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Absstract of: AU2024357209A1
The invention relates to a method for synthesizing ammonia, having the steps of: - providing hydrogen; - supplying the hydrogen to an ammonia synthesis circulator (10) comprising an ammonia converter (3) in which ammonia is catalytically synthesized; a circulator (1) which supplies a reactant gas mixture, containing the hydrogen and nitrogen, to the ammonia converter (3); and a cooling section (5) in which ammonia is condensed out of a product gas mixture of the ammonia converter (3), wherein the ammonia synthesis circuit (10) is first operated in a full-load operation, in which the ammonia synthesis circuit (10) provides a nominal flow rate of hydrogen, and the ammonia synthesis circuit (10) is converted from the full-load operation to a partial-load operation, in which the ammonia synthesis circuit (10) provides a flow rate of hydrogen which is lower than the nominal flow rate. In the partial-load operation, a first gas flow is branched off from the reactant gas flow and is conducted to the inlet of the circulator (1), and a second gas flow is branched off from the product gas mixture and is conducted to the inlet of the circulator (1).
Absstract of: DE102024128720A1
Die Anmeldung betrifft Iridium-beschichtete Platinnanopartikel mit einem Iridiumgehalt der Iridium-beschichteten Platinnanopartikel von 1 bis 40 Gewichts-% bezogen auf das Gesamtgewicht der Iridium-beschichteten Platinnanopartikel, sowie ein Verfahren zur Wasserstoff-getriebenen Abscheidung von Iridium auf Platinoberflächen, insbesondere von Platinnanopartikeln, dadurch gekennzeichnet, dass die Oberfläche von Platinnanopartikeln in einem sauren flüssigen Reaktionsmedium in Anwesenheit von H2-Gas mit Ir-Kationen in Kontakt gebracht wird. Außerdem betrifft die Anmeldung die Anwendung von Irbeschichteten Pt-Nanopartikeln und nicht aus Platin bestehenden Trägermaterialien mit Iridium-beschichteten Pt-Oberflächen in elektrochemischen Vorrichtungen.
Absstract of: AU2024340468A1
The present invention relates to an ammonia synthesis plant having a hydrogen device and a synthesis circuit, wherein the synthesis circuit has a conveying device, a converter and a first bypass line. The hydrogen device is designed to provide hydrogen. The conveying device is designed to cyclically convey a gas mixture, containing nitrogen, hydrogen and ammonia, in a synthesis circuit conveying direction, wherein the conveying device has a suction side and a pressure side. The converter is designed to catalytically convert nitrogen and hydrogen at least partially into ammonia, wherein the converter has an inlet and an outlet, wherein the inlet of the converter is fluidically connected to the pressure side of the conveying device and the outlet of the converter is fluidically connected to the suction side of the conveying device. The first bypass line is arranged from the suction side of the conveying device to the pressure side of the suction device parallel to the conveying device in the fluidically opposite direction and is designed for the stoppable return of a first partial stream of the gas mixture from the pressure side of the conveying device to the suction side of the conveying device, wherein the first bypass line has a cooling device which is designed to cool the first partial stream of the gas mixture. The first bypass line has a second bypass line, which is arranged parallel to the cooling device in the fluidically same direction, and which is designed for the st
Absstract of: AU2024352615A1
The invention relates to an electrolysis system (100) comprising: a wind turbine (1); an electrolysis plant (5) which is connected to the wind turbine (1) in order to supply electrolysis current, wherein an island network is implemented without connection to a power supply network; and a heat supply device (7) which is coupled to the electrolysis plant (5) and can be operated with a working medium (23), and which has an evaporator (13) and a condenser (11), and which is designed in such a way that, during a standstill mode, condensation heat of the working medium (23) can be transferred to the electrolysis plant (5) by means of the condenser (11) so as to maintain the temperature above a minimum temperature. During a standstill mode, the heat supply device (7) evaporates a working medium and condenses the evaporated working medium (23), condensation heat being generated and transferred to the electrolysis plant (5) so as to maintain the temperature above a minimum temperature and prevent freezing of water-carrying components of the electrolysis plant (5).
Absstract of: AU2024352319A1
The invention relates to an offshore electrolysis system (100) comprising: a wind turbine (1) having a platform (3) and an electrolysis plant (5) which is arranged on the platform (3) and is connected to the wind turbine (1) in order to supply electrolysis current; and a water supply device (7) which is connected to the electrolysis plant (5) and has a water collector (13) which is designed such that it is possible, without relying on seawater, to obtain water with little or no salt content which can be used as feed water for operating the electrolysis plant (5). The invention also relates to a method for operating a corresponding offshore electrolysis system (100), wherein, without relying on seawater, water is obtained in a water collector (13), the obtained water being of a quality with little or no salt content.
Absstract of: AU2024351803A1
The invention relates to a modular electrolysis system comprising multiple modules, wherein each of the multiple modules comprises a support frame and at least one interface accessible from outside the support frame and configured to connect the module with at least one of the remaining modules, the multiple modules comprising a water-gas coarse separation module downstream an anode outlet of the electrolysis cell module, and a water-gas fine separation module downstream a liquid outlet of the water-gas coarse separation module.
Absstract of: AU2024350634A1
According to the invention it is provided a method for controlling a grid connected power converter having a DC side with a DC link and an AC grid side, and being configured to control power supply to a hydrogen electrolyzer stack. The power supply to the hydrogen electrolyzer stack is controlled by controlling the DC link to thereby control hydrogen production. The method comprises: determining a grid voltage reference; providing a grid forming control for controlling at least the phase angle of the voltage of the power converter using a grid forming controller, operating according to a grid forming algorithm, the grid forming controller being configured to emulate inertia through control of the voltage of the power converter towards the grid voltage reference; the grid forming controller emulating inertia by charging and discharging an inherent capacitance of the electrolyzer stack; monitoring at least one operating parameter of the hydrogen electrolyzer stack; and limiting a change in charging level of the inherent capacitance based on the monitored operating parameter of the electrolyzer stack.
Absstract of: EP4723419A1
0001 The invention relates to a method for controlling an electrolyzing plant (10, 14) having at least two electrolyzing devices (16, 26), wherein the electrolyzing devices comprise a first and a second electrolyzing device, the method comprising: - converting an alternating voltage of an electric power network (12) into an electrolyzing voltage, wherein converting is affected by an electric converter (22, 24) connected with the electric power network at a connection point (20), - detecting an electric quantity with a sensor (36) at the connection point (20), wherein the electric quantity is indicative for a specific network condition, - comparing the sensor signal (42) with at least one predetermined reference value, and - dependent on a comparing result, a consumed electric power of the at least one first electrolyzing device is reduced and a consumed electric power of the at least one second electrolyzing device is maintained.
Absstract of: WO2024249360A2
A power generation system includes a housing, a lid defining an opening in the housing, and a chamber inside the housing configured to receive a cartridge comprising a powdered fuel mixture. The system also includes a fluid reservoir that stores a fluid configured to react with the powdered fuel mixture to produce hydrogen gas. A processor is configured to control ingress of the fluid from the fluid reservoir to the powdered fuel mixture in the cartridge and control egress of the gas from the cartridge to the gas storage compartment. The system also includes a generator configured to generate electricity from the gas in the gas storage compartment.
Absstract of: EP4722148A1
0001 Provided is an ammonia decomposition apparatus capable of achieving both an improved conversion of ammonia and an improved life of a catalyst. 0002 An ammonia decomposition apparatus (11) includes an ammonia gas inlet (13), a catalyst-supporting honeycomb structure (1) that decomposes ammonia to produce hydrogen and nitrogen, and a gas outlet (14). The catalyst-supporting honeycomb structure (1) includes a ceramic honeycomb structure, a catalyst layer 3 formed in a flow channel (2a) of the honeycomb structure and decomposes ammonia, and a pair of electrodes (4a and 4b) formed on lateral surfaces of the honeycomb structure. A current is applied to the honeycomb structure.
Absstract of: EP1000000A1
The invention relates to an apparatus (1) for manufacturing green bricks from clay for the brick manufacturing industry, comprising a circulating conveyor (3) carrying mould containers combined to mould container parts (4), a reservoir (5) for clay arranged above the mould containers, means for carrying clay out of the reservoir (5) into the mould containers, means (9) for pressing and trimming clay in the mould containers, means (11) for supplying and placing take-off plates for the green bricks (13) and means for discharging green bricks released from the mould containers, characterized in that the apparatus further comprises means (22) for moving the mould container parts (4) filled with green bricks such that a protruding edge is formed on at least one side of the green bricks.
Absstract of: EP4723255A1
0001 A purpose of the present invention is to provide: an electrolyte membrane for a polymer electrolyte fuel cell, said electrolyte membrane having excellent proton conductivity; a membrane electrode assembly that includes the electrolyte membrane for the polymer electrolyte fuel cell; a polymer electrolyte fuel cell that includes the membrane electrode assembly; methods for producing the electrolyte membrane for a polymer electrolyte fuel cell, the membrane electrode assembly, and the polymer electrolyte fuel cell; and an electrolyte membrane for solid polymer water electrolysis. 0002 The electrolyte membrane for a polymer electrolyte fuel cell according to the present invention contains fine fibrous cellulose that is derived from wood or plants, wherein the average fiber width of the fine fibrous cellulose that is derived from wood or plants is 50 nm or less, and the fine fibrous cellulose has a phosphorus oxoacid group.
Absstract of: EP1000000A1
The invention relates to an apparatus (1) for manufacturing green bricks from clay for the brick manufacturing industry, comprising a circulating conveyor (3) carrying mould containers combined to mould container parts (4), a reservoir (5) for clay arranged above the mould containers, means for carrying clay out of the reservoir (5) into the mould containers, means (9) for pressing and trimming clay in the mould containers, means (11) for supplying and placing take-off plates for the green bricks (13) and means for discharging green bricks released from the mould containers, characterized in that the apparatus further comprises means (22) for moving the mould container parts (4) filled with green bricks such that a protruding edge is formed on at least one side of the green bricks.
Absstract of: WO2024249360A2
A power generation system includes a housing, a lid defining an opening in the housing, and a chamber inside the housing configured to receive a cartridge comprising a powdered fuel mixture. The system also includes a fluid reservoir that stores a fluid configured to react with the powdered fuel mixture to produce hydrogen gas. A processor is configured to control ingress of the fluid from the fluid reservoir to the powdered fuel mixture in the cartridge and control egress of the gas from the cartridge to the gas storage compartment. The system also includes a generator configured to generate electricity from the gas in the gas storage compartment.
Absstract of: WO2024249360A2
A power generation system includes a housing, a lid defining an opening in the housing, and a chamber inside the housing configured to receive a cartridge comprising a powdered fuel mixture. The system also includes a fluid reservoir that stores a fluid configured to react with the powdered fuel mixture to produce hydrogen gas. A processor is configured to control ingress of the fluid from the fluid reservoir to the powdered fuel mixture in the cartridge and control egress of the gas from the cartridge to the gas storage compartment. The system also includes a generator configured to generate electricity from the gas in the gas storage compartment.
Absstract of: EP4721857A1
Provided is a catalyst-supporting honeycomb structure capable of achieving both an improved conversion of ammonia and an improved life of a catalyst.A catalyst-supporting honeycomb structure (1) includes a ceramic honeycomb structure (2), a catalyst layer (3) that is formed in a flow channel (2a) of the honeycomb structure (2) and decomposes ammonia, and electrodes (4a, 4b) each formed on a lateral surface of the honeycomb structure (2). A current is applied to the honeycomb structure (2).
