口と1つ以上の未処理分解ガス出口とを有し、前記1つ以上のアンモニアガス入口及び前記1つ以上の未処理分解ガス出口は、前記アンモニアが前記1つ以上のアンモニアガス入口から前記1つ以上の未処理分解ガス出口まで前記第一のチャンバを通って流れ、前記アンモニア分解触媒に接触するように配置される、第一のチャンバと、前記アンモニア分解触媒を加熱するための1つ以上の熱源と、を備え、前記第一のチャンバは、1つ以上のフィンを有し、前記1つ以上のフィンは、前記第一のチャンバの前記内壁と前記外壁との間に配置される、装置。 【選択図】図1
Absstract of: FR3172103A1
L’invention concerne un électrocatalyseur pour la réaction d’évolution d’hydrogène (HER), comprenant un support carboné conducteur, et un matériau catalytique disposé sur le support carboné conducteur, dans lequel le matériau catalytique comprend un complexe de nickel(II) répondant à la formule générale Chem. 4 suivante : Chem 4dans laquelle,R1 et R2 représentent chacun indépendamment un groupe phényle ayant optionnellement un ou plusieurs substituants R3 identiques ou différents, R3 est sélectionné parmi un halogène, un groupe hydroxy, groupe alkyle en C1-C4, un groupe alkoxy en C1-C4, un groupe thioalkyl en C1-C4, un groupe dialkylamino en C1-C4, un groupe cyano, un groupe CF3 et un groupe O-CF3.
Absstract of: US20260235020A1
0000 A method of producing hydrogen and sequestering carbon or sulfur includes generating a fluid including at least one of water, steam, hydrogen sulfide, carbon dioxide and heat as a byproduct of a surface facility and injecting the fluid into a subsurface formation. The subsurface formation can include a porous rock, in various forms of porosity such as intragranular, intergranular, fracture porosity. The method can further include heating the fluid to stimulate an exothermic reaction of the fluid with components of the subsurface rock formation and produce a hydrogen reaction product and one or more of sulfur minerals from the hydrogen sulfide or carbon minerals from the carbon dioxide. The fluid can be heated to between about 25° C. and about 500° C. The method can also include extracting the hydrogen produced from the reaction of the fluid with the subsurface rock formation and mineralizing sulfur or carbon in the porous rock.
Absstract of: US20260234820A1
0000 The present disclosure relates to systems and methods for controlling hydrogen stack power and load. The systems include at least one hydrogen stack, a pressure sensor, and a controller, wherein the controller is operable to increase or decrease the power to the at least one hydrogen stack in response to a change in pressure. The methods include generating hydrogen using at least one hydrogen stack, measuring the pressure of the generated hydrogen, and increasing or decreasing the power supplied to the at least one hydrogen stack in response to an increase or decrease in the pressure.
Absstract of: US20260234024A1
A process for process for preparing a metal hydroxide comprising at least one metal chosen from nickel, cobalt, manganese, lithium and aluminum. The process comprises: reacting a metal sulfate and/or a metal nitrate comprising at least one metal chosen from nickel, cobalt, manganese, lithium and aluminum with a base chosen from LiOH, NaOH, KOH, RbOH, CsOH, Mg(OH)2, Ca(OH)2, Sr(OH)2, or Ba(OH)2 and optionally a chelating agent in order to obtain a solid comprising the metal hydroxide and a liquid comprising at least one of Li2SO4 Na2SO4, K2SO4, Rb2SO4, Cs2SO4, MgSO4, CaSO4, SrSO4, BaSO4, LiNO3 NaNO3, KNO3, RbNO3, CsNO3, Mg(NO3)2, Ca(NO3)2, Sr(NO3)2 and Ba(NO3)2,separating the liquid and the solid from one another to obtain the metal hydroxide;submitting the liquid comprising at least one of Li2SO4 Na2SO4, K2SO4, Rb2SO4, Cs2SO4, MgSO4, CaSO4, SrSO4, BaSO4, LiNO3 NaNO3, KNO3, RbNO3, CsNO3, MgNO3, CaNO3, SrNO3 and BaNO3 to an electromembrane process for converting the least one of Li2SO4, Na2SO4, K2SO4, Rb2SO4, Cs2SO4, MgSO4, CaSO4, SrSO4, BaSO4, LiNO3 NaNO3, K2NO3, RbNO3, CsNO3, Mg(NO3)2, Ca(NO3)2, Sr(NO3)2 and Ba(NO3)2 into at least one of LiOH, NaOH, KOH, RbOH, CsOH, Mg(OH)2, Ca(OH)2, Sr(OH)2, and Ba(OH)2; andreusing the at least one of LiOH, NaOH, KOH, RbOH, CsOH, Mg(OH)2, Ca(OH)2, Sr(OH)2, and Ba(OH)2 obtained by the electromembrane process for reacting with the metal sulfate and/or the metal nitrate.
Absstract of: US20260235084A1
0000 According to aspects of the disclosed subject matter, methods and apparatuses are provided to reduce combustion time and/or combustion temperature in an internal combustion engine. In an exemplary embodiment, intake air and oxygen-rich gas are introduced upstream of a turbofan, wherein the amount of oxygen rich gas provided to the internal combustion engine is controlled in a manner that is proportional to the engine speed.
Absstract of: US20260234673A1
A composition that produces hydrogen includes a nanoparticle or plurality of nanoparticles; an external source of electrons such as an electrogenic bacterium or a plurality of electrogenic bacteria and a carbon source; and an aqueous medium. The nanoparticles and the aqueous medium are combined in a mixture and, upon exposure to electromagnetic radiation with a wavelength in the absorption profile of the nanoparticles, the nanoparticles generate an electron that can reduce a proton in the aqueous medium. The source of electrons is capable of reducing the nanoparticles. The nanoparticles may comprise cadmium chalcogenide or water-soluble cadmium chalcogenide quantum dots. The nanoparticles may also comprise core-shell nanoparticles, nanorods; dot-in rods, Zn-based II-VI core quantum dots, and nanoplatelets including core-crown and core-shell nanoplatelets. The electrogenic bacterium or bacteria may comprise Shewanella oneidensis, a Geobacter species or any bacterium capable of extracellular electron transfer.
Absstract of: WO2026166566A1
Preparation of phosphate-modified carbon quantum dot nickel-based catalyst and use thereof in alkaline seawater electrolysis, belonging to the technical fields of electrocatalysis and hydrogen production by seawater electrolysis. The method of preparing the present phosphate-modified carbon quantum dot nickel-based catalyst comprises the following steps: mixing citric acid and urea in water to obtain a carbon quantum dot precursor solution; and mixing the carbon quantum dot precursor solution, phytic acid, and a nickel substrate, then allowing for the reaction thereof so as to obtain the phosphate-modified carbon quantum dot nickel-based catalyst. In the present invention, a phosphate-modified carbon quantum dot nickel-based catalyst is designed by introducing a composite modification layer of carbon quantum dots and phosphate onto the surface of a nickel substrate. The synergistic effect of PO4 groups and CDs in the catalyst markedly improves OER activity, thereby allowing the catalyst to exhibit excellent oxygen evolution reaction activity and long-term stability in alkaline seawater containing Br- and Cl-.
Absstract of: AU2024424555A1
Provided is a hydrogen production system (100) which comprises: an electrolysis module (19) that supplies steam to a hydrogen electrode and produces hydrogen through steam electrolysis; a steam supply unit (20) that supplies steam to a hydrogen electrode (11); an air supply unit (70) that supplies air to an oxygen electrode (12); a hydrogen supply pipe (43) that supplies hydrogen to the oxygen electrode (12); a power supply unit (18) that supplies power to the electrolysis module (19); and a control device (80) that controls the hydrogen production system (100). The control device (80) controls the power supply unit (18) so as to start supplying power to the electrolysis module (19) in response to the temperature of the electrolysis module (19) exceeding Temp4 that is lower than the ignition temperature of hydrogen.
Absstract of: AU2025215475A1
A hydrogen production facility is disclosed, comprising a plurality of electrolyser stacks arranged for electrolyzing water using an electrolyte and for generating at least a hydrogen-aqueous solution mixture; and a hydrogen separator arrangement for producing a flow of hydrogen from the hydrogen-aqueous solution mixture; wherein the hydrogen separator arrangement comprises a plurality of first stage hydrogen collector separators, the first stage hydrogen collector separators being fluidly coupled to a respective sub-set of the plurality of electrolyser stacks; and wherein the plurality of first stage hydrogen collector separators are fluidly coupled to a downstream hydrogen buffer vessel. A related method is further disclosed.
Absstract of: US20260233146A1
0000 The present invention relates to a process for purifying a hydrogen stream polluted with water, oxygen and possibly nitrogen, said process involving placing the hydrogen stream to be purified in contact with a zeolite-based adsorbent material comprising at least one metal chosen from the metals of columns 3 to 12 of the Periodic Table of the Elements, in zero-valent metal form, or in oxidized or reduced form, and recovering the purified hydrogen stream. 0000 The invention also relates to the use of a zeolite-based adsorbent material comprising at least one metal from columns 3 to 12 of the Periodic Table of the Elements for the purification of hydrogen, and to the use of the hydrogen thus purified in industrial processes.
Absstract of: US20260233991A1
0000 A hydrogen carrier manufacturing system includes a hydrogen manufacturing device configured to manufacture hydrogen by using power; a hydrogen tank configured to store the hydrogen manufactured by the hydrogen manufacturing device; and a plurality of hydrogen carrier manufacturing devices configured to convert the hydrogen stored in the hydrogen tank into different types of hydrogen carriers.
Absstract of: AU2025215031A1
Aspects of the present disclosure relate to a hydrogen production facility. The hydrogen production facility includes one or more electrolyser stacks to electrolyze water using an electrolyte and generate a hydrogen-aqueous solution mixture and an oxygen-aqueous solution mixture, the one or more electrolyser stacks comprising a plurality of membranes. The facility also includes a hydrogen separator to produce a flow of hydrogen from the hydrogen-aqueous solution mixture and an oxygen separator to produce a flow of oxygen from the oxygen-aqueous solution mixture. The hydrogen separator comprises a hydrogen gas-liquid separation device and a hydrogen coalescing device. The oxygen separator comprises an oxygen gas-liquid separation device and an oxygen coalescing device.
Absstract of: US20260233204A1
0000 A catalyst for decomposition of ammonia and a method for decomposition of ammonia using the catalyst. The catalyst includes a carrier and a catalytically active components supported on the carrier, the catalytically active components including i) ruthenium (Ru) as a first metal; ii) a second metal; and iii) a third metal, wherein each of the second metal and the third metal is independently one or more selected from the group consisting of lanthanum (La), cerium (Ce), aluminum (Al), and zirconium (Zr), the amount of the first metal ruthenium is 0.1 to 1 part by weight, based on 100 parts by weight of the total catalyst, the porosity is 30 to 60%, and the median value of pore diameter is 50 to 200 μm.
Absstract of: WO2026168071A1
This water electrolysis system comprises: a water separation tank that is connected to a water electrolysis cell stack and that stores water discharged therefrom; an external water supply path that supplies normal-temperature external water; a water circulation path that is provided with a water circulation pump, that is connected to the water separation tank and the external water supply path, and that circulates the water in the water separation tank via the external water supply path; an ion exchange resin provided on the downstream side of a part where the external water supply path merges with the water circulation path; a cooling unit that cools the water in the water circulation path so that the temperature of the water that merges with the external water and flows into the ion exchange resin, and has a temperature higher than normal temperature, falls below a prescribed ion exchange resin upper limit temperature; and a water supply path that serves as a path separate from the water circulation path, said water supply path being provided with a water supply pump, heating the water from the water separation tank through use of a heating unit, and supplying the heated water to the water electrolysis cell stack.
Absstract of: AU2025215616A1
A hydrogen production facility is disclosed, comprising: a plurality of electrolysis systems to electrolyze water using lye; and a mutualized lye circulation system coupled with the plurality of electrolysis systems to circulate the lye among the plurality of electrolysis systems to facilitate electrolyzing the water, the lye circulation system comprising one or more pumps, wherein a number of the one or more pumps is less than a number of electrolysis systems of the plurality of electrolysis systems. A hydrogen production facility comprising first and second modular structures is also disclosed.
Absstract of: US20260234819A1
Provided is an electrolysis system including an electrolysis module; a water vapor supply system that supplies water vapor to a hydrogen electrode; a hydrogen recovery system that recovers hydrogen-enriched water vapor; an air supply system that supplies air to an oxygen electrode; an oxygen recovery system that recovers exhaust air; a hydrogen-enriched water vapor release system that releases hydrogen-enriched water vapor from the hydrogen recovery system into the atmosphere; an exhaust air release system that releases exhaust air from the oxygen recovery system into the atmosphere; a hydrogen-enriched water vapor discharge valve disposed in the hydrogen-enriched water vapor discharge system; and an exhaust air discharge valve disposed in the exhaust air discharge system, wherein the opening degrees of the hydrogen-enriched water vapor discharge valve and the exhaust air discharge valve are controlled to be adjustable when the electrolytic module is stopped.
Absstract of: AU2025216381A1
The disclosure refers to a computer-implemented method for heating up electrolytic units. The method comprises determining whether some electrolytic units of an electrolysis plant require heating up to have them at a temperature within a predetermined range in a future time span; controlling the electrolytic units to power them up based on first electric power available in a current time span; heating up the electrolytic units to have them at the temperature within the predetermined range in the at least one future time span; and repeating the steps such that the heating up is determined for one or more time spans that occur at the same time and/or later than the future time span, thereby repeatedly controlling the temperature of the electrolytic units to be at a temperature within the predetermined range in the future time spans.
Absstract of: AU2025216225A1
A method is disclosed for producing an electrode (4) having a noble metal catalyst for alkaline water electrolysis. The method comprises: (S1) providing the electrode substrate (1); (S2) providing a matrix material (2) and a catalyst material (3) as starting materials for the coating; (S3) mixing the matrix material (2) and the catalyst material (3); and, (S4) coating the substrate (1) with the mixture of matrix material (2) and catalyst material (3) by means of high-velocity oxygen fuel spraying (HVOF). A correspondingly produced electrode (4), an electrochemical cell (10) comprising said electrode, and an electrolyser (20) are also specified.
Absstract of: US20260234823A1
An arrangement for gas-liquid separation includes first and second gas separators for first and second gases, each having one vessel. The vessels have either the same or a different vessel volume, are in hydraulic communicating connection for a liquid via a connecting conduit and are at the same height. The operational configuration is such that a predefined standard fill level of the liquid is established when the pressure in the vessels is equal, and so a liquid volume is provided at the standard fill level, the vessel volume is composed of the liquid volume and the corresponding gas volume, and the liquid volume in the vessels is greater than the corresponding gas volume. A method of operating an electrolyzer, in particular in safe operation of an electrolysis plant with an electrolyzer for alkaline electrolysis, and an electrolysis plant, are also provided.
Absstract of: US20260234821A1
Provided is an electrolysis cell system with energy efficiency improved. An electrolysis cell system (10) includes: an electrolysis cell (11) that has an anode and a cathode and generates hydrogen on the cathode and oxygen on the anode by electrolyzing steam supplied to the cathode; a supply line (20) that supplies air that controls the temperature of the electrolysis cell (11), to the electrolysis cell (11); an exhaust line (30) through which the air exhausted from the electrolysis cell (11) flows; a circulation line (40) that guides the air exhausted to the exhaust line (30), to the supply line (20); and a supply air temperature control heat exchanger (28) that controls the temperature of the air to be supplied to the electrolysis cell (11).
Absstract of: US20260234824A1
An electrolyser system (10) and a method of operating an electrolyser system (10), the electrolyser system (10) comprising an electrolyser (16) and a metal hydride or adsorption-desorption compressor (24), wherein the electrolyser (16) has at least one electrolyser cell with a steam input (22) and at least one gas output. The method comprises supplying steam through a first side of the electrolyser cell at the steam input (22), operating the electrolyser (16) to split part of the steam into hydrogen and oxygen in the at least one electrolyser cell, venting a mixture of the hydrogen and the remaining steam from the first side of the electrolyser cell at the at least one gas output (18), passing the mixture into the metal hydride or adsorption-desorption compressor (24), and cryo-adsorbing the hydrogen of the mixture in the metal hydride or adsorption-desorption compressor (24) to compress the hydrogen and desorbing the compressed hydrogen from the metal hydride or adsorption-desorption compressor (24). The electrolyser system (10) is connected
Absstract of: US20260234016A1
The present invention relates to a pyrogenic process for manufacturing metal oxides or metalloid oxides wherein a metal precursor and/or a metalloid precursor is introduced into a flame formed by burning a gas mixture comprising oxygen and hydrogen, wherein at least a part of the hydrogen has been obtained from electrolysis of water or an aqueous solution, using electrical energy, at least a part of which has been obtained from a renewable energy source, and wherein at least a part of the thermal energy of the flame is transferred to a first heat transmission medium by means of at least one exchanger, thereby heating the first heat transmission medium to a maximal temperature in the range between 8° and 150° C.
Absstract of: US20260234822A1
0000 A control unit for a Power-to-Hydrogen (PtH) plant is provided. The control unit includes at least one model and is configured to: calculate maximum efficiency point tracking of the PtH plant by solving an objective function having a predetermined hydrogen production rate of the PtH plant or a predetermined amount of energy input to the PtH plant using the at least one model, wherein the control unit receives measured parameters indicative of status of components of the PtH plant as an input to the at least one model; determine one or more set points for a coordinated operation of the components of the PtH plant based on a solution obtained by solving the objective function; and provide the one or more set points to one or more of the components of the PtH plant to operate the PtH at the maximum efficiency point.
Absstract of: US20260234085A1
The present disclosure relates generally to integrated processes for the production, storage, and use of methanol. In one aspect, the present disclosure provides a process for producing a H2/CO stream, the process comprising for a first period of time, synthesizing methanol by hydrogenation of CO2, and decomposing a second feed stream including the methanol to form CO and H2; and for a second period of time, decomposing a third feed stream comprising stored methanol to form CO and H2. A synthesized methanol fraction of the second feed stream is substantially greater than a synthesized methanol fraction of the third feed stream.
Absstract of: US20260234815A1
0000 The present invention relates to a porous water-splitting electrode including a support coated with a carbon nanotube assembly and a catalytic active layer formed on the coated support; a method of manufacturing the same; and a water electrolysis device including the same.
Absstract of: WO2026167518A1
Apparatus (100) for the production of hydrogen by means of electrolysis of water, comprising a central body (120) consisting of a refractory chamber and comprising: a first zone (101) comprising a burner; a second zone (102) directly connected with the first zone (101) and arranged downstream of the latter, provided with devices (111) for controlling the temperature of the combusted gas exiting from said first zone and for regulating and delivering a coolant; and a third zone (103), directly connected with the second zone (102), comprising a high-temperature solid oxide electrolytic cell (SOEC), said apparatus (100) further comprising: upstream of the central body (120) at least one supply line (104), (105) and (106) for respectively supplying at least one fuel; oxygen and a diluent, and directly connected with the third zone (103) of the central body: an outlet line (107), and (108) for hydrogen and any carbonaceous combusted gases; and oxygen.
Absstract of: US20260235369A1
A radiator includes a base, a tubular structure, a plurality of fins and a spiral structure. The base has a water input port and a water output port. The tubular structure is coupled to the base and is further connected with the water input port and the water output port. A spiral structure is arranged inside the tubular structure, or the inner surface of the tubular structure has a delay structure formed by a plurality of bumps for improving heat dissipation efficiency of water. The tubular structure runs through the plurality of fins. In addition, the radiator of the present invention is applied to a hydrogen generator. The base of the radiator is directly and integrally formed with the upper cover of the water tank of the hydrogen generator, and the assembly can be completed only by coupling the base to the tube, thereby reducing the assembly process.
Absstract of: US20260237702A1
0000 A power generation system includes an electrolyzer system configured to generate hydrogen using power received from a power grid, a hydrogen storage device configured to store generated hydrogen, a fuel cell system configured to generate power for a load using at least one of hydrogen received directly from the electrolyzer system, hydrogen received from the hydrogen storage device, or a hydrocarbon fuel received from a hydrocarbon fuel supply, and a controller configured to determine a CO<2 >per kWh power grid emission rate (GER) of a power grid electrically connected to the power system, and control operation of the fuel cell system and the electrolyzer system based on a comparison between the GER, a CO<2 >per kWh hydrocarbon fuel (e.g., natural gas) emission rate of the fuel cell system (NER), and a CO<2 >per kWh target emission rate (TER) that is less than the NER.
Absstract of: WO2026167416A1
The underlying invention is related to a device and a process for the direct production of an energy storing fluid from a reactant and an electrolyte in an electrochemical twin reactor, comprising a first reactor part which has at least one anode and an electrolyte for dissolving the reactant and a second reactor part which is comprising at least one further anode and a further electrolyte as a hydrogen source.
Absstract of: WO2026167020A1
The invention relates to a method for preparing methanol, comprising the method steps of: a) acidifying seawater and heating same to at least 45°C, b) removing oxygen from the gas mixture obtained in step a) while preserving carbon dioxide, c) distilling some of the low-carbon-dioxide seawater remaining in step a) to obtain distilled water and brine, d) electrolysing the distilled water, e) obtaining acid and an alkaline residue from the brine, f) using the acid obtained in step e) to acidify the seawater in step a), g) recovering at least some of the waste heat produced in steps b) to e) and using same for heating the seawater in step a), h) synthesising methanol from the hydrogen from step d) and the carbon dioxide from step b) and separating the methanol from the product mixture.
Absstract of: US20260234818A1
0000 Systems, methods, and devices for enhancing catalyst layer performance in electrolytic cells are described. The enhanced catalyst layers include a catalyst mixture having catalyst particles and corrosion-resistant, conductive nanoparticles to optimize interfacial contact and reduce in-plane discontinuities even at low areal loadings of catalyst particles. For example, a catalyst layer includes a matrix with a homogenous mixture of catalyst particles and corrosion-resistant, conductive nanoparticles. The catalyst particles are configured to promote water electrolysis. The catalyst particles include iridium and have a high surface area. The corrosion-resistant, conductive nanoparticles are configured to resist oxidation, to reduce packing discontinuities of the catalyst particles, and to provide an electrically conductive bridge between the catalyst particles. The matrix is configured to support the catalyst particles and the corrosion-resistant, conductive nanoparticles.
Absstract of: DE102025105318A1
Die Erfindung betrifft eine katalysatorbeschichtete Membran (100) mit einer Kathode (5a), einer Anode (5b) und einer zwischen der Kathode (5a) und der Anode (5b) liegenden lonomermembran (2), zur Anwendung in der Wasserelektrolyse, wobei die lonomermembran (2) eine erste Oberfläche (2a) und eine zweite Oberfläche (2b) aufweist und die erste Oberfläche (2a) eine erste aktive Fläche (3a) und die zweite Oberfläche (2b) eine zweite aktive Fläche (3b) aufweist, wobei die erste aktive Fläche (3a) und die zweite aktive Fläche (3b) jeweils mit einer Katalysatorschicht beschichtet sind; wobei die erste aktive Fläche (3a) von einer ersten passiven Fläche (4a) und die zweite aktive Fläche (3b) von einer zweiten passiven Fläche (4b) umgeben ist; die katalysatorbeschichtete Membran (100) ferner umfassend eine Folie (12), die einen Außenumfang (11) der lonomermembran (2) umgibt ohne mit der lonomermembran (2) zu überlappen, wobeia) wenn eine Schichtdicke der Folie (12) größer ist als eine Schichtdicke der lonomermembran (2), ein Unterschied der Schichtdicke der Folie (12) und der Schichtdicke der lonomermembran (2) in Schichtdickenrichtung (Z), senkrecht zur Schichtausdehnungsrichtung (XY), weniger als 50 µm, bevorzugt weniger als 30 µm, weiter bevorzugt weniger als 20 µm, noch weiter bevorzugt weniger als 10 µm und am meisten bevorzugt weniger als 5 µm beträgt undb) wenn die Schichtdicke der lonomermembran (2) größer ist als die Schichtdicke der Folie (12), ein Unt
Absstract of: WO2026170113A1
A method for hydrogen production includes providing an aqueous solution comprising ammonia, generating a spray in a reaction chamber from the aqueous solution, the spray comprising water microdroplets, and collecting hydrogen from the reaction chamber produced via decomposition of the ammonia along a gas-liquid interface of the water microdroplets.
Absstract of: GB2703723A
A method of producing hydrogen may comprise, receiving an ammonia fuel source and an oxidised first form of a metal oxide at a first reactor 11, and reacting to produce a second form of the metal oxide. The second form of the metal oxide may be transferred to a second reactor 12 and reacted with a water supply to form hydrogen and a third form of the metal oxide. The third form the metal oxide may be transferred to a third reactor 13 and reacted with a supply of air and/or oxygen to produce the oxidised first form of the metal oxide, which is then transferred to the first reactor. The metal oxide may be circulated through the three reactors in a flow loop. The metal oxide is preferably iron oxide, where the first form is Fe2O3, the second form is Fe/Fex-σOy-σ, and the third form is Fe3O4. Figure 1
Absstract of: EP4790030A1
Provided is a zero-carbon glass furnace process, a system required for the process includes a photovoltaic power generation unit, an air separation unit, a water electrolysis hydrogen production unit, a mixer, a methanation unit, a first waste heat boiler, a reforming unit, a glass furnace, a second waste heat boiler, and a dedusting and desulfurization unit. The present disclosure adopts green electricity to produce green oxygen, green nitrogen and green hydrogen; flue gas of the glass furnace is circularly enriched into a high concentration of carbon dioxide (95.0v% or higher), which is methanized with green hydrogen to produce methane, and the methane is reformed with carbon dioxide and water vapor to produce carbon monoxide and hydrogen; the carbon monoxide and hydrogen are used as fuel of the glass furnace, the oxygen and carbon dioxide are mixed into carbon-based enriched oxygen as a combustion aid of the glass furnace, and the excess carbon dioxide is sold externally, achieving the purpose of green, energy-saving, almost nitrogen oxide-free and zero carbon.
Absstract of: WO2025037092A1
A membrane-electrode assembly for a water electrolyser is provided. The membrane- electrode assembly comprises a polymer electrolyte membrane with a first face and a second face; an anode catalyst layer on the first face of the membrane, the anode catalyst layer comprising an oxygen evolution reaction catalyst; and a porous web of polymer fibres in contact with the anode catalyst layer, the polymer fibres comprising a conductive metal additive.
Absstract of: WO2025012373A1
The invention relates to porous oxidic materials, which contain niobium and/or the heavy homolog thereof, tantalium, of oxidation number +5, and to the use thereof. The invention also relates to iridium-containing (electro-)catalysts, which comprise a porous oxidic group 5 element material, in particular a porous oxidic niobium(V)- and/or tantalium(V)-containing material. The invention further relates to the use of (electro-)catalysts of this type.
Absstract of: EP4790015A1
0001 Die vorliegende Erfindung betrifft ein Verfahren zur Gewinnung von atomarem Wasserstoff aus einem Rohgas. Weiterhin wird atomarer Wasserstoff, erhältlich gemäß dem erfindungsgemäßen Verfahren bereitgestellt. Schließlich ist die vorliegende Erfindung auf ein Verfahren zur Herstellung von elementarem Metall aus einem Metalloxid mit Hilfe von atomarem Wasserstoff gerichtet.
Absstract of: EP4790170A1
A control device includes a step of determining a current command value to be applied to an electrolysis stack; and a step of determining a pure water adjustment amount command value for adjusting a pressure or/and a flow rate of water to be supplied to the electrolysis stack based on the current command value, and includes a step A of causing an actually measured value of the pressure or/and the flow rate to reach a second pure water adjustment amount command value (pure water adjustment amount command value w2) from a first pure water adjustment amount command value (pure water adjustment amount command value w1) before an actually measured value of a current applied from a power converter to the electrolysis stack reaches a second current command value (current command value c2) from a first current command value (current command value c1) when the current command value is changed from the first current command value to the second current command value that is a different value and the pure water adjustment amount command value is changed from the first pure water adjustment amount command value to the second pure water adjustment amount command value that is a different value.
Absstract of: EP4534727A1
The present invention relates to a tightening apparatus for selectively opening and closing respective adjacent electrolysis cells in an electrolyser. The tightening apparatus comprises: a movable member moveable in a first direction and a second direction, the first direction being a direction in which the cells are to be closed each other and the second direction being an opposite direction to the first direction; at least one actuator configured to move the movable member selectively in the first and second directions; a pressure plate arranged on the first direction side with respect to the movable member; and a spacer arranged between the pressure plate and the movable member.
Absstract of: EP4534726A1
0001 The present invention relates to a tightening apparatus for selectively opening and closing respective adjacent electrolysis cells in an electrolyser. The tightening apparatus comprises: a movable member moveable in a first direction and a second direction, the first direction being a direction in which the cells are closed each other and the second direction being an opposite direction to the first direction; at least one main actuator configured to move the movable member selectively in the first and second directions; a pressure plate arranged on the first direction side with respect to the movable member; and a sub-actuator configured to move the pressure plate selectively in the first and second directions with respect to the moveable member.
Absstract of: EP4790295A1
0001 Provided is a multilayer resin pipe suitable for use in a water electrolysis system operating at high voltage, a water electrolysis system including the multilayer resin pipe, and a method of transporting hydrogen using the multilayer resin pipe. The multilayer resin pipe includes an electrically insulating main pipe, an electrically insulating pressure-resistant layer covering an outer surface of the main pipe, an electrically insulating gas barrier layer covering an inner surface of the main pipe, and an electrically insulating elution-suppressing layer covering an inner surface of the gas barrier layer.
Absstract of: WO2025080121A2
The present invention discloses an electrolyser for water splitting in hydrogen/oxygen production and methods thereof. The electrolyser comprises a first electrode plate (100) coated with a first catalyst comprising a first ion transfer opening (101) formed therethrough along a first lateral axis of the first electrode plate (100); a second electrode plate (200) coated with a second catalyst comprising a second ion transfer opening (201) formed therethrough along a second lateral axis of the second electrode plate (200); and an electrically insulative adhesive layer (300) configured for securing together the first electrode plate (100) and the second electrode plate (200) in a face-to-face manner or a back-to-face manner, forming separate compartments each for a hydrogen gas and an oxygen gas resulting from the water splitting that provide immunity against any mixing of the hydrogen gas and the oxygen gas at any level of an electrical power supply.
Absstract of: CN122543083A
0001 本申请涉及电解水制氢领域,并提供了一种过渡金属单原子多孔碳基贵金属催化剂的制备方法及应用,方法包括:制备过渡金属掺杂ZIF‑8前驱体;向过渡金属掺杂ZIF‑8前驱体中加入模板剂的醇水溶液,研磨并干燥,经热解处理,冷却,经水洗、抽滤,制得富含介孔的过渡金属‑氮‑碳复合材料;将富含介孔的过渡金属‑氮‑碳复合材料与氨气源前驱体混合,于惰性气氛下进行热解处理,制得富含微孔和介孔的过渡金属‑氮‑碳复合材料;采用化学气相沉积法,得到过渡金属单原子多孔碳基贵金属催化剂。上述的制备方法,克服现有阴离子交换膜电解水阴极催化剂在高电流密度下存在的活性位点易团聚失活、气泡排阻严重以及三相界面传质极化高的问题。
Absstract of: CN122540802A
0001 本发明公开了一种固体产氢颗粒及其在植物抗旱中的应用方法,属于农业抗旱技术领域;该固体产氢颗粒由产氢核芯和速溶控释包膜层组成,产氢核芯含供氢剂、促渗分散剂、粘结剂和产氢速率调节剂,包膜层含聚乙烯醇、聚乙二醇、海藻酸钠和叶面亲和改性剂;应用时将颗粒按比例溶于灌溉水中,搅拌即形成高浓度富氢水喷施液,立即喷施于植物叶片;本发明的颗粒专为叶面喷施设计,实现即溶即用,喷施液具有良好的叶面铺展和滞留性能,氢气叶片吸收率高,抗旱效果显著优于传统富氢水喷施和固体产氢材料埋土施用方式,操作简便,易于大面积推广。
Absstract of: CN122543093A
本发明涉及电解水领域,公开了一种IrRu/TiON酸性析氧反应电催化剂的制备方法和应用。本发明IrRu/TiON酸性析氧反应电催化剂的制备方法包括:1)TiON多孔纳米带的制备:TiO2、NaOH和表面活性剂经水热反应制得钛酸钠纳米带;将钛酸钠纳米带分散于酸溶液中经离子交换反应得到氢钛酸纳米带;将氢钛酸纳米带置于氮气气氛中氮化,得到TiON多孔纳米带;2)IrRu/TiON酸性析氧反应电催化剂的制备:将Ir前驱体和Ru前驱体分散于多元醇中,加入TiON多孔纳米带,经还原反应,得到IrRu/TiON酸性析氧反应电催化剂。本发明通过优化制备方法制得了得到催化活性更好、稳定性更好的IrRu/TiON酸性析氧反应电催化剂,可将其应用于质子交换膜水电解中。
Absstract of: CN122538098A
0001 本发明公开了一种基于In掺杂诱导各向异性晶格畸变的ZnO基压电催化材料及其制备方法与应用,涉及压电催化与功能氧化物材料技术领域。本发明通过适量In掺杂提高ZnO的压电催化性能。具体地,In<3+>取代Zn<2+>进入ZnO晶格形成固溶体,由于In<3+>离子半径大于Zn<2+>,引起晶格畸变;该畸变在晶体内部形成局域应变场,并在c轴方向表现出各向异性增强;在机械振动作用下,该结构更易产生较高的压电极化电势;增强的压电势促进电子‑空穴对分离并抑制复合;同时,In掺杂提供施主能级,提高材料导电性;二者协同作用显著提升材料压电催化效率。
Absstract of: CN122543092A
0001 本发明公开了一种用于酸性析氧反应的钌基核壳催化剂及其制备方法与应用。所述制备方法包括:使包含六亚甲基四胺、聚氧丙烯聚氧乙烯共聚物、金属源、水和乙二醇的混合反应体系进行水热反应,制得金属有机物;其中,所述金属源包括钌盐及钴盐;以及,对所述金属有机物进行煅烧处理,制得用于酸性析氧反应的钌基核壳催化剂。本发明提供的催化剂能够维持高的催化活性和优异稳定性,能够实现酸性环境下的电催化析氧反应。
Absstract of: CN122543100A
本发明公开了一种镍铁基催化电极及其制备方法和应用,属于析氧催化电极技术领域。本发明将泡沫镍采用HCl溶液超声清洗、洗涤、干燥得到预处理泡沫镍;将预处理泡沫镍浸泡于FeCl3溶液中,然后取出洗涤、干燥得到NiFe LDH催化电极;将NiFe LDH催化电极浸泡于NaBH4溶液中,然后取出洗涤、干燥得到NiFe LDH@NiFeB复合催化电极。本发明通过浸渍腐蚀结合还原在电极表面得到NiFe基两相催化电极,LDH具有较大的比表面积,活性位点多,能加快活性物质的吸附与转化,而原位还原得到的NiFe B合金具有较高的电导率,能降低界面电阻,加快电子传输,提高电极导电性,优化电极析氧性能;同时由于NiFeB合金与NiFe LDH间存在的费米能级差异,促进内建电场的产生,加快电子定向迁移,助力提升析氧性能。
Absstract of: CN122543082A
本发明属于海水电解制氢技术领域,具体涉及一种海水电解析氢电极及其制备方法与应用。所述电极包括基底和包覆在基底表面的催化剂层;所述催化剂层由硼氧化物和氮化钼酸钴组成,所述硼氧化物负载在氮化钼酸钴表面,所述氮化钼酸钴中,氮掺杂在钼酸钴的晶格内。本发明电极N掺杂进了CoMoO4的晶格之中,B以氧化物的形式均匀负载于CoMoN的表面,二者协同调控Co的电子结构使其位于一个有助于H2O分子解离的最优态。同时,B与N通过捕获‑转移机制实现了对界面pH的动态调控,使得阴极催化HER的过程中局部的pH始终稳定在9以下,抑制了钙镁氢氧化物的沉积。
Absstract of: CN122543095A
0001 本发明涉及光电化学领域,公开了一种钨掺杂钒酸铋单晶电极及其制备方法,其中,单晶电极包括:绝缘支撑衬底;设置在绝缘支撑衬底之上指定区域的导电层;贴合在导电层之上的钨掺杂钒酸铋单晶层;钨掺杂钒酸铋单晶层的表面粗糙度Sa为0.5 nm~5.0 nm,厚度为0.2mm~1mm;钨掺杂钒酸铋单晶层的周边使用绝缘防水材料进行封装,并且绝缘防水材料覆盖所述导电层的外露区域。本发明可以提高单晶电极的化学稳定性和光分解水能力。
Absstract of: CN122543077A
0001 本发明涉及催化电极材料制备技术领域,具体是一种镍钽合金催化电极及其制备方法与应用,首先将镍源、钽源粉末与铝粉混合均匀,并在模具中压制成型,将成型后的坯体置于气氛炉或真空炉中进行烧结处理,烧结温度400~800℃,保温时间1~4 h,冷却后得到镍钽合金催化电极。本发明通过高温烧结工艺在镍骨架上形成Ni<3>Ta合金催化相,制备出具有三维多孔结构的镍钽合金催化电极,Ni<3>Ta合金催化相优化了氢原子吸附与转化动力学,提升了电极催化活性。本发明无需复杂设备或贵金属负载,适合规模化生产,制备的镍钽合金催化电极兼具优异的催化活性、出色的渗透性能和良好的大电流稳定性,有望攻克现有碱水电解技术中电极材料催化活性与耐久性难以平衡的技术瓶颈。
Absstract of: CN122543105A
0001 本发明公开了一种水电解复合催化剂及其制备方法和应用,属于电解水制氢及电催化技术领域。本发明将磺酸基团的Grotthuss质子穿梭功能引入氧化钛负载金属铱纳米颗粒催化剂体系,从传质动力学、结构稳定性和本征活性三个维度同步提升了催化剂的综合性能,解决了传统氧化物载体催化剂在质子传导和局部酸性积累方面的技术瓶颈。本发明为低铱、高效、长寿命PEM电解水阳极催化剂的设计提供了新思路,对于推动质子交换膜电解水制氢技术的规模化应用、降低绿氢制备成本、助力实现碳中和目标具有重要的科学意义和工程应用价值。
Absstract of: CN122553097A
本发明公开了一种面向波动直流输入的模块化海水电解制氢系统,涉及新能源技术领域,具体为一种面向波动直流输入的模块化海水电解制氢系统,该系统包括风电接入与整流模块、直流母线分配网络、模块化电解反应单元阵列、海水预处理与供给子系统、气液分离与纯化模块、热能回收与管理模块及智能监测与控制中枢。通过各模块协同工作,实现利用海上风电直接电解海水制氢。系统采用模块化设计,便于维护与扩展,并集成防腐防污涂层施加模块以延长设备寿命。智能监测与控制中枢可动态调节工作状态,确保系统高效稳定运行,有效解决了海上风电消纳与绿氢制备问题。
Absstract of: CN122543111A
本发明涉及电解工艺控制技术领域,尤其涉及一种电解水制氢纯化系统脱氧器的防超温控制方法及系统;该方法包括:获取电解槽运行状态监测数据与脱氧器入口的氧含量监测数据。依据预置的扰动参数阈值集合对电解槽运行状态监测数据执行逻辑判断计算,得到前馈控制信号。依据预置的第一氧含量阈值对氧含量监测数据执行偏差计算与反馈控制算法计算,得到与预设阈值相关的反馈控制信号。根据前馈控制信号与反馈控制信号,执行控制逻辑运算,生成控制指令。通过这样的方式,解决了现有脱氧器温度控制技术存在的响应滞后的技术问题,提升了碱性电解水制氢系统在复杂运行工况下的控制品质、设备安全性与运行可靠性。
Absstract of: CN122543106A
0001 本发明属于离子交换膜技术领域,公开了一种应用在高浓度碱性电解水所用的亲水微孔聚合物膜及其制备方法。本发明通过合理调节主链中B<1>和螺环双茚部分的比例,提高亲水基团密度来增加微孔的亲水性,制备系列离子交换膜材料,可为氢氧根离子在膜内传导提供快速传递通道。本发明提供的刚性、高自由体积阴离子交换膜具有高电导率、耐溶胀,耐碱稳定性的特点,同时表现出十分优异的单电池性能,因此在碱性电解池领域具有广阔的应用前景。
Absstract of: EP4570745A1
The present disclosure relates to apparatuses for producing hydrogen, and to top-down methods for producing nanoparticles. Different mechanical mills may be used to break down micron sized soil or sand particles and to react the particles with water, particularly sea water.
Absstract of: CN122540801A
0001 本发明公开了一种分步光解水制氢制氧的方法,包括:将氧化剂和光催化剂分散在水与第一有机溶剂组成的混合溶剂中,得到水氧化产氧反应体系,进行可见光照射,水发生氧化反应产生氧气,同时以水为质子源,使氧化剂还原为富氢的还原剂,对还原剂和光催化剂进行分离回收,并分散在第二有机溶剂中,得到产氢反应体系,进行可见光照射,使富氢的还原剂释放氢以产生氢气,同时还原剂被氧化为氧化剂。本发明通过构建稳定、可再生且易分离回收的有机氧化还原介质的可逆氧化还原循环,分别耦合水氧化产氧反应与完全来源于水的质子还原产氢反应,使产氧反应与产氢反应在不同反应阶段分步进行,从而实现产氧与产氢过程的时空解耦及高量子效率分步进行。
Absstract of: CN122543112A
0001 本发明涉及电解水制氢技术领域,公开了一种碱性电解槽电极性能快速检测装置及方法,包括:电解槽,电解槽内通过双极板分隔形成多个串联的电解小室,电解小室内设置有阴极电极和阳极电极,阴极电极和阳极电极与恒流稳压电源电连接;多路电压采集模块,用于采集电解小室的单室电压;碱液循环模块,与电解槽以及气液分离器连通,碱液循环模块用于将碱性电解液、氧气与氢气的混合物输送至气液分离器,气液分离器将氢气和氧气分离后,碱液循环模块将碱性电解液输送至电解槽形成回路。本发明将多个电解小室串联在同一电解槽内,使各个待测电极能够在相同电流、温度、碱性电解液循环和液位条件下进行对比检测。
Absstract of: CN122538094A
0001 本发明公开了一种CuCo
Absstract of: CN122543086A
0001 本发明提供一种Ru@Cl‑C催化剂的制备及应用,首先以杨木和PVC为原料,混合后共热解处理,得到氯掺杂碳前驱体;而后采用碱进行活化处理,进一步优化碳载体的比表面积、孔道分布及表面活性位点,经洗涤、干燥后得到氯掺杂活性炭载体;最后将钌源前驱体与活化后的Cl‑C载体混合,通过水热煅烧工艺实现钌活性组分的均匀负载,经后续后处理得到Ru@Cl‑C催化剂;将制备得到的Ru@Cl‑C催化剂应用于电解水制氢反应中,可充分发挥Cl掺杂的电子调控作用与Ru活性组分的催化性能,显著提升反应效率。本发明制备工艺设计合理、绿色环保,为高效电解水制氢催化剂的制备提供切实可行的技术方案。
Absstract of: CN122543096A
0001 本发明涉及催化剂制备技术领域,具体涉及一种用于电解水析氧的Bi基异质结催化剂及其制备方法。一种用于电解水析氧的Bi基异质结催化剂的制备方法,包括:Bi‑MOF前驱体的制备、Bi基异质结催化剂的制备。本发明以MOF为前驱体,利用硝酸铋、硫脲及2‑甲基咪唑在甲醇溶液中进行一步法合成,获得高比表面积和均匀掺杂的Bi<2>S<3>前驱体。随后,通过Te粉碲化工艺,原位构建Bi<2>S<3>/Bi<2>Te<3>多相异质结构催化剂。
Absstract of: CN122543102A
本发明属于电催化材料与电解水技术领域,具体涉及一种基于阴阳离子修饰的双功能异质结电解水催化剂及其制备和应用。以镍盐、钴盐、氟化铵和尿素为原料,预处理干净的泡沫镍为基底,在聚四氟乙烯内衬不锈钢反应釜中,水热反应获得前驱体NiCo‑LDH@NF;接着以尿素为氮源,前驱体NiCo‑LDH@NF置于管式炉下游,氮化处理获得异质结NiCoO/CoN@NF;然后浸渍到0.1~10mmol的硝酸铬溶液并保持1~10min,自然干燥后得到阴阳离子修饰的异质结催化剂NiCoO/CoN@NF‑CrNO,其双功能催化活性显著提升,并且稳定性优异,能够良好的应用在电解槽阴阳极或AEM器件中。
Absstract of: CN122538200A
本发明公开了一种单原子稀土‑钌共掺杂氮化碳纳米管、制备方法及其在光催化产氢中的应用,该稀土‑钌共掺杂氮化碳纳米管通过先以三聚氰胺为前驱体,经水热反应、冷冻干燥及高温煅烧制得氮化碳纳米管,再经稀土掺杂与钌单原子负载而制成。该材料以七嗪环为构筑单元形成层状堆叠结构,具有三维纳米管形貌,稀土与钌均以单原子形态均匀分布于层间及表面。稀土掺杂可调控能带结构、抑制光生载流子复合,钌单原子提供高效析氢活性中心,二者构建电子结构调控与位点催化协同体系。作为催化剂兼具优异光催化产氢性能与重复循环利用性能。本发明制备工艺简单温和、可控性及重复性好,适配多种稀土元素,易于规模化制备,可广泛用于光催化分解水产氢领域。
Absstract of: CN122542992A
本发明涉及铁镍催化电极制备技术领域,本发明公开了一种形貌可控的铁镍氧化物催化电极及其制备方法,通过磁控溅射在镍基体上掺杂元素,随后通过碱液浸泡去除掺杂元素,在镍基体上制备得到铁镍氧化物纳米片;纳米片的形貌可控,通过控制掺杂元素的磁控溅射电流密度,即可控制铁镍氧化物纳米片的尺寸大小,进而调控制备得到的铁镍氧化物电极的比表面积和电学性能;使得铁镍氧化物电极的性能能够得以优化提升。本发明的制备方法制备得到的铁镍氧化物电极表面具有厚度为50nm‑300nm的铁镍氧化物纳米层,在100mA/cm2电流密度下的过电位仅为292mV,且运行24h不发生明显衰减,具有优异而稳定的电性能;适宜推广应用。
Absstract of: CN122543103A
本发明公开了一种用于电解海水制氢的Co‑Te‑Cr催化材料,其采用如下方法制备得到,具体为:以导电基体作为阴极、以石墨片作为阳极,采用恒电流电沉积法在电镀水溶液中进行电沉积,电沉积后,得到Co‑Te‑Cr催化材料;所述Co‑Te‑Cr催化材料包括导电基体以及电沉积在导电基体表面的Co‑Te‑Cr活性层;所述Co‑Te‑Cr活性层由Co‑Te‑Cr纳米片堆积而成。本发明方法制得的Co‑Te‑Cr化材料应用在尿素阳极氧化反应过程中具有良好的催化活性,能够大幅降低尿素阳极氧化反应的能垒,从而实现低能耗海水电解制氢。
Absstract of: CN122543097A
本发明公开了一种基于Fe2O3的析氢催化剂的制备方法。包括以下步骤:按照质量比为1:1~5分别称取LFPO和Glc·H2O,将二者置于玛瑙研钵中研磨5~20 min,形成一混合物,随后将得到的混合物置于马弗炉中,在空气氛围中于500 ℃~900℃下煅烧0.5~4 h,即得到一种含Li3Fe2(PO4)3、Fe2O3和C的HER析氢催化剂。I‑t 曲线测试表明,在测试时间达到10小时时,所制备的催化剂的HER催化性能明显高于商业铂碳的性能,这说明,这种不含贵金属的催化剂具有优良的析氢性能。本发明制备工艺简单,成本低廉,适合规模化商业生产。
Absstract of: CN122543094A
本申请涉及电催化剂技术领域,公开了一种稀土掺杂IrOx电催化剂及其制备方法和应用。所述稀土掺杂IrOx电催化剂,其为具有三维多孔结构的固溶体氧化物MaIrbOx;其中,M为镧系稀土金属;a为M的摩尔数,b为Ir的摩尔数,且a:b=(0~0.7):(0.3~1)。本申请基于无机盐硬模板法,通过将多种金属前驱体均匀包覆在无机盐晶粒表面,经退火形成均匀的氧化物,进而得到具有三维分级多孔的形貌的电催化剂;本申请的稀土‑铱固溶体氧化物电催化剂呈三维多孔结构,具有三维空间传质优势和高比表面积的结构特点,赋予其高电催化活性;引入的合金化效应、无定形结构及丰富的缺陷位点赋予材料极高的电催化活性,使得电催化分解水产氧的性能显著提高。
Absstract of: CN122544552A
本发明公开了一种用于质子膜水电解制氢的热交换系统,包括冷源供给设备;氢气分离系统;氧气分离系统;冷源供给设备通过管道同时为氢气分离系统和氧气分离系统提供冷源介质,且冷源介质分别经过氢气分离系统和氧气分离系统后回流至冷源供给设备;氢气输送管,氢气输送管的一端与电解槽氢气侧连通,另一端连通氢气分离系统;氧气输送管,氧气输送管的一端与电解槽氧气侧连通,另一端与氧气分离系统连通。本申请的冷源供给设备可同时为氢气分离系统和氧气分离系统提供冷源,流量调控系统的设置使得两个分离过程可以共用一套冷源系统,既能实现系统的热力学平衡,同时简化了系统整体的结构布局,减少了设备投入成本,又降低了系统运行的能耗。
Absstract of: CN121666467A
The present invention relates to an electrolytic cell frame (100) configured to be integrated in an electrolytic cell. The frame forms a closed shape with an inner contour (InnCnt) defining an opening (Op) extending in an extension plane (ExtP1). The inner contour has at least two steps (St1, St2, St3, St4, St5, St6), each step comprising a first surface (S1) perpendicular to the extension plane and a second surface (S2) parallel to the extension plane. The respective second surfaces of two of the steps (St1, St3, St5) are configured to support two respective bipolar plates (BP-1, BP-21, BP-22).
Absstract of: EP4495290A1
0001 The present invention relates to an electrode comprising or consisting of an electrocatalyst, the electrocatalyst comprising a metal boride, wherein the metal boride comprises at least one element M1 selected from Ti, Zr and Hf, and at least one element M2 selected from Co, Ni, Ru, Rh, Pd, Ir and Pt; and the metal boride contains more than 10 atomic % of M2. The present invention also provides an electrode obtainable by subjecting the electrode to an electrocatalytic reaction. It also relates to an electrolyzer comprising said electrode. It is also concerned with a method for producing an electrode, and use of an electrode in an electrocatalytic reaction.
Absstract of: WO2025127502A1
Provided according to exemplary embodiments of the present invention is an ammonia decomposition system capable of minimizing the generation of iron nitride, which is a by-product.
Absstract of: WO2025002798A1
The invention relates to a reactor (2) for generating hydrogen and at least one other product from at least one reactant, the reactor comprising a tubular reactor vessel (4) which contains a catalyst (6) in the form of a ceramic bed. Improved corrosion resistance against a variety of media and thus an increased service life of the reactor (2) is achieved by forming the reactor vessel (4) from silicon-infiltrated silicon carbide (SiSiC).