Absstract of: WO2024249360A2
A power generation system includes a housing, a lid defining an opening in the housing, and a chamber inside the housing configured to receive a cartridge comprising a powdered fuel mixture. The system also includes a fluid reservoir that stores a fluid configured to react with the powdered fuel mixture to produce hydrogen gas. A processor is configured to control ingress of the fluid from the fluid reservoir to the powdered fuel mixture in the cartridge and control egress of the gas from the cartridge to the gas storage compartment. The system also includes a generator configured to generate electricity from the gas in the gas storage compartment.
Absstract of: EP1000000A1
The invention relates to an apparatus (1) for manufacturing green bricks from clay for the brick manufacturing industry, comprising a circulating conveyor (3) carrying mould containers combined to mould container parts (4), a reservoir (5) for clay arranged above the mould containers, means for carrying clay out of the reservoir (5) into the mould containers, means (9) for pressing and trimming clay in the mould containers, means (11) for supplying and placing take-off plates for the green bricks (13) and means for discharging green bricks released from the mould containers, characterized in that the apparatus further comprises means (22) for moving the mould container parts (4) filled with green bricks such that a protruding edge is formed on at least one side of the green bricks.
Absstract of: EP1000000A1
The invention relates to an apparatus (1) for manufacturing green bricks from clay for the brick manufacturing industry, comprising a circulating conveyor (3) carrying mould containers combined to mould container parts (4), a reservoir (5) for clay arranged above the mould containers, means for carrying clay out of the reservoir (5) into the mould containers, means (9) for pressing and trimming clay in the mould containers, means (11) for supplying and placing take-off plates for the green bricks (13) and means for discharging green bricks released from the mould containers, characterized in that the apparatus further comprises means (22) for moving the mould container parts (4) filled with green bricks such that a protruding edge is formed on at least one side of the green bricks.
Absstract of: US2025091862A1
A plant, such as a hydrocarbon plant, is provided, which has a syngas stage for syngas generation and a synthesis stage where the syngas is synthesized to produce syngas derived product, such as hydrocarbon product. The plant makes effective use of various streams; in particular, CO2 and H2. The plant does not comprise an external feed of hydrocarbons. A method for producing a product stream, such as a hydrocarbon product stream is also provided.
Absstract of: CN222499404U
The utility model provides an AEM water electrolysis electrode and a water electrolysis device. The AEM water electrolysis electrode comprises a catalyst carrier, the catalyst is formed on the catalyst carrier; the gas dredging channel is arranged on the catalyst carrier, and at least part of the surface of the catalyst carrier is exposed through the gas dredging channel. The water electrolysis electrode provided by the utility model can be applied to a water electrolysis device, and has the advantages of high catalytic activity and low energy consumption.
Absstract of: WO2024261365A1
The invention relates to a method for producing and storing hydrogen by means of heterogeneous catalytic electrolysis and to a device for the method. The invention specifically concerns the electrolysis of freshwater or seawater (H2O) by means of direct current using electrodes (6, 7) having a structure defined by a porous substrate (8), preferably activated carbon, and a semiconductor formed by a coating layer (9) of oxides, nitrides or hydroxides of transition metals, preferably titanium dioxide, with a valence band energy level substantially below the oxidation potential of H2O and a conduction band energy level above the reduction potential of hydrogen in the standard hydrogen electrode (SHE), allowing dynamic H2 generation and static H2 generation involving simultaneous storage with cumulative electronic capacitance.
Absstract of: WO2025061814A1
The invention relates to a system and method for controlling the operation of the gas-liquid separators (GLSan, GLSca) of an electrolyser comprising a stack (10), and anode and cathode gas-liquid separators that separate the electrolyte and the gas along an alkaline solution level (lan, lca), wherein the dioxygen and dihydrogen gases flow from their respective chambers through a gas control valve (V <sb /> an <sb />, V <sb /> ca <sb />), such that the control system uses control data representative of the anode gas pressure (p <sb /> an <sb />), the cathode gas pressure (p <sb /> an <sb />), the anode alkaline solution level (lan) and the cathode alkaline solution level (lca) to control each of the two gas control valves (V <sb /> an <sb /> , V <sb /> ca <sb /> ), and wherein each of the sensors transmits operating signals to the two gas control valves (Van, Vca) in order to control the gas pressures (p <sb /> an <sb />, p <sb /> ca <sb />) and the alkaline solution levels (lan, lca) in the anode gas-liquid separator (GLSan) and the cathode gas-liquid separator (GLSca).
Absstract of: WO2026072650A1
An apparatus for generation of carbon dioxide and hydrogen a saline water source are disclosed. The apparatus may include an anodic compartment having an inlet and an outlet, an anode disposed on a first side of the anodic compartment, a cathodic compartment having an inlet and an outlet, a cathode disposed on a first side of the cathodic compartment, a first cation permeable fluidic separator disposed on a second side of the anodic compartment, a second cation permeable fluidic separator disposed on a second side of the cathodic compartment, a center compartment defined between the first cation permeable fluidic separator and the second cation permeable fluidic separator, and a source of acidic catholyte that is one of fluidly connectable to or in fluid communication with the inlet of the cathodic compartment. Methods of generating hydrogen, carbon dioxide, and oxygen from seawater using the apparatus are also disclosed.
Absstract of: US20260092378A1
Water electrolysis installation, comprising of an electrochemical stack device comprising at least a stack having at least two electrodes immersed in an electrolyte; a balance of plant defining an inner fluid handling volume of the balance of plant to convey an incoming fluid to the electrochemical stack device and to recover an outcoming fluid from the electrochemical stack device; at least one sensor comprising at least one optical fiber probe having a sensing region, the sensing region measuring at least an information representative of sludge formation in the vicinity of the sensor; characterized in that the sensing region of the optical fiber probe is located inside the inner fluid handling volume of the balance of plant outside of the electrochemical stack device.
Absstract of: WO2026071256A1
This ion exchange membrane comprises: a sulfonic acid-type membrane body containing a polymer having a sulfonic acid group; and a reinforcing material disposed inside the sulfonic acid-type membrane body. The sulfonic acid-type membrane body has a first surface having a surface roughness R1 of 10 μm or more. The sulfonic acid-type membrane body also has a second surface having a surface roughness R2 of 10 μm or more.
Absstract of: WO2026064984A1
The present application relates to the technical field of water electrolysis for hydrogen production and discloses a hydrogen removal layer, a preparation method therefor, a hydrogen removal proton exchange membrane, a membrane electrode, and a water electrolysis hydrogen production apparatus. The hydrogen removal layer comprises the following components in parts by weight: 10-20 parts of a metal oxide, 10-20 parts of a catalyst, and 2-10 parts of an ionomer. The catalyst comprises at least one of a platinum black catalyst, an iridium black catalyst, and a palladium black catalyst. The hydrogen removal layer described in the present application can effectively reduce the hydrogen content in oxygen on the anode side of a proton exchange membrane.
Absstract of: DE102024128012A1
Verfahren zum Betreiben einer Wasserstoffproduktionsanlage (10) mit mehreren Elektrolysevorrichtungen (11), die zur Erzeugung von Wasserstoff aus Wasser mit Hilfe von elektrischem Strom eingerichtet sind, wobei die Elektrolysevorrichtungen (11) vorzugsweise mehrere parallel geschaltete Kaskaden (12) aus jeweils in Reihe geschalteten Elektrolysevorrichtungen (11) bilden, wobei zur Wasserstoffproduktion die Elektrolysevorrichtungen (11) über einen Wasserkreislauf (13) mit Wasser versorgt werden, wobei zur Wasserstoffproduktion die Elektrolysevorrichtungen (11) von einer elektrischen Stromquelle oder elektrischen Spannungsquelle mit elektrischer Leistung versorgt werden. Zur Überprüfung, ob an einer Elektrolysevorrichtung (11) eine Wasserstoffleckage vorliegt, werden folgende Schritte einer Sicherheitsroutine ausgeführt werden: Die zu überprüfende Elektrolysevorrichtung (11) wird mit einer definierten elektrischen Eingangsgröße beaufschlagt. An der zu überprüfenden Elektrolysevorrichtung (11) wird eine von der definierten elektrischen Eingangsgröße abhängige, elektrische Ist-Ausgangsgröße erfasst. Die an der zu überprüfenden Elektrolysevorrichtung (11) erfasste Ist-Ausgangsgröße wird mit einer Soll-Ausgangsgröße verglichen. Abhängig von dem Vergleich der Ist-Ausgangsgröße mit der Soll-Ausgangsgröße wird auf eine Wasserstoffleckage oder die Wahrscheinlichkeit einer Wasserstoffleckage an der Elektrolysevorrichtung (11) geschlossen.
Absstract of: AU2024352604A1
The invention relates to an offshore electrolysis system (100) comprising: a wind turbine (1) with a platform (3) and with an electrolysis plant (5) which is arranged on the platform (3) and is connected to the wind turbine (1) in order to supply electrolysis current; and a heat supply device (7) which is coupled to the electrolysis plant (5) and is designed in such a way that heat can be transferred to the electrolysis plant by means of the heat supply device (7) during a standstill mode so as to maintain the temperature above a minimum temperature. The invention also relates to a method for operating a corresponding offshore electrolysis system. During a standstill mode, heat is transferred to the electrolysis plant (5) by means of the heat supply device (7) so as to maintain the temperature above a minimum temperature and prevent freezing of water-carrying components of the electrolysis plant (5).
Absstract of: US20260091976A1
A thermochemical gas splitting reactor system and a method of splitting gas are disclosed. The system includes a reactor including a reaction zone comprising active material, a gas heating zone, and a gas distribution plate assembly interposed between the reaction zone and the gas heating zone. Exemplary systems can include multiple reactors. The method can include providing one or more reactors and performing one or more of an oxidation and/or reduction process using each of the reactors.
Absstract of: US20260094846A1
An electrochemical cell is disclosed having a porous metal support, a gas transport layer on the porous metal support, and an electrode layer on the gas transport layer. The gas transport layer is electrically conductive and has an open pore structure comprising a pore volume fraction of 20% by volume or higher and wherein the electrode layer has a pore volume fraction lower than the pore volume fraction of the gas transport layer. Also disclosed is a stack of such electrochemical cells and a method of producing such an electrochemical cell.
Absstract of: US20260091374A1
The present invention relates to a catalyst comprising Ni, Ru, and a promoter metal M1, wherein the catalyst displays an Ru:Ni weight ratio in the range of from 0.0001:1 to 0.5:1, wherein the promoter metal M1 is selected from the group consisting of Li, K, Na, Cs, Mg, Ca, Sr, and Ba, including mixtures of two or more thereof, and wherein the catalyst further comprises one or more support materials onto which Ni, Ru, and the promoter metal M1 are respectively supported. Furthermore, the present invention relates to a method for the preparation of a catalyst comprising Ni, Ru, and a promoter metal M1, as well as to a catalyst obtainable according to said method, and to a process for the reforming of ammonia employing the inventive catalyst.
Absstract of: WO2026072487A1
Systems and methods are provided for conversion of renewable power into hydrocarbons, such as hydrocarbon fuels, via a methanol intermediate. In addition, it is desired to capture and reuse carbon dioxide in order to form these hydrocarbons. When the conversion of carbon dioxide is performed using hydrogen generated by electrolysis (preferably from renewable electricity), the management of process water is beneficial for reducing or minimizing the overall water requirements for the process as well as extending the lifetime of the electrolyzers. Systems and methods are also provided for recovery and purification of process water for recycle to the electrolyzers.