Absstract of: PL451147A1
Przedmiotem zgłoszenia jest sposób wytwarzania wodorotlenku sodu z jednoczesnym magazynowaniem prekursora wodoru, który charakteryzuje się tym, że: w pierwszym etapie prowadzona jest elektroliza stopionego chlorku sodu w elektrolizerze stopionych soli (1) z ujęciem chloru, magazynowanego w zbiorniku chloru (2), zużywanego w innych procesach przemysłowych, a ciekły sód po schłodzeniu przechowywany jest w zestawie zbiorników sodu w postaci stałej (3), a w następnym etapie po zadysponowaniu wytworzenia partii wodorotlenku sodu i wodoru, zbiornik (3) podgrzewany jest do osiągnięcia stanu ciekłego sodu w zbiorniku (4), skąd ciekły sód trafia do reaktora reakcji metalicznego ciekłego sodu z wodą (5), zasilanego sodem i wodą ze zbiornika (6), skąd (5) wodór trafia do zbiornika wodoru (8), a wodorotlenek sodu do zbiornika wodorotlenku sodu (7), alternatywnie sód przechowywany jest w zbiorniku (zbiornikach) termosach ciekłego sodu, a elektrolizer stopionych soli (1) jak i zbiorniki sodu w postaci stałej (3), czy zbiornik termos ciekłego sodu (9) geograficznie usytuowany są w innej lokalizacji niż pozostałe instalacje wg sposobu, dodatkowo wprowadzony może być elektrolizer stopionego wodorotlenku sodu (10) zasilany ze zbiornika wodorotlenku sodu (7) z magazynowaniem ubocznych produktów - wodoru - w zbiorniku wodoru (8) i tlenu w zbiorniku tlenu (11).
Absstract of: WO2025093251A1
An energy production and storage system comprises a power input connection (10) for a renewable energy source (2); an electrolysis device (16) for electrolysis of water to produce oxygen, hydrogen, and heat; an electrical energy storage device (14); a two-way grid connection (12) coupled to an external electrical grid (4); and a controller (8). The controller (8) is configured to: (i) receive information relating to: actual or potential energy production from the renewable energy source (2), the amount of stored energy in the electrical energy storage device (14), and balancing requirements for the external electrical grid (4); (ii) use the energy from the renewable energy source (2) to power the electrolysis device (16) and/or for storage in the energy storage device (14); and (iii) based on the received information, operate the energy production and storage system as a balancing service provider by either: drawing power from the grid (4) to supply the electrolysis device (16), or supplying power to the grid (4) from the electrical energy storage device (14), thereby acting as a switch to aid in balancing for the external electrical grid (4).
Absstract of: CN122522324A
0001 本发明公开了基于槽温功率协同的光伏‑PEM制氢站全时段控制方法,属于光伏‑氢能制备及运行控制技术领域,该方法包括:建立光伏模型获取实时功率,建立PEM电解槽电热耦合模型预测温度;采集运行参数,比较光伏功率与制氢能耗并联合SOC判定电力状态;根据电力状态匹配常规、过载或冷却运行模式;采用模糊控制生成PEM电解槽参考电流,采用模糊‑PID生成冷却水泵参考流量指令,实现协同控制。本发明能够在光伏出力充足时提高PEM电解槽对剩余光伏功率的吸收能力,在槽温接近上限时及时降低PEM电解槽负荷并增强冷却作用,从而提高光伏能源利用率、优化产氢效率,并保障PEM电解槽全时段安全稳定运行。
Absstract of: WO2025016560A1
The disclosure concerns a process of carbon oxides-free hydrogen production is disclosed. The process comprises the following steps: - heating a gas stream of a reacting compound including hydrogen atoms in absence of oxidizing agents, to thermally decompose the reacting compound into smaller product compounds, including hydrogen molecules, obtaining a stream of decomposition product compounds; - separating hydrogen molecules from other product compounds of the stream of decomposition product compounds; - reacting a portion of the stream of separated hydrogen molecules with a stream of an oxidizing agent, in particular oxygen or air, to obtain combustion product compounds, including steam and heat, in a stream of combustion product compounds; - providing heat obtained in the previous step to the step of heating the reacting compound; and wherein the process can comprise a step of - recovering energy from the stream of decomposition product compounds and/or from the stream of combustion product compounds. Additionally, a system of hydrogen production is also disclosed, the system being configured to operate according to the above process.
Absstract of: FR3171864A1
Cellule d’électrolyse Cellule d’électrolyse d’eau à membrane électrolytique polymère PEM pour la production d’hydrogène, comprenant une membrane d’échange protonique (11), un compartiment de cathode (7), un compartiment d’anode (9), une première plaque conductrice (30), une deuxième plaque (7) conductrice et un bâti (31) supportant la membrane d’échange protonique (11). Le compartiment de cathode (7) est délimité par la membrane d’échange protonique (11) et la première plaque conductrice (30). Le compartiment de cathode (7) est latéralement délimité par le bâti (31). Le bâti (31) est muni d’au moins deux premières ouvertures (43) communiquant chacune avec le compartiment de cathode (7) par un canal anodique (47) et au moins deux deuxièmes ouvertures (45) communiquant chacune avec le compartiment d’anode (9) par un canal cathodique (48). Les première et deuxième plaques conductrices (30) sont munies de premières et de deuxièmes ouvertures (37, 39) de plaques. Les ouvertures (37, 39) de la plaque conductrice (30) sont délimitées chacune par un bord de plaque. Le bâti (31) comprend une âme rigide (49) recouverte au moins en partie par une couche souple isolante (51). L’âme rigide (49) présente une épaisseur constante. La couche souple isolante (51) recouvre les bords des ouvertures (43, 45) du bâti (31). La couche souple isolante (51) présente au moins des premières surfaces et des deuxièmes surfaces. Les premières surf
Absstract of: FR3171857A1
Cet abrégé résume l’invention en présentant brièvement son domaine technique, le problème technique à résoudre et la solution apportée. La présente invention propose un système novateur de production d'hydrogène qui exploite la chaleur d’un réacteur nucléaire de Génération IV couplé à des cycles thermochimiques (dont le cycle soufre–iode, calcium–brome, cuivre–chlore, etc.) et l’activation par neutrons libres. Cette combinaison permet d’atteindre une efficacité de conversion supérieure, une réduction des coûts et une production d'hydrogène vert à faible émission de CO₂, tout en offrant une solution évolutive pour l’industrie.
Absstract of: CN122522285A
0001 本发明提供一种用于水分解反应的高稳定催化剂载体及其制备方法与应用,所述催化剂载体为含Ni<3>Se<2>的材料,其中Ni<3>Se<2>具有非中心对称结构,其晶体空间群为R32。Ni<3>Se<2>载体采用一步水热合成方法制备得到,利用载体负载贵金属元素(Pt或Ru)制备电解水复合催化剂。与传统碳基载体相比,本发明所得的Ni<3>Se<2>载体具有抗电化学腐蚀能力,粗糙表面提供更多活性面积,与贵金属之间形成强金属‑载体相互作用,提高催化剂质量活性。采用本发明中的水分解反应的高稳定催化剂载体,可以在减少贵金属用量的条件下,实现低过电位和稳定性;且该催化剂载体的制备工艺简单,易操作,在规模化电解水领域具有应用价值。
Absstract of: CN122517057A
0001 本发明涉及于主/助光催化材料技术领域,具体是涉及一种含缺陷的主/助ZnS/MoS<2>材料及制备方法与应用。方法包括如下步骤:将硝酸锌溶解在去离子水中,溶液中加入尿素进行水热反应,得到Zn LDHs粉末;将Zn LDHs粉末分散在去离子水中,将钼酸铵、硫代乙酰胺溶解在溶液中进行水热反应,得到灰色ZnS/MoS<2>粉末;将ZnS/MoS<2>粉末在Ar气氛围下煅烧,得到具有硫缺陷的ZnS/MoS<2>材料。本发明制备原料易得,成本低且过程简单,提高材料的光催化性能及稳定性;制备出了同时具有适宜缺陷浓度和较高结晶度的主/助ZnS/MoS<2>材料,光催化析氢速率达到736.44 μmol·h<‑1>·g<‑1>且在连续144小时的稳定性测试中保持了良好的循环稳定性。
Absstract of: CN122520096A
0001 本发明提供了一种高活性氧化镁的制备方法及其应用,该制备方法包括:将柠檬酸和/或柠檬酸盐溶解于去离子水中,再加入镁盐混合均匀形成混合溶液,向所述混合溶液中缓慢加入碱液,搅拌反应不超过6h,再缓慢加入与首次加入量相同的碱液,搅拌均匀,得到白色絮状的悬浊液;将上述悬浊液进行水热反应,得到的产物经抽滤、洗涤,干燥,得到白色固体粉末,然后在氮气氛围下经梯度升温至500~550℃,保温时间为3~6h,得到高活性氧化镁;本发明制备的氧化镁可作为催化剂载体应用于氨分解制氢催化剂中。本发明的制备方法简单,原料易得,获得的氧化镁粉末具有高活性、均匀微观形貌和高比表面特征,可作为催化剂载体应用于氨分解催化剂中。
Absstract of: CN122522178A
本发明涉及析氢电极材料技术领域,尤其涉及一种形貌可控的硫化钼析氢电极及其制备方法,其包含以下步骤:选择去除了表面油脂、锈迹的基材,将基材固定后放入磁控溅射镀膜系统真空室,启动单极性HALL源,进行等离子清洗;启动磁控溅射镀膜系统对清洗后的基材进行硫化钼涂层沉积,其中,沉积过程中磁控溅射镀膜系统真空室舱室反应真空度为0.5~2 Pa,成膜温度为80‑200℃,单极性脉冲磁控溅射功率为1~5 kW,沉积时间为5~180 min。基于此温度调控方法所制备的催化电极,其析氢催化活性得到显著增强,表现出更低的过电位与良好的运行稳定性。该方法实现了涂层高度一致的竖直取向、高纯度以及与基底之间牢固的结合强度,为高性能析氢电极的制造提供了有效的解决方案。
Absstract of: CN122522306A
本发明公开了一种Sr原子修饰的CoOOH纳米片催化剂及其制备方法和应用。本发明通过简单的溶剂热法制备锶掺杂的硫化钴纳米片作为前驱体,并在碱性阳极析氧反应条件下发生原位电化学重构制备得到。本发明提供的Sr原子修饰的CoOOH纳米片,通过锶原子修饰降低了金属钴周围的电子云密度,同时d带中心向费米能级上移,使得Co位点与反应中间体的轨道杂化作用增强,促进含氧中间体的吸附,从而提高碱性阳极析氧反应的活性。该催化剂在阴离子交换膜电解水制氢阳极析氧反应中,表现出优异的催化活性与稳定性,为阴离子交换膜电解水制氢技术产业化发展提供新思路。
Absstract of: CN122533001A
本发明公开了一种混合电解槽集群控制方法及装置,属于混合电解槽控制技术领域。该方法包括:获取混动电解槽集群并网运行时的第一状态信息;基于第一状态信息和计划制氢功率,确定基础制氢功率;基于第一状态信息、虚拟惯量系数和虚拟阻尼系数,确定频率支撑附加功率;基于基础制氢功率和频率支撑附加功率,确定混动电解槽集群并网运行的总功率;基于第一状态信息,将总功率自适应分解为第一总功率和第二总功率;基于修正后的第一总功率和第二总功率,控制混合电解槽运行。本发明通过将储氢罐状态深度融入功率生成和分解的全过程,实现了制氢与调频的有效解耦,提升了系统调频性能与供氢安全性。
Absstract of: CN122517053A
0001 本申请公开了TiO<2>‑ZnIn<2>S<4>核壳结构S型异质结光催化剂及其制备方法和应用,涉及光催化材料领域。该TiO<2>‑ZnIn<2>S<4>核壳结构S型异质结光催化剂包括TiO<2>内核;以及包覆在TiO<2>内核外部的ZnIn<2>S<4>外壳;ZnIn<2>S<4>外壳由ZnIn<2>S<4>纳米片在TiO<2>内核表面原位生长形成三维分级纳米花结构;其中,TiO<2>与ZnIn<2>S<4>之间形成S型异质结。该光催化剂通过核壳结构的紧密异质界面实现光生载流子的高效空间分离,同时利用S型异质结保留强氧化还原能力的载流子,提升了光催化分解水制氢性能及循环稳定性。
Absstract of: CN122522299A
本发明涉及电解水制氢技术领域,公开了一种镍‑铂纳米析氢催化剂及其制备方法。所述制备方法包括制备六方相镍纳米材料;将制得的六方相镍纳米材料分散于溶剂中,加入油胺,在加热条件下加入铂前驱体溶液,在所述六方相镍纳米材料表面原位生长亚稳六方相铂壳层,得到六方相镍‑铂核壳结构纳米材料,即为所述镍‑铂纳米析氢催化剂。该材料通过油胺与铂盐的配位反应,抑制了铂盐与镍纳米晶之间的置换反应,实现了具有几个原子层厚度的亚稳六方相铂纳米壳层在镍模板上的可控合成。利用镍核与铂壳之间的相互作用,有效调制了亚稳相铂壳的电子结构,从而实现了高效电催化析氢。
Absstract of: CN122517605A
0001 本发明公开了一种NiMo合金催化剂的制备方法及其应用,属于电极催化剂技术领域。本发明包括以下步骤:将镍颗粒、铝颗粒、钼颗粒混合均匀后放置坩埚中,熔炼后得到合金锭;将合金锭进行急冷甩带,获得合金薄带;将合金薄带研磨成粉末,置于氢氧化钾溶液中选择性刻蚀,经洗涤干燥后得到纳米多孔结构的NiMo合金催化剂。本发明通过刻蚀铝构造纳米多孔结构,增大比表面积、暴露活性位点;通过调控镍钼比例优化电子结构,降低析氢能垒。本发明工艺流程简单、无污染、能耗低、成本低,所制得的NiMo合金催化剂具有优异的析氢催化活性和长期服役稳定性,适合工业化大批量生产,可应用于碱性电解水制氢领域。
Absstract of: CN122522307A
本发明公开了异质多相界面生物质碳负载催化剂的制备方法,具体为:将内源铬配位胶原纤维前驱体置于乙醇/水混合溶液中浸泡,洗涤、干燥,得到预处理粉末;将预处理粉末在惰性气氛下进行预碳化,得到稳定碳前驱体;将稳定碳前驱体进行酸活化处理,洗涤干燥,得到含铬氮氧碳骨架;将含铬氮氧碳骨架与镍盐前驱体混合并浸渍负载,烘干后在惰性气氛下进行碳化即可。本发明通过预处理‑预热解‑酸活化‑Ni后引入‑高温碳化的分步工艺路线,构建了一种包含连续生物质碳骨架、Cr基相和Ni物种的异质多相界面催化材料。Cr/N掺杂碳骨架能够诱导Ni选择性沉积,抑制高温烧结,形成小尺寸、高分散颗粒,使得活性位点更多、界面利用率更高、金属颗粒更稳定。
Absstract of: CN122522294A
0001 本发明涉及电解水制氢技术领域,具体涉及一种氧化锰基核壳结构催化剂及其制备方法和应用、工作电极及其制备方法和应用。本发明以硼掺杂二氧化锰为载体,负载贵金属。本发明通过在二氧化锰中掺杂硼,能够有效调节二氧化锰的电子结构,显著提升二氧化锰载体的电子电导率,进而改善OER过程中的电荷传输;而且,硼原子缺电子的特性也使其对表面金属原子具有强亲和力,可形成金属‑B‑O结合位点,从而强化对贵金属活性组分的锚定能力,进一步构筑贵金属‑基底稳定界面,显著降低贵金属的用量。本发明提供的氧化锰基核壳结构催化剂本征导电性好,电催化活性高,结构耐久性优异,为实现低成本、长寿命的PEM电解技术提供了可行的材料解决方案。
Absstract of: CN122522293A
0001 本发明公开了一种锰氧化物负载的铱单原子催化剂,包括载体锰氧化物和负载在载体锰氧化物上的铱,铱以单原子形式分散于锰氧化物表面或晶格中,铱的负载量为6wt%~8wt%。本发明通过一步水热反应即可同时完成锰氧化物载体的合成、晶相调控和铱单原子的锚定,无需分步操作,工艺流程短、操作简便,适合规模化生产;仅需改变柠檬酸与高锰酸钾的摩尔比,即可在同一反应体系中实现锰氧化物载体晶相在MnO<2>与MnO(OH)之间的选择性切换,克服了传统方法需改变整个合成体系的不足。
Absstract of: CN122522179A
本发明涉及析氢电极材料技术领域,尤其涉及一种厚度可控的硫化钼析氢电极及其制备方法,其包含以下步骤:将基材固定后放入磁控溅射镀膜系统真空室,启动单极性HALL源,对基材表面进行等离子清洗;等离子体清洗完成后,关闭HALL电源,启动单极性脉冲磁控电源,进行硫化钼涂层沉积,其中,沉积过程中舱室反应真空度为0.5~2 Pa,成膜温度为室温‑200℃,单极性脉冲磁控溅射功率为1~5 kW,沉积时间为5~180 min。优选地,涂层沉积过程中舱室反应真空度为1 Pa,成膜温度为室温,单极性脉冲磁控溅射功率为4.0 kW,沉积时间60 min。本发明突破了常规工艺参数下硫化钼涂层主要呈水平层状生长的局限,通过特定的工艺参数组合,首次实现了硫化钼催化层垂直于基底的定向可控生长。
Absstract of: CN122522282A
0001 本发明涉及一种用于电解水的一体化阳极及其制备方法和应用,其包括提供镍基底;对镍基底实施第一次阴极电沉积,在镍基底表面形成镍铁合金中间层,得到NiFe@镍基底;对NiFe@镍基底实施第二次阴极电沉积,在镍铁合金中间层表面形成NiFeCr合金表层,得到原始态NiFeCr@镍基底前驱体;将原始态NiFeCr@镍基底前驱体置于碱性溶液中进行水热氧化处理,使NiFeCr合金表层原位重构形成包含镍铁羟基氧化物活性相与三氧化二铬保护层的多孔重构外层,制得一体化阳极。本发明采用两步分层电沉积搭配碱性水热重构,分层实现导电、催化与防腐功能,解决传统电极催化剂易脱落、镍铁活性组分大量溶出、铬离子污染电解液等问题。
Absstract of: CN122522276A
0001 本发明涉及氢能制备技术领域,具体涉及一种用于质子交换膜水电解池的多孔传输层及其制备方法和应用。所述多孔传输层包括钛基体和复合涂层,所述复合涂层从基体向外依次包括:Ta阻隔层、PtTa过渡层和Pt表面导电层。本发明采用磁控溅射工艺制备该复合涂层,具备工艺参数精准可控、批次制备重复性优异的特点,可广泛应用于质子交换膜水电解装置中多孔传输层的表面改性,有效提升电解器的整体性能与使用寿命。
Absstract of: CN122522304A
本申请涉及一种镍硫调控氧化铜纳米阵列的电子重构型催化材料及其制备方法与葡萄糖电氧化制氢应用。催化材料中镍硫的引入可有效诱导氧化铜的电子结构重构,从而促进电荷转移和氧化还原反应动力学,为葡萄糖电化学氧化替代传统OER的制氢新技术提供了科学依据和技术支持。泡沫铜基底上原位生长的氧化铜纳米线阵列具有高导电性三维骨架,可降低电荷传输阻力;同时,电子重构作用可暴露出更多的活性位点,提升材料导电性,在葡萄糖氧化过程中加速电子传递,显著提高催化活性。本申请的原位电化学动态制备方法工艺简单、能耗低、适用性广。整个制备过程原料廉价易得,能耗低,环境友好,产物结晶度良好,适合批量制备。
Absstract of: CN122522312A
本发明公开了一种基于电化学活化重构铁相的析氢/析氧双功能材料,其制备方法包括以下步骤:1,NiCoOH/NF的制备;2,NiCoOH/CoFeOH/NF的制备;3,NiCoP/CoP2‑FeP2/NF的制备。所得NiCoP/CoP2‑FeP2/NF具有通过电化学活化实现重构的特点,重构后,铁相由FeP2重构为FeOOH,形成NiCoP/CoP2‑FeOOH/NF;NiCoP/CoP2‑FeP2/NF呈芽状结构形貌,形成三相异质结构。作为析氢催化剂材料的应用时,过电位为38‑41 mV;析氢Tafel斜率为35‑38mV·dec‑1;电流保持率为85‑95%;Cdl为30‑32mF·cm‑2。作为析氧催化剂材料的应用时,过电位为220‑230 mV;析氧Tafel斜率为35‑40mV·dec‑1;电流保持率为85‑95%;Cdl为15‑20mF·cm‑2。
Absstract of: CN122517103A
0001 本发明公开了一种基于Cu<1.94>S‑ZnS的Pickering乳液及其应用,属于Pickering乳液制备技术领域。本发明将含有Cu<1.94>S的有机膦配体悬浮液与含有Zn<2+>的有机溶液通过阳离子交换反应制得Cu<1.94>S‑ZnS纳米颗粒;Cu<1.94>S‑ZnS纳米颗粒经含巯基的羧酸类配体表面修饰、去质子化处理后制得亲水性Cu<1.94>S‑ZnS纳米颗粒;以含有硫源的水溶液为水相,正辛醇为油相,亲水性Cu<1.94>S‑ZnS纳米颗粒为乳化剂,经均质化处理得到Pickering乳液。与单相水体系和非均相未乳化体系相比,基于Cu<1.94>S‑ZnS的Pickering乳液的光催化制氢的性能得到显著提升。
Absstract of: CN122522248A
自支撑电极材料可在导电基底上原位生长催化活性物质,无需粘结剂辅助,能够有效解决粉末催化剂脱落、位点堵塞的问题,同时具备优异的电子传导性和结构稳定性。但现有自支撑电极普遍存在活性组分分散不均匀、界面结合力弱、电化学比表面积小的缺陷,在高电流密度下过电位偏高、稳定性不足,严重制约了其工业化应用。基于此,本发明设计一种新型复合结构自支撑电极材料,通过简易可控的制备工艺优化材料微观结构与电子结构,大幅提升电催化析氢性能。
Absstract of: CN122522292A
0001 本发明涉及PEM电解水制氢技术领域,具体公开一种PEM电解水高比表面积粉末催化剂的制备方法。本发明先采用磁控溅射法在膜基材表面构建金属氧化物纳米结构骨架作为模板,通过调控溅射工艺参数实现对纳米结构骨架的密度、尺寸和形貌的精准控制;再利用磁控溅射法在该模板表面负载催化剂,通过沉积参数调控催化剂负载量;最后经脱模、球磨、分离干燥工艺获得粉末催化剂。本发明制备的催化剂粉末分散性好、团聚率低、比表面积高,尺寸和形貌均一可控,且制备工艺简单、可实现批量生产,解决了传统制备方法中催化剂易团聚、形貌粒径难以精准控制的技术问题,大幅提升了PEM电解水制氢的催化效率和稳定性。
Absstract of: CN122522311A
本发明公开了一种用于析氧反应的锆钴镍铁四元金属的磷基化合物自支撑催化剂及其制备方法和应用。所述催化剂原位生长于镍铁泡沫基底上,活性组分包含锆、钴、镍、铁四种金属元素,且物相组成中同时存在Ni2P2O7相和Ni2P相。其制备方法包括:将镍铁泡沫清洗预处理后,与含锆、钴、镍、铁可溶盐的前驱体溶液进行水热反应,使溶液中四种金属离子共同成核生长,再经气相磷化处理,得到同时含Ni2P2O7和Ni2P两相的催化剂。该催化剂在碱性电解液中析氧过电位低、Tafel斜率小,在不低于1000mA cm‑2的电流密度下可稳定运行不少于40小时,法拉第效率≥95%,且能直接作为自支撑阳极使用。本发明催化剂活性高、稳定性强、制备工艺简单,适用于碱性水电解制氢领域。
Absstract of: CN122522320A
0001 本发明公开了一种羟基氧化铝基碱性电解水复合隔膜及其制备方法,属于碱性电解水制氢隔膜技术领域。本发明复合隔膜包含聚砜树脂基体和分散于其中的羟基氧化铝填料,羟基氧化铝的质量不超过聚砜树脂质量的80%;其制备方法包括:将聚砜树脂与致孔剂在有机溶剂中混合形成聚合物溶液,加入羟基氧化铝粉末分散均匀后脱泡得到铸膜液,经刮膜、相转化、洗涤、干燥得到复合隔膜;本发明采用羟基氧化铝替代传统ZrO<2>填料,原料成本大幅降低,同时利用羟基氧化铝表面富含羟基的特性赋予隔膜优异的本征亲水性,构建的亲水网络有效降低面电阻,解决了现有技术中ZrO<2>基复合隔膜成本高、传统亲水改性长效性不足的技术问题。
Absstract of: CN122522288A
本发明属于催化剂制备技术领域,具体涉及一种Co负载型Cs2PtI6钙钛矿材料及其制备方法、应用,所提供的Co负载型Cs2PtI6钙钛矿材料,利用Cs2PtI6为载体,配位锚定钴前驱体,调控制备工艺,在温和条件下实现了钴纳米颗粒原位负载。利用钴与Cs2PtI6钙钛矿形成的紧密耦合异质界面优化电荷传输效率,及光辅助电催化,提高了析氢催化剂的催化性能。
Absstract of: CN122522287A
0001 本发明属于材料合成及电催化制氢技术领域,涉及一种面向波动工况的高稳定性含Ce高熵合金氧化物催化剂及其制备方法与碱性析氢/析氧催化应用,以镍盐、钴盐、铁盐、钌盐、铈盐为原料与有机配体通过水热法在载体基底上制备高熵MOF前体,再通过管式炉热解得到NiCoFeRuCe五元高熵合金氧化物;其具有碱性析氢和析氧双功能,在碱性析氢波动工况下电位保持率为98.44%。本发明制备方法简单,成本低,得到的NiCoFeRuCe五元高熵合金氧化物材料在波动工况下具有优异的稳定性,适于大力推广,市场前景广阔。
Absstract of: CN122517028A
0001 本发明公开了一种氨裂解制氢用的镍铝氧化物催化剂、制备方法及应用,属于催化剂技术领域,本发明提供了一种氨裂解制氢用的镍铝氧化物催化剂,用于解决现有技术中合成镍基催化剂的过程中,易产生大量固废液、不耐高温稳定性差的技术问题。本发明合成的镍铝氧化物催化剂由NiO相和NiAl<2>O<4>相组成;所述催化剂以氧化物质量计,包含27%‑59%的NiO和41%‑73%的Al<2>O<3>。所述催化剂的制备方法,包括以下步骤:镍的前驱体和铝的前驱体混合、高温焙烧,即为制备的氨裂解制氢用的镍铝氧化物催化剂。本发明采用固相法合成催化剂,工艺简化高效、过程无废水废气产生。部分NiAl<2>O<4>相的存在有助于提高镍铝氧化物催化剂的稳定性和耐高温性。
Absstract of: CN122522295A
0001 本发明公开了一种梯度浓度添加非贵金属溶液的合金制氢催化剂制备方法,包括:基底预处理、合金型催化剂前驱体的制备、梯度混合溶液的添加等步骤。通过上述方式,本发明梯度浓度添加非贵金属溶液的合金制氢催化剂制备方法,通过梯度浓度溶液添加的方式,表现出远超传统催化剂的高活性、高稳定性与高性价比。
Absstract of: CN122522043A
本发明公开了一种Pt基金属间化合物及其制备方法,所述Pt基金属间化合物的化学式为Pt3ScxTm1‑x,x=0.2~0.8,所述Pt基金属间化合物由铂源、钪源、铥源、碳载体、形貌调节剂经碳热还原反应制得。本发明成功向Pt基金属间化合物中引入Tm元素,Tm独特的4f轨道电子的调控作用,显著优化了Pt3Sc的电子结构,增强了电催化析氢反应(HER)活性、催化稳定性,展现出了巨大的能源应用前景。
Absstract of: CN122522327A
0001 本发明提供一种电解槽故障检测系统、方法、装置、终端设备及计算机可读存储介质,电解槽故障检测系统包括双极板组件、光纤传感器和控制器;光纤传感器设置在流道网结构上,光纤传感器被配置为获取双极板组件内沿光纤传感器的延伸方向的温度分布数据;控制器被配置为:根据光纤传感器获取的温度分布数据计算每个测量点的电流密度;判断多个测量点的电流密度是否均匀,多个测量点的电流密度不均匀时,确定双极板组件发生故障。光纤传感器获取沿光纤传感器的延伸方向的温度分布数据,控制器根据光纤传感器获取的温度分布数据计算每个测量点的电流密度,在多个测量点的电流密度不均匀时,控制器判断双极板组件发生故障。
Absstract of: CN122522316A
本发明属于新能源纳米材料技术以及电解水制氢领域,具体涉及一种含非对称Fe‑Se‑Ru位点的富硒空位硒化钌电催化剂及其制备方法与应用。电催化剂由富硒空位的立方相RuSe2及非对称Fe‑Se‑Ru位点构成。其制备方法包括以下步骤:水热法合成前驱体粉末,再对粉末在惰性气氛环境下焦耳加热处理,即可得到含非对称Fe‑Se‑Ru位点的富硒空位硒化钌电催化剂。本发明催化剂在碱性水和碱性海水条件下表现出优异的析氢性能,分别实现10 mA·cm‑2电流密度下仅12 mV和20 mV的过电位,且在自组装的膜电极1000 mA·cm‑2电流密度下稳定运行1000小时,展现出卓越的电化学稳定性和工业应用潜力。
Absstract of: CN122522318A
一种有机小分子修饰的铁镍层状双氢氧化物催化剂及其制备方法和应用,它涉及二元NiFe层状双氢氧化物电催化剂及其制备方法和应用。它是要解决现有的电解海水制氢催化剂依赖贵金属、稳定性差的技术问题。本发明的有机小分子修饰的铁镍层状双氢氧化物催化剂是以泡沫镍为基底,在泡沫镍表面生长NiFe层状双氢氧化物,且NiFe层状双氢氧化物层间含有机小分子。是利用电沉积法制备的。有机小分子均苯三甲酸修饰的铁镍层状双氢氧化物催化剂在1 M KOH海水中,在10 mA cm‑2的电流密度下的OER过电势仅为207 mV,并且以其作为阳极的电解槽在碱性海水中析氧反应稳定运行超2500小时,可用于工业电解海水制氢领域。
Absstract of: CN122517019A
本发明涉及一种贵金属/稀土氧化物复合催化剂及其制备方法和应用,属于氨分解催化剂技术领域,解决了现有氨分解催化剂活性低、热稳定性差、成本高、难以在500℃以下高效稳定使用等问题中的至少一种。制备方法,包括:S1,将可溶性矿化剂溶液与稀土盐溶液搅拌混合后,进行陈化,得到第一产物;S2,将第一产物与溶剂搅拌分散均匀后,进行溶剂热反应,得到第二产物;S3,将第二产物在预定气氛下进行焙烧,得到稀土氧化物载体;S4,将Ru前驱体溶液与稀土氧化物载体的分散液混合,进行加热反应,得到第三产物;S5,将第三产物进行焙烧,得到第四产物;S6,将第四产物在还原气氛下进行焙烧,得到负载型贵金属/稀土氧化物复合催化剂。
Absstract of: CN122533374A
本申请提供一种电源控制方法和相关设备,电源控制方法包括:获取制氢电源在当前时刻的实际电流值,并根据所述实际电流值确定所述制氢电源在一阶惯性阶跃响应下的期望电流值;根据所述期望电流值确定所述制氢电源在下一时刻的预测电流值;对所述预测电流值进行滚动优化得到目标电流值,并根据所述目标电流值确定目标电流调整值;根据所述目标电流调整值,调整所述制氢电源当前输出的电流值。本申请中,有效避免了PI控制中常见的超调和震荡现象。
Absstract of: WO2025051333A1
The invention relates to a plate-like element (10) of a cell stack (2) of an electrochemical system (1), having a first plate side (26), a second plate side (27), a plurality of openings (13, 21, 22, 23, 23') and a first structure (14) for forming a flow field for coolant and several further structures (14') for forming distributors for operating media on the first plate side (26). The structure (14) comprises a coolant conducting structure (15, 16) through which a first coolant path (15) and a second coolant path (16) arranged mirror-symmetrically thereto are formed, each of which have, starting from one of the openings (21), an elongate inflow portion (17), a centre portion (18) which starts from the inflow portion (17), fans out and describes at least one meandering bend (19), and an elongate outflow portion (20) which adjoins the centre potion (18) and is narrower than the centre portion (18). A longitudinal axis (30) of the inflow portion (17) of the first coolant path (15) matches a longitudinal axis (30) of the outflow portion (20) of the second coolant path (16), and a longitudinal axis (30') of the inflow portion (17) of the second coolant path (16) matches a longitudinal axis (30') of the outflow portion (20) of the first coolant path (15). The invention also relates to a cell stack (2) comprising a plurality of such plate-like elements (10) which are parallel to one another.
Absstract of: WO2026162628A1
System (100) for exploiting hydrogen (H2) produced as by-product by a chlor-alkali plant (10) comprising a compressor (20), a storage unit (30) and a power generation unit (40). The compressor (20) is fluidly coupled to the chlor-alkali plant (10) and is configured to receive and compress the hydrogen (H2) produced by the chlor-alkali plant (10) so to discharge a compressed hydrogen flow (CH2). The storage unit (30) is fluidly coupled to the compressor (20) and is configured to receive and store the compressed hydrogen flow (CH2) at least for a predetermined time and to discharge a stored hydrogen flow (SH2). The power generation unit (40) is fluidly coupled to the storage unit (30) and is configured to receive a first hydrogen flow (HF1) of the stored hydrogen (SH2) as a fuel and/or one or more external fuels (F), so to perform a combustion and produce electrical power (E1) and/or mechanical power (M1). The power generation unit (40) is further electrically coupled to the chlor-alkali plant (10) and/or mechanically coupled to the compressor (20) so that the electrical power (E1) produced by the power generation unit (40) is supplied to the chlor-alkali plant (10) and/or at least part of the mechanical power (M1) is used to drive the compressor (20).
Absstract of: WO2026162388A1
The present disclosure relates to a green hydrogen power plant (1) comprising a renewable energy generation facility (11); a hydrogen production facility (12); and an 5 energy storage unit (13) to store electrical energy; and a plant controller (14) configured to: determine (101) a total value of electrical energy demanded by the hydrogen production facility (12) to operate continuously during an energy production cycle period of the renewable energy generation facility (11); calculate (102) an energy threshold for the energy production cycle period based on said total value of electrical 10 energy demanded by the hydrogen production facility (12); detect (103) whether the current electrical energy produced at said instant by the renewable energy generation facility (11) reaches the energy threshold; in response of detecting that the current electrical energy produced by the renewable energy generation facility (11) is above or equal to the energy threshold, generate (104) an instruction for controlling the 15 renewable energy generation facility (11) to direct excess electrical energy to the energy storage unit (13); and in response of detecting that the current electrical energy produced by the renewable energy generation facility (11) is below the energy threshold, generate (105) an instruction for controlling the energy storage unit (13) to supply the hydrogen production facility (12) with the stored electrical energy to allow 20 the hydrogen production facility (12) to o
Absstract of: US20260225880A1
The invention provides a system and method for the distributed generation and storage of hydrogen utilizing solid-state chemicals. Surplus electrical energy from renewable sources, such as solar and wind, is converted into green hydrogen, stored in the form of sodium borohydride (NaBH4). This solid-state storage medium facilitates safe and efficient hydrogen containment, overcoming limitations in transportation and storage. The hydrogen can be regenerated for use in electricity and heat generation across residential, commercial, agricultural, and industrial applications, including refueling facilities. A cycle of NaBH4 synthesis, hydrogen extraction, and regeneration using renewable energy ensures long-term sustainability. This innovation addresses grid intermittency, enables peak shaving, and decentralizes energy systems, contributing to energy security and a low-carbon economy. The process integrates renewable energy, electrochemical synthesis, and catalytic reactions to provide a scalable solution for modern energy challenges, supporting both immediate and long-term energy needs.
Absstract of: WO2026162948A1
A system comprising an electrolyser cell stack of electrolyser cell units, a separation unit and a Fischer-Tropsch reactor unit and a method for operating the system. The method comprising providing fuel to a fuel volume of the electrolyser cell stack, wherein the fuel comprises steam and carbon dioxide and is provided to the fuel volume at a first temperature. The method comprises powering the electrolyser cell stack with electrical energy thereby converting, at least partially, the steam into hydrogen and oxygen, wherein hydrogen is released into the fuel volume and oxygen is released into an oxygen volume. Carbon dioxide and hydrogen are at least partially converted into carbon monoxide and water in the fuel volume. Powering the electrolyser cell stack comprises controlling a voltage supplied at an endothermic value.
Absstract of: WO2026163573A1
The present invention reduces fluctuation of a grid voltage due to generated power from a renewable energy power generation system by adjusting a load of a water electrolysis system. This control device for a water electrolysis system, which is connected to a grid via an interconnection point shared with a renewable energy power generation system for outputting generated power generated using renewable energy to at least the grid and produces hydrogen by electrolyzing water upon reception of the output of the generated power, is characterized by including: a renewable energy-generated power acquisition unit that acquires renewable energy-generated power that is generated power outputted by the renewable energy power generation system; and a water-electrolysis-system load command-value setting unit that sets a value obtained by multiplying the acquired renewable energy-generated power by a prescribed proportional gain, as a command value for a water electrolysis load of the water electrolysis system.
Absstract of: US20260225080A1
0000 An oxygen evolution reaction (OER) catalyst for reaction in acidic media comprising: a Ru(M1M2M3M4)O<2 >catalyst, wherein the Ru(M1M2M3M4)O<2 >catalyst comprises an M1, an M2, an M3 and an M4 co-doped in ruthenium oxide (RuO<2>), wherein M1 is chosen from Cr, Fe, Co, Ni, Cu, Zi, Al, Ga, Ge, Mg, La and combinations thereof, wherein M2 is chosen from Cr, Fe, Co, Ni, Cu, Zi, Al, Ga, Ge, Mg, La and combinations thereof, wherein M3 is chosen from Cr, Fe, Co, Ni, Cu, Zi, Al, Ga, Ge, Mg, La and combinations thereof, and wherein M4 is chosen from Cr, Fe, Co, Ni, Cu, Zi, Al, Ga, Ge, Mg, La and combinations thereof.
Absstract of: US20260225878A1
0000 A hydrogen production system utilizes Floquet-engineered photonic excitation and at least one dielectric laser excitation unit, including an Ava-assisted dielectric laser amplifier accelerator (AADLAA), under integrated quantum AI control. The system employs a multi-chamber architecture comprising a first dissociation chamber, a second dissociation chamber for partially processed effluent, and a purification and reinjection chamber. Catalyst-free water dissociation is achieved using synchronized laser modulation, AI-directed routing, and adaptive feedback. An AI-regulated safety network provides photonic alignment control, thermal and pressure management, gas purity safeguards, predictive hazard modeling, and fail-safe isolation. A thermal recovery module captures heat from one or more chambers for feedwater preheating and energy stabilization. The modular architecture supports upgrades in optics, safety, and energy inputs, including solar thermal, nuclear waste-heat, and geothermal sources. Purified hydrogen, oxygen, and water vapor are recovered, compressed, and selectively reinjected for closed-loop operation, achieving high efficiency with reduced entropy loss.
Absstract of: US20260225879A1
A method of multi-stage ammonia cracking to produce hydrogen (H2), the method including providing a pressurized ammonia (NH3) to a first reactor including a first hydrogen-selective membrane tube at a first pressure. The method further includes catalytically cracking the NH3 within the first reactor to form H2 and nitrogen (N2). A first permeate from the first membrane tube includes the H2, and a first retentate from the first membrane tube includes unreacted NH3. The method further includes recovering the first permeate as a pressurized H2 product stream. The method further includes providing the first retentate to a second reactor including a second hydrogen-selective membrane tube at a second pressure that is lower than the first pressure. The method further includes catalytically cracking the unreacted NH3 within the second reactor to form additional H2 and N2. The method further includes recovering a second permeate as an additional H2 product stream.
Absstract of: DE102025000418A1
Die Erfindung betrifft ein Verfahren zur Entfernung von Gasblasen (P) aus einer kontinuierlichen Flüssigphase (1), die hierbei durch einen Abscheidebehälter (B) geführt wird. Kennzeichnend herbei ist, dass die Koaleszenz der Gasblasen (P) durch ein Hilfsgas (4) unterstützt wird, das unter Bildung von Hilfsgasblasen (H) in die Flüssigphase (1) eingeleitet wird.
Absstract of: DE102025104344A1
Elektrolysevorrichtung zur Erzeugung von Wasserstoff aus Wasser mit Hilfe von elektrischem Strom, mit einem Zellstapel aus mehreren Zellstapelelementen, die Elektrolysezellen ausbilden, mit Endplatten (16), zwischen welchen der Zellstapel aus den mehreren Zellstapelelementen angeordnet ist und verpresst ist, wobei die Zellstapelelemente und die Endplatten (16) des Zellstapels sich in Stapelrichtung der Zellstapelelemente erstreckende Strömungskanäle (23) für Wasserstoff, Strömungskanäle (24) für Wasser und Strömungskanäle (25) für Wasser und Sauerstoff bilden, und mindestens eine Endplatte (16) mindestens eine Inspektionsöffnung (26) aufweist, über die eine Inspektionseinrichtung in mindestens einen der Strömungskanäle (23, 24, 25) einführbar ist.
Absstract of: WO2026164246A1
Provided is an adhesive sheet which comprises a substrate layer comprising a polymer having a sulfur atom in the molecule and an adhesive layer disposed on the substrate layer on the side of one surface thereof, wherein the adhesive layer comprises a styrene-based block copolymer and a tackifier.
Absstract of: US20260226640A1
The invention relates to a bipolar plate (34) for an electrolyzer (44), wherein the bipolar plate (34) comprises a plurality of media channels (36), i.e. at least one H2O inlet port (38), an H2O/O2 outlet port (40), and an H2 outlet port (42). Bipolar plates (34), in the form of repeating components (48), are arranged in the electrolysis cell stack (46) of the electrolyzer (44) one over the other, each of which is arranged so as to seal a port (38, 40, 42), such that an insert seal (56) is fixed on an X/Y plane (86) between two respective bipolar plates (34) lying one over the other. The invention additionally relates to the use of the bipolar plate (34) in an electrolysis cell stack (46) of an electrolyzer (44).
Absstract of: US20260229568A1
The invention relates to a system for solid-state electricity storage and solid-state electricity generation that allows electricity to be stored when the renewable energy sources produce excess electricity and electricity to be generated when the electricity demand on the market exceeds the electricity production from renewable energy sources. The system comprises a solid-state electricity storage device having a first electrolysis device for producing chlorine from a melt of zinc chloride and solid zinc, a second electrolysis device for producing hydrogen from water, a first reactor for producing hydrogen chloride, and a vessel with a water sprayer for producing hydrochloric acid. The system further comprises a solid-state electricity generation device having a second reactor for reacting zinc and hydrochloric acid to produce hydrogen and a fuel cell for generating electricity.
Absstract of: US20260225925A1
0000 The present disclosure relates to methods of sequestering CO2 comprising a first cathodic chamber, performing a first alkaline process, a first anodic chamber, performing a first acidic process, and dechlorinating a solution by contacting the solution with a dechlorinating agent. Also provided herein are systems comprising a first cathodic chamber and a first anodic chamber.
Absstract of: US20260226631A1
An electrolyte solution comprising an electrolyte, wherein the electrolyte is used in an amount ranging between 1 wt % to 10 wt % of the electrolyte solution; an ionic liquid, wherein the ionic liquid is used in an amount ranging between 1 wt % to 5 wt % of the electrolyte solution; and a solvent, wherein the solvent is used in an amount ranging between 75 wt % to 98 wt % of the electrolyte solution.
Absstract of: US20260226638A1
An electrode for use in the electrolysis of water under alkaline conditions, comprising a nickel metal substrate, a ceramic material with a perovskite-type structure comprising an oxide of at least one metal selected from among lanthanides including lanthanum, cerium and praseodymium, where said ceramic material is forming a coating on said nickel metal substrate, and metal nanoparticles are socketed into the said ceramic material. The metal nanoparticles facing the alkaline solution have electrochemical activity, whereas the metal nanoparticles facing the said metal substrate form an anchoring points between the metal substrate and the said ceramic material.
Absstract of: US20260226637A1
The present disclosure concerns an electrocatalytic system and methods of the use thereof for the generation of hydrogen at both electrodes. In aspects, the present disclosure concerns an anode of a copper-silver bimetallic alloy, Cu3Ag7, and a basic anolyte with an aldehyde therein. The aldehyde reacts with the hydroxyl groups from the catholyte to produce hydrogen and the catholyte reacts water therein with the electrons from the anolyte to also produce hydrogen in a highly Faradaic efficient system. Application of the present disclosure not only provides for production of clean hydrogen, but also offers an approach for aldehyde decontamination.
Absstract of: US20260225881A1
0000 Provided herein are water-reactive aluminum compositions comprising aluminum or an alloy thereof and an activating metal alloy (e.g., a non-eutectic activating metal alloy comprising bismuth, tin, indium, and gallium; or an activating metal alloy comprising bismuth, tin, and indium). Some water-reactive aluminum compositions provided herein contain no gallium. Also provided herein are methods of activating aluminum to provide water-reactive aluminum compositions. Further provided are fuel mixtures comprising the water-reactive aluminum compositions described herein and water-reactive aluminum compositions with increased gallium content; and methods of providing hydrogen and/or steam using the water-reactive aluminum compositions described herein.
Absstract of: US2024240328A1
0000 A water electrolysis stack in which a water electrolysis cell is laminated, a water supply side path for supplying water to the water electrolysis stack, and a hydrogen side path for recovering hydrogen generated from the water electrolysis stack are provided, and the water supply side path includes a pump which is a power source for supplying water to the water electrolysis stack, an ion exchanger arranged between the pump and the water electrolysis stack, a bypass which is a path for flowing water from the pump to the water electrolysis stack without passing through the ion exchanger, a valve for adjusting an amount of water flowing to the bypass, and a controller for adjusting a valve.
Absstract of: AU2024406508A1
A separator for alkaline water electrolysis comprising: - a porous support (100) and on at least one side of the support, in order: - an optional porous layer including a Polymer A (200), and - a non-porous layer including a Polymer B (300), characterized in that the separator is obtainable by coating on the porous support (100) or the optional porous layer (200) a Polymer B solution having a viscosity of at least 400 mPa.s, measured at 20°C and a shear rate of 100 s-1, and wherein the separator has a Bubble Point, measured according to ASTM F316, of at least 5 bar.
Absstract of: US20260225903A1
0000 A system and method of producing ammonia comprises reacting a nitrogen feed gas and a hydrogen feed gas in a reactor to form ammonia, wherein the reaction produces a reaction mixture comprising ammonia gas, unreacted nitrogen and unreacted hydrogen, absorbing the ammonia from the reaction mixture in an absorber column containing an absorber, the absorber comprising a support and a metal halide, outputting the ammonia absorbed by the absorber, and recycling the unreacted nitrogen and unreacted hydrogen.
Absstract of: CA3296799A1
Disclosed is an e-methanol SAGD plant system applicable to unconventional oil production areas capable of producing e-methanol using CO2 and carbon-reduced green hydrogen generated by a plant configured to recover bitumen using only a mixture of eco-friendly hydrogen generated by a water electrolysis apparatus and natural gas and steam instead of expanding solvent SAGD (ES-SAGD), which is a recovery method using steam, natural gas, and an additive (a solvent) used to reduce the steam-to-oil ratio (SOR), which impacts environmental pollution, when recovering an oil component from subterranean oil sands based on the widely adopted steam-assisted gravity drainage (SAGD) technology, among methods of recovering bitumen from oil sands.
Absstract of: EP4786037A2
This disclosure relates to polymer electrolyte membranes, and in particular, to a composite membrane having at least two reinforcing layers comprising a microporous polymer structure and a surprisingly high resistance to piercing. This disclosure also relates to composite membrane-assemblies and electrochemical devices comprising the composite membranes of the disclosure, and to methods of manufacture of the composite membranes.
Absstract of: US2025101608A1
An illustrative example embodiment of an apparatus and method includes providing a weave body downstream of an electrolyzer, purifying hydrogen by demisting a hydrogen stream exiting the electrolyzer via flow through the weave body; and de-oxidizing the hydrogen stream during flow through the weave body.
Absstract of: GB2703568A
Methods for producing synthetic fuels (synfuels) include reacting hydrogen and carbon dioxide in with a first catalyst (wherein a first catalyst bed inlet temperature in the rWGS reactor ranges from 250-400 degrees C), and an adsorbent in a first reverse water gas shift (rWGS) reactor to produce hydrogen, carbon monoxide, and water; cooling the hydrogen, carbon monoxide, and water produced in the rWGS, to produce a cooled syngas; separating, from the cooled syngas, water to produce a syngas comprising carbon monoxide, hydrogen, unconverted carbon dioxide, and methane; purifying the cooled syngas; reacting the cooled syngas with a second catalyst to produce a synthetic hydrocarbon solution; and purifying the synthetic hydrocarbon solution to produce a final product. A corresponding system is also claimed. No fig
Absstract of: EP4787698A1
0001 Provided in the present application are an isolation circuit for a hydrogen production system and a renewable energy hydrogen production system comprising same. The isolation circuit includes at least one direct-current conversion module and at least one DC-AC converter. The direct-current conversion module comprises a single-output port and a multi-output port, the single output port of the direct-current conversion module being in coupled connection with the DC side of the DC-AC converter, the multi-output port of the direct-current conversion module being in coupled connection with a plurality of external unidirectional power flow units and/or bidirectional power flow units, and each unidirectional power flow unit at least comprising a hydrogen production unit. The AC side of each DC-AC converter is in series coupled connection with an external alternating-current power grid or direct-current power grid. The present solution simultaneously satisfies application requirements of two coupling scenarios, effectively integrates various types of external units, and combines all components in systems into one, thus facilitating positioning of faults and repair while reducing costs.
Absstract of: EP4786651A1
0001 An off-grid hybrid electrolytic hydrogen production system provided in the present application comprises a new energy power generation unit and an energy storage unit. A power conversion unit converts electric energy output by the new energy power generation unit and the energy storage unit into electric energy suitable for hydrogen production. An electrolysis unit comprises a proton exchange membrane hydrogen production module and a solid oxide electrolysis module, used to produce hydrogen after the introduction of electric energy. A controller uses control of charge and discharge of the energy storage unit to track an electric energy fluctuation value output by the new energy power generation unit, so that a value of total electric energy power fluctuation output by the new energy power generation unit and the energy storage unit is within a set range. The described solution provided by the present application can improve the hydrogen production efficiency of the entire hydrogen production system, and ensure that the hydrogen production system can achieve off-grid operation. Moreover, the present application eliminates the influence of power generation fluctuation of a new energy power generation unit on a hydrogen production result, by means of causing the total power fluctuation output by the new energy power generation unit and the energy storage unit to be within a set range.
Absstract of: EP4529979A1
0001 Disclosed is a process for producing thermal energy and base chemicals and a reactor used for this process. The reactor contains a reaction space for oxidizing metal fuel with water and optionally other oxidants. The reaction space is connected at its outlet with a separation device for solids contained in the product gas leaving the reaction space. In the reaction space a first flame is generated which triggers the reaction of metallic fuel with oxidant to generate a second flame within the reaction space. The first flame is generated by using a fuel mixture which is introduced into the reaction space via one or more feed lines. At the end of this feed line(s) an ignition device acts on the fuel to ignite the first flame which in turn triggers the formation of the second flame. The thermal energy generated by the oxidation reaction is recovered by using one or more heat exchangers which may be placed at different lociations of the reactor. 0002 With the reactor and the process of this invention hydrogen and/or cabon monoxide is generated from metal fuel and water or CO<2>. When using water and carbon dioxide as oxidant a mixture of hydrogen and carbon monoxide is produced. These products can be used as base chemicals in various processes.
Absstract of: EP4530376A1
The invention relates to a modular electrolysis system comprising mulitple modules, wherein each of the mulitple modules comprises a support frame and at least one interface accessible from outside the support frame and configured to connect the module with at least one of the remaining modules, the mulitple modules comprising a water-gas coarse separation module downstream an anode outlet of the electrolysis cell module, and a water-gas fine separation module downstream a liquid outlet of the water-gas coarse separation module.