Absstract of: US20260091373A1
In a method of preparing an ammonia decomposition catalyst according to embodiments of the present disclosure, a mixture of a metal oxide including lanthanum and a heterogeneous metal and aluminum oxide is prepared, the mixture was subjected to steam treatment to form a carrier, and a catalytically active metal is supported on the carrier to prepare an ammonia decomposition catalyst. The ammonia decomposition catalyst according to embodiments of the present disclosure is prepared by the above-described preparation method.
Absstract of: WO2026066209A1
Provided are a charged ligand post-modified photocatalyst, a preparation method therefor, and a use thereof, relating to the field of photocatalysis. A zirconium salt and 1,3,5-tris(4-carboxyphenyl)benzene are dissolved in N,N-dimethylformamide, and then formic acid is added to obtain Zr-BTB; Zr-BTB and a potassium chloroplatinate solution are added to ethanol to implement a reaction to obtain Zr-BTB@Pt; and Zr-BTB@Pt and a quaternary ammonium salt ligand are added to methanol to implement a reaction to obtain Zr-BTB@Pt-NH4 +. When used in a photocatalytic reaction, the prepared Zr-BTB@Pt-NH4 + can significantly improve the hydrogen production efficiency of a photocatalytic material.
Absstract of: WO2026066212A1
The present disclosure belongs to the technical field of material synthesis and utilization of renewable clean energy, and provides a red titanium dioxide heterojunction, and a preparation method therefor and the use thereof. The preparation method for a red titanium dioxide heterojunction comprises: forming a first precursor of B-doped titanium dioxide; calcining the first precursor at a high temperature to obtain a second precursor of a B-doped titanium dioxide heterojunction; and mixing any one of (NH4)2TiF6, NH4TiOF3 and (NH4)2TiOF4 with the second precursor, followed by a nitridation treatment in an ammonia gas flow to obtain a red titanium dioxide heterojunction uniformly doped with a rutile phase and an anatase phase. In the present disclosure, titanium dioxide in a rutile phase can be nitrided by means of an ammonium fluotitanate treatment, such that a red titanium dioxide heterojunction uniformly doped with both a rutile phase and an anatase phase is formed, which heterojunction exhibits relatively high water oxidation activity in a photocatalytic water decomposition reaction.
Absstract of: WO2026069743A1
To safely and easily burn hydrogen. A combustion device comprises: a hot water generation unit 1 provided with a storage unit 112 for storing water, an arrangement unit 113 for arranging a solid fuel that reacts with the water within the storage unit 112 to discharge hydrogen, and a combustion unit for burning the generated hydrogen; and a control unit for controlling the water temperature of the stored water.
Absstract of: DE102024209677A1
Die Erfindung betrifft einen Gas-Flüssigkeitsseparator (1) zum Abscheiden von Gasen aus einem Gas-Flüssigkeitsgemisch für ein Elektrolysesystem, aufweisend einen im Querschnitt kreisrunden Grundkörper (2) mit einem Einlass (3) für das Gas-Flüssigkeitsgemisch sowie mit einem Gasauslass (4) und einem Flüssigkeitsauslass (5). Erfindungsgemäß ist der Einlass (3) für das Gas-Flüssigkeitsgemisch tangential in Bezug auf den Grundkörper (2) angeordnet und der Grundkörper (2) weist eine Temperiereinrichtung (6) auf.
Absstract of: AU2024349761A1
The invention relates to an offshore electrolysis system (100) comprising: a wind turbine (1) with a platform (3) and with an electrolysis plant (5) which is arranged on the platform (3) and is connected to the wind turbine (1) in order to supply electrolysis current; and a heat supply device (7) which is coupled to the electrolysis plant (5) and has a combustion device (13), wherein a fuel reservoir (15) is connected to the heat supply device (7) such that, during a standstill mode, heat generated by means of the combustion device (13) can be transferred to the electrolysis plant (5) so as to maintain the temperature above a minimum temperature. The invention also relates to a method for operating a corresponding offshore electrolysis system (100), wherein, during a standstill mode, heat is generated by means of the heat supply device (7) and transferred to the electrolysis plant (5) so as to maintain the temperature above a minimum temperature and prevent freezing of water-carrying components of the electrolysis plant (5).
Absstract of: DE102024209486A1
Die Erfindung betrifft eine Elektrolyseanlage (1) für die Zerlegung von Wasser in Wasserstoff und Sauerstoff umfassend einen Elektrolysestapel (2) mit einer ersten Elektrodenseite (3) und einer zweiten Elektrodenseite (4), einen ersten Separator (5), eine von der ersten Elektrodenseite (3) des Elektrolysestapels (2) abzweigende und in den ersten Separator (5) mündende erste Sammelleitung (6) und eine vom ersten Separator (5) abzweigende und in die erste Elektrodenseite (3) des Elektrolysestapels (2) mündende erste Flüssigkeitszirkulationsleitung (7) mit einem ersten Flüssigkeitszirkulationsventil (8), weiter umfassend einen zweiten Separator (9), eine von der zweiten Elektrodenseite (4) des Elektrolysestapels (2) abzweigende und in den zweiten Separator (9) mündende zweite Sammelleitung (10) und eine vom zweiten Separator (9) abzweigende und in die zweite Elektrodenseite (4) des Elektrolysestapels (2) mündende zweite Flüssigkeitszirkulationsleitung (11) mit einem zweiten Flüssigkeitszirkulationsventil (12), wobei ein erstes Sicherheitsventil (13) in der ersten Sammelleitung (6) angeordnet ist und ein zweites Sicherheitsventil (14) in der zweiten Sammelleitung (10) angeordnet ist. Die Erfindung betrifft ferner ein Verfahren zur Trennung eines Elektrolysestapels () von einem ersten Separator (5) in einer Elektrolyseanlage (1).
Absstract of: WO2026072719A1
Methods for stabilizing metal electrodes in saltwater electrolysis include pretreating the saltwater to obtain pretreated saltwater. The pretreated saltwater is mixed with a metal hydroxide to create a basic saltwater solution. The basic saltwater solution has about a 3 molar (M) or greater concentration of metal hydroxide. The basic saltwater solution is electrolysed in an electrolyzer system comprising an anode and a cathode, the anode comprising NiFe layered double hydroxide (LDH) and the cathode comprising NiFe; and producing hydrogen gas by the cathode.
Absstract of: DE102024209484A1
Die Erfindung betrifft eine mehrsträngige Elektrolyseanlage (1) für die Zerlegung von Wasser in Wasserstoff und Sauerstoff, umfassend mehrere parallel geschaltete Elektrolysestränge (2) mit jeweils mehreren in Reihe geschalteten Elektrolysestapeln (3), sowie einen ersten Separator (4), der über eine erste Hauptzufuhrleitung (5) und davon abgehende erste Zweigleitungen (6) mit ersten Eingängen (7) einer jeweils ersten Elektrodenseite (8) der Elektrolysestränge (2) verbunden ist, wobei erste Ausgänge (9) der jeweils ersten Elektrodenseite (8) der Elektrolysestränge (2) über erste Sammelleitungen (10), die in eine erste Hauptabfuhrleitung (12) münden, mit dem ersten Separator (4) verbunden sind, sowie einen zweiten Separator (12), der über eine zweite Hauptzufuhrleitung (13) und davon abgehende zweite Zweigleitungen (14) mit zweiten Eingängen (15) einer jeweils zweiten Elektrodenseite (16) der Elektrolysestränge (2) verbunden ist, wobei zweite Ausgänge (17) der jeweils zweiten Elektrodenseite (16) der Elektrolysestränge (2) über zweite Sammelleitungen (18), die in eine zweite Hauptabfuhrleitung (19) münden, mit dem zweiten Separator (12) verbunden sind, wobei in den ersten und zweiten Hauptzufuhrleitungen (5, 13), den ersten und zweiten Zweigleitungen (6, 14), den ersten und zweiten Sammelleitungen (10, 18) und den ersten und zweiten Hauptabfuhrleitungen (11, 19) Ventile (20) angeordnet sind. Ferner betrifft die Erfindung ein Verfahren zum Betrieb einer mehrstr�
Absstract of: WO2026072631A1
An apparatus for generation of at least one of carbon dioxide or hydrogen from saline water is disclosed. The apparatus includes an anodic compartment, an anode on a first side of the anodic compartment, a cathodic compartment, a cathode on a first side of the cathodic compartment, a first cation permeable fluidic separator on a second side of the anodic compartment, a second cation permeable fluidic separator on a second side of the cathodic compartment, a center compartment between the first and second cation permeable fluidic separators, and a mixing chamber including an inlet fluidly connectable to or in fluid communication with the outlet of the anodic compartment and an outlet, the center compartment having one of an outlet fluidly connectable to or in fluid communication with the inlet of the mixing chamber or an inlet fluidly connectable to or in fluid communication with the outlet of the mixing chamber.
Absstract of: DE102024209653A1
Die Erfindung betrifft eine Zelle (1) für die PEM-Wasser-Elektrolyse, die zumindest eine Abfolge von einer GDL Anode (GDLA), einer MEA, einer Kathode (GDLK)in einem Rahmen (10) aufweist, wobei die Stirnseiten (26, 28) der Anode (GDLA) und Kathode (GDLK) mit einer Dichtung (25, 27) versehen sind,die unter Druck dicht an den Rahmen (10) anlegen, sowie Bipolarplatten (BPP) auf der Anode (GDLA) und unter der Kathode (GDLK).
Absstract of: DE102024209483A1
Die Erfindung betrifft ein Sicherheitssystem (1) mit einem Detektor (2) für Strukturschäden in einem Elektrolysestapel (3) mit einer Vielzahl von Elektrolysezellen (4), wobei der Detektor (2) als optischer Sensor, Ultraschallsensor, Kontaktband zur mechanischen Detektion, raumakustische Überwachung, Körperschallüberwachung an Endplatten des Elektrolysestapels oder als Sensorik in Blindflanschen, Gasverteilern oder Gassammlern ausgestaltet sein kann. Die Erfindung betrifft ferner eine Elektrolyseanlage mit einem solchen Sicherheitssystem (1) und ein Verfahren zur Detektion von Strukturschäden in einem Elektrolysestapel (3).
Absstract of: US20260092384A1
A modular solid oxide electrolyzer cell (SOEC) system including a stack of electrolyzer cells configured to receive steam in combination with hydrogen, and a steam recycle outlet configured to recycle a portion of the steam.
Absstract of: WO2026065648A1
Disclosed are an anode slurry, a preparation method therefor, and a use thereof. The present invention provides a method for preparing anode slurry C, which comprises the following steps: step 1, mixing an iridium catalyst, a perfluorosulfonic acid resin dispersion, and a solvent to obtain slurry A; step 2, adding a platinum precursor to slurry A to obtain slurry B; and step 3, reacting slurry B at 50-90 °C to prepare anode slurry C. In the present invention, by means of directly adding a water-soluble platinum precursor into an anode oxidation iridium catalyst slurry, the dispersion of platinum and the hydrogen removal capability in oxygen per unit mass of platinum are significantly improved.
Absstract of: US20260092381A1
An electrocatalyst including a first layer, including a porous nickel foam, and a second layer, including an iron-vanadium oxide (FeVOx). The iron-vanadium oxide includes an iron oxide and a vanadium oxide. The iron-vanadium oxide contains 10 to 30 atomic percent (at. %) iron and 15 to 30 at. % vanadium based on the total number of atoms in the iron-vanadium oxide. The second layer includes iron-vanadium oxide particles having the longest dimension of 0.5 to 5 micrometers (μm). The electrocatalyst of the present disclosure may be used in oxygen evolution reactions.
Absstract of: DE102024128389A1
Die Erfindung betrifft einen photoelektrochemischer Reaktor, mit zumindest einem Behältnis, welches zumindest teilweise mit einem Elektrolyten befüllt ist und mit zumindest einer Solarzelle zur Umwandlung auf den Reaktor auftreffender elektromagnetischer Eingangsstrahlung in elektrische Leistung, wobei die Solarzelle eine Anodenseite und eine der Anodenseite gegenüberliegende Kathodenseite und eine oder mehrere Seitenflächen aufweist, wobei an der Kathodenseite eine kathodenseitige Katalysatorschicht und an der Anodenseite eine anodenseitige Katalysatorschicht angeordnet ist und wobei die Solarzelle derart angeordnet ist, dass die kathodenseitige Katalysatorschicht und die anodenseitige Katalysatorschicht mit dem Elektrolyten in Kontakt stehen. Wesentlich ist, dass der Reaktor derart ausgebildet ist, dass eine Strahlungseinkopplung der Eingangsstrahlung in die Solarzelle im Wesentlichen durch eine oder mehrere Seitenflächen der Solarzelle, bevorzugt im Wesentlichen durch eine Seitenfläche der Solarzelle, erfolgt.
Absstract of: EP4717798A2
Provided herein are methods for cleaning a diaphragm and/or membrane in an electrolysis system. For example, provided herein is a method of chemically cleaning a diaphragm and/or membrane comprising immersing the diaphragm and/or membrane in an acidic medium, immersing the diaphragm and/or membrane in a weak alkaline medium, and rinsing the diaphragm and/or membrane with deionized water. Also provided herein is a method of electrochemically cleaning a diaphragm and/or membrane comprising reversing the direction of current applied across the diaphragm and/or membrane, applying a cathodic current to the electrolyte solution, applying an anodic current to the electrolyte solution, rinsing the diaphragm and/or membrane with deionized water, and removing deposits from the electrolyte solution. Also provided herein is a method of mechanically cleaning a diaphragm and/or membrane comprising applying a voltage across the diaphragm and/or membrane that is higher than the normal operating voltage, and mechanically agitating the electrolyte solution.
Absstract of: EP4717797A2
An electrolysis system includes an electrolyzer stack having an anode side that provides an anode-side gas having a hydrogen-to-oxygen (HTO) ratio, an oxygen separator tank fluidically coupled the anode side, and an anode-side dilution system that is changeable between a closed-monitor state and an open-dilution state.
Absstract of: WO2024240830A1
The present invention relates to a method for controlling a hydrogen production installation (100), the method comprising the following successive steps: - determining a first magnitude of a nominal operating electric current (In) of at least one electrolyser (50); - measuring a second magnitude of an electric current (Imes flowing through a connection (22) between the electrolyser (50) or at least one of the electrolysers (50) and at least one photovoltaic conversion device (10); and - orienting the device (10) or at least one of the devices (10) such that the second magnitude (Imes) is less than or equal to the first magnitude (In).
Absstract of: WO2024240599A1
The invention relates to a method for producing hydrogen by steam electrolysis, using the heat from a hot effluent (102) discharged by an industrial plant, the method comprising the following steps: - heat exchange, in a heat exchanger (106), between the hot effluent (102) and a flow of water (104) in order to produce a first flow of steam (108), - cogeneration of electricity (118) and a second flow of steam (116) by a cogeneration unit (110) supplied with the first flow of steam (108), and - electrolysis of at least part of the second flow of steam (116) in an electrolysis unit (120) powered by the electricity (118), in order to produce a hydrogen flow and an oxygen-rich flow. The invention further relates to a system (100) implementing such a method and to a plant implementing such a system.
Absstract of: EP4717716A1
Provided are: a polymerizable composition containing a quaternary ammonium salt represented by formula (I), a polymerizable monomer, a linear or branched C1-4 alkylene glycol, and at least one hydroxyl group-containing compound selected from the group consisting of a C4-15 primary alcohol, a C4-15 secondary alcohol, and a C5-15 diol which has a hydroxy group bonded to a secondary carbon atom; an ion exchange resin; an ion exchange membrane; a membrane electrode assembly; and a hydrogen production device.
Absstract of: EP4717795A1
The present invention relates to an electrolyser architecture and a method for performing electrolysis. The electrolyser comprises a proton exchange membrane (PEM) and a plurality of electrodes arranged on a surface of the PEM. A microfluidic fluid channel structure is aligned with the electrodes, forming multiple channels parallel to the surface of the PEM. These channels are designed to feed water to the electrodes and are configured to collect gases produced during electrolysis above the electrodes.
Absstract of: AU2024303520A1
Methods for producing renewable hydrogen and systems related to the same are provided.
Absstract of: WO2025047802A1
Provided is a junction photocatalyst exhibiting higher catalytic activity and greater freedom in molecular design than conventional junction photocatalysts. The junction photocatalyst has a solid mediator between an oxygen generating photocatalyst and a hydrogen generating photocatalyst including an organic semiconductor, wherein the hydrogen generating photocatalyst and the solid mediator are bonded together, and the oxygen generating photocatalyst and the solid mediator are bonded together.
Absstract of: KR20260043353A
본 발명은 수소발생반응(HER) 촉매 전극 제조방법, 이에 의해 제조된 수소발생반응(HER) 촉매 전극 및 수전해를 통해 수소를 발생시키기 위한 전기분해 장치에 관한 것이다. 스테인리스 스틸 전극을 양극산화하여 니켈을 전해질 용액으로 용출시키는 니켈용출 단계; 및 상기 전해질 용액에서 상기 양극산화된 스테인리스 스틸 전극에 전압을 인가하여 상기 양극산화를 통해 용출된 니켈 이온을 상기 양극산화된 스테인리스 스틸 전극에 전착하는 니켈재전착 단계를 포함하는, 수소발생반응(HER) 촉매 전극 제조방법을 제공한다.
Absstract of: AU2024308720A1
The disclosure provides a method of producing hydrogen. The method comprises conducting a thermochemical reaction by contacting an active reagent and a basic aqueous solution, to thereby cause water from the basic aqueous solution to react with the active reagent and to produce hydrogen and a basic aqueous solution comprising an oxidised product. The method further comprises disposing the basic aqueous solution comprising the oxidised product in an electrochemical cell comprising an anode and a cathode, such that at least a portion of the cathode contacts the solution; and conducting an electrochemical reaction by applying a voltage across the anode and the cathode to produce hydrogen, oxygen and the active reagent. The active reagent comprises a metal or metal ion in a first oxidation state and the oxidised product comprises the metal or metal ion in a second oxidation state which is higher than the first oxidation state.
Absstract of: JP2026054606A
【課題】優れた耐熱性、耐薬品性を維持しながら、優れた親水性を有するポリアリーレンスルフィド繊維を得ることができる。【解決手段】ポリフェニレンスルフィドと、ポリフェニレンエーテル樹脂、ポリカーボネート樹脂、ポリエーテルサルホン樹脂、ポリフェニレンサルホン樹脂、ポリエーテルイミド樹脂、ポリサルホン樹脂から選ばれる少なくとも１種の熱可塑性樹脂を原料とし、前記熱可塑性樹脂の少なくとも一部が表面に露出することを特徴とする繊維。【選択図】なし
Absstract of: CN121219225A
An ammonia cleavage reactor, the ammonia cleavage reactor comprising: one or more reaction tubes, the reaction tubes containing an ammonia cleavage catalyst; one or more fuel combustion elements for combusting fuel in a fuel combustion zone surrounding the one or more reaction tubes to provide thermal energy to support ammonia cracking in the one or more reaction tubes; and one or more electrically powered heating elements for providing thermal energy to support the ammonia cracking in the one or more reaction tubes wherein the one or more fuel combustion elements and the one or more electrically powered heating elements are disposed in the same reactor to support the ammonia cracking in the same reaction tube, and together form an electrically assisted fuel combustion ammonia cracking reactor.
Absstract of: KR20260041196A
수소생산 시스템이 개시된다. 본 발명의 일 측면에 따른 수소생산 시스템은, 헬륨이 유입되고 상기 헬륨을 전기저항식 가열을 통해 제 1 온도까지 가열시키는 예열기 및 상기 예열기와 연결되고 상기 예열기를 통해 가열된 상기 헬륨을 전기저항식 가열을 통해 상기 제 1 온도보다 높은 제 2 온도까지 가열시키는 주가열기를 포함하는 헬륨 가열부, 물이 유입되고, 유입된 상기 물을 가열하여 증기를 발생시키는 증기 발생기, 상기 증기 발생기로부터 발생된 증기와 상기 헬륨 가열부로부터 가열된 상기 헬륨이 유입되고, 가열된 상기 헬륨을 이용하여 상기 증기를 과열시키는 과열증기 발생기, 공기와 상기 과열증기 발생기로부터 발생된 과열증기가 유입되고, 상기 과열증기를 수소와 산소로 분리하는 고체산화물 수전해 전지(SOEC) 스택 및 수소와 상기 고체산화물 수전해 전지(SOEC) 스택으로부터 발생된 산소가 유입되고, 상기 수소 및 상기 산소가 반응하여 전류가 발생되는 고체산화물 연료 전지(SOFC) 스택을 포함하고, 상기 증기 발생기는 상기 과열증기 발생기에서 유출되는 상기 헬륨이 유입되고, 유출된 상기 헬륨에 의해 상기 물이 가열된다.
Absstract of: US2025011953A1
Disclosed herein is an electrolyte comprising H+ or OH− and precursors used to make a hydrogen evolution electrocatalyst, an oxygen evolution electrocatalyst, a bifunctional hydrogen/oxygen evolution electrocatalyst, or any combination thereof for use in in situ catalyst synthesis, deposition and/or utilization.
Absstract of: US20260085433A1
There is disclosed a flow arrangement 100 for an electrolyser, comprising: first and second porous walls 110, 120, corresponding to first and second electrodes of the electrolyser; an inlet chamber 102 disposed between the first and second porous walls and configured to receive a fluid through an inlet; first and second outlet chambers 130, 140 for retaining respective fluid reaction products of electrolysis. One of, or each of, the porous walls has a discontinuous porous structure comprising a body 116 and a plurality of porous regions 117 extending through the body at discrete locations to permit the fluid to flow from the inlet chamber to the respective outlet chamber, each porous region defining a respective network of flow paths through the body. There is also disclosed an electrolyser and electrolysis installation, methods of operation, and methods of manufacture.
Absstract of: US20260085437A1
An oxygen evolution reaction (OER) catalyst for reaction in acidic media comprising: a chromium (Cr) and nickel (Ni) co-doped ruthenium oxide (RuO2) catalyst, and wherein the chromium (Cr) and nickel (Ni) co-doped ruthenium oxide (RuO2) catalyst comprises a Cr and a Ni co-doped in a ruthenium oxide (RuO2). Methods of preparing the OER catalyst are disclosed.
Absstract of: US20260088309A1
An electrochemical cell is disclosed having a porous metal support, at least one layer of a first electrode on the porous metal support, a first electron-blocking electrolyte layer of rare earth doped zirconia on the at least one layer of the first electrode, and a second bulk electrolyte layer of rare earth doped ceria on the first electron-blocking electrolyte layer. The first electron-blocking electrolyte layer of rare earth doped zirconia may have a thickness of 0.5 μm or greater, and the second bulk electrolyte layer of rare earth doped ceria may have a thickness of 4 μm or greater.
Absstract of: US20260085431A1
The problem addressed by the present invention is that of specifying a process for the electrochemical production of LiOH from Li+-containing water with the aid of an electrochemical cell with LiSICon membrane that can be operated economically on an industrial scale too. In particular, the process should have good energy efficiency and achieve a high membrane lifetime even when the employed feed contains impurities that are harmful to LiSICon materials. The problem is solved by the flow conditions in the anodic compartment of the electrochemical cell being established such that the anolyte flows along the membrane with a certain minimum crossflow velocity.