Absstract of: WO2025068691A1
The present invention provides a process for preparing solid, non-porous, de-alloyed electrocatalyst particles, the process comprising the steps of: providing solid, non-porous, platinum group metal alloy precursor particles PMn in which P is a platinum group metal and M is at least one alloying metal; in a de-alloying step to provide the solid, non-porous, de- alloyed electrocatalyst particles; supplying carbon monoxide to the precursor particles under conditions which remove at least some of the metal M from the surface of the precursor particles; wherein the de-alloyed electrocatalyst particles are particles of a platinum group metal alloy PMX in which P is a platinum group metal and M is at least one alloying metal, wherein the total atomic composition relative to P of M at the surface of the de-alloyed electrocatalyst is lower than the total atomic composition relative to P of M in the bulk of the de-alloyed electrocatalyst, and wherein x is less than n.
Absstract of: EP4786653A1
Provided is an electrolysis system in which current efficiency of an electrolytic hydrogenation reaction is improved by restricting the amount of water migrating to a cathode while also supplying moisture to an electrolyte membrane and reducing resistance of the electrolyte membrane. Provided is an electrolysis system including an electrolyte membrane having proton conductivity, a cathode containing a catalyst for an electrochemical reaction involving protons, an anode containing a catalyst for oxidizing water to produce protons, and a structure that supplies water vapor to the anode, wherein the anode catalyst layer contains, in part thereof, an ionomer having proton conductivity, and a ratio of (002) diffraction peak intensity of carbon relative to (110) diffraction intensity of Ir oxide of the anode catalyst layer and ohmic resistance of the electrolysis system are within specific ranges.
Absstract of: WO2025124791A1
The invention relates to an offshore electrolysis system (100) comprising a wind turbine (1) having a tower (19), which is anchored to the seabed, and having an electrolysis plant (5), wherein the electrolysis plant (5) is connected to the wind turbine (1) by a supply line (11), and wherein the electrolysis plant (5) has an electrolyser (13) which is arranged in a container (9), wherein the container (9) is arranged below sea level (25). The invention also relates to a method for operating a corresponding offshore electrolysis system. In this method, water is broken down into hydrogen (H2) and oxygen by an electrolyser (13) of the electrolysis plant (5), which electrolyser is located below sea level (25), wherein the hydrogen (H2) produced is transported away via a product gas line (7).
Absstract of: WO2025068713A1
The specification describes bilayer electrolyte membrane comprising: a first layer comprising a polymer electrolyte having particles of a recombination catalyst dispersed therein; and a second layer comprising a polymer electrolyte not having any recombination catalyst dispersed therein; wherein the thickness of the bilayer electrolyte membrane is 40-60 µm; the concentration of recombination catalyst in the first layer is 1-100 µg/cm2; and the bilayer electrolyte membrane is a single coherent polymer film. Also described is a method for preparing the bilayer electrolyte membrane, a catalyst coated membrane for an electrochemical device comprising the bilayer electrolyte membrane, and a fuel cell comprising the catalyst coated membrane.
Absstract of: EP4786049A1
0001 The present invention relates to a catalyst composite and a polymer electrolyte membrane including same, wherein the catalyst composite is manufactured by complexing platinum and a metal having a higher ionization tendency than platinum with a functional support. When applied to a polymer electrolyte membrane, the catalyst composite effectively reduces the gas permeating from the counter electrode.
Absstract of: WO2025068933A1
The present invention relates to an integrated system for demineralization and/or purification of water and for the simultaneous production of hydrogen comprising a heat-dissipating element thermally connected to a system for demineralization and/or purification of water which is hydraulically connected to an electrochemical cell producing hydrogen, wherein the system for demineralization and/or purification of water is a system operating through the principle of thermal distillation via membrane and comprises at least two units, each comprising a first chamber, inside which waste water to be demineralized and/or purified flows under pressure and a second chamber, inside which demineralized and/or purified water flows under pressure in the opposite direction with respect to the direction of flow of the waste water, the two chambers being separated by a preferably microporous hydrophobic membrane, wherein the at least two units are placed thermally in series and hydraulically in parallel with continuous flow, wherein each unit is hydraulically connected to a source of waste water and a source of demineralized and/or purified water, in particular wherein each first chamber comprises an inlet portion, hydraulically connected to the source of waste water, for introduction into the first chamber of waste water, while each second chamber comprises an inlet portion, hydraulically connected to the source of demineralized and/or purified water, for introduction into the second chamber
Absstract of: WO2025067620A1
According to the invention it is provided a method for controlling a grid connected power converter having a DC side with a DC link and an AC grid side, and being configured to control power supply to a hydrogen electrolyzer stack. The power supply to the hydrogen electrolyzer stack is controlled by controlling the DC link to thereby control hydrogen production. The method comprises: determining a grid voltage reference; providing a grid forming control for controlling at least the phase angle of the voltage of the power converter using a grid forming controller, operating according to a grid forming algorithm, the grid forming controller being configured to emulate inertia through control of the voltage of the power converter towards the grid voltage reference; the grid forming controller emulating inertia by charging and discharging an inherent capacitance of the electrolyzer stack; monitoring at least one operating parameter of the hydrogen electrolyzer stack; and limiting a change in charging level of the inherent capacitance based on the monitored operating parameter of the electrolyzer stack.
Absstract of: EP4786656A1
Provided are a hydroxide ion-conductive membrane including a porous substrate and a hydroxide ion-conductive polymer disposed at least in pores of the porous substrate and having a thickness of the hydroxide ion-conductive membrane of 5 µm or more and less than 50 µm, in which the polymer has 50% by mole or more of a constituent component (I) derived from a polyfunctional polymerizable monomer having a total of two or more atoms of at least one of an oxygen atom, a sulfur atom, or a nitrogen atom in a structural moiety other than a polymerizable group in constituent components of the polymer, and a method for producing the hydroxide ion-conductive membrane, and a membrane electrode assembly, and a method for producing hydrogen and a hydrogen production system, each using the membrane electrode assembly.
Absstract of: EP4786655A1
Provided are a membrane electrode assembly having a structure in which a cathode catalyst layer, a hydroxide ion-conductive membrane, and an anode catalyst layer are laminated in this order, in which a tensile strength (a) and a breaking elongation (b) of a water-swollen body of a polymer contained in the cathode catalyst layer and/or the anode catalyst layer and a tensile strength (c) and a breaking elongation (d) of a water-swollen body of a hydroxide ion-conductive polymer constituting the hydroxide ion-conductive membrane satisfy the following relationships (Ri) and (Rii), a method for producing hydrogen, and a hydrogen production system. Tensilestrengtha>tensilestrengthcBreakingelongationb>breakingelongationd
Absstract of: WO2025124766A1
The invention relates to an electrolytic cell (01) for the electrolysis of CO2, comprising a cathode side (02) and an anode side (03). The electrolytic cell (01) comprises a cathode plate (04), a gas chamber (06), a gas-diffusion layer (08), a catalyst layer (09), a water chamber (07) and an anode plate (05). The contacting of the catalyst layer (09) is optimized by using a plurality of current bridges (10). To this end, these current bridges (10) are electrically conductively connected to the cathode plate (04) and to the catalyst layer (09) while penetrating the gas-diffusion layer (08).
Absstract of: GB2703615A
A method 300 of operating an electrolyser system comprising a plurality of stacks of electrolyser cell units wherein production rate differs between stacks, comprising identifying 305 a first subset of stacks characterised by a first production rate at a nominal temperature and voltage; identifying 310 a second subset of stacks characterised by a second production rate at the nominal temperature and voltage; identifying 315 an overall production rate target; determining 320 a plurality of subsidiary production rate targets for the respective subsets of stacks based on dividing the overall production rate target by the number of stacks; deriving 330 a value for a first control parameter for the first subset of stacks to satisfy their subsidiary production rate target; and controlling 325 the plurality of stacks at the overall production rate target using a first control parameter derived for the first subset of stacks. Also disclosed is a method comprising calculating first and second collective production rates for the first and second subsets of stacks; identifying that the first collective production rate is greater than the second collective production rate; and controlling the plurality of stacks using at least one control parameter derived for the first subset of stacks. Figure 3
Absstract of: CN122503912A
本发明公开了一种兼具安全运行与快速复启的电解槽控制系统及方法,通过气体纯度异常判定阈值:氢中氧>0.2%、氧中氢>1.5%。当检测到气体纯度不达标时,系统自适应提升电解槽运行负荷,通过强化电解液循环、均衡槽内工况抑制气体互窜杂质;若超负荷调节无效,系统立即进入安全待机模式。对管路氮气置换、排出不合格气体,向电解槽施加微电压维持电极活性,全程保持槽温与碱液循环;安全待机模式持续时长不超过24h。本发明无需停机即可规避传统停机产生的逆电流对电极的衰减损伤,通过24小时限时安全机制严控运行风险,大幅减少设备启停频次,兼具运行安全性与快速复启能力,有效延长电解槽电极、隔膜使用寿命,适用于各类大中型碱性水电解制氢系统。
Absstract of: CN122507055A
本发明公开了基于光伏电解制氢的直流电输出适配控制系统,涉及直流电输出适配控制技术领域,主要是针对光伏电解制氢中,缺乏对电解槽老化状态的精准识别与分级管控的技术问题,本发明中,先结合制氢过程中的电流、电压及效率参数曲线,精准识别电解槽恒定状态与波动状态下的老化异常,针对性采取停机维护、错峰运行或强度调节等措施,避免老化加剧与制氢效率下降,再以环境温度、气压为核心参数,检测运行环境对制氢效率的干扰,及时调整环境控制策略或效率参数设定,保障制氢稳定性,最后结合季节变化划分光伏时段,根据满负荷与低负荷运行的参数差异,结合季节光照变化调整运行参数,实现制氢供需与光伏出力的动态适配。
Absstract of: CN122503907A
0001 本发明涉及电催化材料。本发明提供了一种钒掺杂镍磷化物双功能电催化剂的制备方法,包括以下步骤:(1)水热反应:将镍源、钒源、氟化铵、尿素加入水溶解,室温条件下磁力搅拌混合均匀,将预处理后的碳布浸入,进行水热反应,干燥,得到亲氧性钒掺杂的氢氧化镍前驱体;(2)磷化处理:将磷酸盐与氢氧化镍前驱体分别置于两个陶瓷舟中,在氩气气氛下焙烧,升温,保温,冷却至室温,即得钒掺杂镍磷化物双功能电催化剂。本发明提供的钒掺杂镍磷化物双功能电催化剂,通过引入亲氧性钒元素重构界面氢键网络和诱导肼双位点吸附,实现了优异的析氢与肼氧化反应动力学,同时有效缓解了活性组分溶解、晶格应力累积等问题,从而实现了超长稳定运行。
Absstract of: CN122503890A
本发明公开了一种电解水制氢系统及热管理方法,包括:电解槽连接氢分离器的输入端和氧分离器的输入端,氢分离器的气体输出端连接氢气洗涤器,氧分离器的气体输出端连接氧气洗涤器,氢分离器和氧分离器的液体输出端依次连接换热器、电加热器、碱液循环泵和电解槽,换热器的热循环输出端依次连接S3三通球阀、S2三通球阀、S1三通球阀、冷却水循环泵和换热器的热循环输入端,S3三通球阀与S2三通球阀之间还并联设置有蓄热水箱,S1三通球阀和冷却水循环泵之间还并联设置有冷却塔。本发明通过余热回收储存利用,搭配电加热,增大冷启动碱液升温速率,减少冷启动时间,减少冷启动人、物力消耗,提高能源利用率。
Absstract of: CN122499730A
本发明公开了一种低温等离子体催化储能技术及设备,涉及可再生能源利用、等离子体催化及电能化学储存领域。一种低温等离子体催化储能技术,主要包括以下操作步骤:步骤一、将设备电源接入公共电网或可再生电源,启动控制柜与中控屏,检查系统自检项,由电解槽电源启动电解槽与液流泵;步骤二、通过纯水器向纯水箱供应电解用纯水,液流泵将纯水箱内的纯水输送至电解槽;本发明通过将电解水制氢系统与多通道并联介质阻挡放电等离子体催化反应器模块化集成,以可再生电力为输入,制氢后与氮气或二氧化碳等配气引入反应系统,通过低温等离子体与催化协同作用转化生成氨、甲醇、甲烷等高能化学产物,实现电能化学储存。
Absstract of: CN122503895A
0001 本发明涉及电解制氢技术领域,公开了一种泡沫镍负载催化剂及其制备方法和应用、一种电解制氢的方法。所述制备方法包括:将含M1源的有机溶液和含M2源的水溶液混合,得到前驱体溶液与泡沫镍接触并进行静置反应,得到泡沫镍负载催化剂;其中,M1和M2均为二价金属元素,各自独立选自Co、Fe、Ni和Zn中的至少一种,且M1≠M2。该制备方法采用一步异质成核的有机‑无机溶剂诱导自组装纳米花结构催化剂;同时,将其用于电解制氢,显著提高了电催化氧析出反应的催化性能和稳定性。
Absstract of: CN122499813A
本发明提供一种催化甲酸分解产氢催化剂的制备方法,属于催化材料技术领域。该催化剂以具有大π共轭体系的g‑C3N4为载体,负载金属纳米颗粒(钯、铂及其合金),通过浸渍还原法或光还原法实现金属颗粒在载体表面的高分散负载。本发明利用g‑C3N4的π共轭体系与金属纳米颗粒的d轨道形成d‑pπ相互作用,显著降低金属表面电子密度,促进甲酸根离子与金属活性位点的结合,在室温下实现甲酸向H2和CO2的100%选择性转化。所制备催化剂具有催化活性高、稳定性好、制备工艺简单,尤其Pd/g‑C3N4及Pt‑Pd/g‑C3N4催化剂的TOF值显著优于传统载体负载催化剂,为甲酸制氢技术的工业化应用提供了高效催化材料。
Absstract of: CN122503887A
0001 本发明涉及氢能制备技术领域,具体地说,涉及一种中压式碱性水电解制氢设备,其包括电解槽以及与电解槽相连通的分离罐,所述分离罐的排气端设置有稳压阀,还包括储液罐,内部储存有备用液体,并与分离罐连通;控制机构,包括随所述分离罐内液位同步升降的漂浮件和限位机构,所述漂浮件根据液位的高度变化,驱动限位机构在第一位置与第二位置之间切换。本发明通过所设的控制机构跟随分离罐液位变化,当电动补水机构失效导致液位异常下降时,控制机构可强制锁闭稳压阀,利用分离罐自身憋压所产生的气压升高,作为判断电解槽仍在产气的状态信号和驱动后续动作的动力源。随后通过感压驱动阀开启储液罐与分离罐之间的补水管路。
Absstract of: CN122501824A
本发明公开了一种利用锰介导的水岩反应制氢的方法,包括以下步骤:(1)取含锰橄榄石进行破碎和研磨处理,得含锰橄榄石粉末;(2)将含锰橄榄石粉末和氯化钠稀水溶液混合,调节反应温度为150~450℃,控制压强为0.1‑100MPa,进行水岩反应,收集气体样品并去除水蒸气即得。该方法采用的新型矿物产氢剂锰橄榄石,同样在自然界大量分布,且可人工合成,并在锰铁矿冶炼废渣中作为废料被遗弃,易获得,原料充足;与传统的镁铁橄榄石相比,锰橄榄石产氢效率快30%左右,产氢量高达2‑16余倍;制氢工艺简洁、稳定,可大规模工业化应用。
Absstract of: CN122503896A
0001 本发明公开了一种强酸中稳定的铱‑三氧化钨析氧催化剂的制备方法及其应用,催化剂技术领域。本发明以六氯化钨为原料,氯化锂与氯化钾的混合盐为熔盐体系,将三者混合均匀后空气气氛煅烧;煅烧后的混合盐用盐酸溶解,离心、洗涤、干燥后得到钨酸前驱体;随后将钨酸前驱体在氩气条件下退火得到正交晶相的三氧化钨;进一步通过KOH溶液刻蚀构建富金属钨空位缺陷的三氧化钨载体,再经IrCl<3>溶液浸泡负载,空气氛围煅烧,制备得到正交晶相铱‑三氧化钨催化剂。本发明制备的正交晶相铱‑三氧化钨催化剂在强酸体系中展现出优异的OER催化性能与长期稳定性,解决了传统铱基催化剂在强酸环境中稳定性差、成本高的技术瓶颈。
Absstract of: CN122499581A
0001 本发明涉及电解水制氢设备的技术领域,提供一种电解水制氢用T型耦合式气液分离冷凝一体化装置及工作流程,包括壳体,所述壳体包括水平分离段、垂直冷凝段和集液段,所述集液段与所述垂直冷凝段位于同一垂直面且垂直冷凝段位于集液段的上方,所述水平分离段与垂直冷凝段、集液段连通并共同构成T型结构;所述垂直冷凝段与所述水平分离段的交汇处形成气体转向通道,使初步脱液后的气体由水平流动转变为垂直向上流动,所述转向通道行成导流过渡结构,避免气体流动产生涡流导致二次夹带。本发明采用三级协同净化,气液分离与除沫效率优异采用气液旋流初分+冷凝深度脱水+丝网除沫三级协同处理机制,配合强旋流场强化液滴脱离、均流板优化气流分布,可高效去除气体中夹带的电解液雾滴与水蒸气。
Absstract of: CN122503898A
本发明公开了一种电解水制氢涂层及其制备方法,属于表面工程技术领域。所述电解水制氢涂层的制备方法包括以下步骤:(1)采用激光诱导表面改性技术对金属基底进行表面纳米化处理,随后进行等离子体处理,得到预处理基体;(2)采用原子层沉积技术在预处理基体上沉积致密钛基纳米层;(3)采用化学气相沉积技术在底层上沉积掺杂纳米材料中间层;(4)采用物理气相沉积技术在中间层上沉积NiFe2O4高活性催化材料顶层;(5)采用等离子体增强化学气相沉积技术在顶层表面沉积导电功能聚合物保护层。本发明制备的电解水制氢涂层具有优异的附着力、催化活性和长期稳定性,使用寿命较长。
Absstract of: CN122503897A
0001 本申请提供了一种NiMn‑LDH析氧电极及其制备方法,所述NiMn‑LDH析氧电极的制备方法包括以下步骤:以导电基底为工作电极,置于电镀液中进行电沉积处理,电镀液含有镍盐、锰盐以及聚四氟乙烯,在导电基底上沉积形成NiMn‑LDH催化层。本申请通过将导电基底在含有镍盐、锰盐、导电盐以及聚四氟乙烯分散液的电镀液中进行电沉积处理,所形成的NiMn‑LDH催化层具有由亲水的催化剂活性中心和分散的疏水聚四氟乙烯位点组成的非均相表面,既能缩短气泡停留时间,提升传质效率,消除气泡屏蔽效应,又能增强催化层与导电基底、催化层内部之间的结合强度,提升NiMn‑LDH析氧电极的机械稳定性与服役寿命。
Absstract of: JP2026125887A
【課題】水などの酸素発生源から酸素を発生させる触媒において、酸素発生に必要な電圧を低下させることができる触媒、その触媒を有するアノード電極、および電気化学反応器を提供する。【解決手段】酸素発生源から酸素を発生するための触媒であって、2つのCu原子と、ハロゲン原子と、N原子含有有機配位子と、有する金属錯体である、触媒である。【選択図】なし
Absstract of: CN122499802A
0001 本发明公开了一种中空球状CdS/Ag<2>S光催化剂及其制备方法和应用,属于光催化材料制备技术领域。制备方法包括以下步骤:水解缩合制备SiO<2>模板纳米球;将SiO<2>模板纳米球分散于水中,加入柠檬酸钠、镉源、氨水和硫源进行回流反应,得CdS/SiO<2>复合纳米球;将CdS/SiO<2>复合纳米球分散于有机溶剂中,再加入银源进行阳离子交换反应,得CdS/Ag<2>S/SiO<2>复合材料;采用刻蚀法去除SiO<2>,即得。本发明还公开了中空球状CdS/Ag<2>S光催化剂及其应用。本发明可解决现有CdS光催化剂光生载流子复合率高、光腐蚀严重、比表面积小且本征活性低的问题,应用前景广泛。
Absstract of: CN122503889A
0001 本发明公开了一种防泄漏的水雾制氢装置,包括:雾化装置,所述雾化装置的外壁固定连接有电解装置,所述电解装置的外壁固定连接有过滤装置,所述过滤装置的外壁固定连接有储存装置,本发明涉及制氢装置技术领域。该防泄漏的水雾制氢装置,通过设置电解装置和储存装置,电解环节中,密封罩与电解腔通过卡环、卡扣的机械锁止结构紧密贴合,配合密封罩内设的密封圈形成双重密封,可有效阻挡电解产生的混合气体外泄;储存环节里,密封板初始密封储存腔,密封环通过夹爪的精准夹紧进一步强化密封,且夹爪的锁止由拉杆与卡盘、复位弹簧协同实现,确保储存过程中氢气零泄漏。
Absstract of: CN122503913A
0001 本公开提供一种绿电氢氨协同控制系统、方法、装置、设备及存储介质,主要技术特征包括:管理模块,用于根据生产运行数据及可再生能源发电预测数据,生成生产调度指令;其中,生产调度指令至少包括目标制氢量、目标储放氢量及目标合成氨量;制氢控制模块,用于基于目标制氢量,确定电解槽群组中的各个电解槽的目标功率,控制各个电解槽基于对应的目标功率执行制氢;储氢控制模块,用于基于各个电解槽的实时产氢量及目标储放氢量,控制储氢设备执行充氢操作或放氢操作;空分与制氨控制模块,用于基于目标制氢量及目标合成氨量,确定空分装置及合成氨装置的控制参数,以达到目标合成氨量。
Absstract of: CN122499848A
本申请属于纳米光催化材料技术领域,公开了一种介孔TiO2/香豆素掺杂石墨相氮化碳(CM‑CN)复合光催化剂及其制备方法和应用。本发明首先采用结晶驱动的单胶术组装法制备具有均匀介孔结构的TiO2颗粒,用热缩聚法将二羟基香豆素与尿素混合处理后进行高温煅烧,得到CM‑CN;再用溶剂分散促进技术将CM‑CN与介孔TiO2在溶剂中自组装后制得介孔TiO2/CM‑CN复合光催化剂。该介孔TiO2/CM‑CN复合光催化剂具有多级孔结构、高比表面积、优异的亲水性与牢固的界面结合力,实现了光生载流子的高效转移与分离,可构建绿色、稳定、高活性的光催化体系。该材料制备流程简便、原料成本可控、无二次污染,光催化性能显著,具备规模化生产和推广应用的良好潜力。
Absstract of: CN122512780A
本发明公开了一种制氢电源、可再生能源制氢系统及制氢电源控制方法,该制氢电源包括第一级AC/DC变换器和第二级DC/DC变换器,第一级AC/DC变换器的输入端用于连接构网型变流器的输出端,第二级DC/DC变换器的输入端连接第一级AC/DC变换器的输出端,其输出端用于连接电解槽的输入端;制氢电源被配置为根据构网型变流器输出端的电压频率和/或电压幅值自动调整其输出功率,以维持构网型变流器输出端的电压频率和/或电压幅值稳定。本申请的制氢电源能够在可再生能源功率波动时自主维持交流母线稳定,避免制氢系统因功率缺额而停机,保障制氢业务连续性,并延长电解槽使用寿命。
Absstract of: CN122501825A
0001 本发明公开了一种便捷式化学制氢剂,成分组成包括金属铝、氧化钙、氯化钠、氯化镁、二氧化硅,金属铝、氧化钙、氯化钠、氯化镁、二氧化硅的质量比为:金属铝:氧化钙:氯化钠:氯化镁:二氧化硅=45%~55%:35%~45%:1%~10%:1%~5%:1%~5%。本发明利用二氧化硅的作用在于快速吸收原料中的水蒸气,同时氯化镁除了协助吸收水蒸气还能在反应过程中起到缓和pH的作用,避免反应之后的水溶液pH值过高导致气体不宜吸入,而有效吸收包装中的氧气以及后续储存过程中透过包装渗透进来的氧气,避免氧气跟铝粉过度接触产生氧化铝,导致铝粉不能有效的参与反应了。
Absstract of: CN122500208A
0001 本发明涉及析氢电极材料制备技术领域,特别是涉及一种析氢阴极催化剂的制备方法、产品及应用。该析氢阴极催化剂的制备方法,包括以下步骤:将镍源、钼源、柠檬酸、高价金属盐、碳酸氢钠及尿素溶于溶剂中,配制成混合溶液;对混合溶液进行第一温度的恒温加热反应,之后加入有机溶质进行第二温度的恒温加热反应,得到前驱体;对前驱体进行热处理,得到析氢阴极催化剂;高价金属盐为Co、Zr、Cr、Ce、Ti、Nb、La金属盐中的至少一种。本发明提供的分段式成核生长制备方法所制备的高价金属掺杂NiMo基析氢阴极催化剂为不易团聚的超细粉体,比表面积大,产率高,具有良好的析氢活性,和耐氧化稳定性。
Absstract of: JP2026125682A
0001 【課題】 本発明は、上記事情に鑑み、電解質膜、特にアニオン交換膜型水電解法に有用であるポリマーと、それを用いた電解質膜を提案するものである。具体的には、アルカリ耐久性に優れ、更には電解性能に優れる電解質膜用ポリマーの提供を目的とする。 【解決手段】 下記式(1)で表される骨格を構成単位中に有するポリマー。 [化1] [式(1)中、R<1>は、それぞれ独立に、イオン交換基又はハロゲノ基で置換されていても良いC13-C20の直鎖状、分岐状又は環状のアルキル基を表す。] 【選択図】なし
Absstract of: CN122503888A
0001 本申请涉及电解水制氢技术领域,公开了一种面向纯水电解的一体化膜电极,该膜电极由质子交换膜、复合催化层及界面处的三维连续铂金属网络组成,复合催化层由非贵金属催化剂、羟基化碱性氧化物及阴离子树脂制成,制备通过在界面引入铂颗粒层后进行原位重构,使铂动态溶解并再沉积,形成贯穿锚定在界面两侧的导电网络,利用三维连续铂网络显著降低了界面接触电阻,通过机械互锁增强界面稳定性;利用羟基化氧化物构建局部弱碱性环境,配合铂网络阻隔作用,使非贵金属催化剂能够在纯水工况下稳定运行;同时,铂网络可催化氧化渗透氢,抑制了氢脆风险。本申请最终实现了高活性、低成本且高安全性的纯水电解。
Absstract of: CN122503903A
本发明公开了一种磷掺杂镍铁复合氧化物碱性电解水催化剂及其制备方法,涉及电解水制氢技术领域。所述催化剂以泡沫镍为基底,表面负载化学式为NiFeOx:P的磷掺杂镍铁复合氧化物,其中Ni与Fe原子比为1‑4:1,磷掺杂量为0.5‑3 wt%,并呈垂直纳米片结构,片层厚度10‑30 nm。其制备方法包括:泡沫镍预处理;将镍盐、铁盐和磷源溶于醇‑水混合溶剂得前驱体溶液;水热反应生长前驱体;惰性气氛煅烧。该催化剂在1 M KOH中10 mA/cm2过电位低至225 mV,塔菲尔斜率38 mV/dec,100小时衰减<5%,且成本低廉,适用于碱性电解水制氢领域。
Absstract of: CN122503886A
本发明公开了一种风光电力离网制氢碱性电解槽的电力补偿协同系统,属一种电解制氢系统,包括风光发电单元与碱性电解槽,碱性电解槽接入直流母线,直流母线还接入风光发电单元;可逆固体氧化物燃料电池堆也接入直流母线,直流母线还接入PLC控制单元;可逆固体氧化物燃料电池堆与碱性电解槽分别接入氢气储运装置;PLC控制单元用于通过阈值判断当前碱性电解槽与可逆固体氧化物燃料电池堆的输入状态。通过在系统中集成可逆固体氧化物燃料电池堆,并通过PLC控制单元根据阈值判断切换不同的系统模式,即闭环保护体系使碱性电解槽运行过程中无需外部干预,解决了碱性电解槽在离电网运行时受到风光发电波动影响,频繁启停和功率波动的不匹配问题。
Absstract of: CN122503892A
0001 本发明涉及电解水制氢技术领域,提供了一种超纯水电解制氢用低能耗恒温供水系统,包括PEM电解槽、超纯水供给单元、循环供水回路、局部净化及旁路单元、数据获取模块、数据分析模块、能耗判定模块和能耗控制模块;数据分析模块根据电流、电压、循环流量及进回水温度确定热负荷匹配参数,并确定水质表征状态和流动表征状态;能耗判定模块先判断升温是否为真实热负荷;在非真实热负荷状态下,能耗控制模块根据水质和流动状态确定能耗异常原因,并执行降泵降冷、短时流动纠偏、局部净化或降低电流密度控制,以降低恒温供水附加能耗。
Absstract of: CN122499645A
0001 本发明涉及一种气液混合在线清洗工业废水电解制氢传质膜装置及方法,属于清洁能源与氢能技术领域。本发明的装置包括壳体、隔板、疏水透气膜、环形射流分布器及气液混合单元,其中,壳体经隔板分隔为碱液腔与废水腔,环形射流分布器环绕疏水透气膜碱液侧布置。所述方法通过监测跨膜压差或补水速率触发,先停止或旁路进料并排空残留液体,再经环形射流分布器向碱液侧喷射气液混合流体反吹膜孔污染物,同步通过废水侧通入反洗水协同冲刷携带污染物排出,无需拆卸膜组件或使用化学药剂。本发明实现原位自动清洗,无清洗死区,能显著延长膜寿命、提升系统运行连续性,降低运维成本与安全隐患,兼顾经济性与环境友好性。
Absstract of: CN122503891A
0001 本发明公开了一种密封结构及碱性电解槽,涉及电解槽密封技术领域,包括双极板,通过在双极板设置第一弯折部和第二弯折部,同时套设一体成型的密封层,并在密封层轴向两侧分别设置第一密封部、第二密封部和第一槽、第二槽,其中一个密封层的第一密封部能够嵌于另一个密封层的第一槽,其中一个密封层的第二密封部能够嵌于另一个密封层的第二槽,实现相互嵌合,能显著提升密封能力,并且在压紧时能实现定位,能简化装配流程。通过第一弯折部、第二弯折部和密封层代替极框和密封圈,能够简化结构和组装工序,避免了因定位偏差导致的密封失效问题。同时,拆卸后密封层的密封结构仍保持完整,可重复装配使用,从而降低运维成本。
Absstract of: CN122503904A
本发明公开了一种宽层间距二硫化钼催化剂及其制备方法和应用,属于电解水制氢能源转换技术领域,该制备方法包括以下步骤:采用钼源和硫源配制二硫化钼前驱体溶液,然后将二硫化钼前驱体溶液和含碳层间距调控剂进行水热反应,经离心洗涤后得到宽层间距二硫化钼催化剂;其中,所述含碳层间距调控剂用于在水热反应过程中插入二硫化钼层间,提高所得二硫化钼催化剂的(002)晶面层间距。本发明的宽层间距二硫化钼催化剂有利于电解液的渗透和氢气泡的释放,能有效避免活性位点阻塞、增强催化剂的本征电导率,加速材料内部电荷传输、增加析氢反应活性位点和提升催化剂本征析氢催化活性。
Absstract of: CN122499838A
本发明提供一种氨基化多壁CNTs/TpBD‑COF复合材料及其制备方法,所述氨基化多壁CNTs/TpBD‑COF复合材料通过溶剂热法在所述氨基化多壁CNTs表面上原位生长TpBD‑COF层,形成以氨基化多壁CNTs为核、TpBD‑COF为壳的复合结构。所述TpBD‑COF呈现其花瓣为片状结构组装而成的花状形貌,所述氨基化多壁CNTs外径为8‑15 nm,长度约为50μm。本发明提供的氨基化多壁CNTs/TpBD‑COF复合材料在可见光照射下呈现出优异的光催化裂解水制氢性能,产氢速率高达9.10 mmol·g‑1·h‑1,且经过多次循环测试后,表现出良好的性能稳定性和结构稳定性,是一种高效、稳定的新型光催化剂。
Absstract of: WO2021209547A1
The present invention relates to a method for the preparation of an electrode suitable for electrocatalysis comprising an electrocatalytically active material, in particular an anode for alkaline water hydrolysis, said method comprising the steps of (i) providing a carrier suitable for an electrode comprising an electron conductive material, (ii) providing a precursor mixture suitable for the combustion synthesis method, (iii) transferring to the electron conductive material of the carrier of step (i) the precursor mixture of step (ii) to produce an electrode precursor; and (iv) heating the electrode precursor obtained in step (iii) to produce self-ignition of the transferred precursor mixture. The invention also relates to an electrode obtainable by the method of the invention and to its use in electrocatalysis.
Absstract of: US2025027210A1
A PEM electrolyzer PTL is created from micro-expanded mesh metal foil layers to allow for a precise level of control over the thickness of the layers, porosity, tortuosity, pore size, interlayer connectivity, and surface roughness. Pore sizes range from 3 μm to 30 μm with a porosity (mesh open area) of 10-50%. A PEM anode pack assembly is formed from the micro-expanded PTL layers with a multi-layer expanded metal flow field and bipolar plate. The 3 subcomponents are diffusion bonded together to form an integrated pack and PVD coated on the outside surfaces.
Absstract of: EP4501433A1
Process of separating hydrogen from an effluent gas produced by an endothermic ammonia cracking reaction, said effluent gas comprising hydrogen and nitrogen, said process comprising a step of pressure swing adsorption separation of the effluent gas, said step comprising separating the effluent gas by pressure swing adsorption according to a pressure cycle, thereby producing a hydrogen product gas and generating off gas, the pressure cycle comprising an off gas generation period of time during which said off gas is generated, said off gas generation period of time comprising :- a fuel off gas generation period of time during which a fuel off gas is generated,- a nitrogen richer off gas generation period of time during which a nitrogen richer off gas is generated, said nitrogen richer off gas having a higher nitrogen content than the fuel off gas, wherein the process comprises :- routing the fuel off gas to a furnace (5) and combustion of said fuel off gas in said furnace (5) to provide heat to the endothermic ammonia cracking reaction,- diverting the nitrogen richer off gas from the furnace (5).
Absstract of: WO2025216105A1
Provided is a stainless steel material for solid oxide water electrolysis, which contains, on a mass basis, 0.030% or less of C, 1.6% to 3.5% of Si, 0.10% to 1.00% of Mn, 0.050% or less of P, 0.0030% or less of S, 16.0% to 21.0% of Cr, 1.00% or less of Al, 0.030% or less of N, 1.00% or less of Nb, 1.00% or less of Ti, 1.00% or less of Ni, and 1.00% or less of Cu, with the balance being made up of Fe and impurities.
Absstract of: WO2025126055A1
A system is described for the production of hydrogen and thermal power through a spontaneous electrochemical oxidation-reduction reaction, formed by at least one reactor (1) composed by a loading line (2) that introduces a reacting material into a reaction basin (6); at least one discharge body (12) for the hydroxide produced during the reaction, wherein the pH is transformed into a desired value by the introduction of an acidic solution through a loading line (13); at least one loading line (3) of water that is supplied into the reaction basin (6); at least one cathode body (5) made of porous material containing gaseous oxygen; at least one loading line (4) that allows the oxygen to be replenished at the cathode body (5); at least one porous material filter (7) for separating the gaseous hydrogen from solid residues produced during the reaction; and at least one discharge line (8) for the release of gaseous hydrogen. The system is configured to perform a process for the production of hydrogen and thermal power through an oxidation-reduction reaction between a material acting as an anode, a material acting as a cathode and a material acting as an electrolyte.
Absstract of: WO2025147706A1
The present disclosure relates, generally, to an electrochemical system and method of producing hydrogen peroxide.
Absstract of: WO2025163301A1
A catalyst-coated membrane for a water electrolyser is provided. The catalyst-coated membrane comprises a thin film coating of an oxide of iridium on a first major surface of an electrolyte membrane. The thin film coating satisfies the following requirements: (i) the thin film coating has a first region adjacent to the electrolyte membrane and a second region distal to the electrolyte membrane; (ii) the porosity of the second region of the thin film coating is higher than the porosity of the first region of the thin film coating; and (iii) the thin film coating has a total porosity in the range of and including 20 to 60 vol%.
Absstract of: KR20260118584A
0001a 본 발명은 킬레이팅 에이전트와 전이금속 전구체가 용해된 침출용액에 니켈 및 침출금속의 합금을 침지시켜 침출금속을 침출시킴과 동시에 갈바닉 반응을 통해 전이금속 또는 전이금속 화합물을 침출금속이 침출된 위치에 담지하는 레이니 복합 니켈 촉매전극의 제조 방법에 관한 것이다.
Absstract of: CN224086689U
A chemical loop system capable of adjusting the ratio of produced hydrogen to produced heat in one embodiment comprises a cyclone separator, a combustor, a reducer, an oxidizer, a buffer tank and a gas supply device which can be sequentially communicated from top to bottom, the ascending pipe is used for communicating the air supply device at the bottom and the cyclone separator at the top end; wherein the carrier particles can continuously circulate up and down in the system.
Absstract of: WO2025143196A1
This water electrolysis electrode comprises a substrate and a catalyst portion. The catalyst portion includes Raney nickel particles and metal particles that contain nickel as a main component. The metal particles are in contact with the Raney nickel particles and include aluminum. The ratio of the total number of moles of aluminum to the total number of moles of nickel in the Raney nickel particles is greater than the ratio of the total number of moles of aluminum to the total number of moles of nickel in the metal particles.
Absstract of: AU2024412736A1
This cathode for water electrolysis includes a catalyst part and a reverse current absorber that is electrically connected to the catalyst part, wherein the reverse current absorber contains a hydrogen storage alloy, and the hydrogen storage alloy contains Al.
Absstract of: EP4786650A1
0001 A membrane electrode assembly includes: an anode; a cathode; and an electrolyte membrane provided between the anode and cathode. The anode includes: a porous and conductive anode conductive transport layer; and an anode catalyst layer provided between the anode conductive transport layer and the electrolyte membrane. The anode catalyst layer includes first sheet layers and first gap layers, each first sheet layer and each first gap layer being alternately stacked. The cathode includes a porous and conductive cathode conductive transport layer, and a cathode catalyst layer provided between the cathode conductive transport layer and the electrolyte membrane. The cathode catalyst layer includes second sheet layers and second gap layers, each second sheet layer and each second gap layer being alternately stacked. A porosity of the cathode conductive transport layer is higher than a porosity of the anode conductive transport layer.
Absstract of: EP4786649A1
A membrane electrode assembly includes an anode having an anode catalyst layer, a cathode having a cathode catalyst layer, and an electrolyte membrane provided between the anode and the cathode. An ion exchange equivalent weight of the electrolyte membrane is equal to or higher than an ion exchange equivalent weight of the cathode catalyst layer. An ion exchange equivalent weight of the anode catalyst layer is higher than the ion exchange equivalent weight of the cathode catalyst layer and is equal to or higher than the ion exchange equivalent weight of the electrolyte membrane.