Absstract of: US20260088313A1
The invention relates to a bipolar plate and an electrochemical cell comprising a plurality of such bipolar plates. The bipolar plate comprises a first half-plate and a second half-plate which are fixedly connected to one another, wherein the bipolar plate has a plurality of fluid passage openings comprising fluid inlet openings and fluid outlet openings and a first distributor field for distributing a fluid, an active field, and a second distributor field for distributing the fluid are located on both sides of the bipolar plate.
Absstract of: WO2026062122A1
The invention relates to a method and a device (10) for checking and testing a hydrogen production plant (100) having a plurality of electrolysis devices, which are designed to generate hydrogen from water with the aid of electrical current, having a water circuit for supplying the electrolysis devices with water, and having electrical connections for connecting the hydrogen production plant (100) to an electrical current source or electrical voltage source or an electrical power network which, for generating hydrogen, supplies the electrolysis devices of the hydrogen production plant (100) with electrical power (11), wherein the device (10) has an encapsulated receiving space (11) which is designed to receive the hydrogen production plant (100) to be checked or tested.
Absstract of: WO2026060816A1
The present invention relates to a seawater electrolysis hydrogen production system and a control method therefor. The seawater electrolysis hydrogen production system comprises: an electrolytic cell (16), an oxygen-liquid separator (1), a hydrogen-liquid separator (6), a seawater heat exchanger (28), a seawater condenser (32), an alkaline-solution heat exchanger (12), a demineralized low-salinity water storage tank (40), a salt-precipitation storage tank (45), an alkali tank (20) and a water tank (18). The seawater electrolysis hydrogen production system of the present invention can effectively use waste heat generated during electrolysis to remove easily deposited ions from seawater, and reduce the concentration of monovalent ions in the seawater so that the seawater can be used as feed water for water electrolysis hydrogen production; moreover, the content of salt accumulated in the hydrogen production system is reduced by means of evaporating a solvent to precipitate salt, so as to address the adverse effect of ions in the seawater on the performance of the seawater electrolysis hydrogen production system.
Absstract of: WO2026061302A1
An electrolytic hydrogen production system coupled with capturing carbon dioxide from flue gas. The system comprises an absorption device (1), an electrolytic hydrogen production device (2), a first gas-liquid separation device (3) and a second gas-liquid separation device (4). The electrolytic hydrogen production device (2) comprises an anode chamber (21), an intermediate chamber (22) and a cathode chamber (23), which are separated by anion exchange membranes (24). In addition, the present invention further relates to a method for using the electrolytic hydrogen production system coupled with capturing carbon dioxide from flue gas. The method comprises: absorbing carbon dioxide from flue gas by using the absorption device (1); allowing the obtained absorption liquid to enter the anode chamber (21), so as to obtain a carbon-dioxide-containing gas-liquid mixture; allowing the gas-liquid mixture to enter the first gas-liquid separation device (3) to undergo separation, so as to obtain carbon dioxide and a first separation liquid; allowing the first separation liquid to enter the intermediate chamber (22), so as to realize the regeneration of the absorbent under the action of ion exchange; and returning the regenerated absorbent to the absorption device (1) again to continue the absorption of carbon dioxide.
Absstract of: US20260085436A1
A water electrolysis electrode includes an electroconductive substrate and a layered double hydroxide layer. The layered double hydroxide layer is disposed on a surface of the electroconductive substrate. The layered double hydroxide layer includes two or more transition metals. A contact angle of a surface of the layered double hydroxide layer is 20° or more and 100° or less. The contact angle on the surface of the layered double hydroxide layer may be 26° or more.
Absstract of: JP2026053994A
【課題】電解セルに求められるガス透過性を維持しつつ、強度を高めた支持層を備えることにより、水蒸気の電解反応と機械的強度を両立させることを可能にした電解セルとその製造方法を提供する。【解決手段】電解セルは、ガス透過性を有し、かつ内部に流入した水蒸気を酸素イオンと水素に電気分解可能な水素極と、水素極で生成される酸素イオンを伝導可能な固体酸化物電解質層と、ガス透過性を有し、かつ固体酸化物電解質層から到達した酸素イオンから酸素分子を生成可能な酸素極と、水素極または酸素極を支持する支持層と、を具備する。支持層は、複数の酸化ニッケル粒子と、複数の部分安定化ジルコニア粒子と、を有する多孔質焼結層を有する。複数の部分安定化ジルコニア粒子の粒度分布を示す頻度分布曲線は、粒径３０μｍ以上７０μｍ以下の範囲の第１のピークと、粒径０．５μｍ以上４．０μｍ以下の範囲の第２のピークと、を有する。【選択図】図２
Absstract of: JP2026053957A
【課題】一部電解槽の劣化加速抑制の対策策定を支援する情報を提供する。【解決手段】本発明の一側面に係る保守支援システム２００は、電解槽の電解特性情報と、電解槽の配置パターンの情報と、電解システムの運転条件に関する情報と、を少なくとも含む入力情報に基づいて、複数の電解槽のそれぞれにおける劣化状態の変化の情報を電解槽の配置パターン毎に予測し、予測した各電解槽の劣化状態の変化に関する情報を出力する演算部６３を備える。【選択図】図２
Absstract of: WO2026064419A1
The present disclosure relates to compositions, systems, and methods that enable the electrochemical conversion of ammonia into hydrogen and nitrogen gases under mild operating conditions, including ambient temperature and pressure. This approach addresses key limitations of conventional ammonia thermal cracking, including the need for high temperatures and pressures and complex downstream gas separation, while overcoming media and catalyst constraints in electrolytic cracking of ammonia.
Absstract of: US20260088620A1
A system for producing clean hydrogen and clean hydrogen derived products using water electrolysis and time correlated renewable power whereby the operation of the electrolysis is optimized for using time correlated renewable power amongst other factors. The system includes a hydrogen production unit that uses an electrolyzer to produce hydrogen from water and electricity, where the electricity is delivered via a connection to the electrical grid and/or behind the meter renewables and whereby a control unit manages the production of hydrogen based on the attributes of the renewable power, including time correlation and other factors. The hydrogen produced from time correlated renewables may be used directly to decarbonize industrial, transportation, or other applications or the hydrogen may be used to produce hydrogen derived products such as ammonia, methanol, transportation fuels (such as sustainable aviation fuel (SAF), diesel, gasoline), LPG, chemicals, or other low carbon products that use hydrogen as an input for the production process.
Absstract of: WO2026062314A1
The present invention relates to the use of a device for generating hydrogen and oxygen as a fuel source.
Absstract of: WO2026060686A1
The present application relates to the technical field of hydrogen production via water electrolysis, and specifically relates to a method for preparing a proton exchange membrane comprising a hydrogen barrier coating. The method comprises the following steps: S1, mixing an inorganic filler with a functional resin, adding a solvent, and stirring same to obtain a slurry; S2, coating a surface of a proton exchange membrane with the slurry, the wet thickness of the resulting coating being 10-100 μm, and drying the wet coating to obtain a dried proton exchange membrane; and S3, performing a heat treatment on the dried proton exchange membrane to obtain a proton exchange membrane comprising a hydrogen barrier coating. The present application further relates to a proton exchange membrane comprising a hydrogen barrier coating, a membrane electrode, and a device for hydrogen production via water electrolysis. The hydrogen barrier coating described herein can physically block hydrogen gas from permeating through the proton exchange membrane, thereby improving the efficiency of a water-electrolysis membrane electrode made of the proton exchange membrane, reducing the content of hydrogen in oxygen at an anode side, and further improving the service life and safety of the device for hydrogen production via water electrolysis.
Absstract of: US20260085430A1
A water electrolysis system includes: a water electrolysis device configured to perform water electrolysis; a water supply device configured to supply water to the water electrolysis device; a power supply configured to supply current to the water electrolysis device; and a control unit. The control unit is configured to adjust a current density of the current supplied from the power supply to the water electrolysis device, and adjust a water flow rate of the water supplied from the water supply device to the water electrolysis device. The control unit is configured to: measure the water flow rate and the current density during operation of the water electrolysis device; and perform an operation change when at least one of the water flow rate and the current density during the operation of the water electrolysis device is outside a corresponding one of threshold ranges.
Absstract of: WO2026064734A1
A device for catalyzing a reaction includes a substrate, an array of nanostructures supported by the substrate, each nanostructure of the array of nanostructures including a sidewall surface that extends outward from the substrate and an end surface at an outer end of the nanostructure, and a protection architecture composed of a metal oxide and disposed on each nanostructure of the array of nanostructures, the protection architecture including a continuous capping layer that covers the end surface of each nanostructure and a discontinuous distribution of the metal oxide disposed on the sidewall surface of each nanostructure.
Absstract of: WO2026060623A1
Provided are a metal composite oxide, a composite product, an oxygen evolution catalyst, a catalyst ink, and an electrode that have excellent catalytic performance, and a method for producing the metal composite oxides. The metal composite oxide is a multi-element metal composite oxide including iridium, ruthenium, and a third metal (M) . The third metal (M) is one or more elements selected from the group consisting of Group 2 elements, Group 13 elements, Group 14 elements, and transition metals. The composite oxide is a low crystalline oxide or an amorphous oxide.
Absstract of: US20260084139A1
An ammonia dehydrogenation catalyst, a method for producing same, and a method for producing hydrogen using same are disclosed. More specifically, a catalyst for ammonia dehydrogenation capable of preparing hydrogen at a high yield from ammonia, a method of preparing the same, and a method of preparing hydrogen using the same are provided. The disclosed ammonia dehydrogenation catalyst comprises: a zeolite having an intracrystalline cation; and an alkali metal and ruthenium impregnated on the zeolite.
Absstract of: CN121100420A
Gas pressure equalization systems (400-401) and methods of operation for electrosynthetic or electrical energy liquid gas cells or cell stacks (210) are disclosed in one example. The gas pressure equalization systems (400-401) include a first pressure equalization tank (410) for partially containing a first liquid (470) and a first gas. The first gas is positioned above a first liquid level (471). A first gas conduit (430) is provided for transporting the first gas between the battery or battery stack (210) and the first pressure equalization tank (410). In another example, a second pressure equalization tank (420) may additionally be provided for partially containing a second liquid (473) and a second gas positioned above a second liquid level (472). A second gas conduit (440) is then provided for conveying the second gas between the cell or cell stack (210) and the second pressure equalization tank (420).
Absstract of: EP4715089A1
Ahydrogen generator includes a water tank configured to contain electrolysis water, an electrolysis module disposed in the water tank and configured to electrolyze the electrolysis water to generate a gas comprising hydrogen, a humidifying module having a humidifying chamber configured to contain supplement water, a diffusing device disposed in the humidifying module and configured to diffuse the gas comprising hydrogen, and a sound-proof shield disposed in the humidifying module and including a sound-proof cavity, a connecting tube communicating the water tank and the diffusing device, and a gas outlet. The gas comprising hydrogen flows through the connecting tube and the diffusing device to the supplement water in the sound-proof cavity, and then passes through the gas outlet to the humidifying chamber. The sound-proof shield blocks sound generated by the gas comprising hydrogen flowing in the device, thereby improving user experience.
Absstract of: CN121175118A
Disclosed herein is a catalyst comprising a multi-component alloy having a single-phase structure. The multi-component alloy includes iridium, ruthenium, or a combination thereof in combination with at least four metals, wherein the at least four metals do not include platinum group metals. Methods of making the catalyst are also provided herein.
Absstract of: WO2024234026A1
The invention relates to an electrolysis cell (1) for alkaline hydrogen electrolysis, comprising an electric anode (2), an electric cathode (3), a separation layer (4) which is substantially permeable to ions, is electrically insulating, is preferably in the form of a membrane or a diaphragm and is placed between the anode (2) and the cathode (3), and two electrically conductive half-shells (5, 5') which are electrically insulatingly connected to one another at their edges, wherein: the anode (2) is electrically conductingly connected to the first half-shell (5), and the cathode (3) is electrically conductingly connected to the second half-shell (5'); the anode (2), the cathode (3) and the separation layer (4) are placed between the two half-shells (5, 5') such that an anode chamber (6) and a cathode chamber (7) are formed; each of the half-shells comprises at least one inflow pipe (8, 8') and at least one outflow pipe (9, 9') for a medium; and each of the half-shells (5, 5') comprises a metal support frame (10, 10') for absorbing compressive forces, and a substantially flat outer skin (11, 11'), the support frame (10, 10') and outer skin (11, 11') being integrally bonded together, preferably welded together.
Absstract of: CN121152900A
A water and carbon dioxide co-electrolysis system (1) comprises an anion exchange membrane (AEM) cell (2) having at least one AEM cell (2c) comprising a cathode (8), an anode (12), and an AEM membrane (16) separating the cathode from the anode, and an anolyte circuit (18) in which the AEM membrane (16) is separated from the anode, an anolyte is fluidly connected to the anode (12) via an anolyte inlet (14i) and an anolyte outlet (14o) of the anode (12). The CO2 and H2O co-electrolysis system further comprises a mineralization system (3) comprising a mineralization unit (27) connected to the anolyte circuit (18) and comprising a mineralized metal configured to react with carbonate and bicarbonate ions circulating in the anolyte circuit (18) to form a metal carbonate.
Absstract of: EP4715093A1
The present invention relates to a sealing device (100) for sealing a membrane electrode assembly (210) of an electrolyser cell (200) against one or more bipolar plates (220) of the electrolyser cell (200). The sealing device (100) comprises a seal (110), which extends in a width direction (101) between two opposite seal surface sides (111, 112) for sealing against respective seal counter-surfaces (211, 221) of the electrolyser cell (200) and further comprises a seal lateral side (113), which is provided laterally of the seal surface sides (111, 112). The sealing device (100) comprises further at least one limiter (120) for limiting a compression of the seal (110) in the width direction (101) by engaging two opposite limiter surface sides (121, 122) of the limiter (120) with the seal counter-surfaces (211, 221). The limiter (120) comprises further a limiter lateral side (123), which is provided laterally of the limiter surface sides (121, 122). At least a part of the limiter lateral side (123) is mechanically connected to at least a part of the seal lateral side (113).
Absstract of: CN120476490A
The present invention provides a reinforced ion conducting membrane comprising: (a) a reinforcement layer comprising a porous polymer structure; and (b) a polymer ion conducting membrane material impregnated within the porous polymer structure; wherein the porous polymer structure comprises a polymer backbone based on a nitrogen-containing heterocyclic ring, and the polymer ion-conducting membrane material has a transition temperature T alpha in the range of from 60 DEG C to 80 DEG C and including end values.
Absstract of: CN120936421A
A method for generating and treating a two-phase effluent from one or more pressurized electrolysis cell stacks adapted to electrolyze water into hydrogen and oxygen, whereby a pump supplies a cathodic electrolysis fluid stream from a first gas-liquid gravity separator vessel to the electrolysis cell stack, whereby another pump supplies an anode electrolysis fluid flow from a second gas-liquid gravity separator vessel to the electrolysis cell stack, and whereby at least one cyclone gas-liquid separator receives a combined effluent from the cathode electrolysis chamber and/or receives a combined effluent from the anode electrolysis chamber, these combined effluents are respectively located within respective gas-liquid gravity separator containers, whereby further, the at least one cyclonic gas-liquid separator separates the gas from the liquid within the gas-liquid gravity separator container along a substantially horizontal cyclonic axis of rotation. An electrolytic cell system is also provided.
Absstract of: CN121358894A
Proton exchange membranes are described. The proton exchange membrane includes: a reinforcing membrane; a continuous non-porous hydrogen recombination catalyst coating, the continuous non-porous hydrogen recombination catalyst coating comprising a mixture of a hydrogen recombination catalyst and a proton conducting ionomer; and a continuous non-porous cross-linked polyelectrolyte multilayer coating, the continuous non-porous cross-linked polyelectrolyte multilayer coating comprising alternating layers of a polycationic polymer and a polyanionic polymer. Catalyst coated membranes incorporating proton exchange membranes and methods of making proton exchange membranes are also described.
Absstract of: EP4716049A1
The invention relates to a water electrolysis installation (P) drawing power from an electrical network (NET) and providing an hydrogen production rate, the installation (P) comprising a plurality of clusters (C<sub>i</sub>). The installation (P) comprises a supervision unit (SU) defining, repetitively at successive sampling periods (k), the operating mode of the clusters (Ci) and a current setpoint (x<sup>i</sup><sub>k</sub>) of each active cluster (C<sub>i</sub>). The supervision unit (SU) comprises a candidate module (CM) configured to establish, during each sampling period, a candidate list (SL) consisting of all cluster pools capable of satisfying a production constraint and an optimization module (COM) configured to calculate, during each sampling period (k), for each cluster pool of the candidate list (SL), optimal current setpoints of the clusters and an associated efficiency value of said pool, the optimal current setpoints optimizing an objective function under the production constraint.
Absstract of: WO2025016765A1
The invention relates to a water treatment loop (20) for connection to at least one electrolysis stack (8) of a hydrogen producing electrolysis plant (40), comprising: a water inlet section (21) into which water drained from at least one electrolysis stack (8) can be recirculated; an ion exchanger (2) arranged downstream of the water inlet section (21); a water outlet section (22) arranged downstream of the ion exchanger (2) and adapted to supply water treated by the ion exchanger (2) to said at least one electrolysis stack (8); and a catalytic surface (23) arranged downstream of the water inlet section (21) and upstream of the ion exchanger (2), so that water recirculated via the water inlet section (21) is made to contact the catalytic surface (23) prior to interaction with the ion exchanger (2), whereby oxidants such as peroxides are at least partly removed from the water, prior to being treated by the ion exchanger (2).
Absstract of: WO2024249360A2
A power generation system includes a housing, a lid defining an opening in the housing, and a chamber inside the housing configured to receive a cartridge comprising a powdered fuel mixture. The system also includes a fluid reservoir that stores a fluid configured to react with the powdered fuel mixture to produce hydrogen gas. A processor is configured to control ingress of the fluid from the fluid reservoir to the powdered fuel mixture in the cartridge and control egress of the gas from the cartridge to the gas storage compartment. The system also includes a generator configured to generate electricity from the gas in the gas storage compartment.
Absstract of: CN119020815A