Absstract of: FR3171664A1
Système d’électrolyse comprenant une pluralité d’ensembles modulaires. L’invention concerne un système d’électrolyse (1) caractérisé en ce qu’il comprend une pluralité d’éléments modulaires, la pluralité d’éléments modulaires comprenant : au moins un module d’électrolyseurs (4) comprenant N stacks d’électrolyseurs, N étant un nombre entier naturel supérieur ou égal à deux, les N stacks d’électrolyseurs étant configurés pour produire, à partir d’un fluide, un premier mélange et un deuxième mélange,un groupe de traitement du premier mélange (6), ledit groupe de traitement du premier mélange (6) comprenant : au moins un module de séparation du premier mélange (10), configuré pour séparer le premier mélange en un premier gaz et en ledit fluide,au moins un premier module de recirculation (12) configuré pour assurer la recirculation du fluide vers l’au moins un module d’électrolyseurs (4), la pluralité d’éléments modulaires étant physiquement déconnectée les uns des autres et configurée pour être interconnectée fluidiquement entre eux. (Figure 1)
Absstract of: CN122479791A
0001 本发明涉及一种氮化碳包覆镍钌合金催化剂及其制备方法与应用,属于氨分解催化剂制备技术领域。包括步骤:按照镍与钌的摩尔比为(7~9):(1~3)的比例,将镍源和钌源混合为金属盐混合物;按照络合剂与金属盐混合物中的金属元素的摩尔比为(1.0~1.5):1,将络合剂、金属盐混合物、助燃剂与溶剂混合为混合液;去除混合液中设定量的溶剂后获得第一混合物,将混合物在第一保护气氛下于200~350℃引发自蔓延燃烧反应,获得第二混合物;将第二混合物在第二保护气氛下加热至600~750℃焙烧1~3h,获得所述氮化碳包覆镍钌合金催化剂。络合剂避免了传统浸渍法在干燥和焙烧过程中因溶质偏析导致的颗粒聚集,自蔓延放热燃烧反应促进Ni‑Ru完全互溶,形成晶格匹配的合金结构。
Absstract of: CN122482403A
0001 一种无需外加牺牲剂的基于金属负载的塑料光催化制氢的方法,它属于光催化能源转化与塑料废弃物资源化利用技术领域。方法:一、塑料碱水解;二、制备Fe/TiO<2>催化剂;三、光催化产氢。本发明以塑料水解液为光重整底物,在不添加牺牲剂的条件下,利用金属负载催化剂实现塑料水解液的直接光重整产氢,解决了传统技术依赖牺牲剂、催化剂效率低等问题。本发明构建塑料水解‑光催化产氢闭环体系,突破传统塑料回收高能耗、低附加值的局限,将废弃塑料直接转化为高价值氢气,相同条件下产氢速率较未负载金属的TiO<2>显著提高;同时水解液无需分离提纯,无需外加牺牲剂,简化流程的同时降低了能耗与处理成本,实现“污染治理‑能源生产”的协同。
Absstract of: CN122484832A
0001 本发明公开了一种Fe<3>C/Fe/单壁碳纳米管复合电催化材料及其制备方法与应用,属于电催化析氢材料技术领域。本发明方法将对苯二甲酸、二茂铁和乙醇混合,通过加热搅拌形成均一前驱液,再经雾化和浮动催化剂化学气相沉积,一步原位合成Fe<3>C/Fe纳米颗粒镶嵌或部分包覆于单壁碳纳米管管束的复合电催化材料。本发明通过特定前驱体配方和工艺,协同调控了活性相与导电骨架的原位生长。所得材料在碱性电解液中表现出优异的析氢反应活性,过电位低至191±2 mV,且稳定性好。该方法简单可控,易于规模化,在电解水制氢领域具有广阔应用前景。
Absstract of: CN122484838A
0001 本发明公开了一种柠檬酸辅助CeO<2‑x>修饰的NiMo合金催化剂的制备方法及应用,包括S100,选取导电基底并对导电基底进行除杂;S200,通过镍盐水溶液和钼盐水溶液制备镍钼混合盐溶液;S300,将导电基底放入镍钼混合盐溶液后,进行水热反应,获得镍钼氧化物前驱体;S400,通过铈盐与柠檬酸制备含铈纳米颗粒溶胶;S500,将镍钼氧化物前驱体在含铈纳米颗粒溶胶中得到CeO<2‑x>/NiMo复合前驱体;S600,将CeO<2‑x>/NiMo复合前驱体还原气氛中进行还原反应,得到CeO<2‑x>修饰的NiMo合金催化剂;本发明借助柠檬酸酯化交联实现CeO<2‑x>均匀包覆NiMo合金,所得催化剂在碱性电解水中兼具低过电位与超长大电流稳定寿命,制备工艺简单、成本低廉。
Absstract of: CN122484818A
本发明涉及电解水制氢技术领域,具体涉及一种铱锰氧化物催化剂及其制备方法和应用。商品化二氧化铱对OER反应的电催化稳定性不佳。针对上述问题,本发明提供一种铱锰氧化物催化剂,采用由硝酸钠与氢氧化钾按质量比1:1组成的复合熔盐介质进行高温煅烧,所得IrMnO催化材料在长时间析氧反应测试中表现出平稳的电位响应。计时电位曲线显示,催化剂在持续运行过程中电位无明显升高,未出现明显的活性衰减或材料溶解失活现象,其稳定性优于传统二氧化铱催化剂。
Absstract of: CN122484834A
本发明提供一种AlCoCrFeNi2.1/高熵氧化物/TiB2三元电催化剂及其制法与应用。该电催化剂包含高熵合金AlCoCrFeNi2.1、TiB2以及位于二者界面处的纳米级高熵合金氧化物,形成高熵合金/纳米级高熵氧化物/TiB2的三明治式三元异质结构。其制备方法包括:将AlCoCrFeNi2.1与TiB2混合后,采用分段式球磨工艺进行机械合金化处理,所得复合粉末负载于导电基底上,通过原位电化学氧化处理,在界面处原位生成纳米级高熵合金氧化物中间层。本发明电催化剂实现了析氧反应电催化剂的高催化活性、超长耐久性(1000小时)和优异耐海水腐蚀性能的协同提升。适用于电解水析氧反应及碱性海水电解。
Absstract of: CN122482525A
一种纳米级低价态铱钌氧化物催化剂及其制备方法与应用,属于纳米材料制备技术领域。催化剂晶体结构为单斜晶系,颗粒尺寸为纳米级,其中Ru和Ir分别稳定于+3~+4的混合低价态。与传统+4价金红石相不同,本发明催化剂的金属价态经历长时间催化后仍能保持低价态,避免了不可逆过氧化,同时氧化物骨架保持结构刚性。本发明还提供了该催化剂的制备方法,通过共沉淀、煅烧、混合溶剂热还原及惰性气氛热处理的组合工艺,实现晶相转变与价态调控。该方法操作可控、重复性好,所得催化剂兼具高活性和高稳定性,在10 mA cm−2电流密度下可连续稳定运行100小时以上,可作为酸性水分解制氢领域的高效阳极电催化剂,具有广阔的应用前景。
Absstract of: CN122484849A
本申请公开了一种离网光伏制氢系统的控制方法及相关装置,应用于离网光伏制氢系统的控制模块,该方法包括:获取离网光伏制氢系统的历史工作数据集;基于历史工作数据集确定离网光伏制氢系统对应的目标模型;目标模型用于对离网光伏制氢系统的运行过程进行仿真;基于预设优化算法和预设多优化目标对目标模型进行求解,得到最优配置参数集;基于最优配置参数集对离网光伏制氢系统进行控制,以实现预设多优化目标。采用本申请实施例,提升了离网光伏制氢系统的控制效果。
Absstract of: CN122484846A
本发明提供了一种电解水制氢用电解槽长期停机储存方法,包括以下步骤:步骤一:停机处理,将电解槽运行负载降为0,排空内部工作介质;步骤二:清洗置换,使用去离子水对电解槽内部进行冲洗,并通入惰性气体进行气体置换;本发明的有益效果是:在电解槽停机时使用大量去离子进行冲洗,一方面是为了使得里面的氧气和氢气可以充分排出,且防止停机时残留的电流对电解槽造成大的伤害;另一方面是为了将里面的脱落的材料等充分冲洗干净,防止长期储存时发生化学反应损伤里面的关键部件和材料。
Absstract of: CN122484790A
0001 本发明涉及电解水制氢技术领域,特别是涉及一种碱性电解水制氢用膜电极及其制备方法和应用,制备方法包括以下步骤:改性镍丝网;将两层改性镍丝网平行固定在模具中,向模具中加入膜前驱体溶液至没过上层改性镍丝网,进行溶剂蒸发和交联得到改性镍丝‑膜基底;在电解液中分别进行恒电位电沉积,得到具有催化剂的改性镍丝‑膜基底;浸泡在氢氧化钾溶液中,去离子水清洗后干燥,裁剪后得到膜电极。本发明采用上述步骤的一种碱性电解水制氢用膜电极及其制备方法和应用,膜电极为一体化结构,改性镍丝网被聚合物膜包埋,镍丝网与季铵化聚苯醚膜通过化学键合与机械互锁实现高结合强度,从根本上消除了分层失效风险,大幅降低欧姆电阻。
Absstract of: CN122484811A
0001 本发明公开了一种电解水阳极催化剂及其制备方法与应用,涉及锂离子电池回收技术领域。本发明以回收的钴酸锂电池正极材料为原料,利用过硫酸盐对钴酸锂正极进行表面调控,结合液相复合与热处理工艺,实现钌元素在钴酸锂表面的高效负载与掺杂,获得Ru/LCO‑PMS催化剂。该催化剂在酸性析氧催化反应中,表现出优异的电化学活性与稳定性。本发明将废弃钴酸锂锂离子电池高值化回收利用,实现了废弃电池正极材料高值转化,不仅为无害化处理废弃电池正极材料提供了新的思路,也为低成本、高性能电催化材料的制备提供了新的技术方案。而且原料成本低、工艺流程短、绿色无污染等特点,为废弃锂离子电池的回收及高值转化提供了高效的解决方案。
Absstract of: CN122484836A
0001 本发明属于电催化技术领域,具体涉及一种硼掺杂含钽高熵层状双氢氧化物及其制备方法和应用。该硼掺杂含钽高熵层状双氢氧化物的制备方法包括将镍源、铁源、钴源、钽源和钼源置于含有尿素和氟化铵的溶液中,得到混合溶液;向所述混合溶液中加入泡沫镍铁,经水热反应,得到负载在泡沫镍铁上的含钽高熵层状双氢氧化物;按照硼氢化钠、负载在泡沫镍铁上的含钽高熵层状双氢氧化物和硼氢化钠的加料顺序,将硼氢化钠和负载在泡沫镍铁上的含钽高熵层状双氢氧化物置于石英舟中,在通入饱和氩气的条件下进行程序升温硼化,得到硼掺杂含钽高熵层状双氢氧化物。采用该方法制备得到的硼掺杂含钽高熵层状双氢氧化物具有大电流密度下的高催化活性的特点。
Absstract of: CN122484841A
本发明公开了一种由Ni3Se2与CoFe基金属‑有机框架组成的复合电催化剂的制备方法及其在电催化析氧反应中的应用,该催化剂由Ni3Se2与CoFe基金属‑有机框架材料复合而成,属于纳米材料制备与新能源电化学技术领域。该方法通过复合CoFe基MOF与Ni3Se2合成了一种高活性的碱性OER电催化剂CF‑MOF@Ni3Se2。在三电极体系中,CF‑MOF@Ni3Se2电催化剂直接作为工作电极置于1 M KOH电解液中,进行电催化OER。由于两相组分间的电子相互作用及协同催化机制,显著降低了反应能垒,使其在碱性介质中表现出优异的OER性能。本发明主要目的在于合成新型高效非贵金属OER催化剂。
Absstract of: CN122494004A
0001 本申请提供了一种AEM电解槽氧中氢浓度预测方法及相关装置,所述方法包括:确定AEM电解槽对应的多个核心机制;多个核心机制包括:跨膜浓差扩散机制、压差对流机制、旁路电流电解机制和循环流道混合机制;根据多个核心机制中每一核心机制进行模型构建,得到多个流量模型;根据多个流量模型计算多个氧中氢流量;计算多个氧中氢流量之和,得到目标氧中氢流量;构建AEM电解槽对应的氧中氢理论计算公式;根据氧中氢理论计算公式对目标氧中氢流量进行计算,得到目标氧中氢浓度。可以通过AEM电解槽对应的多个流量模型计算氧中氢流量,再结合理论公式计算得出氧中氢浓度,从而脱离实验建模实现氧中氢浓度的精准预测。
Absstract of: CN122484700A
本发明属于材料科学领域,公开了一种基于退火增强的Ti‑Au复合耐蚀导电镀层制备方法、镀层及应用,该制备方法包括:选取钛片作为基底,并对基底进行预处理;选取Au靶材与Ti靶材,配置磁控溅射设备,并在配置后的磁控溅射设备中对预处理后的基底依次执行沉积处理,得到初始镀层基底;将初始镀层基底置于退火炉中,执行退火处理,得到目标镀层基底,以实现Ti‑Au复合耐蚀导电镀层的制备。本发明采用Au内层、Ti外层及Ti‑Au共溅射过渡层的复合结构,仅在内层使用Au贵金属,外层采用低成本、高耐蚀的Ti,可大幅减少Au的使用量,有效降低钛基双极板的制造成本,兼顾性能与经济性。
Absstract of: CN122482401A
本发明属于新能源技术领域,公开了一种氨醇共分解制氢的方法,包括以下步骤:将催化剂置于反应装置中,然后向反应装置中通入混合反应气,其中:混合反应气包括气态氨和气态醇,进行氨醇共分解反应,制得氢气。本发明提出了一种氨醇共分解制氢的方法,以氨和醇为混合反应气,在非贵金属催化剂的作用下,即制得高产率氢气。同时解决了氨分解的高催化剂成本及醇分解制氢过程中的积碳问题,提高了制氢产率。本发明的氨和醇在共分解过程中,氨的存在有效抑制了醇的积碳产生,两者发生协同效应,使制氢产率高于氨和醇单独裂解制氢的产率之和。
Absstract of: CN122484805A
本发明公开了一种磷化镍布电极的制备方法及其应用。所述方法包括:对镍布依次进行乙醇清洗、酸洗、碱活化及电化学氧化预处理,其中电化学氧化在6M KOH溶液中以镍布为工作电极、碳棒为对电极、Hg/HgO为参比电极,于0.7 V(vs. Hg/HgO)恒电压下处理1小时;随后一次磷化生成片状磷化镍;再以过渡金属与稀土金属混合离子溶液为电解液,在磷化镍布表面电沉积异质金属;最后二次磷化形成Ni5P10晶相,得到自支撑复合电极。该工艺简洁、无粘结剂,所得电极在碱性水电解中表现出高活性、低过电位和长寿命,适用于大规模绿氢生产。
Absstract of: CN122484833A
0001 本发明属于电催化及新能源材料技术领域,涉及一种分层析氧催化剂、制备方法及其应用。所述分层析氧催化剂负载于导电基底表面,所述分层析氧催化剂包括:底层保护层,所述底层保护层结合于所述导电基底表面,所述底层保护层为致密层,且所述底层保护层包含铁元素和硫元素;上层催化阵列,所述上层催化阵列设置于所述底层保护层背离所述导电基底的一侧,所述上层催化阵列为离散纳米阵列结构,且所述上层催化阵列包含镍元素。本发明解决了现有表面核壳包覆和均质阴离子插层方式中存在的传质与防护难以兼顾、外层结构易失稳以及底部界面抗氯腐蚀能力不足等技术问题。
Absstract of: CN122484840A
本发明属于电解水制氢电催化技术领域,具体涉及一种负载铂的Co3O4纳米复合电催化剂及其制备方法和应用。所述负载铂的Co3O4纳米复合电催化剂,包括基底以及分布在其表面的针状Co3O4,针状Co3O4的表面负载有铂原子簇。其中,基底表面分布针状Co3O4的方法如下:将六水硝酸钴、氟化铵和尿素溶加入水中,得到混合溶液。将基底放入混合溶液中,在100℃~150℃温度下水热反应4h~10h。冷却,洗涤,干燥,升温至300℃~400℃热处理1h~3h。所述六水硝酸钴、氟化铵和尿素的物质的量之比为1~3:4~7:19~21。本发明的针状Co3O4纳米复合材料在强酸性、中性和强碱性环境下均具备良好的催化活性和稳定性。
Absstract of: CN122484816A
本发明公开了一种缺陷富集的NiFe‑LDH非贵金属电催化剂及其制备方法,属于催化剂领域。所述制备方法包括以下步骤:将镍盐和铁盐溶于去离子水中,加入柠檬酸钠,溶解完全,记为A液;将尿素溶于去离子水中,搅拌至完全溶解,记为B液;将A液加热,在搅拌条件下将B液缓慢滴入A液中,使其充分混合;将预处理后的泡沫金属浸入上述混合溶液中,转移至反应釜中进行水热反应,反应结束后自然冷却,取出泡沫金属,清洗、干燥后得到NiFe‑LDH前驱体;将所得NiFe‑LDH前驱体置于碱性溶液中进行腐蚀处理,腐蚀结束后清洗、干燥,得到缺陷富集的NiFe‑LDH电催化剂。本发明为富空位LDH基电催化剂的设计提供了一条简便可行的新途径。
Absstract of: CN122484820A
0001 本发明公开了一种纳米片层状结构催化剂及其制备方法与应用,该制备方法包括如下步骤:将氧化钇、三氯化钌和三氯化铱溶解后,加入硝酸溶液进行反应制备得到凝胶;将所述凝胶干燥后,进行热还原反应,制备得到纳米片层状结构催化剂;所述氧化钇、三氯化钌和三氯化铱的添加摩尔比为:(8‑12):(0.5‑2):(0.5‑2)。本发明方案的方法原料简单,工艺流程简洁、易操作,适合大规模制备,反应过程绿色安全,没有其他有毒性。
Absstract of: CN122488875A
0001 本发明公开了一种碱性电解制氢系统温度与氧中氢综合控制方法,属于新能源技术领域。该方法将温度控制与氧中氢安全控制纳入分层协同框架,基于 Koopman 算子理论构建槽前温度及氧中氢状态预测模型,分别设计模型预测控制的温度双环控制策略与氧中氢安全控制策略。可在强功率波动运行工况下,抑制温度波动与阀门振荡;协同调节压力与碱液流量,降低氧中氢超限风险,提升系统动态适应性与功率调节范围,适用于可再生能源波动供电等变工况场景,有效提高制氢系统安全性、稳定性与运行性能。
Absstract of: CN122484801A
本发明涉及碱性电解水制氢电极材料技术领域,具体为一种适用于波动工况碱性电解水双层电极及其制备方法,其中,双层电极包括电极基材,为多孔网,作为支撑基底;催化层,涂覆在电极基材上,包括用于提高高粗糙度与强结合力的多孔雷尼镍催化层与用于提升活性与耐蚀性的纳米镍异质结催化层。本发明具有:高活性;高结合力;超稳定;耐波动;低成本。通过底层粗糙化+热处理强化界面结合,实现极低失重率;能够在反向电流与波动启停工况下无明显性能衰减;能够直接用于10kW级及以上碱性电解槽,连续运行3个月无电势抬升。
Absstract of: CN122487602A
0001 本申请实施例公开了一种消氢层寿命测试平台及测试方法。消氢层寿命测试平台包括:反应容器,具有气流通道和水流通道,反应容器用于安装分隔气流通道和水流通道的消氢层;气源装置,与气流通道连通,气源装置用于向气流通道供应氢氧混合气;以及检测装置,与气流通道连通,检测装置用于检测流经消氢层的气体中氢气的含量。该消氢层寿命测试平台可实现构建加速老化工况,直接强化消氢层的降解驱动条件,缩短测试周期,提升研发效率;同时其采用独立测试体系,在液态水环境下直接针对消氢层核心功能开展专项测试,排除干扰因素,使寿命评估结果更具可靠性。
Absstract of: CN122484800A
0001 本发明涉及电化学制氢技术领域,提供了一种析氢电极、其制备方法以及碱性电解水装置,包括:具有三维贯通多孔结构的多孔金属镍基底,包覆于多孔金属镍基底骨架表面的镍钼合金层,镍钼合金层为亲水疏气层,多孔金属镍基底通过氢气模板法电沉积得到且其孔道具有沿轴向逐渐扩展的锥形特征。与现有技术相比,本发明通过物理结构疏导与化学界面排斥的协同,锥形孔道在轴向建立拉普拉斯压力梯度主动驱动气泡加速排出,亲水疏气层大幅降低气泡粘附力,两者结合产生协同增强效应,实现气泡快速脱离,有效解决高电流密度下气泡滞留问题,显著降低电解能耗并提升运行稳定性。
Absstract of: CN122479774A
0001 本发明涉及一种ZnIn<2>S<4>/NiCo<2>O<4>光催化析氢的复合材料的制备方法及其应用。属于无机光催化领域。本发明在NiCo<2>O<4>原位生长出ZnIn<2>S<4>,形成异质结构,本发明在氙灯照射下,具有良好的光催化活性,复合后的材料的产氢速率最高大36.8mmol g<‑1>h<‑1>,可回收利用,循环稳定性良好。
Absstract of: CN122484787A
本发明属于太阳能集热器制氢技术领域,具体的说是基于宽光谱吸收光热材料的光热电解耦合制氢装置;包括太阳能集热器和制氢系统;所述太阳能集热器为集热器单元;所述反射镜的非反射面设有矩型架;所述矩型架两侧位于矩型架上下两侧均固定有侧板;位于同侧的两个相对的所述侧板之间均固定有三个连板;两个所述反射镜之间设有支架;所述支架顶部固定有连接套;所述连接套两侧设有集热管;所述支架与两个反射镜之间均设有第一弧板,且第一弧形板内开设有第一弧槽;所述第一弧槽位于反射面的一侧固定有第一擦拭层;本发明通过对反射镜与集热管的清洁,可以保障太阳能集热器稳定输出高温热能,满足电解水反应的恒温高温工况需求。
Absstract of: CN122484806A
0001 本发明提供一种电解水制氢用电极及其制备方法与应用,涉及电解水制氢技术领域,所述电解水制氢用电极包括:基体以及负载在基体上的催化剂,所述催化剂包含镍元素和稀土元素,所述催化剂具有微球与纳米棒相互交织的形貌;所述微球的直径为3~30 μm,所述纳米棒的长度为5~50 μm。本发明提供的电解水制氢用电极在大电流密度下具有优异的气泡管理能力。催化剂独特的微球与纳米棒相互交织的形貌能够有效切割气泡,阻止气泡合并长大,加速氢气逸出,从而降低传质过电位,提高大电流密度下的电解效率,明显提升电极的催化性能。
Absstract of: CN122484854A
本发明公开了一种电解水制氢的一体增压装置,包括:电解水制氢设备上的氧气管路出口端连接气气引射器氧气入口,气气引射器上还设置有空气管路和混合气体管路,混合气体管路的出口端连接气动增压设备的驱动端,气动增压设备连接液压油箱的吸油管路,液压油在气动增压设备中增压后通过高压液压管路储存在液压蓄能器中成为高压液压油,高压液压油驱动液驱增压泵对电解水制氢设备产生的氢气进行增压,增压后的氢气通过高压氢气管路存储在高压储氢瓶。本发明通过电解水制氢的副产物氧气进行氢气增压,高效利用电解水制氢产物,降低电解水制绿氢的使用成本,通过混合气体进行氧气利用,增加氢气加压的安全性。
Absstract of: CN122484825A
本发明公开了一种Al掺杂ZnO纳米棒压电催化剂及其制备方法与应用,涉及压电催化与半导体材料技术领域。所述Al掺杂ZnO纳米棒压电催化剂中Al元素的掺杂量为Zn元素的摩尔量的2‑5%。所述Al掺杂ZnO纳米棒压电催化剂通过水热法制备。本发明通过合理掺杂Al元素调控ZnO纳米棒载流子浓度与压电性能的平衡关系(Al掺杂引起晶格畸变,导致c轴晶格常数缩短、键角调整,从而同步提升载流子迁移率和压电极化能力),在显著提高电荷传输效率的同时避免压电极化削弱,从而实现高效、稳定的压电催化制氢。
Absstract of: JP2026124411A
【課題】水電解用電極触媒の製造における安全性及び水電解用電極の性能を高める。【解決手段】水電解用電極触媒1は、LDH20aと、酸化ニッケル(NiO)粒子10とを備えている。LDH20aは、2種類以上の遷移金属イオンを含んでいる。酸化ニッケル粒子10の表面は、LDH20aによって被覆されている。水電解用電極11は、水電解用電極触媒1を含んでいる。水電解セルのアノード及びカソードからなる群より選ばれる少なくとも1つは、水電解用電極11を含む。【選択図】図1
Absstract of: CN122484708A
本发明涉及PEM电解水制氢技术领域,公开了一种PEM电解水制氢催化剂卷对卷连续生产工艺和设备,设备包括依次连通的溅射腔室和氧化腔室,聚酰亚胺膜经放卷轴、导向辊贯穿两腔室后由收卷轴收卷,两腔室分别配置独立的抽气、控温、通气装置,且氧化腔室设特定宽度狭缝实现腔室隔离与膜体顺畅传输;工艺通过分腔室精准调控气压、气氛、温度等参数,依次完成铋金属膜磁控溅射、高温氧化构建纳米结构、催化剂磁控溅射负载的连续化操作。本发明实现了催化剂生产的卷对卷连续化,大幅提升生产效率,且制备的催化剂负载均匀、活性位点暴露充分,应用于膜电极后在1A/cm电流密度下电压仅1.7~1.8V,制氢性能优异。
Absstract of: CN122483342A
本发明公开了一种高熵氢键有机框架及其制备方法和应用,涉及氢键有机框架技术领域,该高熵氢键有机框架由至少两种不同的氢键有机构建单元共组装而成;高熵氢键有机框架具有至少五种不同类型的孔道结构,且孔道结构呈统计随机分布,形成非规整序列;每个氢键有机构建单元为具有羟基、胺基、羧基、磺酸基、脲基、酰胺、羰基、醚氧、含氮基团、含卤素基团、含磷基团、含硫基团、芳环、芳杂环、炔烃和烯烃官能团中至少一种的单体。本发明制备的高熵氢键有机框架具有优异的光催化活性,可作为光催化剂用于催化分解水制氢。
Absstract of: CN122484851A
本发明涉及一种自适应频率响应的集成辅助设施PEM电解槽最大效率点跟踪控制方法,方法包括以下步骤:建立辅助设施集成PEM电解槽数学模型;基于辅助设施集成PEM电解槽数学模型构建控制导向MIMO状态方程,定义电解效率指标;以电解效率指标为目标,基于状态方程构建MPC滚动优化问题,求解优化问题得到水阀开度、压缩机转速和温控系统功率指令;将指令发送给考虑水锤效应的电解槽的双闭环变换器进行参数整定,完成电解槽的电流和电压的控制。与现有技术相比,本发明具有使电解槽能够根据电网频率波动自适应调节输入功率,在实现快速频率支撑的同时兼顾制氢效率和系统运行稳定性等优点。
Absstract of: CN122484831A
0001 本发明公开了一种铁掺杂镍钼酸盐/硫化镍电解水催化剂及其制备方法和应用,属于电催化分解水技术领域。该铁掺杂镍钼酸盐/硫化镍电解水催化剂的制备方法包括如下步骤:S01、将铁源、镍源、钼源和硫源加入混合溶剂中,搅拌均匀,得到混合溶液;所述铁源与所述镍源中金属元素的物质的量比为(0.01~0.20):1;S02、将泡沫镍基底垂直置于步骤 S01的混合溶液中反应,然后自然冷却至室温,取出所述泡沫镍基底,清洗后干燥后,得到铁掺杂镍钼酸盐/硫化镍电解水催化剂。本发明采用一步水热法,制备过程简单,反应条件易于控制,成本较低,适于推广应用,制备的催化剂具有较好的稳定性,可作为双功能电解水催化剂进行使用。
Absstract of: CN122484837A
0001 本发明公开了一种非贵金属单原子修饰的二硫化钒催化剂及其制备方法与应用。所述催化剂由碳纤维自支撑导电网络、生长在碳纤维网络上的二硫化钒载体、以及锚定于所述二硫化钒载体表面的非贵金属单原子构成;其制备方法是先将碳纤维材料表面进行氧化预处理,再通过水热法在其表面原位生长二硫化钒材料,然后将表面生长二硫化钒的碳纤维材料浸泡在非贵金属源溶液中,干燥后通过退火还原法对其表面进行非贵金属单原子修饰,即得。该制备方法工艺简单、成本低廉、产率高、条件温和、所需设备简单、对环境友好,有利于实现工业化生产。将非贵金属单原子修饰的二硫化钒催化剂应用到电催化析氢反应中表现出优异的催化活性,在100 mA cm<‑2>电流密度下其最低过电位低至245 mV(相对于标准氢电极),塔菲尔斜率低至77.2 mV/dec。
Absstract of: CN122484850A
本申请涉及电解水制氢技术领域,公开了基于多孔基材的无气泡电解水方法,基于无气泡电解水装置运行,该装置包括多孔金属基材、膜电极及集流体;方法通过供水管路将纯水送入多孔金属基材内部,依靠毛细作用力扩散至两侧膜电极的贴合面;施加电位后,纯水在膜电极表面发生反应,生成的氢气和氧气呈气相穿过具有浓度梯度疏水涂层的集流体向外排出;生成的离子反向进入多孔金属基材内部相向扩散并中和为水分子。该方法实现了气液传输路径的物理隔离,避免气体在液相中成泡而遮挡催化活性位点,降低了极化过电位,结合阻抗与温差监测控制,提高了电解传质效率与设备运行寿命。
Absstract of: CN122479775A
0001 一种碳量子点与Z型异质结掺杂的复合光催化剂的制备方法及应用,涉及光催化材料领域,是要解决现有Mn<0.5>Cd<0.5>S光催化析氢性能较差的问题。方法:一、将NiCo<2>S<4>和Mn<0.5>Cd<0.5>S加入到无水乙醇中,超声,搅拌,蒸发至干,得到固体粉末;真空干燥,得到复合材料;二、将碳量子点溶液加入到复合材料中,超声,搅拌,真空干燥,得到CQDs/NiCo<2>S<4>/Mn<0.5>Cd<0.5>S复合光催化剂。本发明方法能有效促进光生电子‑空穴对的迁移与分离,还可显著提升电子传输速率,抑制在传输过程中的复合,最终提升了复合光催化剂的光催化性能。本发明用于制备析氢性能较高的光催化剂。
Absstract of: CN122484828A
0001 本发明公开了一种热诱导磁相变型水氧化催化电极材料及其制备方法和应用。本发明电极材料以负载于导电基底上Fe<3>O<4>为基体,掺杂过渡金属离子形成掺杂型Fe<3>O<4>催化剂,调控Fe<3>O<4>的磁矩、磁各向异性和电子结构,优化磁学性能、降低磁基态转变温度使其契合电解槽的工作温度,从而诱导掺杂型Fe<3>O<4>催化剂在该温区由亚铁磁态转变为顺磁态,降低电子转移势垒,提升催化效率。此外,过渡金属离子掺杂还可增加材料表面的催化活性位点,加速电极/电解液界面电子转移,进一步提升催化性能。本发明通过调控掺杂量调节磁相转变温度与催化性能,使电极材料具有较低的催化过电位和较快的催化反应动力学,且长期稳定运行,具有广阔的应用前景。
Absstract of: CN122483114A
本发明属于光催化技术领域,具体涉及一种聚集诱导发光材料、薄膜及其制备方法和应用。本发明提供的聚集诱导发光材料一方面能在太阳光照射下实现长时间高效的催化污水产氢,另一方面还能通过光催化作用杀灭污水里的有害微生物,起到净化污水的作用。
Absstract of: CN122484809A
本发明公开一种原位构筑的超低铱限域负载PEM电极材料及其制备与应用。以三维钛基多孔导电骨架为基底,经阳极氧化原位构筑通道曲率为0.025‑0.077nm‑1的纳米管结构,再通过脉冲偏压诱导铱前驱体在高曲率及缺陷位点选择性配位吸附,并经低温固载形成稳定铱单原子活性中心,得到可直接作为PEM电解水阳极使用的一体化电极。结果表明,60℃、纯水进料下,1A cm‑2和2A cm‑2时槽压分别为1.67V和1.8V,1A cm‑2稳定运行1050h,衰减率低于32μ V h‑1,阳极侧铱负载量低至0.11mgIr cm‑2。与传统粉体催化剂涂覆型阳极相比,本发明无需传统粉体催化层与独立PTL的多界面叠加,可直接作为PEM膜电极阳极侧使用,实现催化层与PTL功能耦合,缓解高电流运行下的局部过电位集中与结构不均匀劣化。
Absstract of: CN122484813A
本发明公开了一种具有三维连通网状结构的氧化铱催化剂的制备方法及催化剂,本发明以单分散二氧化硅微球为硬模板,将二氧化硅模板与含铱前驱体、硝酸钠混合球磨均匀,不添加任何有机溶剂;然后将混合物在空气气氛下加热至300~600℃进行亚当斯熔融反应,使铱前驱体氧化生成氧化铱;反应产物经水洗去除可溶性盐后,用碱液或氢氟酸溶液刻蚀去除二氧化硅模板,得到具有三维连通网状结构的氧化铱催化剂。本发明方法全程无需有机溶剂,工艺简单、环境友好;所制备的催化剂具有相互连通的开放网络骨架,孔道贯通性好,比表面积高达600~800 m²/g,克服了传统颗粒堆积型催化剂接触电阻大、传质受限的问题。
Absstract of: CN122484793A
0001 本发明涉及AEM电解水膜电极领域,公开了AEM电解水膜电极及其制备方法。该AEM电解水膜电极包括从下至上依次设置的阴极催化层、阴离子交换膜、消氢层I和阳极催化层;任选地,在阴极催化层和阴离子交换膜之间还设有消氢层II;消氢层I含第一消氢层和第二消氢层,第一消氢层中的消氢催化剂选自铂、钯、铱中的至少一种;第二消氢层中的消氢催化剂选自氧化铈、氧化铜、氧化铝、氧化锆、氧化铌、氧化钽、氧化钨、氧化钇、氧化锶和氧化钒中的至少一种。该AEM电解水膜电极减少了第一消氢层中贵金属催化剂的使用量,且避免了贵金属暴露于高电位下发生氧化腐蚀失去消氢效果的问题,在AEM电解水制氢消氢领域具有广阔的应用前景。
Absstract of: CN122484817A
本发明提供了一种电解水制氢阳极及其制备方法和应用。所述制备方法包括:S1、配制化学镀液,所述化学镀液包括铈盐和/或至少一种过渡金属盐,还包括氯化钠;S2、将镍基集流体浸入所述化学镀液中反应,反应结束后取出干燥;S3、重复步骤S2若干次,使集流体表面原位生成析氧催化层;并且,在所述配制化学镀液的过程中加入环氧化合物;或,在每次重复步骤S2的过程中,在化学镀液中加入环氧化合物。本发明通过在化学镀液中引入环氧化合物与氯化钠,诱导在集流体表面原位形成多金属氧化物沉淀,从而在微观尺度上增强了催化层与集流体的结合力,提高了催化剂在安培级电流密度下的抗脱落性与长期稳定性。
Absstract of: CN122484791A
0001 本发明公开了一种中高温蒸汽电解制氢系统及方法,属于氢能制备技术领域。包括:制氢单元、气体纯化单元、压缩储存单元、制冷供暖单元和供电单元。通过制氢单元、气体纯化单元、压缩储存单元、制冷供暖单元和供电单元的配合,实现了中高温余热蒸汽的高效电解制氢与产物低能耗压缩储存。制氢单元利用发电厂余热蒸汽作为热源和反应物,降低电解所需的电能消耗;气体纯化单元通过冷凝与气液分离,高效提纯电解产物;压缩储存单元利用输入蒸汽的剩余压力驱动活塞进行气体压缩,避免额外的高能耗机械压缩;制冷供暖单元为气体纯化提供冷量,并回收废热用于供暖,实现系统内部的能量梯级利用;供电单元采用风光互补供电模式,为系统提供稳定的可再生电力。
Absstract of: WO2025127526A1
According to exemplary embodiments of the present invention, a hydrogen production system is provided. The present invention comprises: a hydrogen generation unit configured to receive reduced iron from a reduced iron generation unit configured to generate reduced iron by reducing powdered iron ore in a reducing gas atmosphere, and to generate hydrogen from ammonia by bringing the reduced iron into contact with the ammonia; and a regeneration unit configured to receive the reduced iron from the hydrogen generation unit and to regenerate the reduced iron by reducing the reduced iron in a hydrogen gas atmosphere. According to other exemplary embodiments of the present invention, a method for producing hydrogen is provided.
Absstract of: US20260221479A1
0000 The present invention provides a reinforced ion-conducting membrane comprising: (a) a reinforcing layer comprising a porous polymer structure; and (b) a polymeric ion-conducting membrane material impregnated within the porous polymer structure; wherein the porous polymer structure comprises a polymer backbone based on nitrogen-containing heterocycles and the polymeric ion-conducting membrane material has a transition temperature Ta in the range of and including 60 to 80° C.
Absstract of: WO2026159929A1
Provided are an electrolysis cell stack, an electrolysis cell cartridge, an electrolysis cell module, and a method for producing an electrolysis cell stack which make it possible to suppress a decrease in H2/CO yield, even when a methanation catalyst is contained in a flow passage through which a generated gas generated by a hydrogen electrode via co-electrolysis flows. An electrolysis cell stack (101) according to the present disclosure comprises: an electrolysis cell (105) in which a hydrogen electrode (109), a solid electrolyte (111), and an oxygen electrode (113) are stacked, in this order; a flow passage (117) through which a generated gas generated by the hydrogen electrode flows; and a methanation suppression film (116) that covers the surface of a member (103), which defines the outer contour of the flow passage, on the side thereof on which the generated gas flows. The member defining the outer contour of the flow passage contains a methanation catalyst, and the methanation suppression film does not contain a methanation catalyst.
Absstract of: US20260218395A1
The invention provides an electroly ser system (10) comprising a heat storage unit (14) and an electrolyser (16). The heat storage unit (14) comprises at least one heat source infeed. The electrolyser (16) comprises at least one electrolyser cell (20), a steam inlet and at least one off-gas outlet. The off-gas outlet is connected to the heat source infeed to heat the heat storage unit (14). The heat storage unit (14) is configured to use its stored heat to produce steam for feeding into the steam inlet and for generating electrical power, either one at a time or both at the same time. The invention also provides a system comprising an intermittent or variable electricity source (12) and an electrolyser system (10) as defined above. The intermittent or variable electricity source (12) can be configured to power the electrolyser (16) and to heat the heat storage unit (14) via a heating element, either both at the same time or individually.
Absstract of: US20260218391A1
0000 A method of electrocatalytic dual hydrogenation includes loading a first hydrogenation solution and a second hydrogenation solution into a first hydrogenation compartment and a second hydrogenation compartment of an electrocatalytic hydrogenation assembly, in which the first hydrogenation compartment and the second hydrogenation compartment are separated from an electrochemical cell by a hydrogen-permeable anode and a hydrogen-permeable cathode. The method includes applying and maintaining a voltage to the electrochemical cell to reduce a cathode solution and to oxidize an anode solution to provide hydrogen in the cathodic compartment and/or the anodic compartment. The hydrogen may be absorbed through the hydrogen-permeable anode and/or the hydrogen-permeable cathode and hydrogenate an unsaturated substrate in the first hydrogenation solution and/or the second hydrogenation solution. The method includes producing a first hydrogenated product and a second hydrogenated product with a total Faradic efficiency from 150% to 200%.
Absstract of: US20260218394A1
0000 In a water electrolysis system, an AC-side connection end of a power converter is connected to an AC power grid, a series circuit constituted by at least one electrolysis stack and a circuit breaker connected to the at least one electrolysis stack is connected to a DC-side connection end of the power converter, a controller reduces the power flowing to the DC-side connection end before the electrolysis stack is isolated from the series circuit, while maintaining a speed at which the power converter reduces the power flowing to the DC-side connection end below a speed that allows a difference of an amplitude of a voltage of the AC power grid from a reference value to be less than a predetermined value, and when reaching a power level enabling disconnection of an internal DC circuit by the circuit breaker, disconnects the circuit breaker connected to the DC circuit and isolates the electrolysis stack from the series circuit.
Absstract of: US20260218066A1
0000 Subject of the invention is a method for producing fuel which comprises C8+ aromatics and C8+ hydrocarbons, the method comprising the steps: (i) converting a feed mixture comprising CO<2 >with H<2 >into a mixture comprising CO, C6+ aromatics and unsaturated C<2>-C<6 >hydrocarbons, wherein the CO<2 >is at least partially converted into methanol using a metal oxide-based catalyst and wherein the methanol is at least partially converted into C6+ aromatics using a zeolite-based catalyst, wherein said unsaturated C<2>-C<6 >hydrocarbons are subsequently at least partially converted into unsaturated C8+ hydrocarbons by oligomerisation, and (ii) alkylating C6+ aromatics from step (i) at least partially with unsaturated C<2>-C<6 >hydrocarbons from step (i) into C8+ aromatics using an acid catalyst different from the zeolite-based catalyst used in step (i).
Absstract of: AU2025213224A1
A system and method of making hydrogen from water. A reaction vessel is provided with an outer shell, a central shaft, and concentric inner tubes separated by annular spaces. Water is delivered to the annular spaces by a water pump through an inlet defined in the reaction vessel. The water courses along a tortuous flow path. That path begins at an inner annular space around a central shaft. It ends at an outer annular space. The water emerges from the reaction vessel through an outlet associated with a manifold. A vibratory stimulus is applied to the reaction vessel and water. Water molecules are dissociated into hydrogen molecules and oxygen atoms. These reaction products are delivered through the manifold along an effluent flow path to a receiving pressure vessel before deployment to a sub-assembly for harnessing clean energy.
Absstract of: AU2024420420A1
This electrolysis cell comprises: an ion exchange membrane; a power feeder which is provided on the surface of the ion exchange membrane and composed of a plurality of fibers formed in a sheet shape; a binder layer that covers the surface of each of the fibers; and an electrode catalyst layer that contains catalyst particles at least partially protruding from the surface of the binder layer. At least a part of the catalyst particles protrudes from the surface of the binder layer. Consequently, the surface area of the exposed portion of the catalyst particles is increased, and thus the contact area with an electrolyte can be increased.
Absstract of: US20260221470A1
0000 Problem To provide a catalyst-loaded carbon having a high initial activity and excellent durability. SolutionA catalyst-loaded carbon including catalyst particles and a carbon support, the catalyst particles being loaded on the carbon support. The carbon support has a crystallite size of 3.5 nm or greater and 9 nm or less, a BET specific surface area of 300 m<2>/g or greater and 450 m<2>/g or less, and a pore size of 5.0 nm or greater and 20.0 nm or less. The catalyst particles are made of platinum or a platinum alloy, have a crystallite size of 2.5 nm or greater and 5.0 nm or less and a surface area of 40 m<2>/g or greater and 80 m<2>/g or less.
Absstract of: US20260218393A1
0000 The invention provides a system for continuous generation of gases, the system comprising an electrochemical device and an active-material regeneration device.
Absstract of: US20260218390A1
Systems and methods are described for producing lithium hydroxide from lithium chloride through an electrolysis process.
Absstract of: US20260217522A1
0000 A process for producing a synthesis gas product by an endothermic reaction of a feedstock stream, including providing an ammonia fuel stream, performing a first combustion in which the ammonia fuel stream is partially burned, generating heat and a combustion flue gas stream comprising an unburned portion of ammonia fuel stream being not burned, providing heat from the first combustion and from the combustion flue gas stream to the endothermic reaction, thereby obtaining a cooled flue gas stream, performing a second combustion of the cooled flue gas stream in which the unburned portion of ammonia fuel stream is burned, and providing heat from the second combustion to the endothermic reaction.
Absstract of: WO2026159979A1
This synthetic fuel generation system comprises: a synthetic fuel generation device that generates a synthetic compound and water by reacting hydrogen and carbon dioxide; a combustion unit that is supplied with a generated gas generated by the synthetic fuel generation device and combusts the generated gas; a heat supply unit that supplies combustion heat in the combustion unit to the synthetic fuel generation device; a generated gas delivery path through which the generated gas is delivered from the synthetic fuel generation device; a combustion supply path that branches from the generated gas delivery path and supplies the generated gas to the combustion unit; and a switching control unit that switches between a combustion mode in which the generated gas is delivered to the combustion supply path and a non-combustion mode in which the generated gas is not delivered to the combustion supply path.
Absstract of: WO2026159980A1
This synthetic fuel generation system comprises: a synthetic fuel generation device that reacts hydrogen and carbon dioxide to generate a synthetic compound and water; a product gas delivery path through which a product gas is delivered from the synthetic fuel generation device; a flowmeter that is provided in the product gas delivery path and measures the flow rate of the product gas; a resupply path that is branched off from the product gas delivery path and returns the product gas to the synthetic fuel generation device; and a switching unit that, when the ratio between the flow rate measured by the flowmeter and the flow rate of the raw material gas supplied to the synthetic fuel generation device exceeds a prescribed ratio, performs switching such that the entire amount of the product gas is delivered to the resupply path when the synthetic fuel generation device is running and such that the amount of the product gas exceeding the flow rate corresponding to the prescribed ratio is delivered to the resupply path when the synthetic fuel generation device is not running.
Absstract of: US20260217529A1
A hydrogen plant includes hydrogen liquefiers, individual pipes, a confluent pipe, and branch pipes. The hydrogen liquefiers convert hydrogen gas into liquefied hydrogen. The individual pipes respectively belong to the hydrogen liquefiers and serve as hydrogen flow passages. The confluent pipe includes a confluence where downstream ends of the individual pipes of the hydrogen liquefiers meet to combine to one, and a collecting pipe located at a downstream position of the confluence. The branch pipes respectively branch from the individual pipes to each take out hydrogen flow having a phase of gas or two phases of liquid and gas.
Absstract of: US20260218402A1
0000 A membrane having excellent radical durability and low gas permeability, a membrane electrode assembly including the membrane, and a water electrolysis apparatus are provided. A membrane having a laminated structure including a layer B1, a layer A, and a layer B2 in this order, in which the layer A contains a hydrocarbon-based polymer (a) which has an ionic group and may be fluorine-substituted, and each of the layers B1 and B2 contains a perfluoro-carbon polymer (b) having an ionic group.
Absstract of: US20260218071A1
0000 The present disclosure relates to a system for producing hydrogen from feedstock and a method thereof. The system comprises a first chamber adapted to thermally decompose the feedstock, and a second chamber adapted to receive a first portion of the gaseous stream and to receive a first portion of the solids stream to form a reactants combination. The second chamber adapted to partially react the reactants combination with steam to produce a product gas. The system further comprises a third chamber adapted to receive a second portion of the gaseous stream and adapted to receive a second portion of the solids stream to form a combustibles combination. The third chamber adapted to at least partially combust the combustibles combination to produce process heat for the first chamber and/or the second chamber. The system further comprises a controller adapted to adjust the composition of the reactants combination and of the combustibles combination.
Absstract of: US20260218401A1
The present disclosure relates to a hybrid electrode including plasmonic nanoparticles and an electrolysis system including the same. The hybrid electrode and the electrolysis system including the same according to embodiments of the present disclosure may utilize a plasmonic-active (antenna–reactor) composite electrode to re-activate a catalyst surface via plasmonic phenomena during an electrochemical reaction.
Absstract of: US20260217524A1
Among other things, a process for generating hydrogen by valorizing iron ore tailings (IOT) through the oxidation of remnant ferrous iron phases in the tailings is described. The IOT may be either wet (i.e., containing water) or dry (i.e., not containing water). The reaction may be performed using untreated IOT and may generate hydrogen gas capable of being used on site.
Absstract of: DE102025103132A1
Um einen Wasserstofffilter bereitzustellen, mit dem in Elektrolyseverfahren zur Herstellung von Wasserstoff eine Separierung des Wasserstoffs von Wasserdampf ohne aufwändige Kühl-, Kondensations-, Adsorbtionstechnik ermöglicht wird, wird ein Wasserstofffilter (100) für eine Elektrolysezelle (10) oder für einen Verbund (300) aus Elektrolysezellen (10) vorgeschlagen, umfassend ein Metallblech (11), wobei auf mindestens einer Oberfläche (15) des Metallblechs (11) eine Schicht (16) aus einem keramischen Material angeordnet ist, wobei eine Schicht (17) aus einem wasserstoffpermeablen Metall oder einer wasserstoffpermeablen Metalllegierung auf dem keramischen Material angeordnet ist.
Absstract of: DE102025102714A1
Die vorgestellte Erfindung betrifft ein Verfahren (100) zum Betreiben eines Elektrolysesystems (200). Das Verfahren (100) umfasst:- Betreiben (101) des Elektrolysesystems (200) an einem Betriebspunkt, bei dem ein Kathodendruck in einem Kathodenraum (203) des Elektrolysesystems (200) größer ist als ein Anodendruck in einem Anodenraum (205) des Elektrolysesystems (200),- Ermitteln (103) eines Öffnungszustands sämtlicher Sicherheitsventile (207a, 207b, 207c) des Elektrolysesystems (200) in einem vorgegebenen Zeitraum und- Ausgeben (105) einer Warnmeldung für den Fall, dass der Öffnungszustand mindestens eines der Sicherheitsventile (207a, 207b, 207c) sich in dem vorgegebenen Zeitraum mehrfach ändert oder sämtliche Sicherheitsventile (207a, 207b, 207c) sich in dem vorgegebenen Zeitraum in einem geöffneten Zustand befinden.
Absstract of: WO2026159939A1
A hydrogen production method according to the present disclosure includes a supply step for supplying water to a hydrogen boride member containing a two-dimensional arrangement of hydrogen boride, wherein hydrogen is generated as a result of the water contacting the hydrogen boride member.
Absstract of: DE102025103028A1
Es wird ein Verfahren zur Herstellung einer SiC-Elektrode 1 angegeben. Das Verfahren weist auf: Bereitstellen eines SiC-Pulvers und Sintern des SiC-Pulvers zu einem SiC-Sinterkörper.Des Weiteren wird eine SiC-Elektrode 1 angegeben, die ein gesintertes Elektrodenmaterial 3a,3b aufweist.
Absstract of: DE102025103146A1
Um eine Elektrolysezelle, insbesondere eine Hochtemperaturelektrolysezelle, bereitzustellen, die eine verbesserte Gasdichtigkeit und einen erhöhten Wirkungsgrad aufweist, wird eine Elektrolysezelle (100), insbesondere Hochtemperaturelektrolysezelle (10), umfassend eine erste Endplatte (12) und eine zweite Endplatte (13) vorgeschlagen, wobei die erste Endplatte (12) und die zweite Endplatte (13) einen Zwischenraum (14) ausbildend übereinander angeordnet sind, wobei in dem Zwischenraum (14) eine Elektrolyseanordnung (16) umfassend eine Kathode (17), eine Anode (18) und ein Elektrolyt (19) angeordnet ist, wobei der Zwischenraum (14) mittels einer Dichtung (20) abgedichtet ist, wobei die Dichtung (20) ein Aerogel umfasst oder aus einem Aerogel besteht.
Absstract of: WO2025012271A1
The invention relates to a plant for preparing H2 by catalytically decomposing NH3. The plant according to the invention can be operated in a start-up mode in order to heat apparatuses of the plant to an increased operating temperature using a heat-transfer medium, e.g. following interruption of a continuous operation of the plant due to maintenance work. After heating to the operating temperature, the plant according to the invention can be operated in a production mode for continuous production of H2. The invention also relates to a method for starting up a plant for preparing H2 by catalytically decomposing NH3.
Absstract of: WO2025012277A1
The invention relates to a method for the preparation of H2 from NH3. NH3 is introduced into a fixed-bed reactor at a gas temperature in the range from 550 to 850°C, in which fixed-bed reactor NH3 is decomposed on an NH3 decomposition catalyst partly into H2 and N2. The gas mixture obtained in this manner is discharged from the fixed-bed reactor at a gas temperature in the range from 300 to 700°C, is heated to a temperature in the range from 550 to 700°C and is then introduced into a tubular reactor in which further NH3 is decomposed on a nickel-based NH3 decomposition catalyst into H2 and N2. The gas mixture obtained in this manner is discharged from the tubular reactor at a gas temperature in the range from 550 to 750°C.
Absstract of: WO2026158060A1
A recovery method and a recovery device. The recovery method comprises: a recovery process of phosphorus and iron elements in an iron phosphate system and a hydrochloric acid reuse process, wherein the recovery process of the phosphorus and iron elements comprises: an acid leaching step: subjecting the iron phosphate system to acid pickling by using an acid containing hydrochloric acid, so as to obtain an acid pickling solution; and the hydrochloric acid reuse process comprises: a chloride ion removal step: subjecting the acid pickling solution to electrolytic oxidation to remove chloride ions, so as to generate chlorine gas; a hydrochloric acid regeneration step: reacting the chlorine gas with hydrogen gas to generate hydrochloric acid; and a hydrochloric acid reuse step: reusing the hydrochloric acid in the acid pickling step.
Absstract of: KR20260118138A
본 발명은 세척 공정이 간소화된 폴리벤즈이미다졸 전해질막의 제조방법에 관한 것으로, 보다 상세하게는 기존의 물과 알코올을 사용한 2단계의 세척 공정을 물만을 사용하는 1단계의 공정으로 단축함으로써, 기존의 공정으로 세척한 전해질막과 비교했을 때 성능이 저하되지 않고 우수한 성능을 갖는 전해질막을 대량 생산할 수 있는 새로운 제조방법에 관한 것이다.
Absstract of: JP2026123786A
0001 【課題】炭材や炭素化合物の過剰消費を抑制しつつ、カルシウム含有物を用いて効率的に水素ガスを製造する方法を提供する。 【解決手段】容器内にカルシウム含有粉末を装入する工程と、前記容器の外部から、前記容器内の前記カルシウム含有粉末に対して、水蒸気と一酸化炭素ガスとを含有する原料ガスを供給することで、前記水蒸気と前記一酸化炭素ガスとを反応させて二酸化炭素ガス及び水素ガスを生成しつつ、前記カルシウム含有粉末に前記二酸化炭素ガスを固定させる、水素ガス生成工程と、を有する、水素ガスの製造方法。 【選択図】なし
Absstract of: KR20260117878A
본 발명은 액체 혼합 금속 기반 암모니아 분해반응을 통한 수소 생산 장치 및 이를 활용한 생산방법에 관한 것이다. 본 발명은 이종액체 금속을 이용한 버블칼럼 반응기를 활용하여 암모니아를 수소로 전환하는 기술로 종래 기술에서 활용하고 있는 고체 촉매 방식이 아닌 액체금속이 촉매 역할을 하게 된다. 구체적으로, 본 발명은 암모니아 열화학 분해 반응을 통해 수소와 질소로 열분해하는 시스템으로서 암모니아를 해외에서 수입하여 국내에서 수소로 활용하려는 수소 수입, 저장, 운송, 발전 사업에 적용 가능하며, 반도체 및 디스플레이 산업 등에서 배출되는 암모니아 저감을 위한 스크러버로 사용 가능하다.
Absstract of: WO2026161687A1
Disclosed is an electrolyzer, comprising: a cathode, comprising a cathode catalyst and a cathode separator; an anode, comprising an anode catalyst and an anode separator; a cathode flow field, comprising an inlet and an outlet; wherein the cathode flow field is in contact with the cathode; an anode flow field, comprising an inlet and an outlet; wherein the anode flow field is in contact with the anode; and an electrolyte wherein the cathode separator and the anode separator each independently comprise a porous hydrophobic material. Also disclosed are methods of producing H2 and O2 using the electrolyzer.
Absstract of: US20260218403A1
An ion separator is used to produce a stream of positively charged electrolytes and another stream of negatively charged electrolytes with adequate potential difference between the two streams. Short-circuiting these two streams in gas generation chambers produces hydrogen and oxygen gases. This setup of equipment is assembled as a containerized hydrogen and oxygen production cell. An x-y grid layout of many containerized hydrogen and oxygen production cells is used to outline a scalable plant for manufacturing oxygen and green hydrogen in large quantities.
Absstract of: WO2026160583A1
The water electrolysis separation membrane according to the present invention comprises a support mesh and a functional layer in which the support mesh is included, wherein the functional layer includes an ion-conducting material and a hydrogen-oxygen recombination catalyst.
Absstract of: US20260218396A1
A system includes an electrolyzer cell system configured to receive a steam inlet stream and an air inlet stream and to generate a hydrogen containing product stream and an air exhaust stream, and an absorption chiller fluidly connected to the electrolyzer cell system. The absorption chiller is configured to receive the air exhaust stream and to cool the hydrogen containing product stream using heat from the air exhaust stream.
Absstract of: WO2026159932A1
Provided are: an electrolysis cell stack in which a methanation reaction of a product gas that is generated at a hydrogen electrode by co-electrolysis can be suppressed even in cases where a methanation catalyst is contained in a flow passage through which the product gas flows; an electrolysis cell cartridge; an electrolysis cell module; and a method for suppressing methanation in an electrolysis cell stack. An electrolysis cell stack (101) according to the present disclosure comprises: an electrolysis cell (105) in which a hydrogen electrode, a solid electrolyte, and an oxygen electrode are stacked in sequence; a flow passage (117) through which a gas that is generated at the hydrogen electrode flows; and a hollow tube (140) which is disposed in the flow passage (117) so that the gas that is generated at the hydrogen electrode can flow therethrough. A member (103) that defines the outer contour of the flow passage (117) contains a methanation catalyst, and the hollow tube (140) does not contain a methanation catalyst.
Absstract of: US20260216467A1
A breathing equipment for providing a positive pressure gas includes a gas channel, a hydrogen generating device, a pressurizing device, a mixing device, an atomizing device, and an output device. The hydrogen generating device, the pressurizing device, the mixing device, the atomizing device, and the output device are all coupled to the gas channel. The hydrogen generating device is configured to electrolyze water to generate a gas comprising hydrogen. The pressurizing device selectively accelerates an external gas to generate an accelerating gas. The mixing device is configured to mix the gas comprising hydrogen and the accelerating gas to generate a positive pressure gas. The atomizing device is configured to selectively generate an atomizing gas. The output device is configured to selectively output the gas comprising hydrogen, the positive pressure gas, the gas comprising hydrogen with the atomizing gas, or the positive pressure gas with the atomizing gas.
Absstract of: US20260217633A1
Systems and methods for E-methanol production may comprise capturing carbon dioxide from an exhaust gas, the exhaust gas being a byproduct of a gas processing plant; hydrogenating the carbon dioxide with a hydrogen gas to produce a syngas; synthesizing a stream comprising methanol and water from the syngas; and separating at least a portion of the water from the stream to produce an E-methanol.
Absstract of: US20260218400A1
0000 For renewable energy technology to become ubiquitous, it is imperative to develop catalysts useful reactions such as, for example, efficient oxygen evolution reaction (OER) and hydrogen evolution (HER). In accordance with the purpose(s) of the present disclosure, described herein are compounds having one of the following the formula: ABX, ABCX, ABCDX, ABCDEX, ABCDEFX, or ABCDEFGX, wherein (1) A, B, C, D, E, F, and G are, independently, Cr, Mn, Fe, Co, Ni, Cu, and Zn, (2) A, B, C, D, E, F, and G are not the same element, and (3) X is absent or X is C, O, S, P, N, Te, Se, or As. The compounds described herein possess unique electrochemical properties.
Absstract of: WO2026159944A1
The purpose of the present invention is to suppress a methanation reaction of a product gas in a co-electrolysis system and a method for operating same. A co-electrolysis system (120) according to the present disclosure comprises an electrolysis cell stack (101) and a control unit (123). The electrolysis cell stack (101) includes: an electrolysis cell (105) in which a hydrogen electrode, a solid electrolyte, and an oxygen electrode are laminated in this order; a raw material gas flow path (124) through which a raw material gas containing H2O and CO2 supplied to the hydrogen electrode flows; and a product gas flow path (125) through which a product gas produced at the hydrogen electrode flows. The control unit (123) includes a methane concentration suppression unit (135) by which the concentration of methane in the off-gas discharged from the product gas flow path (125) is maintained below a threshold.
Absstract of: US20260217634A1
A method for processing flowback may comprise: providing flowback fluid comprising produced water, methane, hydrogen sulfide, and carbon dioxide; separating the flowback fluid into produced water, methane, hydrogen sulfide, carbon dioxide streams; producing a hydrogen stream and a carbon dioxide stream from the methane stream; producing a hydrogen stream from the hydrogen sulfide stream; and producing a hydrogen stream from the produced water stream. A flowback fluid processing system may comprise: a flowback fluid separator; a water splitting unit; a methane conversion unit; a hydrogen sulfide converter; a carbon dioxide reducing unit; and a synthesis unit.
Absstract of: US20260217525A1
A system and method for producing low-cost, low to zero-carbon, and emission-free hydrogen (H2) is provided. The system includes an auto-thermal reformer which uses electrolytic oxygen (O2), a hydrocarbon fuel source, and water (H2O) to perform a partial oxidation reaction and produce auto-thermal reformed hydrogen and carbon dioxide (CO2). The system also includes a carbon dioxide electrolyzer for receiving electricity and the carbon dioxide from the auto-thermal reformer, and performing electrolysis on the carbon dioxide. The carbon dioxide electrolyzer produces electrolytic carbon monoxide (CO) and a portion of the electrolytic oxygen provided to the auto-thermal reformer. The system also typically includes a water electrolyzer, which performs water electrolysis to produce electrolytic hydrogen and more electrolytic oxygen which can be provided to the auto-thermal reformer. In addition, the carbon monoxide produced by the carbon dioxide electrolyzer can be combined with the hydrogen produced by the auto-thermal reformer to form syngas.
Absstract of: US20260218404A1
An electrolytic cell of the present disclosure includes a first separator, a second separator, an anion exchange membrane disposed between the first separator and a second separator, a cathode disposed between the first separator and the anion exchange membrane, and an anode disposed between the second separator and the anion exchange membrane. The first separator includes a flow path for supplying an electrolyte to the cathode, and at the cathode, at least part of the electrolyte supplied from the flow path is consumed to generate hydrogen and hydroxide ions. The second separator does not include a flow path for supplying the electrolyte to the anode, and at the anode, oxygen and water are generated by the hydroxide ions that have passed through the anion exchange membrane from the cathode in a state where the electrolyte is not supplied.
Absstract of: WO2025059699A1
The invention relates to a device and a method for the continuous and/or semi-continuous, photocatalytic and/or photoelectrochemical production of hydrogen from waste water as reaction medium (1), with a flow element (2) forming the reaction space (2). In order to permit a better degree of effectiveness in both photocatalytic and photoelectrochemical hydrogen production from waste water despite simple design conditions, it is proposed that a multiport fitting (3) is provided upstream of the flow element (2) on the inlet side, via which multiport fitting both an oscillation pump (4) and a metering unit (5) for the reaction medium (1) are connected to the flow element (2), and that the oscillation pump (4) forms a conveying device for the reaction medium (1) by at least partially forming a plug flow in the flow element (2).
Absstract of: EP4782578A1
0001 Verfahren zur Herstellung einer Membran-Dichtungsanordnung für eine elektrochemische Zelle, entsprechendes Zellelement und Elektrolysesystem 0002 Es wird ein Verfahren zur Herstellung einer Membran-Dichtungsanordnung für eine elektrochemische Zelle, insbesondere eine Elektrolysezelle angegeben. Das Verfahren umfasst die Schritte S1, Bereitstellen einer Membran bzw. einer Membran-Elektrodeneinheit, umfassend auf die Membran aufgebrachte Elektrodenschichten, welche im Betrieb der Zelle als Anoden- bzw. Kathodenkatalysator dienen, S2, Bereitstellen einer Dichtung, wobei die Dichtung ausgelegt ist, im Betrieb der elektrochemischen Zelle einen Anodenraum bzw. einen Kathodenraum zu dichten, und S3, stoffschlüssiges Verbinden der Membran bzw. Membran-Elektrodeneinheit und der Dichtung zu einer vorgefertigten Baugruppe. Weiterhin werden eine entsprechende Membran-Dichtungsanordnung, eine diese aufweisende elektrochemische Zelle, ein Zellelement und ein entsprechendes Elektrolysesystem angegeben.
Absstract of: EP4782580A1
An operation method for a water electrolyzer, including an electrolyzer for electrolyzing water, a hydrogen separator to which hydrogen generated in the electrolyzer is to be led, an oxygen separator to which oxygen generated in the electrolyzer is to be led, and a vent line for discharging gas from the hydrogen separator or the oxygen separator and a vent valve disposed in the vent line, includes: a step of stopping electrolysis of water in the electrolyzer; a step of determining whether a first indicator indicating an increase amount of an oxygen concentration in gas in the hydrogen separator or of a hydrogen concentration in gas in the oxygen separator after stopping the electrolysis exceeds a first threshold; and opening, when the first indicator exceeds the first threshold, the vent valve to decrease a pressure of the hydrogen separator or the oxygen separator to a first specified value.