The invention provides an electrode and a preparation method and application thereof, and belongs to the technical field of functional materials. The electrode comprises a substrate, a nickel transition layer wrapping the surface of the substrate and a porous active layer wrapping the surface of the nickel transition layer, the porous active layer is made of nickel-based alloy or cobalt-based alloy, and alloy elements in the nickel-based alloy and the cobalt-based alloy comprise zinc. The electrode provided by the invention has the characteristics of high activity, high stability and high binding force when being used for producing hydrogen by electrolyzing water.
Absstract of: CN121700428A
本发明属于水电解制氢技术领域，涉及一种用于水电解制氢的多级离子膜耦合系统及方法。包括原料水处理单元、多级离子膜电解槽、氢侧分离器和梯度补水罐；原料水处理单元包括依次连接的反渗透装置和电渗析装置；电渗析装置和多级离子膜电解槽的第一水入口连接；多级离子膜电解槽内自下而上依次设置有阳极层、复合离子交换膜和阴极层；多级离子膜电解槽的阴极层上设置有氢气出口；多级离子膜电解槽的阳极层上设置有氧气出口；氢气出口和氢侧分离器的气液混合入口连接；氢侧分离器的液体出口和多级离子膜电解槽的第二水入口连接；梯度补水罐和氢侧分离器的液体入口连接。本发明实现了能耗降低、氢气纯度提升和运行稳定性增强的效果。
Absstract of: CN121700441A
本发明提供一种多孔纳米层叠结构制氢电极材料的制备方法，包括以下步骤：步骤1、先将金属基体依次清洗并干燥，以备用；步骤2、采用溅射法将镍、硅沉积在步骤1清洗后的底层金属基体上，在其上形成镍‑硅掺杂表层；步骤3、将步骤2掺杂表层后的金属基体置于酸洗液中，进行酸洗去除表层中的硅，从而在底层金属基体上形成中间层多孔镍层；步骤4、将步骤3得到的具有多孔镍层的金属基体置于前驱体溶液中，在所述中间层多孔镍层上原位生长表层纳米催化剂层，从而制备多孔纳米层叠结构制氢电极材料。该层叠结构的电极材料为多种催化元素互相协同作用，活性位点增多，活化势垒降低，制氢反应速率加快，制氢所需能耗降低。
Absstract of: CN121700431A
本申请涉及一种极框组件、双极板组件以及电解槽，属于电解水制氢技术领域。该极框组件包括：环形极板外框；第一通道件，设置于环形极板外框的内侧边缘并形成有第一出气通道和第二出气通道；以及第二通道件，设置于环形极板外框的内侧边缘并形成有进液通道；其中，第一通道件和/或第二通道件边缘设有沿环形极板外框的厚度方向凹陷形成的第一安装部，环形极板外框的内侧边缘设有沿环形极板外框的厚度方向凹陷形成的第三安装部，第三安装部与第一安装部连通，并位于同一平面上。本申请提供的极框组件、双极板组件以及电解槽可以减少极板外框的加工工序，并且有效确保阳极室和阴极室之间不会发生相互渗透，避免影响出气纯度和生产安全。
Absstract of: CN121700483A
本申请属于电解水制氢技术领域，公开了一种制氢电极及其制备方法、水电解装置。该制备方法包括将可溶性镍盐、缓冲剂、添加剂和金属掺杂的金属化合物纳米颗粒混合，得到电镀液；将导电基底作为阴极，置于所述电镀液中进行电镀，以在所述导电基底的表面形成镀层，得到制氢电极。采用本申请提供的方法制备得到的制氢电极具有优异的催化活性和稳定性。
Absstract of: CN121700451A
本发明公开了一种稀土掺杂二硫化钒电析氢催化剂的制备方法与应用，属于电催化制氢技术领域。该方法以偏钒酸铵为前驱体、硫代乙酰胺为硫源，稀土氯化物作为掺杂剂，在聚乙烯吡咯烷酮辅助下经水热反应制得稀土掺杂VS₂粉末。所获得的催化剂呈花状纳米片阵列结构，稀土元素均匀分布于晶格中，保持了1T相结构的高导电性并优化了氢原子的吸附自由能。与未掺杂VS₂相比，该催化剂在电解水析氢反应中表现出更低的过电位和更优的反应动力学，其中Ce掺杂1.5%的样品在‑10mA·cm⁻²时过电位低至150mV。该方法工艺简单、成本低廉，所得催化剂稳定性高，具有广阔的应用前景，可应用于新能源电解水制氢等领域。
Absstract of: CN121700462A
本发明涉及工业电解装置的自动化控制技术领域，尤其涉及一种碱性电解水制氢冷启动控制方法，包括包括以下步骤：S1、加载预设的冷启动运行参数序列并读取本地存储的断点记录文件，解析所述断点记录文件中的步骤记录标识，确定当前系统的启动阶段指针，生成包含目标温升曲线与电流爬坡速率的初始启动状态参数；S2、基于所述初始启动状态参数驱动碱液循环泵与辅助加热器运行，实时监测电解槽出口温度。本发明中，通过滑动时间窗口计算电压和温度的变化率，确保了系统仅在工况稳定时更新断点状态记录，这有效地提高了系统在断电或异常情况下的恢复能力，避免了从剧烈波动状态恢复可能引发的控制超调，显著增强了系统的可靠性和安全性。
Absstract of: CN121708716A
本发明涉及碱性电解水制氢技术领域，尤其涉及一种碱性电制氢系统碱液结晶堵塞的预测及预防方法，包括：监测氢侧与氧侧气动调节阀的实时开度值；分析开度值在一个连续时间段内的变化趋势；当趋势表明开度持续单向增加且累计增幅超第一阈值时，触发一级预警并输出预警信息；当未触发一级预警但开度值超过第二阈值时，触发二级预警并自动调整系统工艺参数；当未触发上述预警但开度值超过更高的第三阈值时，触发三级预警并自动降低系统制氢负荷；在触发二级或三级预警后，若开度值未恢复正常，则对堵塞管路执行在线冲洗和吹扫维护；维护完成后，返回实时监测步骤以重新开始循环监测。该方法实现了对碱液结晶堵塞的早期预测、分级干预与闭环预防。
Absstract of: CN121700446A
本发明属于电解水材料技术领域，公开了一种多金属析氢催化剂，所述催化剂为碳封装的纳米颗粒结构，所述催化剂为三维多孔结构，所述纳米颗粒为金属合金结构，所述纳米颗粒均匀分散在掺杂氮的碳骨架的表面以及嵌入碳骨架的内部，多金属中一种金属为Pt，其他金属M选自过渡金属中的一种或多种，Pt与金属M之间的原子距离为本发明制备得到的催化剂，利用铂与其他过渡金属的合金化作用，不仅可以减少铂的用量，降低成本，而且还能提高铂基催化剂在碱性和酸性介质中具有优异的HER性能。
Absstract of: CN121700430A
本发明涉及制氢技术的技术领域，特别是涉及一种太阳能制氢设备。本发明的太阳能制氢设备，高温蒸发模块的蒸发腔室用于引入纯水并利用热源将纯水蒸发为水蒸气；电解模块的供电单元用于向正极电解单元和负极电解单元供电，正极电解单元和负极电解单元布置在电解腔室中以分别将水蒸气电解为氧气和氢气；气体储存模块的氢气存储单元用于接收电解出的氢气并存储，氧气存储单元用于接收电解出的氧气并存储。本申请的太阳能制氢设备，通过聚光集热单元汇聚太阳光向所述蒸发腔室直接提供热源，使纯水充分吸收太阳能并转换为高温水蒸气，热转化率较高，后续进一步对高温水蒸气电解时所需电能较少，运行时成本较低。
Absstract of: CN121695891A
本发明公开了一种双空位ZnCdS固溶体光催化剂及其制备方法和应用，制备方法包括将镉源、锌源和硫源加入无水乙醇中搅拌溶解，镉源、锌源、硫源的质量比为1∶9∶3，于70℃～90℃水浴条件下反应，经抽滤、洗涤、干燥，得到粉末状ZnCdS固溶体，将NaOH加入水中并搅拌溶解，然后加入粉末状ZnCdS固溶体，再超声处理，经抽滤、洗涤、干燥，得到双空位ZnCdS固溶体光催化剂。本发明的制备方法具有产氢率高、重复稳定性好、制备简便、成本低等优点，所得双空位ZnCdS固溶体光催化剂可应用于光催化产氢领域，产氢效率高达12.69mmol·g‑1·h‑1，是纯ZnS的23.94倍，纯CdS的11.64倍。
Absstract of: CN121706442A
本发明公开了一种水电解槽多场智能仿真技术的实验验证方法，涉及水电解槽仿真实验技术领域；包括：S1、构建包含热场、流体场及至少一个选自电场、化学场或结构场的其他物理场的多物理场仿真模型，所述模型通过场间关联参数实现动态耦合，其中热场与流体场的耦合包括：基于热场温度分布动态修正流体场的气泡生成动力学参数，所述修正采用Arrhenius方程关联温度与气泡生成活化能。优点在于：本方法通过热流场动态耦合闭环捕捉温度‑气泡‑传热联动并带动多场优化，以热流优先迭代、仿真实验实时同步提升效率，动态调整收敛阈值与全维验证保精度，为水电解槽结构优化、参数调试提供精准可靠仿真支撑。
Absstract of: CN121700455A
本发明属于纳米材料技术领域，公开了一种高稳定强抗氯MOF基电解海水催化剂的制备方法。制备方法包括：（1）处理产品基底泡沫镍；（2）利用铁盐、镍盐、对甲基苯甲酸、对硝基苯甲酸、水、乙醇和N,N‑二甲基甲酰胺配置合成材料；（3）通过水热法合成最终的硝基功能化的NiFe‑MOF‑PNBA@NF。本发明的电催化材料应用于碱性真实海水析氧反应时，不仅催化性能更优，还能在高电流密度下保持更高的运行稳定性。此外，本发明制备的催化剂还表现出优秀的电解稳定性，在1.5A/cm2的电流密度下保持稳定性能超过4000h。
Absstract of: CN121699088A
本发明公开一种苝酰亚胺基COF材料及其制备方法和在光催化中的应用。该材料以苝酰亚胺作为电子供体，以具有高析氢催化活性的单体作为电子受体，采用传统COF合成技术进行制备，具备全解水所需的双活性位点，和广泛的光吸收范围与优异的电荷分离能力。该PDI‑COF催化剂在可见光下实现了低成本、高效的光催化全解水制氢，在商业化太阳能制氢领域具有巨大潜力。
Absstract of: CN121700459A
本发明属于AEMWE电解槽制氢技术领域，公开了一种阴离子交换膜水电解制氢系统及其运行控制方法。本发明通过提供AEM电解槽，所述AEM电解槽的阳极电极采用以镍毡或泡沫镍为载体的镍铁层状双氢氧化物催化剂；建立所述AEM电解槽的电流密度‑法拉第效率关系模型；基于所述电流密度‑法拉第效率关系模型，计算在波动电流输入条件下的综合法拉第效率；根据所述综合法拉第效率，调整所述AEM电解槽的运行参数，优化制氢效率和安全性能。本发明通过定量模型与智能控制，实现制氢系统对可再生能源波动的高效、安全响应，实现可再生能源的高比例消纳，提升了绿氢制备的经济性与可靠性，为AEMWE制氢系统的动态运行策略提供定量依据。
Absstract of: CN121700429A
本发明公开了一种用于碱性电解槽的极板极框组件及制造方法，包括：极板，包括由非金属材料制成的基板，基板表面设有导电层；基板周向边缘设有导流环带，导流环带与所述导电层形成欧姆接触，以使电流在极板的两边导通；极框，设置于极板周侧，极板与极框连接。本发明能够降低成本、重量和风险，具有优良导电性和可靠性。
Absstract of: CN121698366A
本发明提供一种高暴露{111}晶面氧化镁的制备方法及其应用，所述制备方法包括以下步骤：（1）将表面活性剂的水溶液与混合盐溶液混合均匀，反应后得到沉淀悬浮液；所述混合盐溶液中含有Mg2+、Zn2+和Ba2+；（2）将沉淀悬浮液静置老化，固液分离，干燥，焙烧，得高暴露{111}晶面氧化镁。本发明制得的高暴露{111}晶面氧化镁作为催化剂载体用于氨分解制氢反应中的催化性能优异，活性高，稳定性强。
Absstract of: CN121700478A
本发明属于高熵催化剂技术领域，具体涉及一种高熵硫化物催化剂的制备方法及应用。包括以下步骤：（1）将金属前驱体、金属氰酸盐前驱体和电解质溶于水，超声预处理，得到电镀液；（2）将还原剂溶于溶剂中，得到还原剂溶液；（3）将步骤（1）得到的电镀液置于电解池中，启动电沉积过程；（4）在电沉积开始后的特定时间点，将还原剂溶液一次性注入电解池中，继续完成电沉积过程；（5）将电沉积得到的催化剂进行清洗、真空干燥。本发明制得的催化剂在电催化分解水中展现出卓越的催化活性和稳定性，性能显著优于传统一次性加入还原剂制备的对比样品。本发明工艺简单，重现性好，稳定性优异，为高性能催化材料的可控制备提供了全新的解决方案。
Absstract of: CN121695862A
本发明公开了一种钴铜双金属纳米催化剂及其制备方法与应用。涉及催化化学技术领域,该方法具体步骤如下：S1，将活性炭在酸性溶液中处理，然后洗涤至中性并干燥，得到酸处理的活性炭；S2，将可溶性钴盐和可溶性铜盐溶于水中，配制成混合金属盐溶液A；将尿素溶于水中，配制成溶液B；将溶液B与溶液A混合，搅拌均匀后加入步骤S1所得酸处理的活性炭，经分散形成均匀悬浮液；将悬浮液进行水热反应；本发明通过层状双金属氢氧化物衍生形成层状双金属氧化物，形成Co、Cu双活性位点的纳米催化剂。Co的引入可以通过电子效应和几何效应调节Cu的电子结构和空间位置，显著提高催化活性，其性能优于对应的单金属钴或铜基催化剂。
Absstract of: CN121700449A
本发明提供了一种金属镍掺杂的不规则球状纳米材料及其制备方法和在电催化的应用，制备方法为：第一步电沉积，外加钨源、镍源和2‑甲基咪唑与去离子水混合均匀成电解液，利用外电场的作用将金属离子沉积在阴极表面；第二步退火，将部分Ni离子还原成金属镍，形成一种较小的不规则球状纳米结构使得活性面积增大从而增强了催化剂的HER性能。同时也表现出对两个竞争反应的双功能催化活性，可同时应用于碱性全水解的阴阳极，协调促进整体水裂解。与现有技术相比，本发明合成的催化剂也不仅用于碱性尿素全水解的两个竞争反应，还能分解富水体中的尿素，实现了双功能使用。
Absstract of: CN121700443A
本发明公开了一种高性能镍铁双金属氢氧化物催化电极、制备方法及应用，包括如下步骤：步骤1：分别将一定量的镍盐溶液、铁盐溶液混合均匀，然后将活化后的含镍基底材料放入混合溶液中；步骤2：室温沉积一定时间后得到表面生长镍铁双金属氢氧化物析氧催化剂的催化电极。本发明设计了一种在含镍基底材料上常温原位生长镍铁双金属氢氧化物（NiFe‑LDH）析氧催化剂的合成方法，实现了近100%原料利用率、零废液、无尺寸限制的低成本批量化绿色合成，获得的催化电极具有优异的析氧催化性能和长时间稳定性，可直接应用于碱性（ALK）电解槽和阴离子交换膜（AEM）电解槽，显著降低了ALK电解槽和AEM电解槽的成本，有着重要的工业应用价值。
Absstract of: CN121700436A
本发明属于析氢电极技术领域，提供了一种析氢阴极及其制备方法和应用。本发明在镍基体上重复依次涂覆催化剂溶液体系和烧结的过程，得到前驱体；将所述前驱体置于无机碱溶液中进行电活化，得到所述析氢阴极；所述催化剂溶液体系包括催化金属化合物、盐酸和溶剂；所述催化金属化合物包括镍化合物、铈化合物、钌化合物、钼化合物、铂化合物和铁化合物中的一种或多种；所述烧结的温度独立地为400~600℃，时间独立地为10~60min，所述烧结的气氛为空气。本发明通过涂覆、烧结和电活化在镍基体上得到了具有复合纳米结构的析氢阴极。本发明制得析氢阴极中催化层与镍基体结合力强，延长了使用寿命。
Absstract of: CN121700442A
本发明属于电解水用催化剂技术领域，提供了一种富磷型磷化镍催化剂的制备方法及其应用。所述方法包括以下步骤：氯化镍经水热反应制备氢氧化镍纳米片作为前驱体；前驱体在磷酸二氢铵溶液中，于氩气保护下进行微波反应、磷化；再经过电热耦合反应即得目标产物。所述富磷型磷化镍催化剂呈现多孔且富含晶界的二维纳米片形貌，大量的表面原子排布可暴露丰富的催化活性位点；富磷的引入可显著改变镍的电子结构使其具有独特的类金属特性，催化剂表面的氢吸附自由能非常接近于零，具备最优的吸附和脱附氢的动力学平衡，在工业电解水制氢领域具有广阔的应用前景。
Absstract of: CN121700444A
本发明涉及一种用于质子交换膜电解池阳极的水氧化电催化剂，特别涉及一种SnO2负载的非晶IrCoOx阳极电催化剂及其制备方法与应用。IrCoOx@SnO2质子交换膜电解水阳极电催化剂包括SnO2纳米颗粒以及负载于SnO2纳米颗粒表面的非晶IrCoOx纳米颗粒，1.5≤x≤1.9，其中，SnO2纳米颗粒的质量含量为16%～42%，IrCoOx纳米颗粒的质量含量为58%～84%。本发明克服了现有OER催化剂不能同时兼顾高活性和长久稳定性、从而不适宜大规模商业化应用的缺陷。
Absstract of: CN121695792A
一种集成式金属裂解水蒸汽制氢系统。本发明的水蒸汽装置、分气缸、裂解反应装置、冷凝装置、气液分离器、缓冲罐、转运设备通过管线依次连通；制氢系统还设置有，计量监测装置，对制氢过程的压力、流量、温度进行监测；安全控制装置，执行安全控制工艺；冷凝水管汇，制氢过程产生的冷凝水通过冷凝水管汇排出；吹扫装置，对制氢系统进行吹扫清洁作业。其有益效果是，结构设计合理，提高裂解水蒸汽制氢效率，能耗低；降低成本，具有较高的实用价值和经济效益；采用橇装化设计，机动性强，便于布置、安装连接和运移，实现高效、环保、安全的氢气生产。
Absstract of: CN121700423A
本申请提供了一种基于地热梯级利用的离网光伏制氢热管理系统，涉及碱性电解水制氢技术领域。该基于地热梯级利用的离网光伏制氢热管理系统包括电解槽、换热器、第一气液分离器、第二气液分离器、储热罐、碱液循环泵和换热介质循环泵，电解槽的氢气出口与第一气液分离器相连通，电解槽的氧气出口与第二气液分离器相连通，第一气液分离器和第二气液分离器的液相出口均与碱液循环泵的入口相连通，碱液循环泵的出口与换热器的碱液入口相连通，换热器的碱液出口与电解槽的入口相连通，换热器的介质出口与储热罐的介质入口相连通，该基于地热梯级利用的离网光伏制氢热管理系统能够保障碱液温度适宜，进而缩短系统启动时间。
Absstract of: CN121700456A
本发明提供了一种多孔离子溶剂化膜及其制备方法和用途，该离子溶剂化膜的制备方法包括：将聚芳撑氧吲哚、支化聚芳撑氧吲哚、侧链型聚芳撑氧吲哚中的一种、或所述聚芳撑氧吲哚、所述支化聚芳撑氧吲哚、所述侧链型聚芳撑氧吲哚中的至少两种溶解于第一有机溶剂中，得到成膜液；将所述成膜液通过相转换的方法进行成膜，得到离子溶剂化膜。该类膜有效解决了目前离子溶剂化膜所存在的运行寿命低，电化学性能较差的问题，在碱性电解水应用方面表现出极大的前景。
Absstract of: CN121700463A