Absstract of: EP4782092A1
0001 An operation method for a dehumidification apparatus for dehumidifying hydrogen gas produced by a hydrogen production apparatus, the dehumidification apparatus including a dehumidifier for removing moisture contained in the hydrogen gas, a discharge line for discharging the hydrogen gas dehumidified by the dehumidifier from the dehumidifier, a dew point measurement line connected to the discharge line, a dew point meter disposed in the dew point measurement line, and an inlet valve and an outlet valve disposed on both sides of the dew point meter in the dew point measurement line, the operation method including a stopping step of stopping discharging of the hydrogen gas from the dehumidifier to the discharge line, and a maintaining step of maintaining a state in which a dew point meter installation part of the dew point measurement line including at least an installation position of the dew point meter is filled with a dry gas when the discharging of the hydrogen gas from the dehumidifier to the discharge line is stopped.
Absstract of: US2025236541A1
0000 Methods, systems and devices for removing iodide from an aqueous solution including submerging an iodophilic electrode in an aqueous solution containing iodide, applying a current to the electrode, and electrochemically oxidizing the iodide to iodine within the electrode. The electrode may include an iodophilic material and an electrically conductive material. It may also include a binder. The iodophilic material may be a starch, chitosan, carboxycellulose, cationic polymer, or an anion exchange membrane material, for example. After oxidizing the iodide to iodine within the electrode, the electrode may be submerged in a second solution and a current may be applied to reduce the iodine and release it from the electrode in the form of iodide into the second solution.
Absstract of: WO2025023918A1
The present disclosure relates to an electrochemical method that comprises the direct production of hydrogen from boron compound types by reduction-oxidation reactions, the simultaneous production of boron hydride compounds and the production of hydrogen by oxidation-reduction reactions of boron hydride compounds, which does not require any additional pH adjustment or purification procedure in a solution system containing low-cost boron compounds (boric acid, boron salts, etc.), and which provides direct production of high purity hydrogen in a single step and at room temperature in an environmentally friendly and low-cost manner.
Absstract of: EP4782579A1
0001 A separator according to the present disclosure comprises: a separator body having a first surface and a second surface; a first supply hole and a first discharge hole that are formed on one diagonal line of the separator body on the first surface and pass through the separator body; a plurality of first groove parts that are formed in a region between the first supply hole and the first discharge hole; a trapezoidal first diffusion flow path that spreads from the first supply hole to the first groove part and gradually expands in the width direction from the first supply hole toward the first groove part; a trapezoidal first convergence flow path that spreads from the first groove part to the first discharge part and gradually contracts in the width direction from the first groove part toward the first discharge hole; a first diffusion guide part that is provided in the first diffusion flow path and guides a fluid from the first supply hole to the first groove part; and a first convergence guide part that is provided in the first convergence flow path and guides the fluid from the first groove part to the first discharge hole.
Absstract of: WO2025110878A1
An electrolyzer for generating hydrogen from water comprising electrodes and an electrically non-conductive separator layer extending in a substantially vertical plane comprising macroscopic through holes, and wherein the electrodes themselves comprise an anode and a cathode, characterized in that the electrodes are each furnished at opposite faces of the separator, and that the electrodes each comprise a plurality fins and wherein each fin of the plurality of fins projects outwardly from the layer for restricting the upward movement of electrode generated bubbles to a bubble stream that is substantially parallel to the vertical plane.
Absstract of: EP4783270A1
A composite membrane includes: a porous substrate including a polyolefin microporous membrane; a silica material having a substrate containing silicon dioxide and having a sulfonic acid group on at least a surface of the substrate; and an ion exchange resin, in which a Gurley value is 1,000 sec/100 mL or more.
Absstract of: WO2025061814A1
The invention relates to a system and method for controlling the operation of the gas-liquid separators (GLSan, GLSca) of an electrolyser comprising a stack (10), and anode and cathode gas-liquid separators that separate the electrolyte and the gas along an alkaline solution level (lan, lca), wherein the dioxygen and dihydrogen gases flow from their respective chambers through a gas control valve (V
Absstract of: CN121843809A
Composite materials, methods of making composite materials, and methods of using composite materials are described herein. The composite material includes an incompatible polymer and/or other incompatible materials. The composite material can be used for various industrial applications. A composite material includes a first component including a first material having a fluid permeable portion and a second component including a second material that is incompatible with the first material; the first component and the second component are coupled at an interface, the interface comprising the second material contained in the fluid permeable portion of the first material, and the interface forming a third component separating at least a portion of the first component from the second component.
Absstract of: WO2025061540A1
The invention relates to an electrochemical hydrogen compressor (1) comprising at least one compressor unit (4), wherein an electrode arrangement (4c, 4d, 4e) which is disposed between two gas flow regions (4a, 4b) in the at least one compressor unit (4) comprises a gas-tight proton-permeable layer (4d) which is contacted by a gas-permeable cathode layer (4e) on one side of the layer, and which is contacted by a gas-permeable anode layer (4c) on the other side of the layer, wherein the at least one compressor unit (4) forms a compressor arrangement (3) which is arranged in a housing (2) around the interior of a hollow, preferably tubular, gas-permeable core element (5), wherein the interior of the core element (5) is fluidically connected to the radially innermost gas flow region (4b) of the compressor arrangement (3), and the interior of the housing (2) is fluidically connected to the radially outermost gas flow region (4b) of the compressor arrangement (3).
Absstract of: US2025092538A1
A bipolar plate for an electrochemical device may include, among other things, a conductive main body extending between first and second sides to define a cross-flow arrangement. The cross-flow arrangement may include first flow channels interspersed with first ribs along the first side, second flow channels interspersed with second ribs along the second side, and cross-over channels that may extend across the respective first ribs to interconnect the adjacent first flow channels. A method of forming a component for an electrochemical device is also disclosed.
Absstract of: WO2025012633A1
The invention provides a device for producing hydrogen gas and a process therefor. It also provides a system for generating electrical energy from hydrogen gas. More particularly, the invention provides a device for producing hydrogen comprising an ammonia cracker having one or more raw cracked gas outlets in fluid communication with a common raw cracked gas flow conduit, one or more gas separators in fluid communication with the ammonia cracker via the common raw cracked gas flow conduit, and in fluid communication with a common partially purified cracked gas flow conduit; one or more filter assemblies, each having a first container having one or more walls, one or more partially purified cracked gas inlets and one or more purified cracked gas outlets, wherein the one or more partially purified cracked gas inlets are in fluid communication with the one or more gas separators via the common partially purified cracked gas flow conduit, the first container containing a single mass of adsorbent comprising silica gel, wherein the one or more partially purified cracked gas inlets and one or more purified cracked gas outlets are arranged such that a partially purified cracked gas flows through the single mass of adsorbent in use.
Absstract of: KR20260117236A
본 발명에 따른 가변 주파수 초음파를 활용한 수소 기포 성장 촉진 장치 및 방법은, 수소 생산 공정 시 음향 가진기를 이용하여 전극 주위에 형성된 기포를 향해 초음파를 조사함으로써 기포의 팽창 및 수축을 유도하고, 용존 수소 가스의 유입량을 증대시켜 기포 성장을 촉진할 수 있다. 아울러, 수소 기포 반경의 모니터링을 기반으로 초음파 주파수를 가변 조정하여 전극 주위에 형성된 기포의 급격한 성장을 반복적으로 발생시켜 수소 기포 성장 촉진을 극대화하여 수소 생산량을 향상시킬 수 있다.
Absstract of: KR20260117553A
본 발명의 일 실시예는 질소 기능화와 산소 결함을 동시에 갖춘 Fe-Ni 이종 복합체로 니켈 폼; 상기 니켈 폼 표면 상에 위치하되, 철 및 니켈을 포함하는 시트 구조체; 및 상기 시트 구조체 상에 위치하되, 철을 포함하는 나노구체 클러스터를 내부에 포함하는 탄소 매트릭스;를 포함하는 것을 특징으로 하는 전기촉매 전극를 제공하는 것이다.
Absstract of: KR20260117267A
0001a 본 발명은 전기화학 에너지 디바이스용 스택 장치에 설치되어, 전해액이 전기분해되는 공간을 제공하고, 전해액이 전기 분해되어 발생한 수소 가스와 산소 가스 및 전기 분해되지 않은 전해액이 이동할 수 있는 이원적 이동 경로를 제공할 수 있어, 전기화학 에너지 디바이스용 스택 장치 내부에 흐르는 전해액과 수소 가스가 혼합되지 않도록 하는 효과를 제공하는 발명인 것을 특징으로 한다.
Absstract of: GB2703483A
A method and membrane reactor for production of pressurised hydrogen are disclosed, the method comprises providing a catalyst for conversion of ammonia to hydrogen and nitrogen; contacting a pressurised reaction stream comprising ammonia with the catalyst to convert at least a portion of the ammonia into hydrogen in a reaction zone; and obtaining a hydrogen product stream comprising pressurised hydrogen by selectively driving hydrogen from the reaction zone through a hydrogen-selective membrane under a pressure differential between a reaction-side pressure of the reaction stream and a product-side pressure of the hydrogen product stream; wherein the product-side pressure is at least 30 bara. The membrane reactor comprises a feed vessel comprising a catalyst bed comprising a catalyst for conversion of ammonia to hydrogen and nitrogen; a hydrogen collection vessel for collecting hydrogen at a pressure of at least 30 bara; and a hydrogen-selective membrane separating the feed vessel and the hydrogen collection vessel for selective removal of hydrogen. Figure 1
Absstract of: EP4782577A1
Provided is an ammonia production apparatus, including: a first electrolysis vessel in which at least part of a first electrolysis medium is stored; a first electrode arranged in the first electrolysis vessel; a second electrolysis vessel in which at least part of a second electrolysis medium is stored; a second electrode arranged in the second electrolysis vessel; a separator arranged between the first electrolysis vessel and the second electrolysis vessel; and a first separation unit configured to separate ammonia from the second electrolysis medium, wherein the first electrolysis vessel is configured so that a proton source in the first electrolysis medium is oxidized at the first electrode to generate a proton, wherein the ammonia production apparatus is configured to produce ammonia and hydrogen from nitrogen, a proton, and an electron in the presence of a nitrogen-activating catalyst in the second electrolysis medium, and wherein the ammonia production apparatus is configured to supply, to the first electrolysis medium, nitrogen and hydrogen remaining after ammonia is separated by the first separation unit.
Absstract of: WO2025205879A1
The purpose of the present invention is to realize a diaphragm for alkaline water electrolysis having good airtightness even when a sheet-like gasket is used, and enabling execution of water electrolysis at a low cell voltage. A use method according to the present invention is characterized by using, as a diaphragm for alkaline water electrolysis, a porous film which contains a polyethylene, and in which the content of the polyethylene in resin components is 50 mass% or more, and the tortuosity is 3.00 or less.
Absstract of: CN122466491A
本发明属于电解水制氢技术领域,涉及一种纯水电解制氢的自调节微环境膜电极及其制备方法。包括:阴离子交换膜;阳极催化层,位于阴离子交换膜的一侧;阴极催化层,位于阴离子交换膜的另一侧;阳极催化层为杂化离聚物与析氧催化剂相互混合形成的多孔复合层,杂化离聚物由聚合物基体与无机纳米填料复合而成,聚合物基体的侧链含有亲水基团,无机纳米填料的表面具有羟基或胺基;阳极催化层在厚度方向上具有梯度孔结构,梯度孔结构包括靠近阴离子交换膜的第一孔区和远离阴离子交换膜的第二孔区,第一孔区的亲水性高于第二孔区。本发明能够在纯水进料下自主维持界面微环境的碱性稳定与水气传输平衡,显著降低电解电压并延长运行寿命。
Absstract of: CN122469989A
0001 本发明公开了一种储能光伏耦合制氢电解槽集群功率响应方法,该方法根据电解槽集群的运行状态选择电解槽的运行功率比例区间;根据输入功率计算电解槽的目标功率比例,判断所述目标功率比例是否处于所述运行功率比例区间,并根据判断结果进行运行功率比例区间的自适应调整;计算电解槽的功率变化率;判断电解槽的分配功率是否属于当前电解槽的运行功率区间;当电解槽的分配功率不属于当前电解槽的运行功率区间时,限制所述分配功率,使其属于当前电解槽的运行功率区间;当电解槽的分配功率属于当前电解槽的运行功率区间时,判断电解槽的功率变化率是否符合预设要求;当电解槽的功率变化率不符合预设要求时,限制所述功率变化率,使其符合预设要求;当电解槽的功率变化率符合预设要求时,设置电解槽的设定功率。
Absstract of: CN122466420A
0001 本发明属于非贵金属电催化析氢材料领域,尤其涉及的是一种用于电解水制氢的镍钨钼合金薄膜及其制备方法与应用。该方法通过磁控溅射仪器让钼靶与镍钨靶(原子比例为1:1)在真空状态下共溅射,可获得镍钨钼合金薄膜,通过调节靶材的溅射功率,可精确调控镍钨钼合金组分获得仅包含晶态结构、仅包含非晶态结构或者同时包含晶态结构和非晶态结构的合金薄膜。本发明所制备的镍钨钼合金薄膜表现出了优异的电催化析氢性能;本发明通过往镍钨合金中添加钼得到的合金的催化析氢性能显著优于镍钨二元合金及添加铌、钒、钽得到的合金,在电解水制氢领域具有广阔的应用潜能和发展空间。
Absstract of: CN122466507A
本发明提供一种功能化离子液体修饰的NiFe‑LDH催化剂的制备方法及其应用,涉及电催化材料领域,首先采用共沉淀法制备NiFe‑LDH前驱体:以可溶性镍盐和可溶性铁盐为原料,利用碱性沉淀剂,进行共沉淀反应得悬浮液,经固液分离、洗涤、干燥,得到NiFe‑LDH前驱体;然后采用溶剂蒸发法在前驱体表面修饰功能化离子液体,得到复合催化剂;本发明制备方法简单、条件温和,在碱性电解液中表现出尤为突出的OER催化性能。
Absstract of: CN122466499A
0001 本发明提供了一种高活性堆叠片状含硫钴基析氧催化剂及其制备方法与应用。该高活性堆叠片状含硫钴基析氧催化剂的制备方法,包括步骤如下:(1)将醋酸钴水溶液加入四丁基氢氧化铵中,进行加热搅拌反应;之后经离心、洗涤、干燥,得到前驱体;(2)将步骤(1)所得前驱体和硫脲加入水中,超声分散均匀,得到混合液,将所得混合液进行水热反应;之后经离心、洗涤、干燥,得到高活性堆叠片状含硫钴基析氧催化剂。相较于传统钴基及普通硫化催化剂,本发明样品过电位更低、催化活性更高、耐用性更好,且制备条件温和、工艺简单、原料廉价,适配电解水析氧规模化应用。
Absstract of: CN122466498A
本发明公开了一种基于过渡金属掺杂策略的酸性OER催化剂及其制备方法,属于电解水制氢技术领域。催化剂以Pt纳米颗粒作为载体,载体上负载M‑Ir合金纳米颗粒,M为过渡金属Fe、Co和Ni中的至少一种。将Pt纳米颗粒分散于有机溶剂中,加入IrCl3和所述过渡金属M的前驱体,之后加热反应,结束后搅拌、冷却,对所得产物洗涤后干燥,即得基于过渡金属掺杂策略的酸性OER催化剂。本发明的催化剂将贵金属Ir负载量降低了35%,但催化活性超过了商业IrO2,其在酸性OER中表现出了低过电势、高电流密度和长循环寿命。本发明工艺简单,流程清晰,适于规模化推广应用。
Absstract of: CN122465320A
本发明公开了一种含Tröger’s Base结构的聚芳基哌啶阴离子交换膜及其制备方法和应用。阴离子交换膜的结构特征在于聚合物主链中引入了特定摩尔分数(X=5%~15%)的Tröger’s Base刚性结构单元,其制备方法包括(1)以2‑氨基芴和二甲氧基甲烷为原料合成Tröger’s Base结构单体;(2)将该单体与芳基单体及N‑甲基‑4‑哌啶酮共聚,得到含Tröger’s Base结构的聚芳基哌啶聚合物;(3)对聚合物进行季铵化改性;(4)通过溶液浇铸成膜并碱化处理,最终制得目标阴离子交换膜。本发明通过引入Tröger’s Base结构,有效调节了膜的微相分离形态,成功缓解了阴离子交换膜中离子电导率、尺寸稳定性与耐碱性之间难以兼顾的矛盾。
Absstract of: CN122462547A
本发明公开了一种配体调控还原电势制备RuIrPb八面体合金纳米材料的方法,该方法首先将Ru盐和Ir盐与含氮或含氧的有机配体在溶剂中混合,然后引入Pb盐、表面活性剂、pH调节剂、还原剂和形貌控制剂混合,之后在密闭反应釜中加热反应,再进行分离、洗涤和干燥,得到RuIrPb八面体合金纳米材料。本发明通过含氮或含氧的有机配体与贵金属离子Ru和Ir配位以精细调控其还原电势,协同制备RuIrPb八面体合金纳米材料,具有操作简便、产率高、可控性强的特点,所制备的RuIrPb八面体合金纳米材料呈现八面体纳米形貌,且为单一相材料,在酸性条件下电解水制氢中表现出优异的催化活性和稳定性,具有重要的应用前景。
Absstract of: KR20260116902A
본 발명은 환원극에 생성되는 무기침전물을 용해시키도록 구성되는 복수의 환원극을 포함하는 직접 해수전해장치를 제공한다. 복수의 환원극을 포함하는 직접 해수전해장치는 해수(Seawater)에 침지되는 환원극, 애놀라이트(Anolyte)에 침지되는 산화극, 및 해수를 산성화 시키도록 환원극 및 산화극 사이에 배치되는 양극성 막(Bipolar membrane)을 포함하고, 환원극은 제1 환원극 및 제1 환원극과 전기적으로 분리되도록 이격되어 배치되는 제2 환원극을 포함한다.
Absstract of: CN122466493A
热驱动氧化铱表面铺展制备外延核壳材料的方法、外延核壳材料及在酸性析氧反应中的应用,属于晶格匹配外延核壳材料技术领域。该外延核壳材料由金红石相MO2载体和包覆于其表面的IrO2外延壳层组成,IrO2外延壳层沿金红石相MO2载体表面的晶格取向连续生长,与MO2载体核之间形成晶格匹配的外延界面。本发明还提供了该外延核壳材料的制备方法,通过将可溶性铱源、硝酸盐和MO2载体混合,经蒸发干燥、煅烧、洗涤干燥及高温热处理,使IrO2颗粒在金红石相氧化物载体表面转变为连续外延壳层。该方法工艺简单、原料易得、无需气相沉积等高成本设备,所得材料可提高铱活性组分利用效率,增强氧化铱与载体之间的界面结合。
Absstract of: CN122466494A
0001 本发明涉及一种原位水解制备梯度嵌入型棒状TiO<2>负载IrO<2>氧析出电催化剂的方法及应用,以选定钛前驱体为原料,用氨水精准调控水解速率实现钛前驱体的可控原位水解,用巯基和氨基引导晶体生长成晶相规整的棒状TiO<2>载体;TiO<2>生长过程中,用还原性醇将Ir前驱体还原为超细Ir黑,调控钛与Ir前驱体的添加间隔,实现Ir黑在TiO<2>表层及次表层的原位梯度嵌入;再经酸洗去除载体表面不稳定钛物种,充分暴露活性位点,最后经热处理使Ir黑氧化为晶相规整IrO<2>并形成连续超薄包覆层,强化Ti‑O‑Ir界面共价相互作用,最终获得低铱负载、高催化活性与长效稳定性的氧析出电催化剂,能适配PEM电解水酸性OER苛刻工况。
Absstract of: CN122466511A
0001 本发明公开了一种用于碱性电解槽的复合隔膜及其制备方法,属于碱性电解水制氢技术领域,复合隔膜包括聚苯硫醚织物支撑层、有机膦酸锆纳米片层和交联层,有机膦酸锆纳米片层原位生长于聚苯硫醚织物支撑层,交联层填充于支撑层间隙并包覆有机膦酸锆纳米片层。本发明采用上述的一种用于碱性电解槽的复合隔膜及其制备方法,通过有机膦酸锆纳米片层与交联聚合物协同构建多级亲水结构,并以共价键强化界面结合力,显著提升复合隔膜的亲水性与高温强碱环境下的界面稳定性,解决了传统隔膜亲水性差、界面结合弱、长期运行易衰减的问题,可满足碱性电解槽高效、稳定、安全运行的需求。
Absstract of: JP2026122445A
0001 【課題】アノード触媒層が触媒成分としてイリジウム含有マンガン酸化物を含みながらも、触媒成分に起因する電解質膜の損傷が低減されている触媒層付き電解質膜であって、高い電解性能を示す水電解セルを実現し得る触媒層付き電解質膜、水電解セル及び水電解セルスタックを提供する。 【解決手段】β-MnO<2>を骨格とするIrMnO<X>を含むアノード触媒層と、カソード触媒層と、上記アノード触媒層と上記カソード触媒層との間に配置され、かつ、厚さが120μm以下である電解質膜と、を備え、上記電解質膜が、電解質層と、不織布構造又はメッシュ構造を有するバリア層と、を備える、触媒層付き電解質膜及びその応用。 【選択図】なし
Absstract of: CN122466496A
本发明公开了一种(MnRuIrCrTa)Cx/CNFs高熵合金碳化物电催化材料及其制备方法、电解水制氧方法。本发明将锰盐、钌盐、铱盐、铬盐、钽盐和碳纳米纤维前驱体分散于有机溶剂中,配制得到纺丝溶液,再通过冷却结晶策略,成功制备出(MnRuIrCrTa)Cx/CNFs高熵合金碳化物电催化材料,高熵合金碳化物在纳米纤维上均匀分布,亲氧性Mn元素的引入促进催化剂表面重构,显著提升析氧活性;耐腐蚀性元素Ta的加入促进了TaC主体结构的形成,进一步提升催化剂的结构稳定性,在长时间的运行中仍能保持高效的催化性能,该策略不仅有效降低了贵金属的用量,还实现了催化剂活性与稳定性的同步提升,具有广阔的应用前景。
Absstract of: WO2026160549A1
The present invention relates to a method for regenerating a water electrolysis anode, the method comprising the steps of: (S1) preparing a water electrolysis anode having a voltage increased by 10% or more on the basis of an initial voltage; (S2) preparing an electrolyte by mixing a Ni precursor and a Fe precursor with an electrolyte solution; and (S3) introducing the electrolyte into the water electrolysis anode having a voltage increased by 10% or more on the basis of the initial voltage and applying an electrical load thereto to reactivate the water electrolysis anode.
Absstract of: CN122466483A
本发明公开了一种基于MCDI的制氢系统及水处理方法,属于电解水制氢技术领域。所述系统包括依次连接的MCDI脱盐模块、碱性电解制氢模块、气体纯化模块和氢气储存模块。其中,MCDI脱盐模块用于对进水进行脱盐处理;进水泵将水源泵入该模块;碱性电解制氢模块的碱性电解槽堆直接与MCDI脱盐模块的出水口连接,使得经脱盐处理后的水无需中间储存即可直接进入电解槽堆进行电解制氢;气体纯化模块对产生的氢气进行纯化;氢气储存模块储存最终产品。本发明通过将MCDI脱盐模块与碱性电解制氢模块直接集成,省去了传统独立的预处理单元和中间储水环节,简化了系统结构,降低了能耗与维护成本,并提高了对含杂质离子水源的适应性。
Absstract of: CN122466485A
本发明涉及电解水制氢领域,具体的公开了一种基于质子交换膜的电解水制氢装置及工艺,解决了现有电解水制氢集成化程度低,不方便模块化组合安装,以实现制氢速率灵活调整的问题,现提出如下方案,其包括水箱、氢储罐、氧储罐、托盘、安装座、电解槽、集成管箱、驱动组件、拨板,所述托盘上滑动设置滑板,所述滑板上设置有拨动组件,所述拨动组件用于驱动两侧拨板转动,并将电解槽居中拨动,所述滑板上设置有卡位组件,所述卡位组件用于在集成管箱靠近电解槽滑动时,将电解槽稳定卡装在托盘上。本装置与工艺能够灵活模块化对多个电解槽进行稳定安装使用,以在实现灵活调整制氢速率时,降低成本,并保证使用稳定性。
Absstract of: CN122466486A
本发明公开了一种分段轴线构型的单管式电解槽及电解系统,所述单管式电解槽包括壳体和设置在壳体内的分段式电极管;分段式电极管包括相连通的下部竖直段和上部倾斜段;所述壳体为分段管状结构,其管壁与分段式电极管的管壁平行设置;所述分段式电极管的内部为管程通道,所述壳体与分段式电极管之间为壳程通道。本发明中下部的倾斜段主要作为主体反应区,上部的倾斜段主要作为气液两相排出区,在宏观层面,上部倾斜流道结构可使流体产生环流,增强上下部流体的交换和循环,在微观上促进微细气泡碰撞聚并与脱离,强化气泡聚并,使其从流道迅速脱离。本发明优化了管式电解槽中的流场和温度场,可减少泡沫积聚和局部干烧,提高运行稳定性和电解效率。
Absstract of: CN122466501A
0001 本发明公开了一种基于二硫化钼的催化材料及其制备方法与应用,属于电化学催化析氢技术领域,通过对碳布进行酸化处理引入亲水官能团,提高碳布表面活性与负载稳定性,在其表面原位生长钴基金属有机骨架并经高温碳化,构建掺氮碳/钴纳米复合导电骨架,从而形成连续稳定的电子传输通道,在骨架表面水热原位生长二硫化钼,有效增加活性位点并增强结构结合强度进一步在硒蒸气环境中进行气相硒化调控,实现对二硫化钼电子结构的优化,提高材料催化活性,所得催化材料为自支撑电极结构,可直接作为工作电极应用于海水电解析氢,在海水等复杂电解环境下表现出优异的析氢活性和长期运行稳定性。
Absstract of: CN122466276A
0001 本发明公开了一种共晶高熵合金自支撑催化电极及其制备方法与应用,涉及高熵合金材料加工与电解水技术领域,包括合金熔炼与铸锭制备、坯料预处理、多参数热轧、喷砂去除氧化层、多道次冷轧与中间去应力退火、电化学脱合金,所述共晶高熵合金按原子百分比计包括Co 14~45 at.%,Cr 4~20 at.%,V 4~20 at.%,Ni 15~42 at.%,Al 10~35 at.%,Zr 1~5 at,La 1~5 at.%,Pt 0.2~0.8 at.%,通过上述工艺获得具有纳米多级孔结构和高密度晶体缺陷的大尺寸共晶高熵合金自支撑阳极催化轧制材料,可以直接作为电解水用自支撑电极,适用于析氧反应,具有较高活性、良好导电性和优异稳定性。
Absstract of: CN122472338A
本发明公开了一种储能光伏耦合制氢电解槽集群功率分配方法,该方法包括获取输入功率,根据预设的输入功率与电解槽投运数量之间的对应关系确定电解槽集群中待投运电解槽的数量N;根据所述输入功率与所述待投运电解槽的数量N确定各个所述待投运电解槽的分配功率;基于预设的电解槽框架运行机制,根据待投运电解槽的数量N确定参与投运的框架组数以及各组框架内每次启动的电解槽的数量Mi,i为框架组号;依次遍历各组框架以使N个电解槽分批启动,其中,每一次遍历各组框架时,依次从各组框架中选择Mi个电解槽执行启动任务;判断完成启动任务的电解槽的数量是否等于N;当完成启动任务的电解槽的数量等于N时,统计电解槽集群的运行状态;根据所述电解槽集群的运行状态,选择各组框架电解槽的运行功率区间。
Absstract of: CN122466488A
0001 本发明公开了一种高效质子交换膜电解水制氢系统,涉及电解水制氢技术领域,包括电解槽,所述电解槽的内部固定安装有质子交换膜主体,所述电解槽的两侧共同设置有扰流机构,所述扰流机构包括两个进水管,此高效质子交换膜电解水制氢系统,在进行电解水制氢工作时,电解水通过进水管进入电解槽时,通过锥面管的锥面提升电解水的流速,使得电解水通过螺旋导叶带动其中一个转轴转动,其中一个转轴通过传动组件使另一个转轴同时转动,以使转轴带动斜面导叶转动,斜面导叶带动电解水旋转并与质子交换膜主体接触,从而在离心力作用下将气泡从催化层表面剥离,有效防止气泡堆积阻塞、局部反应物浓度降低等问题,提升气体的排出效率。
Absstract of: WO2025114700A1
A process for preparing an oxygen evolution reaction (OER) catalyst comprises an oxygenated iridium component supported on a particulate solid support, which process comprising the steps of: (i) forming an aqueous mixture comprising a particulate solid support and a solution of a halide-free metal iridate; (ii) reducing the pH of the aqueous mixture to ≤ 5.0 to precipitate an oxygenated iridium component onto the particulate solid support; and (iii) isolating the product of step (ii).
Absstract of: JP2026121810A
0001 【課題】システムが簡便で高い水分解効率を有する水分解装置を提供する。 【解決手段】水分解装置は、光が照射されることで水素を発生する水分解装置であって、表面張力が60mN/m以下である電解液が満たされた電解槽と、電解液に浸漬されている水分解セルであって、メソ結晶を堆積させたアノード電極とペロブスカイト電池セルとカソード電極とが接続された水分解セルと、を備える。 【選択図】図1C
Absstract of: KR20260115804A
0001a 본 발명은 수소 생산 공정 시 발생하는 단일 기포의 직경을 고려하여 미세 전극의 형상 및 크기와, 미세 전극 간의 간격을 조절함으로써, 에너지 소비를 저감하고 효율적인 수소 생산이 이루어질 수 있도록 한 미세 전극의 크기 및 간격이 조절된 수전해 수소 생산 시스템에 관한 것이다.
Absstract of: CN121419830A
The invention discloses a hydrogen extraction catalyst based on ammonia partial oxidation, a preparation method thereof and a hydrogen extraction method using the catalyst. The hydrogen extraction catalyst based on ammonia partial oxidation comprises a support body and ruthenium (Ru) supported on the support body, and the hydrogen extraction method using the catalyst can maintain the internal temperature of a reactor at a high temperature without an external heat source. And the problem that the existing thermal efficiency is reduced due to long reaction time can be solved, and a high ammonia conversion rate can be obtained.
Absstract of: CN122446221A
0001 本发明涉及电解水制氢技术领域,公开了一种宽电源电压范围电解水制氢的装置和方法,该装置包括:风光发电设备、超级电容器、逆变稳压整流器、电流监控器、控制器、电解槽和辅助设备,逆变稳压整流器的电流输出端连接电流监控器和电解槽,电解槽包括电解槽本体、悬挂架和升降平台,电解槽本体包括电解槽水箱、电解液、正极板和负极板,电解槽水箱的内部排列分布若干个电解室,且电解槽水箱内部设置有正对的正极板和负极板,正极板和负极板浸泡在电解液中,每个电解室之间设置连通孔,本发明的电解槽本体采用多电解室串联分布结构,配合连通孔设计,使得电解液在各电解室间均匀流动,维持了电解水制氢的稳定性和可靠性。
Absstract of: WO2024256503A1
The invention relates to a method for manufacturing an assembly for an electrochemical cell, wherein the assembly comprises at least the following structural components: a first plate (10; 10') for supplying and/or discharging fluid, a proton exchange membrane (42), a first electrode (31) arranged between the first plate and the proton exchange membrane, and a first gas diffusion layer (21) arranged between the first plate and the first electrode, and wherein the method comprises the steps of A) providing a base comprising only a portion of the structural components, in particular the first plate and/or the first gas diffusion layer; and B) assembling the assembly, wherein the assembling involves adding the remaining structural components; or the steps of a) providing a base that is different from the structural components; and b) assembling the assembly, wherein the assembling involves adding the structural components; wherein a casing is formed by applying one or more layers of moulding material (70-72) to the provided base, a strength of this moulding material increases after said application, and at least one layer of the moulding material forming the casing or at least a circumferential section of the casing is applied before step B) or b). The invention also relates to an electrochemical cell, in particular a fuel cell or electrolysis cell, a cell stack with cells of this type, as well as a method and a system for manufacturing assemblies for cells or cell stacks of thi
Absstract of: EP4563523A1
0001 The invention relates to a process (100) for the production of hydrogen from ammonia comprising the following steps: - providing a water feed stream to a water electrolyzer (101); - performing a water electrolysis (102) of the water feed stream in the electrolyzer, producing an oxygen product stream and an electrolysis hydrogen stream; - providing an ammonia feed stream to an ammonia cracking reactor (103); - providing an oxidant stream (105) and performing a combustion reaction (106) with said oxidant stream, thereby generating heat; - in the ammonia cracking reactor, performing an endothermic reaction of ammonia cracking (104) of the ammonia feed stream with said generated heat; characterized in that the oxidant stream comprises at least a portion of the oxygen product stream produced by the water electrolysis of the water feed stream.
Absstract of: CN122446256A
0001 本发明涉及电催化材料领域,尤其涉及一种N‑Mn<7>C<3>/Ni<5>P<4>@CC异质结催化剂、制备方法及应用,利用预先生长的Ni<5>P<4>纳米阵列作为晶态导电骨架和结构模板,保障了异质结内核的高导电性与结构稳定性;利用锰卟啉分子在80℃温和条件下的π‑π堆叠与配位锚定自限域组装,实现了壳层厚度的精确控制和完整包覆,在Ni<5>P<4>表面自发形成均匀、厚度可控的非晶壳层,实现原子级界面预排布,碳化后得到紧密核壳界面;惰性气氛碳化过程中,卟啉壳层分解释放还原性气体,形成局部还原微环境,有效抑制Ni<5>P<4>内核的磷流失和表面氧化,同时实现卟啉壳层向非晶N‑Mn<7>C<3>的保形转化和内核组分的完整保持,解决现有双功能电解水催化剂界面接触松散、原子级界面比例低的问题。
Absstract of: CN122446247A
0001 本发明公开了一种基于硼掺杂金刚石的析氧电极及其制备方法和应用,属于电解水析氧的电催化技术领域。制备步骤如下:对钛基底进行表面预处理;采用微波等离子体化学气相沉积法,在预处理后的钛基底表面生长硼掺杂金刚石薄膜,得到硼掺杂金刚石电极;以所述硼掺杂金刚石电极为工作电极,在含有镍盐和铵盐的电解液中进行恒电流电沉积,在硼掺杂金刚石薄膜表面形成氢氧化镍层;将沉积有氢氧化镍层的电极浸入含Fe<3+>离子的溶液中,通过离子交换与结构重建,获得基于硼掺杂金刚石的析氧电极。该方法利用BDD优异的电化学稳定性与界面可控性,构建了结构稳定、活性优异的NiFe‑LDH复合电极,操作简便,适用于碱性电解水环境。
Absstract of: CN122446235A
0001 本发明公开了一种稀土金属铈调控镍钴氮化物泡沫镍自支撑双功能电催化电极及其制备方法和应用。该方法以泡沫镍为自支撑导电基底,将钴盐、镍盐和铈盐在水溶液中混合后进行原位水热反应,使铈、镍、钴前驱体均匀生长于泡沫镍表面;随后以尿素为氮源,在氮气气氛下进行低温氮化处理,得到铈掺杂镍钴氮化物负载泡沫镍电极。在 1.0 mol/L KOH 电解液中,该电极在 10 mA/cm<2>下的析氧过电位为 238 mV,析氢过电位为 80 mV;以该电极同时作为阴极和阳极组装的对称全解水电解槽在 50 mA/cm<2>下电压为 1.49 V,并可稳定运行 50 h。该方法工艺简单、成本较低、无需聚合物粘结剂,适用于高效碱性全解水制氢。
Absstract of: CN122446260A
0001 本申请提供一种负载金属的过渡金属氧化物@过渡金属硫族化合物复合材料及其制备方法和应用,过渡金属硫族化合物纳米壳层包裹在过渡金属氧化物纳米颗粒表面形成核壳结构,过渡金属硫族化合物纳米壳层表面负载有金属微粒,金属微粒为单原子、纳米团簇或者纳米晶。本发明复合材料具有金属和硫族空位双活性位点,纳米壳层和金属微粒在分子尺度上紧密结合,以本发明核壳结构复合材料作为电催化剂进行电催化HER具有更低的过电位、更小的塔菲尔斜率和阻抗、更大的表面活性面积以及更优的耐久性。本发明解决了pH对于过渡金属硫族化合物电催化HER的制约问题,为制备高效全pH电催化剂提供了原子级设计策略,对推动电解水可持续制氢具有重要意义。
Absstract of: KR20260115396A
본 발명의 3상 수전해 시스템은, 서로 병렬 연결된 다수 개의 단위 AC/DC 컨버터들로 이루어진 A상 수전해 전력변환 모듈; 서로 병렬 연결된 다수 개의 단위 AC/DC 컨버터들로 이루어진 B상 수전해 전력변환 모듈; 서로 병렬 연결된 다수 개의 단위 AC/DC 컨버터들로 이루어진 C상 수전해 전력변환 모듈; 및 상기 A상 수전해 전력변환 모듈, 상기 B상 수전해 전력변환 모듈 및 상기 C상 수전해 전력변환 모듈의 DC 출력단에 공통으로 연결된 수전해 스택을 포함할 수 있다.
Absstract of: CN122444127A
0001 本发明公开了一种低温无电自启动的放氢装置,主要结构包括第一腔室、第二腔室、第三腔室。第一腔室和第二腔室通过腔室通道连通,该腔室通道的打开或关闭由第一启动模块控制。第一腔室中装有固态储氢材料,第二腔室中装有激发反应物,当腔室通道打开后,固态储氢材料与激发反应物接触,反应释放氢气。第三腔室内装有放热反应物,它们的放热反应由第二启动模块控制。放热反应用于加热凝固的激发反应物,使其恢复液态进而参与放氢反应。本发明提供的放氢装置不需要电力驱动即可实现快速放氢,适用于高寒地区无电的应急情况。采用固态储氢材料,可长时间储存氢气,安全性高,无气体逸散风险。
Absstract of: JP2026121330A
【課題】ケイ素物質とアルカリ液および水を反応させてケイ酸ナトリウムと水素ガスを効率的で経済的に製造する方法を提供する。【解決手段】ケイ素物質と、アルカリ液と、反応容器と、から構成され、前記アルカリ液を前記反応容器に投入する第1工程と、前記反応容器内の前記アルカリ液に前記ケイ素物質を添加する第2工程と、前記反応容器内を所定の温度および圧力に制御する第3工程と、により、前記反応容器内において所定の反応温度および圧力の条件下で前記アルカリ液と前記ケイ素物質を反応させ、前記ケイ素物質と前記アルカリ液の反応を中断し再開させケイ素ナトリウムの性状を調整する第4工程と、前記反応容器内から水素ガスを収集する第5工程と、からなることを特徴とするケイ酸ナトリウムおよび水素ガスの製造方法。【選択図】図1
Absstract of: CN122446254A
本发明公开了一种TiO2/NiMoCH复合电催化材料及其制备方法与应用,包括以下过程:将碳布加入钛源、酸试剂与去离子水的混合溶液,进行第一水热反应,得到TiO2/CC;将TiO2/CC置于含镍盐、钼盐与沉淀剂的水溶液中,进行第二水热反应,得到TiO2/NiMoCH/CC复合电催化材料。具有垂直多孔异质界面,显著增加了电化学活性面积,暴露出更多边缘活性位点。
Absstract of: CN122444277A
0001 本申请涉及一种电热水器的电解富氧水控制方法及装置,通过实时采集电热水器出水端的流量参数与温度参数;当流量参数不小于预设的启动阈值并维持第一预设时长时,判定当前工况为有效用水工况,根据流量参数和温度参数,动态调节电解单元的电解参数,以控制电解单元进行电解反应产生溶解氧;当流量参数小于启动阈值并维持第二预设时长时,判定当前工况为停止用水工况,对电解单元进行断电以停止电解反应,并执行电极除垢操作;与现有技术相比,本申请的技术方案通过实时采集流量与温度参数、依据双参数动态调节电解参数、停机时断电并除垢的三步联动机制,同时解决了现有技术中产氧效率低、高温无效耗能、电极易结垢寿命短等技术问题。
Absstract of: WO2025135726A1
The present invention provides a hydrogen vent system for discharging hydrogen generated in a high-temperature water electrolysis stack to the outside, comprising: a first pipe unit connected to the high-temperature water electrolysis stack and having a curved portion; a drain line which is connected to the first pipe unit and through which condensed water is drained; and a discharge unit which is connected to the first pipe unit and which releases hydrogen upward into the air, wherein a surge tank that maintains pressure and moves the condensed water to the drain line is disposed in the first pipe unit.
Absstract of: KR20260115525A
본 발명은 수소 분포의 제어가 가능한 전기화학적 수소 장입 시스템 및 이를 이용한 방법에 관한 것이다.
Absstract of: FR3171376A1
L’invention concerne un procédé de traitement de scories alumineuses comprenant de l’aluminium, le procédé incluant : une étape de préparation (100) d’une charge solide comprenant les scories alumineuses et des boues rouges, une étape de mélange (200) de la charge solide avec une solution aqueuse une étape de récupération (300) des produits, ladite étape de récupération incluant les sous-étapes consistant à :prélever le produit solide du fluide réactionnel, ledit produit solide comprenant un oxyde d’aluminium et/ou un hydroxyde d’aluminium, et soutirer le produit gazeux contenant du dihydrogène. Figure à publier avec l’abrégé : Fig. 1
Absstract of: WO2026158884A1
The present application provides an electrolytic unit comprising: a first plate and a second plate; a stack formed by an anodic porous transmission layer, an anodic electrode layer, a membrane, a cathodic electrode layer, and a cathodic porous transmission layer stacked in sequence along a stacking direction, the stack being disposed between the first and second plates in the stacking direction; and a first and a second sealing members respectively disposed between the first and second plates in the stacking direction. The first sealing member surrounds the stack in a direction perpendicular to the stacking direction. The second sealing member is disposed outside the first sealing member and surrounding the first sealing member in a direction perpendicular to the stacking direction. The second sealing member is vulcanized to be fixedly attached to the first and second plates and retain the first and second plates as an integral structure, thereby maintaining the first sealing member and the stack therebetween. The present application also provides a method of producing the electrolytic unit and an electrolytic apparatus comprising the electrolytic unit. The electrolytic unit and the electrolytic apparatus according to the present application are easy to manufacture, assemble, and maintain.
Absstract of: WO2026158897A1
The present application provides an electrolysis unit comprising: first and second electrode plates; a stack formed by sequentially stacking an anode porous transport layer, an anode electrode layer, a membrane, a cathode electrode layer, and a cathode porous transport layer along a stacking direction, disposed between the first and second electrode plates in the stacking direction; and first and second sealing members disposed between the first and second electrode plates respectively in the stacking direction. The first sealing member surrounds the stack in a direction perpendicular to the stacking direction. The second sealing member is disposed outside the first sealing member and surrounds the member in a direction perpendicular to the stacking direction. The second sealing member is fixedly attached to the first and second electrode plates to maintain them as an integrated structure, thereby holding the first sealing member and the stack between the first and second electrode plates. The present application also provides an electrolysis apparatus comprising the aforementioned electrolysis unit. The electrolysis unit and electrolysis apparatus according to the present application are easy to manufacture, assemble, and maintain.
Absstract of: CN122446263A
本发明公开一种织物隔膜及其用途,所述织物隔膜的厚度为0.4~3.0mm,且织物隔膜的展开面积与实际面积的比例小于1.4,所述织物隔膜的表面在1cm内的毛羽个数小于10个。本发明的织物隔膜具有高气密性、高耐久性的特点。
Absstract of: CN122446264A
0001 本申请公开了一种电解水制氢系统的自适应控制方法、系统和电子设备,属于氢能制取技术领域,所述方法包括:在滚动时域内,对多目标优化问题进行优化求解,得到预设控制周期内的最优控制输入序列集合;将最优控制输入序列集合中的第一个最优控制输入序列作为实际控制指令,以及将实际控制指令下发至执行机构,以通过执行机构执行实际控制指令,得到多项实际数据;将多项预测数据中的任意一项预测数据与其匹配的实际数据进行比对,得到对应的比对结果;基于比对结果和预设方法,对预测模型中的关键时变参数集中的多项不同时变参数进行在线微调,以进行自适应控制。通过该自适应控制方法,能够做到:在全生命周期内,通过自适应控制保持最优性能。
Absstract of: CN122444135A
本发明属于光电化学水分解光电极材料制备技术领域,具体为一种大晶粒尺寸的Ta3N5薄膜及其制备方法与应用,其方法结合电子束蒸发系统与氩气退火处理,首先构建了Na2Ta4O11中间相,随后在氨气气氛下进行高温氮化,使中间相转变为大晶粒尺寸的Ta3N5薄膜。与现有技术相比,本发明显著增大了薄膜内晶粒尺寸,有效降低了晶界密度,并且具有良好的工艺可控性与重复性,广泛适用于各种常见基底。
Absstract of: CN122446239A
本发明属于电催化材料与功能薄膜制备技术领域,具体涉及一种氧非热等离子体诱导原位构筑Ni‑LDH薄膜电极的方法及其在碱性析氧反应中的应用。所述方法包括:将乙醇胺加入丙酸中混合后,加入镍源,在加热搅拌条件下制得含镍前驱体溶液;将前驱体溶液陈化并离心后取上清液作为成膜溶胶;将所述成膜溶胶旋涂于基底表面并干燥,得到前驱体薄膜;再将所述前驱体薄膜置于氧气气氛下的微波非热等离子体中,原位转化为含层间阴离子的Ni‑LDH薄膜电极。本发明方法无需高温退火、无需后续水热活化,能够直接获得具有层状双氢氧化物特征的Ni‑LDH薄膜。所得薄膜在碱性电解液中表现出良好的析氧催化活性与稳定性,在10 mA/cm²电流密度下过电位小于350 mV,Tafel斜率小于80 mV/dec。
Absstract of: CN122441458A
本发明属于光催化材料技术领域,公开了一种镁掺杂ZnIn2S4光催化剂及其制备方法和应用,本发明利用柠檬酸根的络合作用,通过一步水热法制备镁掺杂ZnIn2S4光催化剂,其化学通式为MgxZnIn2‑xS4,其中0
Absstract of: CN122441442A
本发明公开了一种二维/三维四氧化三钴负载铜催化剂及其制备方法和应用。该催化剂的制备方法包括:将ZIF‑67在空气中氧化焙烧得到蠕虫连接状四氧化三钴;将其浸渍于铜盐水溶液中,密封放置后干燥,再于惰性气氛中焙烧,得到负载铜的蠕虫连接状四氧化三钴;最后在室温下用硼氢化钠水溶液还原处理,即得二维/三维四氧化三钴负载铜催化剂。该方法中,硼氢化钠还原处理不仅能将铜的氧化物还原为金属铜纳米颗粒,还能诱导四氧化三钴载体由蠕虫连接状演化为二维/三维复合结构。所得催化剂中铜纳米颗粒均匀负载于二维/三维四氧化三钴上,形成金属‑载体协同效应,在常温常压下催化氨硼烷水解制氢反应中展现出优异的催化活性。
Absstract of: CN122446250A
本发明公开了一种夹心结构双功能电催化剂的制备方法及其应用在NF基底上制备了“夹心”B掺杂结构的NiCoFe‑B@NF电催化剂。首先进行阴极沉积生成NiCo LDH提供导电骨架,然后进行阳极沉积将B元素锚定在NiCo LDH骨架上,最后进行二次阴极沉积生成NiFe LDH保护层,形成了层状夹心结构的NiCoFe‑B@NF催化剂,该策略创新性地构建了表面电子态可调节的NiCoFe‑B@NF催化剂,这种分层设计能够有效抑制B元素溶解,保障其在反应过程中持续优化金属表面的活性位点的d带中心,对催化剂全解水性能具有显著的提升作用。电化学测试表明,在碱性溶液中,NiCoFe‑B@NF是一种卓越的双功能电解水催化剂,HER(η10=92 mV,η100=216 mV)和OER(η10=213 mV,η100=236 mV),在具有高效催化分解水能力的同时也具有良好的稳定性,在100 mA cm‑2的电流密度下可以稳定反应110h。
Absstract of: CN122446253A
0001 本发明公开了一种Cu<2>O@NiFe‑LDH异质结构电催化剂与集成催化阴离子交换膜电极及其制备方法和应用。所述电催化剂的制备包括:以NaOH与CuCl<2>·H<2>O为原料,加入甲醛溶液经自放热反应合成Cu<2>O纳米颗粒;以Ni(NO<3>)<2>·6H<2>O和Fe(NO<3>)<3>·6H<2>O为原料,经水热反应制备NiFe‑LDH纳米片;再将Cu<2>O加入反应体系中原位生长得到Cu<2>O@NiFe‑LDH复合材料。将所得复合材料通过超声喷涂法负载于W‑25T阴离子交换膜上,得到集成催化膜电极。该膜电极可作为阳极和阴极组装成对称电极用于碱性电解水制氢。本发明具有p‑n异质结界面效应强、电荷转移快、稳定性好等优点。
Absstract of: CN122446234A
0001 一种用于海水电解的双层结构析氧电催化剂及其制备方法和应用,它涉及析氧电催化剂及其制备方法和应用,它是要解决现有的电解海水制氢制氧的电催化剂的效率低、耐腐蚀性差、成本高的技术问题。本发明的催化剂是以泡沫铁为基底,在泡沫铁表面生成负载贵金属修饰的双过渡金属层状氢氧化物,其中贵金属为铱、钌或锇,双过渡金属层状氢氧化物为镍铁双金属层状氢氧化物,或者为铁钴双金属层状氢氧化物。制法:先通过浸泡反应将基底与贵金属进行键合,再通过原位生长过渡金属氢氧化物。该催化剂,在1 M KOH的海水中,在10 mA cm<‑2>下的过电势仅为210mV。在碱性海水条件下实现了超过1400小时的稳定性,用于电解海水制氢。
Absstract of: CN122444572A
0001 本发明公开了一种高熵有机小分子光催化剂及其制备方法和应用,涉及有机小分子材料技术领域,该高熵有机小分子光催化剂由五种以上具有不同化学结构的有机小分子组成;其中的有机小分子是由至少一种核心单元单体与至少两种外围单元单体通过一锅法反应制备得到。本发明制备的高熵有机小分子光催化剂的多重组分协同形成界面电场,促进了光生载流子的分离与传输,除增强了光电流响应特性外,还提升了电荷传输能力,对有机小分子的光催化性能产生了显著的积极影响,可广泛用于光催化制氢领域。
Absstract of: CN122446231A
0001 本发明属于电催化水分解技术领域,具体涉及一种MOOH‑MOF/BNF电极及其制备方法和应用。本发明旨在解决现有技术中析氧反应(OER)催化剂活性不足及稳定性差的问题。本发明通过“室温沉积‑溶剂热‑电化学活化”的合成策略制备得到MOOH‑MOF/BNF电极。该电极具有以纳米片为骨架、纳米针为分支的三维网络结构,表面由Ni、Co、Fe、C、N、O及B元素均匀组成。本发明引入Ni₃(BO₃)₂作为“界面键合增强剂”,通过强Ni‑O‑B键合形成“化学铆钉”,牢固锚定催化层。该电极在10 mA·cm⁻²电流密度下的过电位仅为207 mV,Tafel斜率为66.4 mV dec⁻¹,且在100 mA·cm⁻²大电流下连续运行500小时后电位保持稳定,展现出卓越的催化活性与长程耐久性,适用于碱性条件下电催化水分解析氧反应。
Absstract of: CN122446243A
0001 本发明公开了一种NiFe基催化剂原位修复方法及其应用,属于碱性电解水制氢技术领域,包括:向碱性电解液中引入包含镍源和铁源的离子补充剂;对所述NiFe基催化剂施加反向电流进行原位修复;其中,离子补充剂中的镍离子和铁离子在所述NiFe基催化剂表面电沉积,同时还原剥离所述NiFe基催化剂表面的氧化层,重构活性位点。本发明通过离子补充与反向电流协同作用,实现了催化剂活性位点的原子级重构,在不拆卸电解槽的情况下高效恢复催化剂活性,延长了电解槽使用寿命。
Absstract of: CN122446213A
本发明公开了一种自定位强化预紧的智能电解槽及其使用方法,采用一体化支架,一体化支架上表面设计为倾斜1.2°‑2.5°的固定导轨,固定导轨上安装有若干个自定位滑座与滑块,滑块表面与电解槽直接接触部分采用聚四氟乙烯绝缘棒,以满足电解槽与支架之间的电气绝缘;所述自定位滑座与滑块为一体化支架的支撑与定位结构,与固定导轨配合沿着导轨方向滑动;所述自定位滑座上开设有垂直通孔,通孔中穿设有螺杆,螺杆上套设有碟簧,螺杆下端通过螺母与自定位滑座固定;所述碟簧的定位环底部安装有穿环式压力传感器。本发明解决电解槽安装过程的支撑定位问题,减缓电解槽沉降和变形,并智能监测电解槽变形状态,提升电解槽安全性能与使用寿命。
Absstract of: CN122446233A
0001 本发明提供一种双功能电解水氮磷掺杂高熵催化剂的制备方法,属于电解水制氢技术领域。该方法首先对金属基底进行预处理,随后通过浸渍吸附含有镍、钼、钴、锆、铁的五元金属前驱体溶液,并采用瞬时焦耳热技术快速构建高熵氧化物结构。核心创新在于利用次磷酸铵与次磷酸钠在焦耳热过程中原位分解产生的还原性气氛以实现材料表面的同步氮磷化改性,将传统工艺数小时的耗时缩短至秒级并显著降低能耗。最终制得的催化剂具有优异的析氢(HER)与析氧(OER)双功能活性与化学稳定性:在10 mA·cm<‑2>电流密度下OER过电位<230mV、HER过电位<50mV;在波动电解测试、启停测试和恒流电解中电解电压保持稳定,具有优异的稳定性。
Absstract of: CN122446042A
本发明提供一种合金催化剂及其制备方法,该合金催化剂包含0.01wt%至30.0wt%之Zn、50.0wt%至99.9wt%之其余金属、及0.0wt%至20.0wt%之贵金属,该其余金属包含选自Ni、Fe、Mo及Co所成群中之至少一种金属;该合金催化剂具有藉由去合金化所形成之多孔结构。本发明之合金催化剂具有低过电位、低Tafel斜率及高稳定性。
Absstract of: CN122446226A
本发明涉及电解槽密封技术领域,公开了一种耐高压密封组件及电解槽装置。密封组件包括极板、膜电极、密封圈和增强丝。极板具有反应区及围绕反应区设置的极板密封凹槽,密封圈容纳于极板密封凹槽内并设有沿密封路径延伸的密封圈凹槽,增强丝嵌设于密封圈凹槽内并与密封圈凹槽的轮廓相适配。沿电解槽压装方向,在密封组件未压缩状态下,增强丝厚度h不大于密封圈凹槽在该方向上的容纳尺寸h1,h1小于极板密封凹槽深度h2,h2小于密封圈厚度h3。压装后,密封圈高出极板密封凹槽的部分与膜电极形成环绕反应区的密封接触,增强丝随密封圈共同保持于极板密封凹槽内,以约束密封圈的密封路径轮廓。
Absstract of: CN122446222A
0001 本发明提供了一种电解槽组件及电解槽小室和其在电解水制氢中的应用。该电解槽组件包括顺次设置的弹性网、镍网、多孔镍板和镍基催化涂层;弹性网的孔径大于镍网的孔径,镍网的孔径大于多孔镍板的孔径。本发明采用弹性网‑镍网‑多孔烧结镍板的梯度孔结构设计,将传质通道进行有序设计,优化了碱液在电解槽内的流动特性,减少了死区和涡流的产生,实现了碱液均匀分布在催化层反应活性中心的有益效果,从而提高了电解槽运行电流密度,降低了能耗。
Absstract of: CN122441457A
0001 本发明申请涉及纳米材料制备的技术领域,尤其是涉及一种合成具有锌硫双空位Zn<3>In<2>S<6>光催化剂的方法,将特定体积氨水与去离子水混合形成溶剂,加入硫酸锌、三氯化铟及硫代乙酰胺前驱体,搅拌均匀后在160℃下进行12小时一步水热反应,产物经离心洗涤及真空干燥获得。本申请通过氨水的配位诱导作用,在Zn<3>In<2>S<6>晶格内原位构筑锌空位与硫空位,利用引入的缺陷能级作为电子陷阱捕获光生电子,抑制载流子复合,并增加表面活性位点。本申请能够显著提升可见光下的产氢活性,其析氢速率达未添加氨水的2.25倍,具有工艺路线简单、催化性能优异且结构稳定性强的优点。
Absstract of: CN122441503A
本发明涉及一种铋基纳米线BSO NWs及其制备方法与其在高效压电‑光协同催化析氢中的应用。本发明通过水热反应合成BCSO NWs,并使用Langmuir‑Blodgett(LB)技术将其组装成薄膜。与非手性的BSO NWs薄膜相比,手性的BSO NWs膜具有高的压电催化析氢活性,同时,一定比例的钴掺杂,可以进一步提升析氢活性。此外,基于BSO NWs膜和BCSO NWs膜的手性结构,在光匹配的条件下,即左手性膜(LH‑film)在左圆偏振光(LCP)照射下和右手性膜(RH‑film)在右圆偏振光(RCP)照射下,表现出最强的压电‑光协同催化效应,进一步提高析氢速率。
Absstract of: CN122446246A
本发明涉及一种NiFeMo基球形多孔复合催化材料及其制备方法与应用,属于电催化材料技术领域。旨在解决现有材料制备流程复杂、粉体易团聚、形貌可控性不足及连续化制备能力有限的问题。本发明提供一种NiFeMo基球形多孔复合催化材料,为含Ni、Fe、Mo元素的复合粉体,呈单分散球状颗粒,具有多级多孔结构,Ni、Fe、Mo摩尔比为10:10:(0.5~2);采用超声喷雾热解一步法制备。本发明的材料电化学活性表面积达0.6303 cm2,高于NiFeV(0.3360 cm2)和NiMo(0.1485 cm2);析氢驱动电位更小、电荷传递阻力更低,适用于碱性电解水阴极析氢催化剂。
Absstract of: CN122441463A
一种加快氢化镁水解制氢的复合催化体系及其制备方法与应用,涉及氢化镁水解制氢技术领域,解决了现有氢化镁水解制氢反应在后期传质阻力大,难以在温和条件下实现MgH2的快速且完全转化的问题。复合催化体系由独立机械球磨预活化的氢化镁粉末与氯化铈粉末复配组成。在惰性气氛下,将氢化镁粉末进行独立机械球磨预处理,得到活化氢化镁粉末;将活化氢化镁粉末与氯化铈粉末按设定摩尔比均匀混合,得到铈基复合催化体系。将上述铈基复合催化体系加入水中,在20℃~60℃下引发水解反应制氢。本发明催化体系能够稳定满足便携式供氢装置的快速产气需求,兼具催化效能与成本优势,适配实际场景的规模化应用。
Absstract of: CN122446258A
本发明公开了一种Mo‑Ru双位点过渡金属催化剂及其制备方法,属于电催化材料技术领域。该方法以氧化石墨烯为载体,将三水三氯化钌与四水七钼酸铵的混合溶液加入氧化石墨烯分散液中,超声处理6小时,获得均匀前驱体溶液;随后进行水热反应,得到固态产物;产物经12小时冷冻干燥后,采用化学气相沉积法在800℃、氨气‑氩气混合气氛下高温氮化2小时,最终制得Mo‑Ru双位点过渡金属催化剂。该催化剂在酸性与碱性介质中均表现出优异的二电子析氢反应电催化活性与长期稳定性,可高效应用于电解水制氢领域。
Absstract of: CN122446240A
一种二氧化钌催化剂及其制备方法和应用,涉及电解水催化剂技术领域,解决了现有技术现有钌基析氧催化剂制备繁琐且稳定性差的问题。本发明将明胶和碳酸盐溶于水中,水浴搅拌,得到混合液A;将钌盐溶于水中,超声处理,得到混合液B;将混合液B倒入混合液A中,搅拌混合后形成凝胶,即为催化剂前驱体;经过煅烧处理,得到二氧化钌催化剂。本发明具有成本低、催化稳定性好的优势,作为质子交换膜电解水阳极催化剂应用具有广阔前景。
Absstract of: CN122446242A
本发明公开了一种钛基金属间化合物的应用及其制备方法,钛基金属间化合物的化学式为TiNiSn或TiCoSn。TiNiSn一般为热电材料,本发明将其用于电解水制氢,在碱性条件下保持较高的活性和稳定性。本发明的钛基金属间化合物,可通过高温熔融一步合成,无需进一步退火或控制冷却程序以减少杂相,大幅简化了制备方法。
Absstract of: CN122446220A
本申请涉及碱性电解槽技术领域,具体是一种电解槽的支撑底座,包括:支撑底座本体;限位机构,设置在所述支撑底座本体上,用于连接电解槽的四个底脚;中间支撑机构,设置在所述支撑底座本体上且位于所述支撑底座本体的长度方向的对称轴上,用于对所述电解槽的极板进行支撑,所述中间支撑机构通过第一升降装置调节高度;两组侧支撑机构,设置在所述支撑底座本体上,并对称设置在所述中间支撑机构的两侧,用于对所述极板进行支撑,每组所述侧支撑机构通过第二升降装置调节高度。本申请能够对电解槽的安装位置进行限位和固定,并且能够调节对极板的支撑力度,防止极板下坠。
Absstract of: CN122441386A
本发明提供一种自驱动腔内循环的扁平光解槽、光解制氢系统及制氢方法,属光催化制氢领域。针对扁平空间拟二维流动引发的微泡滞留与传质缓慢问题,构建“渐缩流道+特定倾角导流+光区匹配”协同结构:工作腔高2~5cm,内置倾斜导流构件划分上升流区域与下降流区域,上升流区域横截面积向上递减且投影占光照区90%~95%;气泡沿构件板面爬升聚并,渐缩流道加速液相并在背流侧形成低压涡旋,带动近壁低速区并促进滞留微气泡卷吸回主流,在单一连续腔体内形成无泵气升内循环。该方案将光能输入与气升驱动力空间耦合,光解槽内部循环无需外置泵,常压下可维持稳定循环,降低微细气泡光散射与无效滞留,缓解流光优化互斥,利于规模化应用。
Absstract of: EP4570956A1
The invention refers to an electrochemical system (1) suitable for hot idling comprising- at least one electrochemical module (11) comprising a fuel electrode section, an oxidant electrode section, and a membrane;- at least one fluid inlet line (10) leading to the electrochemical module (11), in particular to the fuel electrode section;- at least one fluid outlet line (12) exiting the electrochemical module (11);- a gas recirculation unit (15) to recirculate a gas or gas mixture exiting the electrochemical module (11) to the fuel electrode section.The system comprises an inert gas unit (3), preferably nitrogen unit, for supplying inert gas to the at least one fluid inlet line (10). The invention refers also to a method of performing electrolysis in a hot idling mode.
Absstract of: US20260209975A1
0000 The present invention provides a system and method for managing hydrogen storage and release, utilizing hydrogen carrier fluid (HCF) and undivided electrochemical reactors (i.e. not containing ion exchange membranes) to achieve hydrogenation/dehydrogenation of HCF.
Absstract of: US20260209965A1
Using optimal indirect thermal coupling between a thermal power plant and a hydrogen production unit by high-temperature electrolysis via a withdrawal branch connection made in a fluid branch of the power plant's thermodynamic conversion cycle to install, on the one hand, a thermal storage tank to provide the heat necessary to preheat the steam intended for the cathodes of the HTE unit and, on the other hand, a pneumatic and thermal storage tank to supply pressurized hot air to the anodes.
Absstract of: US20260210593A1
The present disclosure belongs to the technical field of hydrogen production by water electrolysis, and relates to an energy optimization heat pump system and method for hydrogen production by water electrolysis with low-pressure ratio. It includes a hydrogen oxygen gas-liquid separation unit, a heat pump compressor, and an expander. The hydrogen oxygen gas-liquid separation unit is connected to the hydrogen dryer through a hydrogen cooler. The hydrogen oxygen gas-liquid separation unit is connected to the heat pump absorber through a circulating cooling water pipeline, the hydrogen cooler is connected to the refrigerator through a refrigerant pipeline, and the hydrogen dryer is connected to the steam generator through a hot water pipeline and a steam pipeline respectively. The present disclosure is conducive to reducing the pressure ratio of the heat pump compressor, enriching the selection range of heat pump working fluids, and improving the energy utilization rate of the system.
Absstract of: WO2026152806A1
A chemical looping cycle-based membrane-free water electrolyzer for hydrogen production, and an operating method thereof. The electrolyzer comprises a first end plate and a second end plate separately connected to an external power supply. At least one bipolar plate is arranged between the two end plates. Electrolysis chambers are formed between the two end plates and the bipolar plate and between every two adjacent bipolar plates. A functional assembly is provided in each electrolysis chamber. The functional assembly comprises a bifunctional electrode, a porous partition plate, and an oxygen carrier electrode which are sequentially attached. The bifunctional electrode and the oxygen carrier electrode are used in combination to implement hydrogen evolution and oxygen evolution under different working conditions, accommodating power fluctuations and intermittency of renewable energy and exhibiting the potential of application to off-grid hydrogen production. The operating method comprises implementing stepwise or continuous production of hydrogen and oxygen under different working conditions by means of synergistic energy supply of a temperature field and an electric field.
Absstract of: US20260209978A1
A hydrogen generator with detachable filter comprises a water tank, an electrolysis module configured in the water tank, a filter channel device coupled to the water tank, a humidifying module, vertically configured above the water tank, an integrated channel device vertically configured above the humidifying module, and a condenser configured on the integrated channel device. The electrolysis module is configured to electrolyze water contained in the water tank to generate gas comprising hydrogen. The humidifying module includes a humidifying chamber and a gas channel isolated from the humidifying chamber. The filtering device is arranged in the gas channel to receive and filter the gas comprising hydrogen generated by the electrolysis module. The condenser is configured to condense the gas comprising hydrogen outputted by the filtering device. The integrated channel device includes a gas input channel for guiding the gas comprising hydrogen outputted from the condenser into the humidifying chamber.
Absstract of: US20260209038A1
Process for production of hydrogen from ammonia, including ammonia cracking wherein ammonia is decomposed into hydrogen and nitrogen, wherein the ammonia cracking is performed in a sequence of cracking steps (13, 36, 17, 20) and a finally cracked stream (21) is obtained after a last cracking step (20), wherein the last ammonia cracking step (20) is performed adiabatically and/or the finally cracked stream (21) is quenched by direct mixing with water or steam after the last cracking step.
Absstract of: US20260209954A1
0000 A water electrolysis cell for use in a water electrolysis apparatus that electrolyzes water when irradiated with light to generate hydrogen includes a laminate including an anode electrode, a perovskite battery cell, and a cathode electrode laminated in this order, and an electrically insulating protective material that covers the outer periphery of the laminate.
Absstract of: US20260213641A1
0000 The invention relates to a rectifier arrangement for hydrogen electrolysis, comprising a transformer (1) with a primary winding (2) for connecting an input alternating voltage and a secondary winding (3) for providing an output alternating voltage, and comprising a rectifier (4) connected to the secondary winding (3) for generating an output direct current IDC and an output direct voltage UDC, wherein at the primary winding (2) of the transformer (1) a number N>1 of winding taps (5) are provided, and a load stage switch (6) connected to a controller (7) is provided which is designed for switching the winding taps (5) without interruption such that the transformation ratio of the transformer (1) can be switched via the controller (7) in N stages.
Absstract of: US20260209872A1
0000 The present disclosure relates, according to some embodiments to a method for steel production, the method comprising forming a hydrogen and a carbon from a natural gas using thermal plasma electrolysis; reducing iron ore fines with the H<2> to form an iron briquette; melting the briquette iron from the furnace to form a melted iron and melted non-metallic slag; separating the non-metallic slag from the melted iron in the furnace; combining the carbon and the melted iron in a furnace to form a carbon black and iron mixture; and alloying the melted iron with the carbon black to form a steel.
Absstract of: US2023102312A1
0000 Systems and methods for sequestering carbon, evolving hydrogen gas, producing iron oxide as magnetite, and producing magnesium carbonate as magnesite through sequential carbonation and serpentinization/hydration reactions involving processed olivine- and/or pyroxene-rich ores, as typically found in mafic and ultramafic igneous rock. Precious or scarce metals, such nickel, cobalt, chromium, rare earth elements, and others, may be concentrated in the remaining ore to facilitate their recovery from any gangue material.
Absstract of: US20260209953A1
An alkaline water electrolyzer includes an electronic controller, a stack of electrolysis cells each comprising an anode and a cathode. The electrolyzer is configured to contain an electrolyte made of an anolyte and a catholyte. The electrolyzer also includes a system controlled by the electronic controller configured to maintain a concentration of an impurity in the electrolyte within a target range by measuring a characteristic representative of the concentration of the impurity in the electrolyte and, in response to the measured concentration of the impurity, add a quantity of the impurity into the electrolyte.
Absstract of: US20260209972A1
There is provided a multi-layered proton exchange membrane for water electrolysis, comprising: at least two recombination catalyst layers, each of the at least two recombination catalyst layers comprising a recombination catalyst and a first ion exchange material, wherein at least two recombination catalyst layers are separated by a region devoid of or substantially devoid of a recombination catalyst, and at least two reinforcing layers, each of the at least two reinforcing layers comprising a microporous polymer structure and a second ion exchange material which is at least partially imbibed within the microporous polymer structure.
Absstract of: US20260209961A1
0000 A small scale high-pressure electrolyzer for generating hydrogen and oxygen is provided comprising one or more units each comprising a plurality of high-pressure electrolytic cells, wherein the electrolytic cells of each unit are electrically connected in series, as well as a central electrolyt header, functionally connected to each electrolytic cell for the supply of liquid electrolyt to the cell; a central hydrogen header connected to each electrolytic cell for the discharge of generated hydrogen from the cell; a central oxygen header connected to each electrolytic cell for the discharge of generated oxygen from the cell; a direct current power source for the power supply to each unit of serially connected electrolytic cells; wherein the units of serially connected electrolytic cells are electrically connected in parallel.
Absstract of: AU2024424628A1
This titanium porous body is in the form of a sheet. In the titanium porous body, the maximum height Rz of at least one surface is 5 μm or less, the irreversible deformation amount during pressure application at 100 MPa is 0.2% or less, and the thickness is 500 μm or less.
Absstract of: WO2026154622A1
This photocatalyst is provided with: a support base material having a flat surface; a metal oxide layer that is made of a metal oxide and is applied to the flat surface; and a carbon nitride layer that is made of a polymeric carbon nitride that responds to visible light and is fixed to the flat surface via the metal oxide layer. The carbon nitride layer can be firmly fixed to the support base material, and by immersing the photocatalyst in a liquid, artificial photosynthesis can be performed.
Absstract of: US20260209956A1
0000 A method of hydrogen production includes providing a solution and immersing a device in the solution. The device includes a substrate having a surface, an array of conductive projections supported by the substrate and extending outward from the surface of the substrate, and a plurality of catalyst nanoparticles disposed over the array of conductive projections. The solution includes dissolved sodium chloride (NaCl).
Absstract of: US20260209141A1
0000 A hydrocarbon production system that generates a hydrocarbon having two or more carbon atoms from methane by an oxidative coupling reaction of methane is a hydrocarbon production system including: an oxidative coupling reaction device configured to perform an oxidative coupling reaction between methane and oxygen; a raw gas separation device configured to separate an inert component from a raw gas containing the inert component; a carbon dioxide separation device configured to separate carbon dioxide contained in a generated gas generated in the oxidative coupling reaction device; and a methanation device configured to perform a methanation reaction between hydrogen and carbon dioxide.
Absstract of: US20260213538A1
0000 A power balancing system and process is provided, in which a first electrolysis unit (10) outputs a first hydrogen rich stream (11), which is converted in a methanol synthesis plant (20) to a first methanol-rich stream (21). A methanol storage unit (40) receives and stores the first methanol-rich stream (21). When additional electrical power is required, methanol from the methanol storage unit (40) can be used for power generation. The system and process allow excess electrical power to be converted into and stored as methanol during periods of low demand, and used to generate electrical power when demand is higher.
Absstract of: US20260213228A1
0000 A Solid Oxide Cell stack has a combined flow distributor and contact enabler made of pressed metal foil with flow guides and contact areas located between an interconnect layer and a cell layer in the stack.
Absstract of: WO2026156297A1
Electrochemical devices and associated methods are disclosed for reacting carbon oxides. These devices may include an ion exchange membrane, a cathode, a copper catalyst located on the cathode, a cathodic solution in contact with the ion exchange membrane and the cathode, an anode, a second catalyst located on the anode, an anodic solution, and a cathodic gas in contact with the cathodic solution. The cathodic gas may include hydrogen, ethylene, and an oxide of carbon. The cathode may be configured as a gas diffusion electrode.
Absstract of: WO2026155798A2
Catalyst compositions, methods of making a bimetallic nanofoam catalyst composition, and methods of catalyzing a reaction are described. In an example, the catalyst comprises a nanofoam comprising plurality of intertwined nanowires comprising two or more metals. In an example, the nanofoam comprises a three-dimensional interconnected nanonetwork comprising the plurality of intertwined nanowires. In an example, the nanofoam is an aerogel comprising the plurality of intertwined nanowires. In an example, the nanofoam is self-supported, such as where the catalyst composition does not comprise a substrate supporting the nanofoam.
Absstract of: US20260209969A1
0000 An alloy catalyst, comprising 0.01 wt % to 30.0 wt % of Zn, 50.0 wt % to 99.9 wt % of other metals, and 0.0 wt % to 20.0 wt % of noble metals, wherein the other metals comprise at least one metal selected from a group consisting of Ni, Fe, Mo, and Co. The alloy catalyst features a porous structure formed through dealloying. The alloy catalyst of the present disclosure exhibits low overpotential, low Tafel slope, and high stability.
Absstract of: US20260209974A1
In a water electrolysis system, second current collectors of a plurality of water electrolysis cells each include a cut into which a gas generated in a second electrode catalyst layer flows and which communicates with a gas outlet path and canresonate a sound. The water electrolysis system includes a sound output device that outputs a sound to the gas outlet path, and a sound detection device that detects a resonant sound generated by resonation, in the cut, of the sound propagated from the sound output device to the cut via the gas outlet path. In the plurality of water electrolysis cells, the resonant frequencies of thesound in the cuts are different from each other.
Absstract of: US20260209964A1
An electrolysis system has an electrolyzer, an on-load tap changing transformer, and at least two line-commutated converters, preferably IGBT converters. The on-load tap changing transformer receives an electrical power from an electrical power source and provides an electrical power output to the line-commutated converters. The line-commutated converters are electrically connected in parallel between the on-load tap changing transformer on a AC side and an electrolyzer on a DC side and convert the electrical power output into an electrical power input for the electrolyzer. The converters are connected to the same transformer AC bus. In a ramping phase of the electrolyzer a voltage of the power input is adjusted by only one of the parallel-connected converters to a tap changing voltage and the other converter stays in a stand-by mode. There are also described power supply, a controller, computer program and a related electrolyzer system.
Absstract of: WO2026154223A1
The invention relates to an electrolysis cell, which includes a spacer (50) that is configured to support a separator, extends between a first and a second face (51, 52), and comprises: an inlet (7) and an outlet (8) configured to allow water to circulate within the electrolysis cell; a recess (9) which is intended to be occupied by the separator and is in fluid communication with the inlet and the outlet; a first primary groove (10) which is formed in a thickness of the spacer, opens onto the first face and extends around the recess, the inlet, and the outlet, to accommodate a first sealing member; a first secondary groove (60) which is formed in a thickness of the spacer, opens onto the first face and extends around the first primary groove to accommodate a first sealing device; and a through-hole (70) between the first and the second face, which through-hole is arranged between the first primary and secondary grooves.
Absstract of: WO2026154256A1
The invention provides a hydrogen production device for producing hydrogen gas from ammonia, comprising: an outer chamber comprising an outer chamber wall, one or more inner chambers disposed at least partially within the outer chamber, each of the one or more inner chambers comprising a first inner chamber wall and a second inner chamber wall defining an inner subchamber having an inner subchamber internal volume, each second inner chamber wall comprising one or more fins extending therefrom into the inner subchamber, each inner subchamber comprising ammonia decomposition catalyst and having one or more ammonia gas inlets and one or more raw cracked gas outlets, wherein each of the one or more inner chambers has an internal surface area defined as the inner subchamber internal volume facing surface of the second inner chamber wall and the inner subchamber internal volume facing surface of each of the one or more fins; wherein the ratio of the internal surface area in mm2 to the inner subchamber internal volume in mm3 is between approximately 1:2 and 1:6. Also provided are systems comprising said device.
Absstract of: KR20260114906A
본 발명은 암모니아 산화 분해용 촉매의 제조방법, 암모니아 산화 분해용 촉매 및 암모니아 산화 분해 공정에 관한 것으로, 본 발명에 따른 암모니아 산화 분해용 촉매의 제조방법은, 알루미나에 루테늄을 담지하여 담체를 획득하는 단계; 상기 담체를 건조하는 단계; 상기 건조한 담체를 열처리하는 단계; 상기 열처리한 담체에 지르코늄을 담지하여 혼합 담체를 획득하는 단계; 상기 혼합 담체를 건조하는 단계; 상기 건조한 혼합 담체를 열처리하는 단계; 및 상기 열처리한 혼합 담체를 환원하는 단계;를 포함한다.
Absstract of: KR20260114651A
0001a 본 발명은, 전해조; 상기 전해조로부터 생성된 수소를 저장하는 수소 저장부; 상기 수소 저장부에 저장된 수소를 전달받아 전기 에너지를 발생 및 공급하는 수소 연료전지; 및 상기 전해조에서 사용된 물을 전달받아 외부로 공급하는 온수탱크;를 포함하며, 상기 전해조는, 수소발생량, 수소압력, 전류밀도, 반응면적, 셀수, 셀 간 거리는, 각각, 7Nm3/hr, 40barg, 2.0A/cm2, 1000cm2, 10cell, 10cm 인 고압 수전해 스택(stack)을 포함하는 것을 특징으로 한다.
Absstract of: KR20260114640A
0001a 본 발명은, 암모니아 분해 활성이 우수한 니켈 담지형 알루미나 촉매 및 이의 제조방법에 관한 것으로, 더욱 상세하게는 낮은 온도에서 암모니아를 수소와 질소로 분해가 우수한 암모니아 분해 활성이 우수한 니켈 담지형 알루미나 촉매 및 이의 제조방법에 관한 것이다.
Absstract of: WO2026154283A2
A drinking container is disclosed having a hydrogen-generation compartment isolated from a drinking-fluid chamber. Hydrogen gas accumulates until a threshold pressure opens a one-way valve, releasing the gas into the chamber while preventing backflow of liquid. In some embodiments, the gas passes through an intermediate chamber and porous mesh to form fine bubbles for dissolution. Mixing assemblies, magnetic impellers, oxygen vents, and controlled power delivery may be incorporated to enhance infusion efficiency, user control, and system safety.
Absstract of: US20260209955A1
0000 A method of operating an electrolyzer system includes providing steam to a plurality of hydrogen generation modules (HGMs), each containing at least one electrolyzer cell stack or column of stacks, electrolyzing the steam in the plurality of HGMs to generate hydrogen and oxygen, supplying at least a first portion of a hydrogen-containing product feed from the plurality of HGMs to a recycling conduit, and recycling at least a first portion of the hydrogen-containing product feed to the plurality of HGMs.
Absstract of: US20260209962A1
An electrolysis cell includes: a first separator including a first surface; a second separator including a second surface facing the first surface; an ion-exchange membrane; a first power feeder disposed between the first separator and the ion-exchange membrane; a first catalyst layer disposed between the first power feeder and the ion-exchange membrane; a second power feeder disposed between the second separator and the ion-exchange membrane; a second catalyst layer disposed between the second power feeder and the ion-exchange membrane; and a flow direction changing part provided as a part of the first separator or disposed between the first separator and the first power feeder, the flow direction changing part changing a flow direction of at least a portion of an electrolyte flowing along the first surface in a first direction to a second direction intersecting the first surface at each of a plurality of positions in the first direction.
Absstract of: EP4779059A1
The present disclosure relates to an ion exchange membrane and an electrochemical system comprising the ion exchange membrane. The ion exchange membrane according to the present disclosure can maintain high ion conductivity and durability, and has high gas barrier properties, thereby realizing an electrochemical system with excellent efficiency.
Absstract of: EP4778962A1
According to one embodiment of the present invention, an anion exchange membrane comprising a carbazole-based polymer but having mitigated cracking characteristics of the polymer, and a method for manufacturing the same can be provided.
Absstract of: EP4779728A1
The present disclosure relates to a hollow fiber membrane for a fuel cell membrane humidifier, including a porous polymer and a phenol-based antioxidant dispersed within the porous polymer, a method of preparing the same, and a fuel cell membrane humidifier including the hollow fiber membrane, and thus there is an effect of preventing deterioration and decomposition of the hollow fiber membrane.
Absstract of: EP4779048A1
0001 A stainless steel material for an alkaline water electrolysis device, including, on a mass basis, C: 0.100% or less, Si: 1.00% or less, Mn: 0.30 to 3.00%, Ni: 10.00 to 35.00%, P: 0.0300% or less, S: 0.0030% or less, Cr: 16.0 to 28.0%, N: 0.01 to 0.25%, Cu: 0.01 to 1.00%, Mo: 0.10 to 8.00%, and Al: 0.005 to 0.100%, the balance being Fe and impurities.
Absstract of: EP4778615A1
0001 A hydrogen drying system for hydrogen production using renewable energy is provided. Two adsorbers (1, 2) are arranged in parallel, the two adsorbers (1, 2) alternately perform an adsorption process and a desorption process, the adsorption flow of each of the adsorbers (1, 2) changes along with the fluctuation of input renewable energy, and an operating state of each of the adsorbers (1, 2) is switched by means of accumulating the hydrogen flow treated by each of the adsorbers (1, 2) in a single adsorption process; a pre-adsorber (3) is connected in series to one of the adsorbers (1, 2) and is used for assisting in the desorption process; and in the desorption process, hydrogen in the pre-adsorber (3) or the adsorbers (1, 2) is circulated by means of a hydrogen self-circulation apparatus (4), and the desorption process is independent of the adsorption process. Since the adsorption process and the desorption process are independent of each other, after a raw gas enters the adsorbers (1, 2) and absorption is completed, all the raw gas is output; and in the desorption process, hydrogen in the pre-adsorber (3) or the adsorbers (1, 2) is circulated through the hydrogen self-circulation apparatus (4) to achieve hydrogen regeneration, so that the problem of incomplete desorption due to desorption interruption caused by the flow fluctuation of the raw hydrogen is solved, intermittent and fluctuating renewable energy can be matched to perform hydrogen production, and an operat
Absstract of: WO2025006628A2
The present disclosure is directed to a processing solution composition comprising a metal salt, an acid, a solvent, and a non-metal reductant. The present disclosure is also directed to a method of impregnating a porous material by covering or coating the porous material with a processing solution comprising a metal salt, an acid, a solvent, and a non-metal reductant.
Absstract of: KR20260114118A
0001a 2단의 이오노머 조성 구배를 갖는 일체형 전극-다공성 확산체 및 이를 제조하는 방법으로서, 구체적으로, PTL(porous transport layer) 상에 이오노머 함량이 낮은 전극층이 형성되고, 상기 이오노머 함량이 낮은 전극층 상에 이오노머 함량이 높은 전극층이 형성된 것을 특징으로 하는, 2단의 이오노머 조성 구배를 갖는 일체형 전극-다공성 확산체, 및 이를 제조하는 방법에 관한 것이다. 본 발명에 따르면, 전극층 하단에는 낮은 함량의 이오노머를 갖는 전극층을 스프레이 코팅하고, 그 위에 얇게 높은 함량의 이오노머를 갖는 전극층을 스프레이 코팅함으로써, 우수한 계면 접합력과 수전해 성능을 동시에 갖는 것을 장점을 한다. 이에 따라, 본 발명의 2단의 이오노머 조성 구배를 갖는 일체형 전극-다공성 확산체를 포함하는 수전해 애노드 전극은 더욱 향상된 내구성과 수전해 성능을 가질 수 있다.
Absstract of: GB2703251A
A process for the manufacture of an anode layer for a polymer electrolyte membrane (PEM) electrolyser (PEMWE) is described together with a CCM (catalyst coated membrane), an electrolyser and an ink for an anode layer. The process comprising the steps of: (i) forming a catalyst ink comprising an iridium- and / or ruthenium-containing OER catalyst, an ionomer, a solvent, and a cellulose compound; (ii) applying the catalyst ink to a substrate to form the anode layer; and (iii) drying the anode layer. The cellulose compound may comprise hydroxyalkylcelluose. The catalyst loading may be less than or equal to 1.2mg/cm2. None
Absstract of: EP4524100A1
0001 Process comprising the production of a hydrogen-containing synthesis gas by the conversion of a hydrocarbon feedstock, said process comprising : - providing a fuel stream of ammonia comprising an ammonia content, - decomposing at least a portion of said ammonia content into hydrogen and nitrogen, thereby obtaining an enhanced fuel, said portion of the ammonia content undergoing said decomposition being greater than 50% of the ammonia content of said fuel stream of ammonia, - combustion of said enhanced fuel in a fired equipment to provide a heat input to the process.
Absstract of: GB2633564A
A method of changing the electrolytic conversion rate within at least one electrolyser cell 10 stack 12 of an electrolyser system (figure 1, 20) is described. The stack 12 has a fluid inlet 114, fluid outlet 116 and a power control system 108. The power control system 108 is used to change the voltage, via a voltage interface 100 across the electrolyser cell stack 12, allowing the fluid outlet temperature 104 to change in response to the voltage change, setting an inlet temperature 106 to substantially match the new outlet temperature, and then allowing the voltage to revert to a substantially thermoneutral value. The electrolyser cell stack 12 is thus operating at a changed stack temperature and changed electrolytic conversion rate. A processor 110 and memory circuit 112 can also be provided for storing information such as preset current, voltage or power delivery changes. The current method may lead to a galvanostatic thermoneutral (GTN) strategy for electrolyzer stack control.
Absstract of: KR20260114100A
전이금속 전구체 및 염화물을 포함하는 전해질을 포함하는 전해액에 산화전극을 침지시켜 전기분해하는 단계를 포함하는 전이금속 수산화물의 제조방법으로서, 상기 전이금속 수산화물은 상기 전이금속 전구체가 상기 염화물 유래 염소 이온에 의해 산화된 것인, 제조방법을 제공한다. 특히, 상기 제조방법은 별도의 산화제를 사용하지 않아 공정이 간단함과 동시에 연속적인 전이금속 산화물 제조 및 수소생성 시스템을 제공할 수 있다.
Absstract of: EP4778883A1
Apparatus for producing hydrogen from a cracking reaction of ammonia, said apparatus comprising:- a cracker unit (1) configured for producing a cracked gas from ammonia,- an absorber (2) configured for removing unconverted ammonia from said cracked gas using an absorbent fluid, thereby producing an ammonia depleted gas containing hydrogen, nitrogen and vaporized absorbent fluid,- an adsorption unit (3) comprising at least one adsorber vessel (4), said adsorber vessel or each adsorber vessel comprising a feed end arranged for receiving said ammonia depleted gas, a product end downstream said feed end for discharging a purified hydrogen product from said adsorber vessel, and an adsorbent bed arranged between said feed end and said product end, the adsorbent bed comprising an upstream layer (5) of an adsorbent selectively adsorbent for the vaporized absorbent fluid contained in said ammonia depleted gas and a downstream layer (6) of an adsorbent selectively adsorbent for nitrogen.
Absstract of: KR20260114165A
본 발명은, 양성자 교환막 수전해의 촉매로 사용되는 이리듐 나노 덴드라이트 및 이의 제조방법에 관한 것으로, 본 발명에 따른 이리듐 나노 덴드라이트를 이용하여 우수한 산소 발생 반응 촉매 활성, 내구성 및 고전류 밀도 조건에서 향상된 물질전달 특성 및 감소된 물질전달 과전압을 갖는 양성자 교환막 수전해용 촉매를 제공할 수 있다.
Absstract of: CN122249590A
An electrode for an electrochemical cell designed for electrolysis is a support formed with an open-cell metal structure and provided with a coating that increases the specific surface area on an outward facing surface of a separator facing the electrochemical cell, or with a coating that increases the specific surface area and has improved catalytic activity. The coating is formed from a metal, particles of which are bonded to each other via a sintered bridge and/or an organic binder and to a surface of the perforated metal structure. The coating layer is formed with a plurality of regions between which an uncoated joint is arranged.
Absstract of: US12686931B1
0000 The present invention relates to modular packages of individual electrolyzer stack units arranged to overcome prior art limitations related to power supply costs, as-manufactured stack unit performance variation, operating stack unit performance variation, and operational reliability. The electrolyzer stack module comprises an even number of individual stack units wired in series-parallel and arranged to minimize variation between branches of series-connected stack pairs.
Absstract of: EP4495054A1
0001 Process for producing hydrogen from an ammonia feed stream, comprising the following steps : - non-catalytic partial oxidation of the ammonia feed stream with an oxidant gas, thereby producing steam from the partial oxidation, remaining amounts of ammonia not being oxidized; - endothermic cracking conversion of part of the remaining amounts of ammonia, thereby producing a cracked gas comprising hydrogen, nitrogen and some unconverted ammonia; - mixing of the cracked gas with the steam produced from the partial oxidation, thereby obtaining an effluent gas; - condensing of the steam produced from the partial oxidation, thereby removing at least part of the unconverted ammonia from the effluent gas by absorption.
Absstract of: CN122428316A
一种FeCoNi基稀土高熵电催化剂及其制备方法和应用,属于电解水制氢的新能源技术领域。本发明的FeCoNi高熵电催化剂包括Fe、Co、Ni,以及RE元素中的至少一种,各元素原子百分比at%为Fe:Co:Ni:RE=(5~35):(5~35):(5~35):(5~35),且各元素原子百分比at%的总和为100%,采用恒电位电沉积的方法制备而得。本发明所得FeCoNi基稀土高熵电催化剂形貌为树枝状结构,具有较大比表面积,提高了反应速率和电流密度,并且,该催化剂价格低廉,原材料来源广泛,环境友好,展现出良好的耐腐蚀性、稳定性以及优异的双功能电催化活性,具有较高的工业应用前景。
Absstract of: WO2026155716A2
The present invention relates to a system, which enables a reagent containing aluminum to react with water to generate hydrogen gas with high efficiency and in a controlled manner. In a preferred embodiment, the present invention relates to a system, wherein a reagent containing aluminum powder in the form of pellet (P) is enabled to react with water inside a reactor body (1), at a stoichiometric ratio at every stage of said reaction, wherein, owing to a vibration actuator (2) included in said system, it is made possible to remove the protective oxide layer that is naturally present on the surface of aluminum and accelerate the reaction kinetics, and wherein said system makes a highly efficient, continuous, sustainable, and controllable generation of hydrogen gas possible.
Absstract of: CN122428309A
0001 本申请公开了一种基于镍普鲁士蓝氧化还原电对电极的酸性分步电解水制氢装置及方法,属于电解水技术领域,该装置包括电解槽、酸性电解液、以及置于电解槽内的析氢催化电极、析氧催化电极和镍普鲁士蓝衍生物电极,方法包括产氧步骤和产氢步骤:产氧时,析氧催化电极作为阳极氧化水生成氧气,镍普鲁士蓝衍生物电极作为阴极被还原;产氢时,还原后的镍普鲁士蓝衍生物电极作为阳极被氧化,析氢催化电极作为阴极还原氢离子生成氢气,本发明利用镍普鲁士蓝衍生物作为氧化还原中间体,实现了酸性条件下水电解析氢与析氧过程在时间和空间上的解耦,无需使用质子交换膜,有效避免了氢氧混合,具有成本低、环境友好、操作灵活等优点。
Absstract of: CN122428324A
0001 本发明公开了一种自支撑异质结构复合材料及其制备方法与应用,复合材料,包括泡沫镍和附着其上的异质结构,异质结构为Ni<3>S<2>和1T相的MoS<2>形成的异质结构,异质结构的微观形貌为纳米棒状纤维,表面附着褶皱、卷曲的片层状包裹物。制备方法包括以下步骤:将泡沫镍与钼酸盐溶液、镍盐溶液进行水热反应,冷却至室温后取出泡沫镍,清洗后在惰性气体中升温到440~460℃并保温,获得自支撑NiMoO<4>@NF前驱体;将NiMoO<4>@NF前驱体、水合肼、硫代乙酰胺溶液进行溶剂热反应,通过水合肼辅助的硫化形成1T相的MoS<2>并形成异质结构材料,冷却至室温,取出产物,清洗烘干。本发明能实现高效全解水,合成方法简便易行。
Absstract of: CN122428287A
本发明涉及一种基于工业余热的中高温碱性电解海水制氢方法,属于电解水制氢技术领域。该方法包括:海水经粗滤后,依次通过阴极氢气换热器和阳极气体换热器进行两级预热;预热海水经辅助热源加热蒸发并过热,产生过热蒸汽;过热蒸汽进入电解槽阴极室,与熔融态碱在150~300℃条件下电解生成氢气和阳极气体;阴极产出的高温氢气返回预热海水,阳极产出的高温气体返回预热海水,实现余热回收。本发明采用过热蒸汽作为电解原料,从源头避免了海水氯离子腐蚀;电解温度提升至150~300℃,电流密度可达0.6~0.8A/cm2,产氢率较传统低温电解提高2倍以上,系统综合能效提升15~20%。
Absstract of: CN122428319A
0001 本申请公开了一种钐掺杂镍铁金属磷化物自支撑阳极及其制备方法、应用,属于电解水制氢阳极材料领域。所述钐掺杂镍铁金属磷化物自支撑阳极由钐掺杂镍铁金属磷化物原位生长在基底上。所述制备方法包括:S1、通过电化学沉积法在基底表面原位生长钐掺杂镍铁金属氢氧化物;S2、将钐掺杂镍铁金属氢氧化物进行磷化,得到所述钐掺杂镍铁金属磷化物自支撑阳极。该制备方法简单,反应周期短,制备成本可控。所制备电极对电解水制氢阳极反应具有优良的催化活性,同时具备良好的催化稳定性,具有规模应用的潜力和优势。
Absstract of: WO2026155715A2
The invention relates to a reagent developed for use in the generation of hydrogen gas, said reagent releasing the hydrogen gas in a controlled manner upon contact with water or a similar medium, said reagent being obtained via a mechano-chemical method, and said reagent comprising a mixture of aluminum, sodium stannate (Na2SnO3) and/or potassium stannate (K2SnO3), and an inorganic hydroxide.
Absstract of: CN122428334A
0001 本发明提供了一种金属有机框架异质结光电极材料及其制备方法和应用,涉及光电催化技术领域。该材料由导电衬底、BiVO<4>纳米棒及表面负载的Co
MOF构成,二者形成异质结结构。制备采用电化学沉积结合水热法,先在衬底上制得BiVO<4>纳米棒,再水热负载Co
MOF形成异质结。本发明有效提升电子输运效率、增加氧原子活性位点,抑制载流子复合,显著提高光电催化水分解性能,光电流密度远高于纯BiVO<4>电极,具备高效、稳定、工艺简便等优点,可用于光电水解制氢体系。
Absstract of: CN122428308A
0001 本发明公开了一种三维多孔空腔CrN‑c纳米笼电催化剂及其制备方法和应用,属于三维纳米材料合成和电解水催化技术领域。本发明通过溶剂热法制备氢氧化铬纳米笼作为前驱体,并在高温氮化过程中利用二氧化硅保护,而后刻蚀除去二氧化硅,制备三维多孔空腔CrN‑c纳米笼。本发明提供的三维多孔空腔CrN‑c纳米笼,由于多孔空腔的限域及不饱和配位边缘,不仅能在反应界面富集羟基反应物,还能促进氧气泡的形成与释放,并降低溶解氧产物的浓度,使得该三维多孔空腔CrN‑c纳米笼在阴离子交换膜电解水制氢阳极析氧反应中展示出优于商用氧化钌催化剂的催化活性和长期稳定性。
Absstract of: CN122428298A
0001 本发明公开了一种热电协同的离网型压缩空气储能制氢系统及控制方法,系统包括电解水制氢子系统、混合能源输入子系统、复合储能调频子系统和综合热管理耦合子系统。混合能源输入子系统汇集风电、光伏电能经高压直流母线供电制氢;复合储能调频子系统含电化学储能与压缩空气储能单元,接入母线平抑波动;综合热管理耦合子系统通过高温回路存储压缩储能压缩热并用于电解槽冷启动供热,低温回路回收电解槽运行余热用于压缩空气膨胀侧预热。本发明通过多能互补与热电协同控制,提升压缩空气储能发电效率,延缓电解槽性能衰减,消除冷却塔与启动加热能耗,显著提高离网系统整体能效与经济性。
Absstract of: CN122426711A
本发明公开了一种基于摩擦电材料—水摩擦电效应的氢气制备方法。本发明针对现有氢能制备技术碳排放高、成本高、系统复杂,以及现有摩擦电产氢技术依赖中间环节、材料类型单一的问题,提供了一种无需外部电能输入、无需催化剂修饰,利用金属与水的摩擦电效应直接产氢的方法,实现低成本、绿色、高效的氢气制备。
Absstract of: CN122428303A
本发明提供了一种超薄有序一体化膜电极构建方法及应用,涉及电解水制氢技术领域,膜电极含有:离子交换膜、超薄有序催化层、气液扩散层和阴极催化层;其中,所述超薄有序催化层构建于离子交换膜的底面,并与所述离子交换膜的底面形成连续致密的一体化界面;所述离子交换膜的顶面设置有阴极催化层,所述阴极催化层的表面设置有气液扩散层;超薄有序催化层的另一面具有有序排列的微结构单元,气液扩散层与微结构单元直接接触。
Absstract of: KR20260113438A
0001a 본 발명은 액상의 수소화합물을 연소보조재로 이용하는 증기 생산용 가열로에 관한 것으로, 하단의 버너로부터 공급되는 열과 내부 연소열을 축열실에서 축열하도록 하고, 상기 축열실의 축열에 의해 외부로부터 적당한 양이 지속적으로 공급되는 액상의 수소화합물을 분자 구조로 변환하면서 연소가 가능한 활성증기화 하여 공급하도록 하고, 상기의 축열실에서 공급되는 활성증기와 내부에서 증기를 변환한 활성증기를 연소실에서 연소시키도록 하고, 연소 시에 발생하는 열로 발전용 증기와 전기분해용 증기를 생산하도록 함으로써 최소의 연료비로 내부 연소용 증기와 발전용 증기 및 전기분해용 증기를 얻으면서 최대의 열량을 얻을 수 있도록 구성됨을 특징으로 한다.
Absstract of: CN122428291A
0001 本发明涉及电解水制氢技术领域,特别是涉及一种分布式制氢装置,包括筒体以及开设在筒体顶部的进料口,还包括:电极管,安装在筒体底部内壁;转动筒,转动安装在筒体内部;搅拌杆,由上到下环形阵列安装在转动筒外侧,数量设置多个;叶轮,活动安装在转动筒外侧;升降组件,设在转动筒上,用于带动叶轮上下移动。本发明提供的分布式制氢装置通过竖槽、升降块、连接杆的配合,带动叶轮随转动筒同步旋转的同时实现上下往复移动,形成旋流与竖向脉冲复合的流场,对筒体底部电解液进行全面、充分的扰动,彻底消除电解槽底部边角、转动部件下方的静态死水区。
Absstract of: CN122428286A
0001 本发明公开了一种海水制氢、提锂的方法及其应用,属于海水资源化技术领域,包括:构建三室电解池,利用阴极析氢产生的梯度碱微区,使海水中Mg<2+>和Li<+>在阴极表面原位生成锂镁层状双氢氧化物保护层,同步实现提锂与阻氯,再经弱酸脱锂、深度除镁后,将富锂液电化学氢化制得氢化锂,并实现副产物闭环循环。本发明采用上述的一种海水制氢、提锂的方法及其应用,通过制氢与提锂的深度协同,在阴极析氢反应原位形成的梯度碱微区中生成锂镁层状双氢氧化物保护层,该保护层同时实现高选择性提锂、高效物理阻隔氯离子及抗电极腐蚀的多重功能,并进一步将提锂产物直接电化学氢化制备高附加值氢化锂。
Absstract of: CN122426774A
0001 本发明提供了一种基于协同反应制备三氧化二铋‑氧化亚铜纳米复合物的方法:将铋酸钠、亚硫酸钠和氯化亚铜分散于去离子水中,得固液混合物;将固液混合物置于水热条件下,通过体系内铋酸钠与亚硫酸钠的氧化还原反应,以及氯化亚铜与反应原位生成的氢氧根离子的阴离子交换反应协同作用,一步原位制得Bi<2>O<3>‑Cu<2>O纳米复合物。本发明基于同一水热条件下氧化还原反应与阴离子交换反应的协同作用,无需外加碱源与模板剂,即可一步原位制备出高纯度Bi<2>O<3>‑Cu<2>O纳米复合物,且所制备的复合物能有效形成p‑n异质结,显著抑制光生载流子复合,提升材料的光催化活性与氧化还原能力,同时制备工艺简便、绿色经济,易于工业化生产。
Absstract of: CN122428321A
0001 本发明涉及纳米功能材料及电解水制氢技术领域,具体涉及一种La‑MoS<2>/Mo<2>CT
Absstract of: CN122428302A
0001 本发明提供了一种析氧反应催化剂电极、制备方法以及应用,涉及电催化纳米材料制备技术领域,本发明本发明在镍网表面获得硫化镍和磷化铁组合成的异质结构,作为析氧催化剂电极,应用在阴离子交换膜水电解槽中,提升电催化析氧反应的活化和反应稳定性,分别仅需226 mV 和258 mV的过电位便可以获得10 mA cm<‑2>和100 mAcm<‑2>的电流密度。催化剂电极FeP<4>‑Ni<3>S<2>/NF作为膜电极中的阳极,特别是在50
C低温环境下仅需1.81 V 的槽电压便可以获得1 A cm<‑2>的电流密度,而在30
C和40
C近室温仅需1.94 V 和 1.91 V 的槽电压便可以获得1 A cm<‑2>的电流密度。
Absstract of: CN122428305A
0001 本发明涉及固体氧化物电解池领域,具体涉及一种固体氧化物电解池的空气电极及制备方法,所述复合阳极材料包括离子导体相、电子导体相和催化剂相;其中,所述离子导体相为Gd<0.2>Ce<0.8>O<2>,所述电子导体相为钙钛矿氧化物为La<1‑y>Sr
Absstract of: CN122423745A
本发明公开一种双端控制型富氢杯,富氢杯包括杯盖、杯体和底座,其中底座安装在杯体底部,杯盖安装在杯体上方,制氢装置设置在底座内,杯盖内设置有杯盖控制系统,底座内设置有底座控制系统,制氢装置与底座控制系统电连接,杯盖控制系统与底座控制系统无线连接。本发明在杯盖和底座内分别设置有控制系统,两套控制系统通过无线方式进行通信,极大的增加了使用的方便性。同时,本发明内部设置有炫彩LED,使用时,可产生炫彩效果,增加产品的美感和科技感。另外,本发明在杯盖内设置有触摸显示屏,既方便显示又方便操作。
Absstract of: CN122428294A
本发明提供了基于复合陶瓷的光伏耦合电解制氢芯片,包括立式层叠设置的阳极集流基体、阳极扩散层、阳极催化层、质子交换膜、阴极催化层、阴极扩散层、阴极集流基体,阳极集流基体和阴极集流基体包括Ti3AlC2MAX相陶瓷芯层、纳米金刚石梯度复合层以及钝化层。本发明提出了上述光伏耦合电解制氢芯片的制备方法。还提出了一种光伏耦合电解制氢堆叠模组。本发明的阳极集流基体和阴极集流基体为一体化无粘接架构,大大增加了整体结构强度和界面结合力,较现有金属基电解槽寿命大幅度提升。形成了从内至外的全链路梯度传质体系与原位亲疏水一体化流场,可以充分引导水蒸气进入和冷凝水排放,维持了电解反应系统的畅通,大幅降低绿氢制备成本。
Absstract of: WO2025142261A1
In order to provide a water electrolysis device and an operation controlling method for the water electrolysis device which, when the operation is stopped, are capable of reducing energy consumption and suppressing deterioration of an electrolyte membrane due to hydrogen peroxide generated in a cathode-side hydrogen flow passage when the operation is stopped, this operation controlling method for a water electrolysis device having at least one water electrolysis cell which is divided into an anode-side oxygen flow passage 5 and a cathode-side hydrogen flow passage 6 by an electrolyte membrane, electrolyzes pure water supplied to the oxygen flow passage 5, and discharges hydrogen from the hydrogen flow passage 6 comprises: supplying pure water to the oxygen flow passage 5 during the operation of the water electrolysis device; when the operation of the water electrolysis device is stopped, stopping the supply of pure water to the oxygen flow passage 5, and supplying pure water to the hydrogen flow passage 6 for a prescribed period of time and discharging the same to the outside; and then stopping the supply of pure water to the hydrogen flow passage 6.
Absstract of: WO2025141005A1
The invention relates to a catalyst for the decomposition of ammonia into hydrogen and nitrogen, wherein the catalyst comprises at least ruthenium, mesoporous cerium oxide and at least one oxide selected from among cobalt, nickel and iron oxides, preferably nickel oxide, and to a method for producing hydrogen from ammonia comprising the following steps in this order: activating at least one catalyst according to the invention at a temperature ranging from 300°C to 600°C under a stream of a reducing gas; bringing the activated catalyst into contact with a gas to be treated comprising ammonia at a temperature ranging from 200°C to 800°C, and at a pressure ranging from atmospheric pressure to 100 bar.
Absstract of: WO2025135740A1
The present invention relates to a device for producing hydrogen from ammonia for a ship. According to the present invention, high-pressure hydrogen can be produced by using liquefied ammonia for a ship, and hydrogen can be economically produced by utilizing unconverted ammonia discharged from a decomposition reactor and off-gas discharged from a pressure swing adsorption device as a heat source for ammonia decomposition through a heat exchange network of the ship.
Absstract of: WO2025131626A1
The invention relates to an electrolysis assembly (10) comprising a stack assembly (16). The stack assembly (16) is equipped with precisely one reactant gas manifold structure (66) in order to provide reactant gas to the electrolysis cells (18) and precisely one product gas manifold structure (68) in order to discharge product gas from the electrolysis cells (18). The stack assembly (16) has a reactant gas opening for introducing reactant gas into the reactant gas manifold structure (66) and a product gas opening for discharging product gas out of the product gas manifold structure (68). The reactant gas manifold structure (66) and the product gas manifold structure (68) are formed within the stack assembly (16), in each case by means of manifold openings introduced into the interconnectors, wherein between the membrane electrode assembly and the interconnector of at least some of the electrolysis cells is a reactant gas line structure designed to conduct reactant gas out of the reactant gas manifold structure along the hydrogen side of the membrane electrode assemblies and to the product gas manifold structure, and at least some of the membrane electrode assemblies have an oxygen-permeable structure on the oxygen side, said oxygen-permeable structure being positioned and designed such that oxygen released on the oxygen side of the membrane electrode assembly can be discharged into the interior of the housing (12).
Absstract of: CN122424618A
本发明涉及水电解制氢技术领域,公开了一种碱水电解制氢用气液分离系统,包括电解槽、氢碱气液分离器、氧碱气液分离器、第一循环泵、碱液冷却器、过滤器、碱液流量计、至少一个碱液缓冲罐、第二循环泵以及多个管道组件,所述电解槽的出液口通过管道组件分别与所述氢碱气液分离器的入口和所述氧碱气液分离器的入口连通;氢碱气液分离器的出液口和氧碱气液分离器的出液口分别通过管道组件与第一循环泵的入口连通。将气液分离器中的碱液泄放至碱液缓冲罐,利用压力下降使微小气泡迅速膨胀并逸出,配合超声波释放器或超声装置的超声聚并作用,降低循环回电解槽的碱液中的含气率,减小电解槽内部电阻,降低电解制氢能耗,同时提升氢气和氧气的纯度。
Absstract of: CN122428306A
0001 本发明提供了一种复合金属纳米催化剂及其制备方法和电解水析氢方法,所述复合金属纳米催化剂包括柱状Sm掺杂MoN载体和负载于所述柱状的Sm掺杂MoN载体上的金属纳米颗粒;所述复合金属纳米催化剂中,Sm分散于MoN的晶格中,所述复合金属纳米催化剂呈由纳米柱组成的三维纳米花状结构。本发明通过在MoN载体中原子级掺杂Sm和d‑f轨道杂化,精确调控催化剂的电子结构,同时提升其析氢活性、反应动力学及在苛刻高盐环境中的长期稳定性,所述复合金属纳米催化剂在维持高活性的同时,又具有良好的抗氯离子毒化能力,在电解海水制氢中展现了良好的析氢活性和稳定性。
Absstract of: CN122428341A
0001 本发明涉及电解水制氢技术领域,尤其涉及一种超纯水制氢过程中水质动态调控方法,包括:在质子交换膜两侧对称设置电压监测点,同步采集阴阳极电压信号与关键位置电导率,分别建立水质电化学镜像基线与水质变化镜像基线,通过计算两个镜像的偏离度判定水质异常,结合电化学镜像偏离方向与水质变化镜像偏离的变化特征,精准区分阳极侧金属离子污染、阴极侧结垢离子累积、质子交换膜异常及进水突发污染四类异常并定位来源,针对性执行单端强化、同步强化或保护策略。本发明实现了水质异常的早期识别与靶向调控,可有效降低水处理能耗,延长电解槽运行寿命。
Absstract of: CN122428288A
本发明提供一种基于阳离子界面效应调控碱性电解水析氢气泡行为的电解质优化方法及其应用,属于电化学能源转化技术领域。通过采用本发明的方法,在不改变电解装置硬件结构的前提下,通过科学选择和配置电解质中的阳离子种类,系统调控析氢电极表面气泡的脱附频率、聚并概率和覆盖面积,从而降低气泡诱导的传质阻力和极化过电位,显著提升宏观析氢电流密度和能量利用效率。该方法通过微电极特征化参数为阳离子筛选提供了量化依据,通过宏观电解验证确保了优化结果的工程可靠性,为碱性电解水制氢系统提供了一种科学化、可复现的电解质优化途径。
Absstract of: CN122437076A
The invention discloses a flexible control method of a green ammonia synthesis system and a related device, and relates to the field of new energy chemical coupling, and the method comprises the steps: obtaining the energy storage electric quantity of an energy storage device and the hydrogen storage pressure of a hydrogen storage device; and based on the state combination of the energy storage electric quantity and the hydrogen storage pressure, generating a load regulation instruction aiming at the hydrogen production end and the ammonia synthesis end. According to the invention, closed-loop feedback adjustment is carried out by using real-time state combination of double buffering links of electric quantity buffering and material buffering, so that the problem of system oscillation caused by prediction deviation is fundamentally solved, and the robustness and stability of cooperative control of the whole chain from a power generation end, a hydrogen production end to a synthesis ammonia end are remarkably improved.
Absstract of: CN122428315A
0001 本申请提供一种雷尼镍电极及其制备方法和应用,涉及电解水制氢领域。将表面设置雷尼镍催化层的电极基体进行热处理,得到热处理后电极;将碱液、添加剂和热处理后电极进行混合、活化处理、洗涤、干燥,得到雷尼镍电极;热处理中的氧气的体积浓度依次梯度降低直至为低氧气氛或无氧气氛,温度依次梯度升高。通过在碱液活化前引入可控梯度热处理过程,促进Ni与Al之间的充分扩散形成特定含量稳定的Ni3Al相,Ni3Al相中的Ni‑Al协同结构可在一定程度上调控表面电子结构,改善电极表面的反应活性位点分布,同时提高析氢和析氧性能,另外,在保证多孔电极骨架结构完整性的同时,提高了合金化程度。
Absstract of: CN122426713A
本发明涉及新型纳米材料及控制合成领域,公开了一种高熵氧化物空心纳米球及其制备方法与应用,将F127嵌段共聚物、均三甲苯、聚乙烯吡咯烷酮、去离子水混合得到F127混合溶液;金属M盐溶于去离子水,得到金属盐溶液;金属盐溶液滴加至F127混合溶液中获得前驱体混合溶液;前驱体混合溶液作为内相,正己烷作为外相,通过三通阀结合注射泵装置分散为微液滴,液滴迅速凝固为微球;收集所得微球除去正己烷后冷冻干燥;将前驱体微球在空气气氛中退火,即得到空心纳米球结构的高熵氧化物。本发明通过微流控技术与模板法相结合,设计并合成了一种含高价态金属组分的高熵尖晶石氧化物纳米空心球,其性能优异;本发明的方法形貌可控、组分可控。
Absstract of: CN122428323A
0001 本发明涉及一种过渡金属硫化物异质结构纳米材料及其制备方法与电催化碱性析氢中的应用。本发明中制备的纳米材料为NiS<2>与MoS<2>纳米颗粒异质结电催化剂。异质界面处能优化电子结构,产生强烈的电子相互作用,因此降低水分解的能量势垒,有利于改善碱性HER性能。因此NiS<2>/MoS<2>催化剂材料具有能媲美商业铂碳的碱性析氢性能,58mV的过电位能实现10mAcm<‑2>。制备方法为:(1)六水合硝酸镍与2氨基对苯二甲酸在DMF溶剂中100℃水热反应48h,离心得到Ni‑BDC前驱体;(2)Ni‑BDC前驱体、二水钼酸钠与硫代乙酰胺分散在乙醇中,180℃水热24h,离心后得到目标催化剂。本发明的制备流程便捷,原料成本低廉,所制得的催化剂兼具优异的电催化活性与长效稳定性,完全满足工业绿氢制备的严苛要求。
Absstract of: KR20260113439A
0001a 본 발명은 액상의 수소화합물을 연소보조재로 이용하는 다단 연소식 증기 생산용 가열로에 관한 것으로, 하부의 다중 가열부에서 연소실의 연료와 공기 및 착화열의 연소조건이 활성화되도록 한 상태에서 상부의 가열부에서 완전 연소로 연소되는 중에 효과적으로 증기를 생산할 수 있도록 하되, 열을 이용하여 탄소 성분이 포함되지 않은 액상의 수소화합물에 함유된 각종 불순물을 구성하는 분자 간의 해리 엔탈피가 늘어나도록 함으로써 활성가스를 얻도록 하고, 상기의 연소실을 수직으로 길게 형성하면서 일정한 간격으로 형성한 적어도 하나 이상의 재발화층에서 직접 공급되는 활성증기를 연소시키도록 하여 연소 시에 발생하는 열로 발전용 증기와 전기분해용 증기를 생산하도록 하고, 활성증기를 연소시키는 중에 생성되는 증기로 발전기용 터빈을 가동하는 동시에 전기분해장치에서 산소와 수소를 저비용으로 생산하므로 에너지를 절감시킬 수 있도록 구성됨을 특징으로 한다.
Absstract of: CN122428307A
本发明公开了一种TiO2负载型IrRu基酸性电解水析氧电催化剂及其制备方法和应用,属于电解水制氢材料技术领域。本发明通过软模板法预制备初级TiO2,经盐模板辅助球磨、氩气高温煅烧、洗涤除盐得到高结晶度抗烧结改性TiO2载体;再将Ir、Ru金属盐经除氧、原位共还原负载到载体上,低温煅烧得到IrRuOx/TiO2催化剂。本发明所制备的IrRuOx/TiO2催化剂在0.5M H2SO4溶液中达到10 mA cm‑2电流密度的过电位仅为204 mV,组装为质子交换膜电解水电极后,可在1 A cm‑2电流密度下稳定运行超过540 h,兼具优异的催化活性与长期稳定性,适合酸性电解水制氢的实际应用。
Absstract of: CN122428297A
The invention relates to the technical field of plateau movable oxygen cabins, and discloses a plateau oxyhydrogen thermoelectric movable oxygen cabin system based on data driving, a photovoltaic module is used for converting solar energy into first electric energy, and the first electric energy is stored in an electricity storage module; the power storage module is used for supplying power to the plateau mobile oxygen cabin and the electrolysis module by using first electric energy; the electrolysis module is used for performing in-situ electrolysis on purified water by using first electric energy; the fuel cell module is used for calling hydrogen in the hydrogen storage bottle and oxygen in the oxygen storage bottle to react to generate second electric energy under the condition that the residual electric quantity of the electricity storage module is lower than a preset threshold value, so as to supply power to the plateau mobile oxygen cabin; and the intelligent control and energy management module is used for optimizing the execution process of the system. According to the technical scheme, the problems that a traditional hydrogen power plateau movable oxygen cabin is low in efficiency and high in cost in a high-cold and high-altitude area, cannot adapt to a low-oxygen environment and cannot meet the sustainable energy requirement can be solved.
Absstract of: CN122428322A
本发明公开了一种碳酸根与钙共修饰的硫化镍催化剂及其制备方法和应用,属于电解水制氢技术领域。本发明将“阴离子修饰策略”与“杂原子掺杂工程”相结合,采用水热法成功制备出碳酸根与钙共修饰的硫化镍催化剂。其中,Ca的引入能够增强碳酸根离子的吸附,减少由于碳酸根离子脱附而引起的催化活性降低。将碳酸根离子引入到硫化镍催化剂中,一方面能够促进高活性相NiOOH的生成,提高其催化活性;另一方面,碳酸根离子与Ca相互作用,能够优先吸附在催化剂表面,使得催化剂的结构更加稳定。本发明制备的硫化镍催化剂在400mA/cm2电流密度下,能够稳定运行550h。此外,该本发明的制备方法简单、生产成本低,有利于进行大规模产业化生产。
Absstract of: CN122428335A
0001 本发明公开了一种AEM电解槽性能测试方法,涉及AEM电解槽性能测试技术领域,包括如下步骤:在利用恒定电流密度对AEM电解槽进行活化时,采集AEM电解槽的工作电压,得到活化电压数据;根据历史的活化电压数据获取电压稳定阈值,并根据当前的活化电压数据进行变化预测,得到电压预测数据;根据当前的活化电压数据,并基于电压预测数据以及电压稳定阈值,动态调整当前的AEM电解槽的活化时长;对完成活化的AEM电解槽进行极化曲线性能测试,获取对应的极化曲线;本发明用于解决现有AEM电解槽性能测试技术在测试AEM电解槽的极化曲线时,在活化过程中设置固定的活化时长,容易导致活化不充分或过度活化,影响极化曲线测试的准确性的问题。
Absstract of: CN122428325A
0001 本发明公开了一种基于缺陷调控的Ru修饰的NiFe基层状双氢氧化物及其制备方法与应用,属于电催化技术领域,本发明提供了一种基于缺陷调控的Ru修饰的NiFe基层状双氢氧化物的制备方法,用于解决现有技术中NiFe‑LDH材料导电性差,导电性能改善的改性NiFe‑LDH材料制备工艺复杂的技术问题。一种基于缺陷调控的Ru修饰的NiFe基层状双氢氧化物的制备方法,包括以下步骤:镍源、铁源和牺牲元素加入去离子水中,形成前驱体溶液;预处理后的泡沫基底电位沉积前驱体溶液,碱液刻蚀去除牺牲元素,再采用循环伏安法沉积Ru,得到产物。本发明制备的NiFe基层状双氢氧化物具有催化活性好、制备工艺简化的优点。
Absstract of: CN122428300A
0001 本发明公开了一种一体式双梯度非贵金属析氢阴极,包括三维多孔材料,所述三维多孔材料的表面设置有活性催化涂层;所述一体式双梯度非贵金属析氢阴极靠近质子交换膜的一侧为亲水区域,而靠近双极板的一侧为疏水区域,且所述疏水区的孔径由质子交换膜侧向双极板侧方向呈逐渐扩大的锥形。本发明为三维导电网络骨架的一体化结构,同时通过将在电极的两侧设置不同的孔径分布和亲/疏水性,有效缓解了电极局部压力波动,从而兼顾高催化活性、低接触电阻与长效运行稳定性;其应用于质子交换膜电解水制氢系统时,在大电流密度的电解工况下,使其在大电流密度下的极化性能逼近铂基电极,为实现廉价、高效的PEMWE工业化应用提供关键的技术方案。
Absstract of: CN122424838A
本发明公开了一种Co‑ZnIn2S4光催化剂及其制备方法和应用,属于光催化材料技术领域。所述Co‑ZnIn2S4光催化剂由Co和ZnIn2S4组成,Co与ZnIn2S4基体的质量比为2.0~8.0∶100;Co掺杂至ZnIn2S4晶格中,在光催化剂中形成特异的Co‑OER活性位点和富电子的S‑HER活性位点,实现HER与OER位点空间隔离及·H/·OH动态平衡调控。制法为:首先以氯化锌、四水合氯化铟和硫代乙酰胺为原料,通过溶剂热法合成微球状的ZnIn2S4;随后以CoCl2为原料,添加分散剂和结构调节剂,采用水浴搅拌法将Co离子掺杂至ZnIn2S4晶格中,制得Co‑ZnIn2S4光催化剂微球。本发明在ZnIn2S4中通过Co掺杂构建了空间分离的Co‑OER与S‑HER特异性活性中心,实现了对·H/·OH中间体覆盖度的主动调控与动态平衡,所得Co‑ZnIn2S4光催化剂在纯水中无需牺牲剂即表现出优异的光催化全分解水活性和循环稳定性。
Absstract of: CN122428311A
本发明公开了一种碱式硫酸盐负载Pt复合材料及其制备方法和在海水电催化析氢中的应用,属于电催化材料的制备技术领域。本发明要解决现有催化剂的催化活性低,同时贵金属成本高的技术问题。方法包括:1)制备碱式硫酸镍载体;2)制备Pt源溶液;3)浸泡;4)电化学处理得到碱式硫酸盐负载Pt复合材料。本发明制备得到的碱式硫酸盐负载Pt复合电极材料在碱性条件和海水电催化析氢方面均表现出优越的催化性能,具有优异的电化学性能和稳定性,在电催化分解水电极材料技术领域将拥有广泛的应用前景。本发明方法制备的碱式硫酸盐负载Pt复合材料电解水催化剂用于电催化材料技术领域,改善氢能制备与海水利用问题。
Absstract of: CN122428314A
本发明公开了一种电解制氢用铂铜锡固溶体合金阴极催化剂及其制备方法。所述制备方法包括:配置含铂源、铜源、锡源的混合水溶液,加入碳载体并超声分散均匀;在冰水浴条件下,逐滴滴加强还原剂水溶液,通过液相共还原反应生成铂铜锡固溶体合金颗粒;经洗涤、烘干即得所述催化剂。本发明通过液相共还原法将铂、铜、锡以特定原子比例形成固溶体合金,利用铜的氢溢流效应与锡对氢氧根脱附的协同促进作用,构筑梯度电子结构活性中心。所得催化剂在100 mV过电位下的单位铂质量活性达到225.24 mA/mgPt,较商业化40%Pt/C提升约62.5%,在碱性电解水环境中连续运行600小时性能衰减低于5%,在实质性降低铂绝对用量的同时实现了超高活性与工业级耐久性。
Absstract of: CN122428333A
本发明属于电解水技术领域,特别涉及一种多维分级异质结构双功能催化剂及其制备方法。本发明公开了一种多维分级异质结构双功能催化剂的制备方法,包括以下步骤:将钴源、镍源、硫源和有机配体共同溶解于混合溶剂中,得混合液;将混合液与导电基底共同转移至反应釜中,进行溶剂热反应;于惰性气体保护下,将所得的Ni3S2@MOF‑74前体与磷源于250±30℃进行磷化热处理1.5~2.5h;最终获得作为多维分级异质结构双功能催化剂的Ni3S2‑Co(PO3)2@MOF‑74。该催化剂在1.0 M KOH电解液中表现出优异HER‑OER催化活性和电化学稳定性。
Absstract of: CN122428312A
0001 本发明涉及电催化材料技术领域,具体涉及一种高熵氢氧化物担载金属双原子催化剂的制备方法及其应用,将自支撑基底材料置于含有氯化钠和金属源的溶液中,通过室温氯刻蚀法生成高熵氢氧化物FeCoNiMnCr纳米片,将生长有FeCoNiMnCr纳米片的自支撑基底材料置于含金属双原子前驱体的溶液中,通过水热法将金属双原子担载到高熵氢氧化物纳米片上得到高熵氢氧化物纳米片担载的金属双原子催化剂;本发明实现金属双原子‑基底强耦合,制得的催化剂析氢催化活性提升,作为自支撑电极在碱性析氢反应中展示出10mA/cm<2>@0.018V,全解水电解槽中展现1A/cm@1.82V极佳性能,突破传统单原子催化剂与基底负载稳定性限制。
Absstract of: CN122428299A
0001 本发明公开了一种亲水亲气交替条纹电极及其制备方法,属于电化学能源转换器件技术领域;所述方法将亲水性物质前驱体、亲气性物质前驱体以及可溶性过渡金属盐混合,加入溶剂和分散剂,形成均匀的复合浆料;将所述复合浆料涂覆在导电基底表面,随后进行预干燥,得到覆有固态复合前驱体膜的电极;采用飞秒激光系统,对所述覆有固态复合前驱体膜的电极进行阵列式聚焦扫描,扫描形成条纹区域,完成激光选择性条纹化处理;对激光选择性条纹化处理后的电极进行水浸处理,得到亲水亲气交替条纹电极。本发明通过超快激光加工技术在电极表面创造“功能条纹”,实现反应区与脱附区的空间解耦与协同。
Absstract of: CN122428330A
0001 本发明涉及一种过渡金属基析氧催化剂及其制备方法和应用。过渡金属基析氧催化剂包括离子液体功能化碳纳米管和负载于离子液体功能化碳纳米管表面的过渡金属化合物。本发明通过在碳纳米管表面修饰离子液体,有利于金属离子负载到离子液体功能化碳纳米管表面,构建得到的过渡金属基析氧催化剂中,过渡金属化合物可高效活化和解离反应物分子,离子液体功能化碳纳米管可调节过渡金属化合物的电子结构并调节界面反应局部环境,两者协同作用使得催化活性和稳定性大幅增强,同时解决了过渡金属化合物作为催化剂时动力学受限和长期稳定性不足的难题,为非贵金属基催化剂的设计提供了新策略。
Absstract of: CN122425205A
0001 本发明提供了热诱导自组装矿物基化学产氢材料及其制备方法与应用,属于化学制氢技术领域,包括将铁橄榄石颗粒与可还原性金属盐的水溶液混合,构建反应体系;对所述反应体系施加温和加热条件,使所述可还原性金属盐中的金属离子在所述矿物颗粒表面原位还原并自组装生长,形成由所述矿物颗粒内核与金属单质外壳构成的核壳结构复合颗粒;其中,所述复合颗粒在加热条件下,其内核中的二价铁离子被氧化并释放电子,电子通过固相传导至外壳,在外壳表面催化水分子还原产生氢气;整个过程无需外部电源供电。本发明中原位形成的核壳结构产氢速率较传统反应数量级提升,反应温度大幅降低,为化学制氢提供了高效率和无需外部电能输入的新途径。
Absstract of: CN122429342A
本发明公开了火箭投送式应急照明装置,包括采用二级构型火箭,二级构型火箭包括上面级和助推级,上面级包括头锥,头锥连接上面级箭体,上面级箭体连接助推级箭体;头锥内部设置照明模块,上面级箭体内部设置空中姿态校正模块、航电模块、制氢机构、氢气球、上面级降落伞,尾端设置上面级发动机、上面级尾翼总成;助推级箭体内部设置助推级降落伞、助推级发动机,尾部设置助推级尾翼总成。本发明还公开了火箭投送式应急照明装置的部署方法,解决了现有应急照明装置存在部署慢、携带不便、地形适应性差的问题。
Absstract of: CN122428318A
本发明公开一种复合电催化材料及其制备方法和应用,属于电催化材料技术领域。该复合电催化材料,包括基底、镍铁合金和钌纳米颗粒;所述基底为碳纤维/碳纳米管复合薄膜,所述镍铁合金嵌入所述基底中,所述钌纳米颗粒负载于所述基底上。本发明还提出一种复合电催化材料的制备方法,包括以下步骤:S1、将可溶性镍盐、可溶性铁盐、尿素和碳纤维/碳纳米管复合薄膜分散于醇溶液中,其后,进行水热反应,得到第一中间体;S2、对所述第一中间体进行碳化处理,得到第二中间体;S3、将所述第二中间体和可溶性钌盐在还原剂作用下进行还原反应,得到所述复合电催化材料。本发明实现了在减少贵金属用量的前提下提高了催化剂的催化制氢性能。
Absstract of: CN122437040A
0001 本发明提供一种风光储制氢系统的优化配置方法及系统,涉及风光储制氢技术领域。本发明构建电‑热耦合模型并引入动态自适应调整机制,基于电解槽实时热状态动态标定静态与动态输入功率区间,克服了传统静态功率限值设定过于保守或存在安全隐患的缺陷。同时,从风光联合出力预测曲线中提取功率变化率、波动频次及连续低出力时长等波动特征参数,并以此为约束计算储能的最低能量与最大功率容量,使储能配置能够精准匹配风光波动规律。在此基础上,通过多目标优化算法迭代求解储能最佳容量与协同控制策略,使制氢总量最大化与性能衰减成本最小化形成正向耦合,显著提升了系统的全生命周期运行效率与设备耐久性。
Absstract of: CN122424818A
0001 本发明涉及一种硼氢化钠水解制氢的催化剂,尤其是一种CoB/NF硼氢化钠水解催化剂、制备方法及应用。该制备方法包括以下步骤:使用六水合氯化钴与硼氢化钠反应制取CoB粉末催化剂;将所述CoB粉末催化剂与粘结剂PVDF混合,并添加NMP制成浆料;将所述浆料涂覆在泡沫镍支撑基底上,然后通过退火处理以去除NMP溶剂,得到CoB/NF复合材料。该制备方法操作简单,易于规模化生产,所制备的催化剂具有优异的稳定的,催化活性高,制备成本较低,在硼氢化钠快速水解制氢领域具有良好的应用前景。
Absstract of: WO2025115918A1
This electrode catalyst layer comprises: a catalyst; a polymeric electrolyte that has proton conductivity or anion conductivity; and a polymeric fibrous material that has a functional group capable of forming a hydrogen bond.
Absstract of: EP4567153A1
0001 A method of electrolysing water, the method comprising: - providing an electrolyser comprising an anode; a cathode and optionally a separator; - contacting the cathode and/or the anode with an aqueous alkaline solution comprising water; and - electrolysing the water using a potential difference from the anode to the cathode, wherein at least one of the cathode and the separator comprises a substrate and a coating, wherein the coating comprises 9.5 to 35 wt% chromium; 10 to 75 wt% cobalt; and 10 to 60 wt% one or more further transition metals and/or one or more non-metallic elements selected from C, P, N and B, and wherein the coating catalyses hydrogen evolution at the cathode.
Absstract of: CN122407326A
The invention relates to the technical field of power generation and energy storage, and discloses an energy storage and energy conversion power generation system based on hydrogen-oxygen mixed gas combustion chain reaction, which comprises a power supply module, an electrolysis module, a heat management module, a torque acquisition module, a modulation module, a combustion module, a heat exchange module, a turbine module, a power generator module and an energy distribution module. The power module supplies power to the electrolysis module to generate hydrogen-oxygen mixed gas, and the hydrogen-oxygen mixed gas is adjusted by the modulation module and then enters the combustion module into which a solid catalyst is added for reaction. Heat generated by combustion heats a carbon dioxide working medium through the heat exchange module, pushes the turbine module to rotate and drives the generator module to generate electricity. According to the system, electrolysis waste heat is recycled through the heat management module, stable output is maintained through linkage of the torque collection and modulation module, electric energy is fed back in a closed loop through the energy distribution module when the system is separated from an external power source, and self-sustaining operation of the system is achieved. The energy utilization rate and the operation stability of the system are improved.
Absstract of: CN122399493A
0001 本发明提供了一种电解水生产成品氢气的纯化装置以及控制方法,通过对电解水生产成品氢气的纯化装置以及控制方法进行改进,从而有效避免了能源的浪费。具体包括沿气体流通方向依次布设并连通的增压部件和第一气液分离器;增压部件具有低压入口和高压出口,高压出口与第一气液分离器的进气口相连通;还包括若干个干燥器,定义部分干燥器为第一组干燥器,部分干燥器为第二组干燥器,第一气液分离器的出气口与第二组干燥器的进气口相连通,第二组干燥器的出气口向纯化装置的外部输出成品气的同时还与第一组干燥器的进气口相连通以向其输出成品气;同时,第一组干燥器的出气口连通于增压部件的低压入口,高压出口与第一气液分离器的进气口相连通。
Absstract of: CN122406287A
本发明公开了一种Co‑B@Co(OH)₂‑Ru/NF电极及其制备方法与应用,属于新能源材料技术领域。该电极材料通过原位生长于泡沫镍(NF)基底上,形成纳米球‑纳米片复合结构,其中球形纳米颗粒均匀沉积在二维纳米片上。本发明采用温和的硼还原策略,引入硼元素构建稳固的Co‑B键,调控了Co活性中心的局部电子环境,使d带中心显著下移,从而增强了结构稳定性。该材料兼具优异的析氢反应(HER)和析氧反应(OER)活性与稳定性。实验结果表明,该电极在10 mA cm⁻²电流密度下可实现超过400小时的长期稳定性,组装的全解水电解槽仅需1.40 V的低电压即可驱动,且能稳定运行超过240小时。本发明制备方法简单,无需涂覆粘结剂,为高效稳定的全解水催化剂提供了新思路。
Absstract of: CN122406259A
0001 本发明公开了一种阴离子交换膜电解水膜电极及其高效快速活化方法,属于电解水制氢技术领域。所述方法包括:将阳极、阴极与阴离子交换膜组装成单电池并通入电解液;施加初始电压启动电解池;以预设电压步长逐级升高电压,在每个电压阶梯下保持预设时间,直至达到目标电压,形成一个活化循环;重复进行多个活化循环,并在活化过程中实时监测电流变化,计算相邻两次活化循环中在相同电压阶梯下的电流变化率,当所述电流变化率小于预设阈值时停止活化。本发明通过阶梯式循环升压结合电流变化率判据,实现膜电极的快速、可控活化,显著缩短活化时间,避免电化学冲击,提高膜电极性能稳定性和一致性。
Absstract of: CN122406245A
The invention discloses a method for preparing furfuryl alcohol and furoic acid through paired electrocatalytic conversion of furfural, which comprises the following steps: taking a nickel-doped copper-based electrocatalyst as an anode material and a cathode material at the same time, carrying out paired electrocatalytic reaction at normal temperature and normal pressure, selectively oxidizing furfural into furoic acid by an anode and generating high-purity hydrogen, the cathode selectively hydrogenates furfural to furfuryl alcohol. According to the method, the product selectivity is high, the Faraday efficiency of furoic acid can reach 96% or above, the Faraday efficiency of furfuryl alcohol can reach 98% or above, the performance is not obviously attenuated after multiple cycles, meanwhile, the energy utilization efficiency is improved through cathode and anode reactions, the catalyst does not contain precious metal, preparation is easy and convenient, remarkable economical efficiency and environment friendliness are achieved, and the method is suitable for industrial production. Good industrial application prospects are realized.
Absstract of: CN122406268A
本发明公开了一种钴/碳化钼自支撑电解水制氢电催化剂的制备方法及应用。本发明提供的钴/碳化钼自支撑电解水制氢电催化剂的制备方法,包括如下步骤:将含有钴元素、钼元素的前驱体与泡沫镍混合,水热反应,得到负载前驱体的泡沫镍;将负载前驱体的泡沫镍先低温处理再高温碳化,得到泡沫镍负载的Co/Mo2C催化剂。本发明通过特定工艺及条件制备出具有高性能、良好稳定性、较低过电位驱动工业级电流密度下电解水产氢的催化剂;且制备过程不涉及CH4/H2还原性气体,更安全、稳定。
Absstract of: CN122406277A
0001 本发明涉及电解析氧的技术领域,公开了一种基于含氮有机配体螯合的NiFeCr析氧电极制备方法及应用,包括如下步骤:(1)将镍源、铁源、铬源与含氮有机配体溶解于有机溶剂中,得到前驱体溶液;(2)将预处理后的导电基底浸入前驱体溶液中,经溶剂热反应,得到NiFeCr‑MOF前驱体电极;(3)将NiFeCr‑MOF前驱体电极置于碱性电解液中进行电化学活化,得到N掺杂的NiFeCr析氧电极。本发明利用含氮有机配体配位螯合作用固定铬元素,并在电化学激活过程中原位转化为N掺杂的NiFeCr‑OOH析氧活性相,抑制活性组分溶出并增强抗氯腐蚀能力,从而在海水电解析氧反应中表现出优异的催化活性和长期运行稳定性。
Absstract of: CN122406293A
本发明属于电解水制氢和催化技术领域,公开了一种镍钼复合电极材料及其制备方法与应用,包括:将镍盐、钼盐和有机配体分别溶解于去离子水中,得到均一溶液;将均一溶液进行混合,搅拌,反应生成沉淀,得到NiMo‑MOF前驱体浆液;将NiMo‑MOF前驱体浆液进行离心分离,洗涤,干燥,得到NiMo‑MOF粉末;将NiMo‑MOF粉末在空气气氛下进行煅烧处理,冷却后得到NiMoO4粉体材料;将NiMoO4粉体材料与导电碳混合,在氢/氩混合气氛中进行退火处理,冷却后得到镍钼复合电极材料。本发明所获得的NiMo基MOF衍生催化材料在结构均一性、活性位点利用率及电化学稳定性方面表现优异。
Absstract of: CN122406274A
本发明涉及一种微米球状NiS2催化剂、其制备方法及应用,属于电催化材料及其制备技术领域。本发明所述微米球状NiS2催化剂的制备方法:提供氯化胆碱与乙二醇的混合物;将所述混合物进行第一次加热得到低共熔溶剂DESs;将DESs、升华硫和镍源混合,第二次加热形成均匀的溶液体系;将所得溶液体系进行溶剂热合成反应,得到所述微米球状NiS2催化剂。本发明所述的制备方法具有操作简便、成本低廉的优势,且制得的NiS2催化剂具有规整的形态和良好的结晶性。
Absstract of: CN122406291A
本发明公开了一种掺杂碱金属离子的WO3纳米棒阵列光电极及其制备方法。该方法采用一步融碱刻蚀氧化法,在金属钨基底上原位生长出高结晶度、高取向的WO3纳米棒阵列光电极。本发明通过引入碱金属氢氧化物,降低了从金属钨到氧化钨的转变温度,并且通过一步融碱刻蚀氧化法,在金属W片上制备碱金属掺杂的WO3纳米棒阵列,通过调控WO3的能带结构,扩展其光吸收,改善载流子的分离效率,从而提高WO3光电极在光电催化水氧化反应中的活性与稳定性。
Absstract of: CN122399711A
本发明公开了一种火星原位资源利用的火箭燃料制备系统及制备方法,涉及火星原位资源利用技术领域。本发明包括:火星风化层水提取机构,用于从火星风化层中提取水分;水电解产氢机构,用于对提取的水分进行电解以产生氢气;火星大气富集机构,用于从火星大气中处理并收集二氧化碳;燃料制备与收集机构,用于接收所产生的氢气和所收集的二氧化碳,并通过萨巴蒂尔反应将其转化为甲烷。本发明实现了火星原位水、二氧化碳向甲烷火箭燃料的高效转化,同步回收反应生成水形成闭环循环,并副产氧气,为火星探测任务提供燃料、氧化剂及生命保障物资,显著降低了对地球补给的依赖,具有适应火星低压、高粉尘环境的优点。
Absstract of: CN122411684A
The invention discloses a control method and device of a hydrogen storage system, a storage medium and electronic equipment, and relates to the technical field of energy power. Based on the production operation data, the hydrogen production and use state of the electric hydrogen production ammonia synthesis system is determined; and then according to the hydrogen production and use state, a hydrogen storage system in the electric hydrogen production ammonia synthesis system is controlled to carry out collaborative charging and discharging of hydrogen, and the hydrogen storage system comprises a gaseous hydrogen storage device, a solid hydrogen storage device and/or a liquid hydrogen storage device. Compared with the prior art, on the premise that safe and stable operation of the system is met, the distribution and operation strategy of the hydrogen storage system is dynamically controlled based on the hydrogen production and use state of the system, the hydrogen use amount change can be efficiently and timely responded, full utilization of the cycle life of the hydrogen storage system and dynamic and intelligent distribution of the hydrogen storage capacity are achieved, and the service life of the system is prolonged. And the overall operation economy of the system is improved.
Absstract of: CN122406249A
0001 本申请涉及一种电解海水制氢联产矿物资源的系统及方法,属于可再生能源技术领域。本申请的电解海水制氢联产矿物资源的系统包括海水预处理装置、海水电解装置、气液分离器和海水提铀装置,海水预处理装置的出水口分别连接海水电解装置的第一阴极室的进水口和第一阳极室的进水口;海水电解装置的第一阳极室的出水口连接气液分离器的入口,气液分离器的出气口连接海水提铀装置的第二阴极室的进气口,气液分离器的出水口连接海水提铀装置的第二阴极室的进水口。本申请电解海水制氢的同时从海水中提取了镁、铀两种具有经济价值的金属资源,大幅降低了制取单一氢气产品的生产成本。
Absstract of: CN122418846A
The invention provides a wind and light hydrogen production electricity-heat collaborative optimization control method considering delay and inertia, and belongs to the technical field of energy system modeling and intelligent control, and the method comprises the steps: building a multi-physical field wind and light hydrogen production average value coupling model based on a wind and light hydrogen production system through fusing wind and light, a power grid, an electrolytic cell and a battery control strategy; based on the electrochemical model of the alkaline electrolytic cell, introducing thermodynamic delay and thermal inertia characteristics, and constructing a refined dynamic heat flow model of the alkaline electrolytic cell; and obtaining an optimal cooling water flow controller, carrying out space-time coupling on the multi-physical field wind-solar hydrogen production average value coupling model and the dynamic heat flow model of the alkaline electrolytic cell to obtain an electricity-heat collaborative dynamic model, and finishing wind-solar hydrogen production electricity-heat collaborative optimization control by combining with the optimal cooling water flow controller. The problem that under the renewable energy source fluctuation working condition, it is difficult to synchronously meet the requirements for equipment operation safety and electrolysis process stability through electrolytic cell power adjustment and thermal management is solved.
Absstract of: CN122399923A
0001 本发明提供了一种氨‑氢能源转化催化剂的智能活化方法及系统,涉及催化剂活化领域;包括如下步骤:向装填有催化剂床层的反应器中通入纯氢气,在活化温度低于360℃、活化压力低于0.5MPa的条件下对催化剂进行还原活化;实时监测反应器出口气体中的水汽浓度,获得水汽浓度实时检测值及其变化速率;依据水汽浓度实时检测值及其变化速率,动态调控活化温度和/或氢气流量,使水汽浓度维持在预设的安全窗口内;当水汽浓度实时检测值及其变化速率满足预设的活化终点条件时,停止活化,获得活化的催化剂。本发明通过纯氢低温低压还原避免了金属‑氮键阻碍和水汽滞留,结合基于水汽浓度偏差及速率反馈的智能闭环调控,实现了催化剂的深度、高质量活化。
Absstract of: CN122406280A
本发明涉及电催化材料技术领域,尤其涉及一种高熵 ZnNiCoCuMn MOF‑74 电催化材料的机械球磨制备方法及其应用。本发明将金属盐和有机配体混合,进行球磨反应,得到高熵ZnNiCoCuMn MOF‑74电催化材料;金属盐由锌盐、镍盐、钴盐、铜盐和锰盐组成。本发明克服了传统溶剂热法合成高熵MOF周期长、能耗高、五种金属反应活性差异大易导致分相的问题。所制得的材料具有均一的高熵固溶体结构,金属位点高度分散,且因多元金属间的协同效应展现出优异的析氧反应(OER)催化活性和长期稳定性。
Absstract of: CN122399834A
本发明提供了一种裂解制氢催化剂及其制备方法和应用,氨裂解之情催化剂包括ZrO2‑Bi2O3‑SiO2三元复合载体以及负载在所述载体上的钴和锰。该氨裂解制氢催化剂以ZrO2‑Bi2O3‑SiO2为载体,负载钴和锰,载体形成了“高分散‑强吸附‑富空位”的催化界面,与负载的钴和锰协同作用,使得该催化剂具有优异的氨裂解制氢催化性能。
Absstract of: CN122406294A
0001 本发明公开了一种TiO<2>/Co<3>O<4>/Ni复合电催化析氢材料及其制备方法和应用,包括以下过程:将碳布置于含有钛源、酸和去离子水的前驱体溶液中,进行水热反应,得到TiO<2>/CC;得到的TiO<2>/CC置于含有钴盐和沉淀剂的溶液中,进行水热反应,得到TiO<2>/Co<3>O<4>/CC;以TiO<2>/Co<3>O<4>/CC为工作电极,在含Ni²<+>的电解液中,进行电化学沉积,得到TiO<2>/Co<3>O<4>/Ni/CC复合电催化析氢材料。在材料内部成功构建出TiO<2>/Co<3>O<4>/Ni三相异质界面,大幅提升析氢反应动力学速率。
Absstract of: CN122406328A
本发明公开了一种具有双界面力优化与动态保护层的双维度稳定析氢电极制备方法。针对碱性水电解电极结构失稳与催化成分退化问题,本发明创新采用低能耗“全电沉积法”。基底经预处理,依次通过多步电沉积,原位构筑“多孔网络骨架”与“微米岛耦合插片阵列”复合催化层。该结构优化双界面力,提升基底结合力并促使气泡小体积脱附,有效抵抗大电流气泡冲击。电沉积构筑复合结构后经循环伏安活化,在表面电沉积一层超薄含Cr动态保护层。启停过程的强氧化/还原电位下,该层呈现动态氧化/还原特性,有效保护Ni、Mo等活性成分免遭化学退化。本方法摒弃了高温高压工艺,经济高效且易于规模化生产,所制备电极兼具优异催化活性与双维度稳定性。
Absstract of: CN122406261A
本申请公开了一种缺陷调控型电催化剂及其制备方法和应用。缺陷调控型电催化剂及其制备方法和应用,缺陷调控型电催化剂的制备方法,包括以下步骤:S1将三维导电基底浸入含镍盐、铁盐和钼酸盐的混合水溶液中,并加入硫源和有机模板剂,混合均匀得到前驱液;将导电基底与该前驱液一并进行水热反应,反应温度为140°C至200°C,反应时间为12小时至24小时,冷却后取出并洗涤干燥。本申请实施例的一种缺陷调控型电催化剂及其制备方法和应用,位构筑的多级孔结构、双缺陷活性位与紧密异质界面协同作用,有效提升电催化析氧活性与稳定性。
Absstract of: CN122399844A
本发明提供一种钴掺杂的ZnCdS/MoS2异质结复合材料,所述异质结复合材料为二硫化钼纳米花与硫化锌镉纳米颗粒形成的异质结结构;其中,钴元素同时掺杂于二硫化钼晶格和硫化锌镉晶格中;所述硫化锌镉纳米颗粒均匀生长在二硫化钼纳米花表面,形成三维分级结构。本发明采用一步水热法、工艺流程简单,制备的异质结复合材料可用于光催化产氢,并且在外加磁场条件下达到更高的产氢效率,可作为理想的光催化产氢催化剂,为后续绿色能源的开发利用提供一个可行性选择。
Absstract of: CN122406285A
0001 本发明提供了一种质子交换膜电解水用铂催化剂及其制备方法和应用,包括:S1,先在沉淀容器中加入硫酸溶液,再将偏硅酸钠溶液与盐酸溶液在一定的沉淀温度下同时加入沉淀容器中进行沉淀,添加结束后保温一段时间,对沉淀物进行过滤、洗涤、干燥,获得白炭黑载体;S2,将所得白炭黑载体浸入醇类中,在搅拌过程中滴加碱溶液调节pH到7.5‑9.0,蒸干,得到改性白炭黑载体;S3,将所述改性白炭黑载体制成悬浮液,加入铂源,80‑100℃保温20‑40min,用碱溶液调整pH到8.0‑9.0,加入还原剂进行还原,过滤、洗涤、干燥,即可得所述质子交换膜电解水用铂催化剂。该铂催化剂在高电流密度下仍保持不错的稳定性和高催化活性。
Absstract of: CN122399916A
本发明公开了一种用于光催化析氢的双S型异质结光催化剂的合成方法,包括如下步骤:(1)将MXene材料进行煅烧处理,得到二氧化钛;(2)将三聚氰胺进行煅烧处理,得到石墨相氮化碳;(3)将四羧基苯基卟啉锌和步骤(1)中获得的二氧化钛加入乙醇溶液中,得到TZ复合材料;(4)将TZ复合材料和步骤(2)中获得的石墨相氮化碳分散在水中并搅拌均匀;(5)步骤(4)获得的样品离心,将所得固体进行真空干燥,得到双S型光催化剂gTZ。本发明通过将ZnTCPP,g‑C3N4和TiO2光催化材料制备成双S型异质结光催化剂,协同促进光生载流子的分离与定向迁移,有效抑制电子‑空穴复合,从而大幅提升光催化产氢性能。
Absstract of: WO2025132365A1
The invention relates to a device/method for capturing/converting CO2, comprising/using a CO2 capturing unit (2), a water electrolysis unit (5), an RWGS unit (8), an FT unit (13), a unit for converting by-products into syngas (28) and a hydrogen unit (20), in which a carbon dioxide separation unit (34) is arranged to: treat a first syngas (12) and a second syngas (29); produce a gaseous effluent depleted in carbon dioxide (18) and a gaseous effluent rich in carbon dioxide (35); and recycling the gaseous effluent rich in carbon dioxide (35) to the inlet of the RWGS section (8).
Absstract of: WO2025132918A1
Disclosed is an electrolysis cell element (1) comprising, a support structure (2) comprising an inner aperture (3), and a bipolar plate (4) being suspended in the inner aperture (3). The support structure (2) comprises a structure core (5) and a coating (6), wherein the coating (6) includes a thermoplastic material at least partly enclosing the structure core (5) and wherein the bipolar plate (4) is suspended in the inner aperture (3) by means of the coating (6). An electrolysis cell stack (10) and use of an electrolysis cell stack (10) is also disclosed.
Absstract of: WO2025132935A1
Disclosed is an electrolysis cell stack (10) comprising a plurality of support structures (2) each including an inner aperture (3). The electrolysis cell stack (10) further comprises a plurality of cathodes (17), a plurality of anodes (18), a plurality of bipolar plates (4), a plurality of gas impermeable membranes (19), and pressing means 5 (20) arranged for pressing neighbouring support structures (2) of the plurality of support structures (2) against each other. Further, the electrolysis cell stack (10) comprises a liquid conduit (13) arranged between neighbouring support structures (2) of the plurality of support structures (2), wherein the liquid conduit (13) is arranged outside an outer periphery (40) of the inner aperture (3), deionized water (41) arranged 10 in the liquid conduit (13), and conductivity monitoring means (42) arranged for monitoring a conductivity of the deionized water (41). 0111 A method for detecting a leak in an electrolysis cell stack (10) and use of an electrolysis cell stack (10) is also disclosed.
Absstract of: WO2025135512A1
The present disclosure relates to: a catalyst for an oxygen evolution reaction of a water electrolysis cell; a method for manufacturing same; and a membrane-electrode assembly for a water electrolysis cell, and a water electrolysis cell, comprising same. More specifically, by manufacturing a catalyst for oxygen evolution reaction of a water electrolysis cell, having a structure in which active particles fill pores between nanoparticles of a carrier assembly manufactured in various forms or penetrate into the carrier assembly while being supported by the carrier assembly, performance is improved while reducing the amount of noble metal used. The active particles have stronger bonds than a form in which active particles are simply supported, and thus the active particles and the carrier assembly can have improved durability.
Absstract of: CN122406304A
0001 本申请公开了一种电解槽控制系统、制氢系统及控制方法、电解槽的控制方法。该电解槽控制系统应用于电解槽,电解槽具有阳极、阴极、氢侧出口和氧侧出口,电解槽控制系统包括控制装置以及分别与控制装置连接的供电装置、供水装置、供氢装置、监测装置,供水装置连接电解槽的氧侧出口,供氢装置连接电解槽的氢侧出口,监测装置用于检测电解槽的槽压;控制装置在第一工作模式下,控制供水装置将水通入氧侧出口、控制供氢装置将氢气通入氢侧出口,并控制供电装置的电流输出口连接在阴极、供电装置的电流输入口连接在阳极。通过设置控制装置在第一工作模式下工作,可以将电解槽的阳极上的氧化物薄膜去除至少一部分,以恢复电极的高效状态。
Absstract of: CN122406357A
0001 本发明公开了一种基于双卤素离子调控晶化的聚三嗪酰亚胺(PTI)光催化材料及其制备方法与应用。通过构建溴化锂与氯化钠/氯化钾协同的熔盐体系,在热聚合过程中实现晶体成核与生长的分阶段调控,使材料经历由亚稳相向稳定相转变的晶化路径,从而诱导形成具有部分离子缺位结构的晶相氮化碳材料。该结构能够有效降低缺陷态密度,并将深能级陷阱转化为浅能级陷阱,从而显著提升光生载流子的分离与迁移效率。所制备材料在光催化全分解水反应中表现出优异性能,其表观量子效率可达30%以上。本发明方法工艺简单、可控性强,具有良好的规模化应用前景。
Absstract of: CN122399825A
0001 本发明公开了一种蜂窝多孔状钴‑铁‑钒/氧化钴复合催化剂及其制备方法和应用,属于氢能技术领域。该复合催化剂由Co<3>V、CoFe及CoO三种物相组成,且CoO包覆在Co<3>V和CoFe表面,整体呈蜂窝多孔状。其制备步骤如下:首先,采用熔炼法将钴、铁、钒和铝四种单质熔炼成钴‑铁‑钒‑铝四元合金;然后,采用氢氧化钠溶液对合金粉末进行碱蚀脱合金化处理;最后,将脱合金处理后的合金粉末置于空气中自然氧化或加热氧化,即可制得所述蜂窝多孔状钴‑铁‑钒/氧化钴复合催化剂。本发明所提供催化剂的制备方法简便、安全环保、原料低廉,易于实现规模化生产。将该催化剂应用于催化硼氢化钠水解制氢时,表现出良好的催化活性和循环稳定性。
Absstract of: CN122406286A
0001 本发明公开了一种BiVO<4>/TiC/C‑C光电催化材料及其制备方法和应用,属于功能材料技术领域;该制备方法先通过高温烧结制得TiC粉末、水热法制备BiVO<4>粉体,再将二者分别制成分散均匀的前驱体溶液,以预处理后的碳布为基底,通过梯度电泳沉积先镀TiC层再镀BiVO<4>层,烘干后得到目标光电催化材料;本发明构建了BiVO<4>/TiC/C‑C梯度复合结构,实现光吸收、载流子分离与表面催化的功能协同,TiC与碳布形成高效电子传输通道,抑制光生电子‑空穴对复合,TiC与BiVO<4>协同调控表面电子结构提升析氧动力学;且材料界面结合牢固,结构稳定性和机械强度优异,能抵抗电解液侵蚀,制得的材料可作为光阳极材料应用于碱性环境光催化电解水过程,析氧性能优异。
Absstract of: WO2025143845A1
The present invention relates to a reinforced composite membrane for a water electrolysis cell, a membrane-electrode assembly for a water electrolysis cell, comprising same, and a water electrolysis cell comprising same, wherein in the reinforced composite membrane for a water electrolysis cell, a porous support is arranged to be biased toward the surface adjacent to an oxygen evolution electrode before operation of the water electrolysis cell, on the basis of a prediction of the area that expands after the operation, the oxygen evolution electrode undergoing relatively greater expansion, thereby evenly distributing the expansion stress applied to the reinforced composite membrane for a water electrolysis cell after operation and improving the performance and durability of the membrane-electrode assembly and water electrolysis cell comprising same.
Absstract of: WO2025143687A1
Provided is an electrode for a water electrolysis cell, the electrode comprising: a microporous layer; and a porous pattern layer positioned on one surface of the microporous layer. The porous pattern layer comprises: first patterns that extend in a first direction parallel to the one surface of the microporous layer and are arranged spaced apart in a second direction parallel to the one surface of the microporous layer and different from the first direction; and second patterns that extend in the second direction, are arranged spaced apart in the first direction, and intersect the first patterns, wherein the first patterns and the second patterns each include a plurality of stacked nanowires, and the nanowires include a metal oxide doped with fluorine.
Absstract of: CN122406299A
0001 本发明公开了一种CuCo‑MOF‑74/NiFe‑LDH复合电催化剂以、制备方法及其应用,属于电催化材料技术领域。本发明采用共沉淀法合成CuCo‑MOF‑74,再通过电沉积工艺将其与NiFe‑LDH复合,制得CuCo‑MOF‑74/NiFe‑LDH复合电催化剂。本发明通过添加适量CuCo‑MOF‑74的掺杂维持LDH主体晶体结构,二者形成的界面协同效应能提升催化活性,同时优化材料在紫外‑可见光区的吸收性能,赋予材料高比表面积和丰富活性位点。本发明制备方法工艺简单、可控性强,制得催化剂在电催化水分解析氧反应中表现优异。
Absstract of: CN122406330A
0001 本发明公开了一种具有磷化物/羟基氧化物活性界面的析氧电极及其构建方法和应用。所述构建方法包括:提供负载有钇掺杂镍铁磷化物前驱体的导电基底;将其置于碱性电解液中,施加阳极电位进行电化学原位活化,使前驱体表面部分重构,形成以结晶态钇掺杂镍铁磷化物为核、羟基氧化物为壳的复合活性界面;其中,在不高于1.40V的电位下即可通过原位拉曼检测到β‑NiOOH的特征峰。本发明制备的析氧电极在1mol/L KOH中,10mA/cm<2>过电位不高于150mV,100mA/cm<2>过电位不高于230mV;在不高于1.70V的阳极电位下,可维持不低于500mA/cm<2>的电流密度超过50小时。本发明实现了低电位重构和高电流密度长期稳定性,适用于碱性电解水析氧。
Absstract of: CN122399675A
本发明涉及一种产氢反应器,尤其是一种硼氢化钠溶液产氢反应器及其使用方法。一种硼氢化钠溶液产氢反应器,包括:壳体,设于反应腔和与反应腔相通的废液排出口;上盖,设于壳体的顶部,且设有进液口、出气口和泄压口;支撑盖,设于反应腔内;以及反应舱,设于支撑盖上,内部设有催化剂,反应舱与进液口相通,反应舱与反应腔之间形成缓冲腔;其中,硼氢化钠反应液通过进液口进入到反应舱内与催化剂接触水解产氢,反应废液由于重力进入到反应腔的底部,产生的氢气入缓冲层并通过出气口排出。本发明提供的一种硼氢化钠溶液产氢反应器通过设置缓冲腔来减少气体冲击,提供稳定可靠的气体产出,结构简单、安全性好、稳定性高。
Absstract of: CN122399793A
本发明公开了一种协同高效产氢和降解有机染料亚甲基蓝的ZnWO4/Bi4Ti3O12制备方法,包括以下步骤:称取NaOH溶于去离子水中,持续搅拌后,加入;进行水热反应;干燥,得到最终样品Bi4Ti3O12(BTO)纳米球;将溶液B加入溶液A,放入烘箱中反应;获得ZnWO4(ZWO)纳米颗粒;将BTO按照不同质量比加入溶液A中至搅拌均匀;获得一系列x%ZWO/BTO(x=10,20,30)复合样品。本发明的制备方法采用一步水热法,工艺简单环保、可控性强,原料无毒、无需复杂设备,易于规模化生产。
Absstract of: CN122408053A
0001 本发明公开了一种氨氢混合燃烧装置及系统,装置包括本体、燃料引入管、空气引入机构和第二点火装置。本体通过分隔板上下分隔为第一燃烧室和第二燃烧室。燃料引入管延伸至第一燃烧室内部,由直线引入部分和弯曲结构的分解部分连接组成,分解部分管壁开设有排气孔。空气引入机构固定在第一燃烧室顶部并延伸至第二燃烧室内部,其滑动装置一端固定有滑动挡板。本发明通过弯曲结构的分解部分对氨气进行初步分解,生成氢气以提高第一燃烧室中的预燃烧效果;燃烧后气体经分隔板进入第二燃烧室,结合空气引入机构对空气量与燃烧室体积的调节及扰流作用,使剩余氨气有效燃烧,显著提高了氨气燃烧效率,缓解了点火困难的问题,设备集成度高。
Absstract of: CN122399920A
本发明公开了一种TiO2纳米花负载CoNiCuPdAg高熵合金的光催化剂,包括作为载体的TiO2纳米花和均匀负载的CoNiCuPdAg高熵合金纳米颗粒;其制备方法为:采用改进的溶剂热法制备TiO2纳米花和CoNiCuPdAg高熵合金纳米颗粒粉末,并采用静电吸附改进的浸渍法复合。本发明采用TiO2纳米花载体提供丰富的反应活性位点和光吸收界面,并控制高熵合金组分,综合Cu优异的CO2吸附和活化能力,Ni高的氢亲和力,Co的富电子特性以及Pd、Ag的表面等离子激元效应等,提升光催化CO2还原和产氢性能;本发明通过静电吸附改进的浸渍工艺复合,实现了光催化剂催化活性和稳定性的显著突破,适用于光催化能源转化领域。
Absstract of: CN122399849A
本发明涉及涉及光催化和压电催化材料技术领域,尤其涉及双助剂空间分离结构的光振动协同催化剂及其制备方法。通过在晶格中引入Ta元素,优化比例获得固溶体材料,并将其应用于光–压电协同催化体系,实现超声辅助下对甲基橙等有机染料的高效降解。进一步,通过光沉积在(110)晶面与(001)晶面分别负载金属Bi与CoOx助催化剂。其中金属Bi作为电子捕获位点,CoOx作为空穴捕获位点,通过构建空间分离的双助催化剂结构,进一步促进载流子定向迁移与分离,显著提升材料的光–压电协同催化降解性能。本发明通过固溶体调控、双助催化剂空间构筑与压电场耦合的多重协同作用,构建了一种新型高效光–压电协同催化材料体系。
Absstract of: CN122406281A
0001 本发明公开了一种用于固体氧化物电解池的铁镍合金修饰双钙钛矿材料及其制备方法,属于能源材料与电化学技术领域。所述复合材料包括Sr₂Fe₁.₃₅Mo₀.₄₅Ni₀.₂O₆‑δ经受控还原得到的缺陷型双钙钛矿基体,以及原位析出并均匀分布于基体表面的FeNi₃合金纳米颗粒。本发明创新性采用碳介导的短时高温冲击还原策略,以碳粉为瞬时还原剂,通过多轮次极短时高温冲击,实现FeNi₃合金纳米颗粒的原位脱溶,解决了传统还原工艺能耗高、耗时长、颗粒易粗化的问题。本发明制备的复合材料兼具高催化活性、高离子/电子电导率与优异的结构稳定性,作为固体氧化物电解池阴极材料时,表现出显著提升的CO₂‑H₂O共电解性能,具备极高的产业化应用价值。
Absstract of: CN122398721A
本发明公开了一种基于ZnS负载水凝胶的光催化产氢抗皮肤光老化材料及其制备方法,方法包括:S1、将ZnS纳米颗粒分散在氧化普兰多糖、L‑半胱氨酸、L‑(+)‑乳酸的混合溶液中;S2、加入马来酰亚胺修饰羧甲基壳聚糖,反应后得到ZnS负载水凝胶;其中ZnS纳米颗粒、氧化普兰多糖、L‑半胱氨酸、L‑(+)‑乳酸和马来酰亚胺修饰羧甲基壳聚糖的质量比为1:(5~15):(5~10):(80~200):(2~10)。本发明的ZnS负载水凝胶用于在皮肤表面原位光催化产氢。与传统光催化材料相比,该复合水凝胶材料能够在保持凝胶结构稳定的同时,实现高效光催化产氢,并且ZnS颗粒分散均一、粒径可控,保证材料安全性与生物相容性。
Absstract of: CN122406262A
本发明公开了一种磷酸根涂层修饰的镍铁基电解海水制氢催化剂的制备方法及应用,属于纳米催化与清洁能源转化领域。本发明以泡沫镍为基底,在镍铁混合溶液中室温浸泡,于载体表面原位生长镍铁层状双氢氧化物,经清洗干燥后,依次利用氢氧化钾与六偏磷酸钠溶液,结合循环伏安电化学活化,制得一种磷酸根涂层修饰的镍铁基催化剂。将其作为流动电解池阳极,搭配磷化镍阴极,以碱性海水为电解液完成电催化制氢反应。该制备工艺条件温和、操作简便、原料廉价易得、绿色环保,无需复杂设备,适合规模化量产。改性后的催化剂协同流动电解池体系,可高效实现碱性海水电解,在绿氢制备与清洁能源转化领域应用前景广阔,可为双碳目标实现提供技术支撑。
Absstract of: CN122407990A
本发明涉及纯氨分解制氢技术领域,具体公开了一种纯氨分解制氢的氨能利用装置,包括:纯氨分解制氢的氨能利用装置、输送管和监测机构,输送管设置于纯氨分解制氢的氨能利用装置的顶端,输送管用于输送氢气,监测机构套接于输送管的外壁。本装置实现了纯氨分解制氢装置氢脆效应的实时、在线、无滞后监测,采用纯机械多级联动结构配合少量电子元件完成信号触发,具备温度与压力自适应调节能力,可有效区分正常渗透与氢脆异常渗透,监测精度高、响应迅速、安全性强、适用范围广,显著优于现有技术中定期检测与电气依赖度高的监测方式。
Absstract of: CN122399866A
0001 本发明涉及光催化材料技术领域,公开了一种g‑C3N4光催化剂及其制备方法。所述g‑C3N4光催化剂包括协同改性g‑C3N4基体材料、有机小分子改性剂、孔结构调节剂和层控分散助剂,其中所述协同改性g‑C3N4基体材料是以g‑C3N4为主体,在其表面通过多酚类结构单元、含硫有机硅结构单元以及过渡金属配位结构单元的协同作用进行改性形成,所述有机小分子改性剂为α‑硫辛酸。通过对g‑C3N4基体进行协同改性并配合多组分复合调控,使所制得的光催化剂在光催化反应过程中表现出较好的性能和稳定性。本发明制备方法工艺简单,条件温和,具有良好的可实施性和应用前景。
Absstract of: US2024401211A1
Particular embodiments described herein provide for a synthetic fuel creation system. The synthetic fuel creation system includes a syngas creation station to create syngas, a crude creation station to create heavy syncrude, and a crude cracking station to convert the heavy syncrude into synthetic fuel. The synthetic fuel creation system can use an electrocatalysis system to create the syngas and the electrocatalysis system can include an anode, a cathode, oxygen evolution reaction catalysts, hydrogen/carbon monoxide evolution reaction catalysts, and an electrolyte, where a pH of the electrolyte is acidic during at least a portion of creation of the syngas.
Absstract of: CN122399815A
0001 本发明提供了一种Ni‑CMS空心微球负载不同金属纳米催化剂的制备方法及在不同溶液中催化多种储氢材料析氢的应用,通过金属离子与有机配体结合制备了Ni‑CMS空心微球前驱体,再通过高温煅烧获得Ni‑CMS空心微球,随后使用还原剂硼氢化钠原位还原不同的金属离子,制备了Ni‑CMS空心微球负载不同金属催化剂,并将其应用在催化多种储氢材料析氢反应中。本发明技术方案得到的纳米催化剂的优点为制备工艺简单,对催化多种储氢材料析氢中具有较高的选择性和催化活性。
Absstract of: CN122413735A
0001 基于改进混沌进化算法的PEM电解槽仿真模型参数分阶段辨识方法,包括:建立PEM电解槽半经验模型,确定模型待辨识参数组;划分PEM电解槽极化特性曲线为低、中、高电流密度三个阶段,采用距离相关系数法分析各待辨识参数与不同电流密度阶段输出电压的关联程度,筛选出各阶段的主导参数;引入Logistic混沌初始化策略和Levy飞行机制改进得到ICEO算法,通过ICEO算法对各阶段主导参数进行分阶段精准辨识;将各阶段辨识得到的最优参数代入PEM电解槽半经验模型,输出与实测数据的拟合精度;分别对不同温度和电压下的PEM电解槽进行参数辨识。该方法实现了PEM电解槽极化特性不同阶段主导参数的精准筛选与分阶段高效辨识,提升 PEM 电解槽仿真模型的参数辨识精度、算法收敛效率。
Absstract of: CN122399784A
本发明公开了一种稀土元素掺杂的氧化铈催化剂及其制备方法与在光催化全分解水中的应用。所述催化剂通过高温固相反应将稀土元素掺杂入氧化铈晶格制备。该掺杂策略能够同步降低氧化铈的氧空位与Ce3+浓度,并构筑了表面至体相的内建电场,二者协同作用提升了光生载流子的解离与分离效率,并抑制其在陷阱态的复合。以此改性材料负载析氢与析氧助催化剂,可实现光催化全分解水反应。性能测试表明,本发明所得催化剂表现出优异的光催化全分解水活性与稳定性,产气比例符合2:1的化学计量比,且在58 h循环测试后活性保持率高达95%。本发明制备工艺简单、原料成本低廉,为开发高性能稀土基光催化制氢材料提供了新方案。
Absstract of: WO2025098597A1
The invention relates to an electrochemical cell assembly (10), comprising a first end plate (12), a second end plate and a stack (16) of cell units (18), wherein each cell unit defines an external perimeter, a housing (42) surrounding the stack to define or enclose a fluid volume (48), at least one electrically insulating member (98) being located between the housing and the external perimeters of the cell units and a positioning device (100) for the at least one electrically insulating member, comprising at least one positioning member (106) protruding from either the housing or one of the end plates into the fluid volume, wherein the at least one positioning member has a positioning surface interacting with the electrically insulating member for positioning the electrically insulating member relative to the housing and/or the end plates. The invention also relates to methods of manufacturing an electrochemical cell assembly.
Absstract of: CN122406267A
本发明公开了一种稀土单原子修饰木质素衍生氮掺杂碳纳米片负载钌纳米颗粒催化剂及其制备方法和应用,属于电催化材料与电解水制氢技术领域。该制备方法为由木质素、稀土金属盐和锌盐复合形成前驱络合物,经含氮前驱体辅助热处理得到载体,再经Ru前驱体吸附和焦耳热处理得到。本发明催化剂中超细高分散Ru纳米颗粒可提供丰富的析氢活性位点,稀土位点有利于调节Ru表面OH中间体吸附行为并减轻表面毒化,从而提升碱性析氢反应活性与稳定性。该催化剂在半电池析氢测试及AEM电解槽阴极测试中均表现出较优性能,具有良好的电解水制氢应用前景。
Absstract of: CN122406276A
0001 本发明属于电催化材料技术领域,公开了一种高效碱性水氧化催化剂NiCoS的制备方法及其应用。该方法先对泡沫金属基底进行盐酸‑无水乙醇‑去离子水超声预处理,再采用射频或微波氩氮混合气体非热平衡等离子体进行表面改性,随后通过循环伏安电沉积法在基底表面原位生长三维多孔纳米片结构的NiCoS活性层。本发明工艺简单、成本低廉、绿色环保,可实现大尺寸催化剂的均匀规模化制备。所得催化剂在工业级电流密度下具有优异的催化活性和稳定性,性能显著优于现有商业贵金属催化剂和多数非贵金属催化剂,能够大幅降低电解水制氢的能耗。本发明可广泛应用于碱性电解水制氢、海水制氢及可再生能源耦合制氢系统中。
Absstract of: CN122399913A
0001 本发明涉及一种三维聚苯胺包覆单晶多孔Ni<5>P<4>纳米片阵列催化材料,在碳布上采用水热和原位磷化方法制备,制备周期短、方法简单。本发明还涉及一种上述三维聚苯胺包覆单晶多孔Ni<5>P<4>纳米片阵列催化材料在酸性电解质中催化分解水制氢的应用,本发明的催化材料具有优秀的析氢性能,具有很好的商业应用价值。
Absstract of: CN122406283A
本发明涉及一种用于碱性电解水制氢的镍网基催化电极,其包括镍网基底及功能性涂层,其中,所述功能性涂层包括成分为Ni‑Mo‑Co合金的催化活性层,在催化活性层中,Ni含量为68 wt%‑72 wt%,Mo含量为15.5 wt%‑19.5 wt%,Co含量为10.5 wt%‑14.5 wt%,余量为不可避免的杂质。本发明还提供了一种镍网基底及功能梯度涂层,涂层沿厚度方向依次为Ni‑Co结合层、Ni‑Mo‑Co梯度过渡层和Ni‑Mo‑Co催化活性层。上述电极在1 M KOH中10 mA/cm2下过电位仅90 mV,超声脱落率低于0.2%,60 h稳定性衰减小于2 mV。
Absstract of: CN122403371A
The invention belongs to the technical field of industrial gas preparation, and particularly relates to a method and a device for preparing high-purity oxygen and argon on site. According to the invention, a closed-loop system which is driven only by electric power is constructed, pressure swing adsorption, water electrolysis, catalytic reaction and thermal management technologies are coupled, and efficient circulation of materials and energy is formed. The technological process comprises the following steps: deeply removing nitrogen in air by adopting a first-stage PSA unit and taking a specific zeolite molecular sieve as an adsorbent to obtain oxygen-enriched argon mixed gas; performing secondary PSA separation on the oxygen-enriched argon mixed gas by using a carbon molecular sieve to obtain high-purity oxygen; oxygen-enriched waste gas desorbed by the second-stage PSA and hydrogen generated by the water electrolysis unit are subjected to a combination reaction in a reactor to generate water, and oxygen impurities are removed; dehydrating the reacted gas to obtain high-purity argon; the device has the advantages of modularization, movability, high energy efficiency, zero raw material consumption and the like, and an integrated and autonomous gas supply solution is provided for industrial sites needing high-purity oxygen and argon at the same time.
Absstract of: CN122406257A
The invention discloses a PEM electrolytic bath sealing device, and relates to the technical field of hydrogen preparation. The device comprises a cathode side sealing rubber strip, a cathode frame, a cathode side film sealing gasket, an anode side film sealing gasket, an anode frame and an anode side sealing rubber strip which are oppositely arranged in sequence, the cathode side sealing rubber strip is arranged on a cathode side bipolar plate in a non-uniform-section penetrating mode, and the anode side sealing rubber strip is arranged on an anode side bipolar plate in a non-uniform-section penetrating mode. The cathode side film sealing gasket and the anode side film sealing gasket are symmetrically arranged on the two sides of the film electrode, one side of the cathode frame is matched with the cathode side sealing rubber strip through a convex edge part and a limiting part, and one side of the anode frame is matched with the anode side sealing rubber strip through a groove part and a convex part. And the other side of the cathode frame and the other side of the anode frame symmetrically clamp the cathode side film sealing gasket and the anode side film sealing gasket through the convex edges. According to the invention, the performance of assembly positioning, anti-offset locking, high-pressure extrusion resistance, pressure self-tightening and membrane electrode stress balance can be provided.
Absstract of: CN122406282A
本发明涉及催化材料领域,具体而言,涉及电解水制氢阳极电极及其制备方法与应用,所述电解水制氢阳极电极包括镍基体以及负载在所述镍基体上的电镀层;所述电镀层的元素组成及其原子百分比为:Pt:1%~4%,Ru:0.5%~2.5%,O:10%~15%,C:25%~40%,余量为Ni和不可避免的杂质。本发明通过电镀在镍基体上负载了含有Ni、Pt、Ru等元素的电镀层,制得的电极在碱液中具有良好的稳定性、导电性以及催化活性,且贵金属含量较低,避免了现有技术中烧结制备贵金属氧化物电极存在的导电性差、贵金属含量高、电极成本高、催化剂层易开裂等问题。
Absstract of: CN122399495A
0001 本发明属于氢气分离提纯领域,具体涉及一种用于高温水电解制氢的氢气分离提纯装置。包括预压筒,预压筒容置于分离筒的内腔中,预压筒内腔套设有挡锤组件,挡锤组件的锤头与预压筒的内壁贴合并在预压筒内腔滑动连接,横杆的两端分别固定连接锤头和挡板,预压筒顶部与进气管联通,预压筒底部固定连接支座筒,挡板与支座筒的内壁贴合并在支座筒内腔滑动连接;本发明避免从电解槽出来的高温混合气体因为电解工况的波动而导致送入冷凝空间中时空气压力和流量不稳定,增强冷凝温度的控制稳定性,提升冷凝效率;还使得杂质气体得到充分冷凝后再被带出,提升分离后氢气的纯度。
Absstract of: CN122407964A
The invention discloses a hydrogen energy production, storage and supply integrated skid-mounted integrated station which comprises a movable skid-mounted integrated main body, a hydrogen production device, a hydrogen liquefaction device, a low-temperature liquid hydrogen storage tank, a gaseous hydrogen buffer tank, a hydrogenation machine and a flash steam recovery unit are integrated on the skid-mounted integrated main body, an outlet of the hydrogen production device is divided into two paths, one path is communicated with the low-temperature liquid hydrogen storage tank through the hydrogen liquefaction device and a liquid hydrogen pump, and the other path is communicated with the flash steam recovery unit through the gaseous hydrogen buffer tank. The hydrogenation machine is only communicated with an outlet of the gaseous buffer tank special for hydrogenation, the flash steam recovery valve is communicated with a gas phase space of the low-temperature liquid hydrogen storage tank and is communicated with the gaseous hydrogen buffer tank through the flash steam buffer tank and the flash steam compressor, and the opening pressure of the recovery valve is lower than the take-off pressure of a safety valve of the storage tank; rapid deployment and flexible transition of hydrogen energy stations can be achieved, the construction period and investment cost are reduced, large-capacity storage and instant production and instant use of hydrogen energy are both considered, liquef
Absstract of: CN122406251A
0001 本公开涉及一种采用电化学方法制备高压氢气的装置,包括极板和锁紧结构,其中,极板包括均呈管状的阳极板和阴极板,阳极板和阴极中的一者套设于另一者的外部;锁紧结构包括设置于极板的外侧并用于限制阳极板和所述阴极板在径向上移动的第一锁紧部;和/或,包括设置于阳极板和阴极板并能够连接阳极板和阴极板的第二锁紧部,第二锁紧部用于限制阳极板和阴极板在轴向上的移动。本公开的能够实现制高压氢装置的承压性能和密封性,从而使得采用电化学制备高压氢气的装置能够正常工作。
Absstract of: CN122399852A
0001 本发明涉及多孔非晶/晶体异质结构CoNiP/CC纳米线催化材料,在碳布上采用水热法和原位低温磷化方法制备,制备周期短、方法简单。本发明还涉及一种上述多孔非晶/晶体异质结构CoNiP/CC纳米线催化材料在电催化分解水制氢的应用,本发明的催化材料具有优秀的析氢性能,具有很好的商业应用价值。
Absstract of: CN122406326A
本发明提供了一种一步电沉积方法合成镍钼铜合金的方法,主要包括如下步骤:采用反应电沉积溶液沉积不锈钢片得到。所述反应电沉积溶液包括:硫酸镍六水合物、钼酸铵、硫酸铜五水合物、柠檬酸钠、以及氯化钠。本发明的优点在于,合成方法简单、成本低廉,显著降低析氢反应的过电势,具有良好的稳定性,表现出极佳的电解水析氢反应催化活性,具有良好的应用前景。
Absstract of: CN122406303A
本发明公开了基于铬调控的PtRu基纳米笼催化剂及制备方法与应用,所述方法包括以下步骤:(1)将钌前驱体、铂前驱体及铬前驱体引入ZIF‑8金属有机骨架材料中,通过反应吸附负载形成中空多孔纳米笼结构的多金属前驱体/ZIF‑8复合物;(2)在含氢还原气氛中对多金属前驱体/ZIF‑8复合物进行热处理,得到PtRuCrZnO中间体;(3)采用酸性刻蚀液去除PtRuCrZnO中间体中的ZnO,得到PtRu基纳米笼催化剂。本发明所得催化剂特别适用于AEMWE体系,为构建低贵金属负载、高效率电解水制氢催化材料提供了一种可规模化实施的技术方案。
Absstract of: CN122406296A
本发明公开了一种硼化钴镍纳米片电催化材料及其制备方法,采用泡沫镍为基体,采用镍和钴的混合盐溶液,通过一步还原法将CoNiB负载在泡沫镍上,还原剂为硼氢化钠,通过控制硼氢化钠与金属盐的摩尔比、添加速度调控催化剂的形貌,获得了具有垂直排列片状微观结构的自支撑电极CoNiB/N,本发明的硼化钴镍纳米片电催化材料及其制备方法,生产工艺简单,成本低,通过片状结构增加了反应的活性位点,有利于析氢过程中气体的释放,大幅度提高析氢和析氧反应的催化活性,具有优异的电催化性能。
Absstract of: CN122404641A
The invention discloses a preparation method and application of a branched polyaryl piperidine membrane containing multiple aromatic ring units, and belongs to the technical field of fuel cells and water electrolysis hydrogen production anion exchange membranes. According to the invention, a branched polyarylpiperidine main chain is constructed by introducing a multi-aromatic ring branched unit with multiple reaction sites into a conventional linear polyarylpiperidine main chain, so that the bulk density of the main chain is reduced, formation of ion clusters is facilitated, and the conductivity of the membrane is improved. And the branching degree can be regulated and controlled by flexibly adjusting the feeding of the multi-aromatic-ring branched monomer. The conductivity of the branched polyaryl piperidine membrane is increased by more than 26% compared with that of a linear membrane, and the branched membrane has a lower swelling ratio and higher hydrogen-oxygen fuel cell power density and water electrolysis hydrogen production performance.
Absstract of: WO2025143690A1
Provided is a catalyst for an oxygen evolution reaction in a water electrolysis cell, the catalyst comprising: water electrolysis catalyst particles containing a noble metal oxide; and a conductive additive containing a fluorine-doped metal oxide, wherein in the entire fluorine-doped metal oxide, the content of fluorine is 1 at% to 10 at% relative to a total of 100 at% of the components as measured by X-ray photoelectron spectroscopy (XPS).
Absstract of: WO2025135742A1
A control method of a high-temperature water electrolysis system, according to a first embodiment of the present invention, comprises the steps of: determining an operating temperature of a solid oxide water electrolysis stack in a high-temperature water electrolysis system including the solid oxide water electrolysis stack; selecting an operation mode of the solid oxide water electrolysis stack by comparing the operating temperature with a supply temperature of gas supplied to the solid oxide water electrolysis stack; determining a target voltage applied to the solid oxide water electrolysis stack according to the operation mode of the solid oxide water electrolysis stack; and applying the target voltage applied to the solid oxide water electrolysis stack in a step-up manner according to the operation mode of the solid oxide water electrolysis stack.
Absstract of: WO2025135743A1
The present invention provides a water electrolysis stack assembly and a hot box apparatus. In an embodiment, provided is a water electrolysis stack assembly including: a case including an upper surface part, a side surface part, and a gas outflow pipe formed in the side surface part; and a stack accommodated in an inner space of the case, wherein a surface pressure is applied to the stack by the upper surface part of the case.
Absstract of: CN122406271A
0001 本发明公开了一种基于等离子体处理的铱基催化剂及其制备方法,属于催化材料技术领域。该方法包括:将载体与氯铱酸溶液混合分散,通入氮气并升温至80℃恒温搅拌;在氮气保护下滴加KOH溶液调节pH至11‑12,使铱离子沉积于载体表面;然后转移至水热釜中于180℃进行水热反应,经离心洗涤、干燥、研磨,得到催化剂前驱体;再将前驱体置于等离子体处理装置中,通入氩气,在电压20‑40kV、电流0.4‑0.8mA条件下处理0.25‑1h,即得所述铱基催化剂。本发明通过沉积沉淀法结合等离子体处理,实现了铱活性组分的高度分散和表面电子结构的优化,所得催化剂具有过电位低、稳定性好、贵金属用量少等优点,适用于电解水析氧反应。
Absstract of: CN122406270A
本发明公开了一种泡沫镍负载镍‑钴‑钼磷化物复合材料,首先,以泡沫镍为基底,通过水热法制备泡沫镍负载Ni‑MOF,然后,通过水热法引入钴元素和钼元素,最后,通过磷化处理制得NCM‑P/NF,物相组成为Ni2P和CoMoP2;并且,NCM‑P/NF微观形貌为片状纳米花交错组装形成的三维分级多孔框架结构,Ni、Co、Mo、P元素分布均匀。其制备方法包括以下步骤:1,Ni‑MOF/NF的制备;2,NCM‑MOF/NF的制备;3,NCM‑MOF/NF的磷化。作为电解水析氢/析氧电催化剂应用时,电流密度为10 mA·cm‑2时,HER过电位为70‑80 mV,OER过电位为135‑145 mV;HER塔菲尔斜率为90‑100 mV/dec,OER塔菲尔斜率为24‑26 mV/dec,电化学阻抗值为1‑5 Ω。
Absstract of: CN122406260A
0001 本发明提供了一种镍基磁性中空纤维自支撑电极及其制备方法和在磁场强化水分解反应中的应用,属于电催化功能材料技术领域。本发明通过在镍基体中引入至少一种不同还原电位和扩散速率的过渡金属,利用分子配位调控水热自组装过程,并结合后续热扩散处理,利用不同金属原子热扩散速率差异引发的柯肯达尔效应,在纤维内部形成中空结构,最终实现对纤维表面亚结构形貌、内部中空程度以及磁性能的协同调控,将该电极用于电解水反应时,可采用外磁场增强模式、内场增强模式或磁热辅助模式三种磁场增强模式,显著提升碱性电解水析氢和析氧反应的效率。
Absstract of: CN122406263A
本发明涉及一种具有贯穿孔道结构的气体扩散层及其制备方法和应用,属于PEM电解水制氢技术领域。本发明提供了一种制备具有贯穿孔道结构的气体扩散层的方法,所述方法包括:将除去环氧树脂的碳纤维与分散剂混合后,依次进行解离、疏解、成型、干燥以及压片,得到碳纸前驱体;将碳纸前驱体浸入含树脂、模板扩孔剂和导电剂的浸渍液中浸渍后,依次进行干燥和热压固化,得到碳纸前体;对碳纸前体依次进行高温碳化、去除模板扩孔剂、石墨化以及表面疏水化,得到具有贯穿孔道结构的气体扩散层。所述方法采用硬模板法在气体扩散层制备过程中使其内部形成贯穿的孔道结构,有效降低其内部孔道的迂回度,从而提升PEM电解槽的电化学性能。
Absstract of: CN122406272A
本发明公开了一种自支撑电极及其制备方法和应用,属于电化学电解水技术领域,包括如下步骤:采用第一激光对基底进行预处理,获得具有微纳阵列的基底;将金属前驱体溶解,混合均匀,随后滴在具有微纳阵列的基底上,干燥处理,获得负载前驱体的基底;采用第二激光对负载前驱体的基底进行处理,得到负载合金活性层的自支撑电极。本发明提供的方法制备简单,采用双激光工艺耗时短且结合力强,显著提升了催化剂的析氧反应本征活性与长效稳定性,在质子交换膜水电解及大规模制氢等领域具有极高的工业化应用前景。
Absstract of: CN122406275A
一种氧化诱导金属外延浸润制备全包覆负载型材料的方法、全包覆负载型材料及其应用,属于电催化材料技术领域。M’O2@MO2全包覆负载型材料由金红石相氧化物载体MO2和连续覆盖于所述金红石相氧化物载体表面的氧化物外延浸润层M’O2组成。本发明通过将MO2载体材料与可溶性金属源分散于还原性醇类溶剂中,经回流还原沉积得到M’@MO2前驱体,再经氧化热处理形成连续覆盖的M’O2外延浸润层。该方法不依赖气相沉积或真空沉积设备,工艺流程简单,可在较低贵金属用量下实现氧化物载体表面的连续活性氧化物覆盖,提高贵金属活性组分利用效率。所得材料具有良好活性与稳定性,可作为酸性水裂解析氧反应的催化剂。
Absstract of: CN122406258A
本发明涉及电解槽叠堆技术领域,公开了一种电解槽叠堆定位辅助装置和电解槽叠堆定位系统,包括:定位环,设有滑道,滑道沿定位环的径向延伸,滑道贯穿定位环的内周面,定位环用于套设于电解槽;传感器,与定位环连接,传感器至少从定位环的轴向一侧面露出;滑动组件,包括滑块,滑块可滑动地设于滑道内,传感器与滑动组件电连接,滑动组件根据传感器的电信号控制滑块沿滑道移动。本发明实施例的电解槽叠堆定位辅助装置利用传感器检测高空中被吊装的极片的位置,然后在极片落位后利用滑块驱动极片位移,以调节极片的位置,无需反复吊起极片来调节位置,提高电解槽的组装效率以及叠堆精度。
Absstract of: CN122399828A
0001 本发明涉及能源转化技术领域,公开了一种B‑NiMo催化剂的制备方法及在海水析氢中的应用,该方法包括以下步骤:S1、将钼盐和镍盐分别用水溶解制成溶液,然后混合,并进行水热反应;反应完成后的料液进行冷却过滤,滤渣干燥,即为催化剂前驱体;将前驱体分散于水中,加入硼氢化钠进行还原反应,反应完毕后洗涤干燥,得到B‑NiMo催化剂。本发明通过硼氢化钠还原钼酸镍,成功合成了硼掺杂钼酸镍纳米复合材料(B‑NiMo),并将其用作高效水制氢催化剂。该 B‑NiMo 在以四羟基二硼(THDB)为牺牲剂的海水制氢反应中表现出优异的催化性能。
Absstract of: CN122406250A
本发明公开了一种新能源光伏驱动温和电解制氢设备,属于光伏制氢技术领域,包括机身、光伏板和环境感知箱,机身设置作业与维生柜、制氢储氢柜、中枢控制柜、储能柜和液压动力柜;光伏板与储能柜电连接,储能柜向制氢储氢柜供电;环境感知箱向中枢控制柜传输环境数据,中枢控制柜联动液压动力柜调节机身姿态并控制光伏板展开或收回;制氢储氢柜用于温和电解制氢及储氢,作业与维生柜配合完成水源处理和氢气外供。该设备能够提高户外复杂环境下光伏供能、制氢、储氢和运行保障的协同稳定性。
Absstract of: CN122418809A
The invention provides an energy management optimization method, system and device for reducing voltage fluctuation and improving hydrogen production efficiency and a storage medium, the method is based on a wind and light hydrogen production system, the wind and light hydrogen production system comprises a power grid unit, a photovoltaic power generation unit, a wind power generation unit and an electrolytic cell unit, the power grid unit is connected with a node 1, and the node 2 is connected with a node 3; the photovoltaic power generation unit is connected with the node 3, the wind power generation unit is connected with the node 4, the electrolytic cell unit is connected with the node 5, and the node 1, the node 3, the node 4 and the node 5 are respectively connected with the node 2. According to the energy management optimization method provided by the invention, reactive power cannot be reversely charged to the power grid, and photovoltaic power and wind power are prevented from releasing redundant reactive power; the wind-solar hydrogen production system can improve the hydrogen production efficiency by optimizing the voltage of the access point of the electrolytic cell unit; the system can improve the hydrogen production efficiency, optimize the line loss and avoid energy waste.
Absstract of: US20260201577A1
0000 The invention pertains to an electrolysis system with a high-pressure electrolyzer for producing hydrogen (H2) and oxygen (O2) at a nominal pressure (PN). The system includes multiple electrolysis cells, each with two half-cells separated by an ion-permeable membrane, forming an anode chamber and a cathode chamber. An oxygen product line connects to the anode chamber, while a hydrogen product line connects to the cathode chamber. The hydrogen and oxygen product lines lead to respective gas separators. The system features compressed gas accumulators for hydrogen and oxygen, enabling pressurized gas to be supplied to the electrolyzer on both sides, with adjustable primary pressures. The invention also includes a method for operating the system, where the electrolyzer is precharged with pressurized gas, and differential pressures are regulated to ensure efficient operation. This system supports both proton-exchange membrane (PEM) and alkaline electrolysis for high-pressure hydrogen and oxygen production.
Absstract of: US20260201588A1
0000 A chemical plant in which an electrolysis section is arranged to receive at least a portion of a first steam feed and electrolyze it to provide a hydrogen stream and an oxygen-enriched stream. A first heat exchanger is arranged to receive at least a portion of the oxygen-enriched stream and a combustion air stream to transfer heat from the oxygen-enriched stream to the combustion air stream. The heated combustion air stream and at least a portion of an off-gas stream are arranged to be combusted in at least one burner to provide a combusted gas stream. The first heat exchanger is arranged to receive at least a portion of the combusted gas stream and said water stream. The first heat exchanger is arranged to transfer heat from the at least a portion of the combusted gas stream to the water stream to provide a cooled combusted gas stream and a steam stream.
Absstract of: US20260200556A1
A method (100) for transporting hydrogen from a floating wind turbine (10) to a watercraft (11) is proposed in order to transport environmentally friendly energy generated by an offshore wind turbine from the offshore wind turbine to land in a simple and safe manner, wherein hydrogen is provided in a holding tank (31) of a floating wind turbine (10), wherein a watercraft (11) with a transportation tank (36) is positioned at the floating wind turbine (10), wherein the hydrogen is conveyed from the holding tank (31) to the transportation tank (36) by means of a line (35) configured to convey the hydrogen.
Absstract of: US20260202385A1
0000 The invention relates to a gas chromatographic system (1000) for detecting volatile organic compounds in an analyte (320) with a gas chromatograph (100) having an injector for injecting analyte (320), a pre-concentrator (120), a column (140) equipped with a stationary phase (141) and a gas detector (150) configured to detect the analyte (320) component eluted from the column (140). The invention suggests an aggregate (160) having an outlet coupled to the gas chromatograph (100) and being configured to receive and process a hydrogen containing medium (330) for generating hydrogen (310) and supplying the hydrogen (310) to the gas chromatograph (100). The invention further relates to such an aggregate (160) and to a method of operating such a chromatographic system.
Absstract of: US20260200820A1
0000 A system for converting CO<2 >to methanol includes a reverse water gas shift (“RWGS”) reactor configured to receive a first CO<2 >stream and a hydrogen gas stream under a sufficient temperature and a sufficient pressure for an RWGS reaction to proceed. The RWGS reactor outputs an exit stream that includes CO. The system also includes a heat exchanger/condenser in fluid communication with the RWGS reactor configured to remove water from products of the RWGS reaction to form a dried exit stream that includes CO; and a membrane contactor reactor configured to receive a combination of hydrogen, CO<2>, and the dried exit stream. The membrane contactor reactor also configured to output a first output stream including methanol dissolved in a sweep liquid and a second output stream including gaseous H<2>, gaseous CO, gaseous CO<2>, and gaseous methanol.
Absstract of: US20260201582A1
0000 A symmetrical separator membrane for electrolysis of alkaline water and with homogeneous distribution of the pores. The membranes are obtained by dissolving a thermoplastic polymer in a dispersion comprising inorganic filler and organic solvent, degassing the solution, creating a membrane by applying the solution to a permeable medium positioned at the centre, with a double side casting technique in a coagulation bath, washing the membrane with alcohol, and drying the membrane. 0000 The present invention relates to a symmetrical separator membrane for electrolysis of alkaline water and with homogeneous distribution of the pores.
Absstract of: US20260201576A1
Methods and systems related to valorizing carbon dioxide are disclosed. A disclosed system includes a reverse water gas shift (RWGS) reactor, a carbon dioxide source connection fluidly connecting a carbon dioxide source to the RWGS reactor, an electrolyzer having an anode area and a cathode area, and a carbon monoxide source connection fluidly connecting the RWGS reactor to the cathode area. The RWGS reactor is configured to generate, using a volume of carbon dioxide from the carbon dioxide source connection, a volume of carbon monoxide in an RWGS reaction. The electrolyzer is configured to generate, using the electrolyzer and a reduction of the volume of carbon monoxide from the carbon monoxide source connection and an oxidation of an oxidation substrate, a volume of generated chemicals including hydrocarbons, organic acids, alcohol, olefins, or N-rich organic compounds.
Absstract of: WO2026148798A1
The present application provides an electrode frame, a flow field plate assembly, and an electrolytic cell. The electrode frame is applied to the flow field plate assembly, and is provided with an accommodating cavity, a water inlet, a water outlet, and a first flow distribution channel, the accommodating cavity is configured to accommodate a plate mesh, and the water inlet is in communication with the accommodating cavity by means of the first flow distribution channel. The electrode frame further comprises flow distribution rows, each flow distribution row comprises at least two flow distribution members spaced apart, and the first flow distribution channel is internally provided with at least two flow distribution rows.
Absstract of: WO2026151905A1
A method for passively producing hydrogen from a geological formation includes drilling a plurality of lateral wellbores into an iron-rich geological formation from a mother wellbore extending from a surface location. Each of the plurality of lateral wellbores has an inclination along its length of less than 90 degrees. A biocide configured to inactivate hydrogen-consuming microbes is placed into the plurality of lateral wellbores and thereby into formation water that is flowed from the geological formation into the plurality of wellbores. Hydrogen gas effervesced from the formation water in the plurality of lateral wellbores is collected via the mother wellbore. The hydrogen gas is generated at least in part from a water reduction reaction of minerals of the geological formation with the formation water and risen through the plurality of lateral wellbores passively by buoyancy effects without pumping.
Absstract of: US20260201579A1
A hydrogen-producing cell includes a first and second electrode. The first electrode includes a cathode that includes a nickel single-atom graphdiyne porphyrin analogue (Ni-SGPA) catalyst material deposited on a substrate and the second electrode that includes an anode and a reference electrode. The electrolyte includes H2SO4. The cell also includes an electric power supply for applying a pulsed voltage between the foil and a reference electrode and counter electrode. Another hydrogen-producing cell includes a first and second electrode. The first electrode includes a cathode that includes a nickel single-atom graphdiyne porphyrin analogue (Ni-SGPA) catalyst material deposited on a substrate and the second electrode includes an anode and a reference electrode. The electrolyte includes KOH. The cell also includes an electric power supply for applying a pulsed voltage between the foil and a reference electrode and counter electrode.
Absstract of: AU2025211056A1
The purpose of the present disclosure is to provide an electrolytic cell stack capable of increasing the amount of product generated by electrolysis while suppressing the temperature rise of the cell stack. An electrolytic cell stack (101) according to the present disclosure comprises: an electrolysis unit cell (105) that has a hydrogen electrode containing Ni, an oxygen electrode, and a solid electrolyte membrane and is formed in the circumferential direction of a base tube; and an interconnector that electrically connects a plurality of electrolysis unit cells arranged in the axial direction of the base tube. When the distance between the ends of the oxygen electrode, oriented in the axial direction of the base tube, in each electrolysis unit cell is defined as the width W of the electrolysis unit cell, and the area on the base tube in which the plurality of electrolysis unit cells are arranged is divided into a first end portion (10), a central portion (11), and a second end portion (12) along the axial direction, the widths W1, W3 of the electrolysis single cells (105b, 105c) positioned in the first end portion and/or the second end portion is 1.5 to 3 times greater than the width W2 of the electrolysis unit cell (105a) positioned in the central portion.
Absstract of: AU2024420375A1
The purpose of the present invention is to improve the safety of a hydrogen production plant. This hydrogen production plant (1) comprises: a solid oxide electrolysis cell (SOEC) (10) which produces a hydrogen-containing gas; and a discharge stack (30) into which the hydrogen-containing gas produced by the SOEC (10) is introduced and which discharges the introduced hydrogen-containing gas to air. The discharge stack (30) has a spray unit (32) which supplies, to the hydrogen-containing gas introduced therein, cooling water for cooling the hydrogen-containing gas.
Absstract of: WO2026151470A1
Systems and methods for generating hydrogen. The method includes activating an aluminum composition via alloying with at least one metal, reacting the activated aluminum composition in an aqueous ionic solution to produce hydrogen, and adding a catalyst to the aqueous ionic solution and the activated aluminum composition to increase the reaction rate between the activated aluminum composition and the aqueous ionic solution.
Absstract of: US20260201821A1
A thermal energy storage system with fluid flow insulation, the system including heated thermal storage blocks positioned within a housing, and a method for operating the thermal energy storage system, including providing a flow of fluid into the housing, the fluid convectively extracting heat from a top region, a side region and a bottom region of the thermal energy storage system, to generate heated fluid that insulates the thermal storage blocks from the housing and a foundation of the thermal energy storage system.
Absstract of: US20260201572A1
0000 A reactor is configured to electrochemically convert hydrogen sulfide to produce hydrogen. The reactor includes a first shell, a second shell, a hydrogen-permeable electrode, and a check valve. The first shell defines a first chamber. The first shell defines a first inlet for water, a second inlet for hydrogen sulfide, and a first outlet for hydrogen sulfide. The second shell defines a second chamber isolated from the first chamber. The second chamber stores hydrogen molecules. The hydrogen-permeable electrode is at least partially disposed within the first chamber. The hydrogen-permeable electrode is permeable to hydrogen atoms originating from the hydrogen sulfide. The check valve allows flow of hydrogen molecules, formed from the hydrogen atoms that have permeated into the hydrogen-permeable electrode, into the second chamber while preventing flow of hydrogen molecules back out from the second chamber through the check valve.
Absstract of: WO2026150031A1
The disclosure relates to efficient systems (10, 100) and methods for green-hydrogen production. A system (10) for off-grid green-hydrogen production is provided, the system (10) comprising: a renewable-energy source module (1) configured to provide power from one or more renewable-energy sources, an electrolyser module (2) configured to produce green hydrogen based on the power provided by the renewable-energy source module (1), a grid-forming energy-storage module (3) configured to provide grid-forming capabilities to the renewable-energy source module (1) and the electrolyser module (2), a plurality of power-converter modules (C1, C2, C3) configured to allow power flow between the renewable-energy source module (1), the electrolyser module (2), and the grid-forming energy-storage module (3), which are electrically connected to each other, and a central controller (5) configured to control the power flow by controlling the plurality of power-converter modules (C1, C2, C3).
Absstract of: WO2026151283A1
The present invention provides an AEM water electrolysis system comprising: an electrolytic cell; a cathode separator provided downstream of the electrolytic cell; a degassing device provided downstream of the cathode separator; and an anode separator provided downstream of the degassing device, wherein hydrogen of a KOH solution discharged from a cathode of the electrolytic cell is degassed through the cathode separator and the degassing device, and the KOH solution is continuously supplied to the electrolytic cell through the anode separator.
Absstract of: WO2026151653A1
A cation exchange membrane (CEM)-based electro-synthesizer unit, and process of using same, is described, wherein CEM-based electro-synthesizer unit can be coupled to an air contactor, which can scrub carbon dioxide from any air source, and an acid-base neutralizer, which can release the scrubbed carbon dioxide as a pure gas stream. The overall system and process of using same can continuously and efficiently separate CO2 from any air source (i.e., carbon capture).
Absstract of: DE102025101252A1
Reaktionszelle (1) zur solaren Molekülspaltung, die Reaktionszelle (1) aufweisend:- eine Sandwichstruktur (2), gebildet aus einem Bodenelement (3) und einem lichtdurchlässigen Deckelement (4),- eine innerhalb der Sandwichstruktur (2) angeordnete Elektrode (5), ausgebildet zur solaren Molekülspaltung,- eine Zuführeinrichtung (6), ausgebildet zur Zufuhr eines Elektrolyten (7) zu der Elektrode (5), und- eine Abführeinrichtung (8), ausgebildet zur Ableitung eines Reaktionsprodukts (10).
Absstract of: US20260202368A1
A determination device determines deterioration of an electrolyte membrane in an electrochemical device including an electrochemical cell and a volume portion in which gas generated by the electrochemical cell collects. The determination device includes a deterioration determination unit that determines whether or not the electrolyte membrane has deteriorated based on a detection signal of a detection sensor for detecting a current flowing between a first electrode and a second electrode, an output signal of a pressure sensor for detecting a pressure in the volume portion, a gas generation amount calculated from the current, and the pressure in the volume portion.
Absstract of: US20260200730A1
0000 Metal borohydride, Me(BH<4>)
Absstract of: US20260204593A1
0000 Aspects of the disclosure include a bipolar plate assembly for an electrolysis cell (electrolyzer). An exemplary bipolar plate assembly for an electrolyzer includes an anode half plate having one or more intake headers, an anode-side flow field coupled to the one or more intake headers, and one or more outtake headers coupled to the anode-side flow field. The anode-side flow field is a dimple flow field having a series of dimples. The bipolar plate assembly further includes a cathode half plate coupled to the anode half plate, the cathode half plate having one or more outtake headers and a cathode-side flow field coupled to the one or more outtake headers. The cathode-side flow field is a land channel flow field having alternating lands and channels.
Absstract of: US20260192290A1
A photocatalytic composite material and a method for manufacturing the same. The photocatalytic composite material includes an inorganic semiconductor particle, an organic semiconductor layer, and an electron-transfer interlayer. The inorganic semiconductor particle is formed of a metal-oxide semiconductor material. The organic semiconductor layer is formed from a conjugated polymer and surrounds an outer periphery of the inorganic semiconductor particle. The electron-transfer interlayer includes a noble metal dispersed, in the forms of single atoms or nanoclusters, on a surface of the inorganic semiconductor particle, and bridges between the inorganic semiconductor particle and the organic semiconductor layer so as to form electron-transport channels.
Absstract of: US20260201585A1
A manufacturing process determination method for a determination target molecule includes obtaining an isotope ratio δD of deuterium to protium contained in the determination target molecule; and determining that the determination target molecule is a molecule produced using a method including electrolyzing for generating hydrogen molecules by electrolysis of a liquid containing water when the isotope ratio δD is less than or equal to a predetermined threshold value.
Absstract of: US20260199877A1
0000 A process for removing hydrogen from an oxygen gas stream includes electrolysing water in an electrolyser to generate a hydrogen-rich stream and an oxygen-rich stream. The oxygen-rich stream includes hydrogen. The process also includes feeding the oxygen-rich stream to a reactor having a gold-containing catalyst and contacting, in the reactor, the oxygen-rich stream with the gold-containing catalyst. The gold-containing catalyst includes gold and a second metal on an oxidic support and an oxygen partial pressure of the oxygen-rich stream in the reactor is greater than 1 bar.
Nº publicación: US20260201578A1 16/07/2026
Applicant:
THYSSENKRUPP NUCERA AG & CO KGAA [DE]
thyssenkrupp nucera AG & Co. KGaA
Absstract of: US20260201578A1
0000 Electrolyser stack and production unit are provided, in which the electrolyser stack include endplates and pull rods extending between the endplates. Feet are arranged at the endplates whereby each foot includes a downwardly directed support surface arranged to abut onto a production unit track or handling unit track whereby the production unit tracks are arranged to extend in parallel with the length axis of the electrolyser stack and whereby the electrolyser stack is movable along the production unit track by sliding the feet along upward facing horizontal slide tracks of the production unit track.