本发明公开了一种矿井水电解纯化处理并同步电解制氢的装置及方法，包括水平串联设置的四级阳极电解絮凝池，每一级阳极电解絮凝池内均对称安装有两块板状阳极，每一级阳极电解絮凝池两侧均对称设置有阴极电解水制氢反应池；每一级阳极电解絮凝池与所对应的阴极电解水制氢反应池之间均设置有隔膜；所述阴极电解水制氢反应池内设置有盘状微通道，盘状微通道与隔膜之间安装有板状阴极。本发明采用四级阳极电解絮凝池，通过多级连续电解及电絮凝反应，逐步深入去除矿井水中的污染物，相比传统单级处理方式，净化效果显著提升，能更有效地降低矿井水中悬浮物、重金属离子等杂质含量，使处理后的水质更优。
Absstract of: WO2026019015A1
One embodiment of the present invention provides an anion-exchange membrane water electrolysis system incorporating a reference electrode, and a method for producing same. The anion-exchange membrane water electrolysis system incorporating a reference electrode according to one embodiment of the present invention places the reference electrode not between reduction (cathode) and oxidation (anode) electrodes but outside of a membrane electrode assembly, thereby allowing overvoltage of each electrode to be measured without degrading system performance.
Absstract of: CN120882908A
The invention relates to an electrolysis cell system (10) comprising at least one electrolysis cell (20) comprising at least one steam inlet (41) and at least one exhaust gas outlet (38; 39), and a turbocharger (62) for compressing the exhaust gas from the electrolysis cell (20). The turbocharger (62) comprises a driving fluid inlet, a driving fluid outlet, a compressed fluid inlet, a compressed fluid outlet, a compressor (13) and a turbine (12). The turbine (12) is configured to drive the compressor (13). A driving fluid outlet of the turbocharger (62) is fluidly connected to at least one steam inlet (41) of the electrolysis cell (20). At least one exhaust gas outlet (38; 39) is fluidly connected to a compressed fluid inlet of the turbocharger (62). The system (10) may further include a steam source in fluid connection with the drive fluid inlet of the turbocharger (62) to power the turbine (12) using pressurized steam.
Absstract of: WO2026057995A1
A process for the catalytic cracking of a liquid ammonia feedstock to produce a cracked gas stream, comprising the steps of i) heating the liquid ammonia feedstock to an intermediate temperature by heat exchange with a liquid heat exchange medium to produce a cooled liquid heat exchange medium; and ii) using the intermediate temperature liquid ammonia feedstock to provide cooling to one or more downstream processes.
Absstract of: US20260078218A1
A block copolymer including one or more segments containing an ionic group (hereinafter referred to as an “ionic segment(s)”) and one or more segments containing no ionic group (hereinafter referred to as a “nonionic segment(s)”), wherein the ionic segment has an aromatic hydrocarbon polymer having a number-average molecular weight of more than 40,000 and 50,000 or less, and wherein the block copolymer satisfies the relation of: Mn3/(Mn1+Mn2)>1.5, wherein Mn1 represents the number-average molecular weight of the ionic segment, Mn2 represents the number-average molecular weight of the nonionic segment, and Mn3 represents the number-average molecular weight of the block copolymer. Provided is a block copolymer and a polymer electrolyte material produced using the same, wherein the block copolymer has excellent proton conductivity even under low-humidity conditions, has excellent mechanical strength and physical durability, and has an excellent in-process capability.
Absstract of: AU2024341133A1
Provided herein are systems and methods for utilizing aqua-ammonia as an energy or hydrogen storage and transport medium. A method for delivering power, the method comprises converting enriched ammonia to electrical power and heat; and using the heat to remove water from aqua-ammonia, thereby producing the enriched ammonia.
Absstract of: WO2026059567A1
A method and system for capturing carbon dioxide from the air with a carbon contactor (also referred as to a carbon capture device), using an carbonate lean/poor alkaline solution to produce a carbonate rich alkaline rich solution, sending the resulting carbonate rich solution to an electrolyzer to generate hydrogen gas, and using the hydrogen gas to power a power plant, the hydrogen gas either used alone, or blended with natural gas or ammonia, and at least some of the power generated by the power plant is used to power the contactor and the electrolyzer.
Absstract of: WO2026056375A1
The present application discloses a nitride Ta3N5, and a preparation method therefor and a use thereof. The specific method comprises: subjecting a precursor I to high-temperature hydrolysis to prepare TaOx having a small size; and by utilizing the characteristics of TaOx being amorphous and having a small particle radius, performing short-duration nitridation on same to prepare Ta3N5. The formation of low-valence metal defects is effectively reduced, the charge separation efficiency is improved, and water-splitting activity is exhibited in a photocatalytic water splitting reaction. Compared with Ta3N5 prepared by a conventional method, the activity of the product of the present application is significantly improved.
Absstract of: AU2024336964A1
The present invention relates to a water electrolyser system for production of compressed hydrogen, comprising a water electrolyser stack, a multiphase pump arranged downstream of the electrolyser stack and a hydrogen gas/liquid separator. The multiphase pump is arranged between the water electrolyser stack and the hydrogen gas/liquid separator. The present invention also relates to a method for production of compressed hydrogen in a water electrolyser system including: supplying deionized water or liquid electrolyte to a water electrolyser stack; producing hydrogen in a water electrolyser stack; compressing a mixture of produced hydrogen and entrained deionized water or liquid electrolyte in a multiphase pump; and separating the compressed mixture of produced hydrogen and entrained deionized water or liquid electrolyte in a hydrogen gas/liquid separator.
Absstract of: US20260077326A1
The present invention is generally directed to a reactor for the production of low-carbon syngas from captured carbon dioxide and renewable hydrogen. The hydrogen is generated from water using an electrolyzer powered by renewable electricity or from any other method of low-carbon hydrogen production. The improved catalytic reactor is energy efficient and robust when operating at temperatures up to 1800° F. Carbon dioxide conversion efficiencies are greater than 75% with carbon monoxide selectivity of greater than 98%. The catalytic reactor is constructed of materials that are physically and chemically robust up to 1800° F. As a result, these materials are not reactive with the mixture of hydrogen and carbon dioxide or the carbon monoxide and steam products. The reactor materials do not have catalytic activity or modify the physical and chemical composition of the conversion catalyst. Electrical resistive heating elements are integrated into the catalytic bed of the reactor so that the internal temperature decreases by no more than 100° F. from the entrance at any point within the reactor. The catalytic process exhibits a reduction in performance of less than 0.5% per 1000 operational hours.
Absstract of: CN120981607A
A selective membrane is described that includes a porous polymer membrane and a selective material on at least one outer surface. A selective material comprising a composite material of an ion exchange polymer and zirconia particles (ZrO2) distributed throughout the ion exchange polymer may be applied as a liquid by a spray method. Selective membranes made by the methods described herein are suitable for alkaline water electrolysis applications.
Absstract of: US20260078509A1
This invention discloses a Co3O4@IrOx catalyst, its preparation method, and its applications, belonging to the technical field of catalyst materials for hydrogen production through water electrolysis. The preparation method of the Co3O4@IrOx catalyst is as follows: using ZIF-67 as the core, adding a quaternary ammonium salt surfactant and an imidazole organic ligand, and reacting it with a zinc source to obtain a ZIF-67@ZIF-8 core-shell material; coating it on carbon paper to obtain a ZIF-67@ZIF-8 electrode sheet; pyrolyzing it to obtain a Co3O4@defective ZIF-8 electrode sheet; using a standard three-electrode system, with the Co3O4@defective ZIF-8 electrode sheet as the working electrode, performing pulsed potential etching in potassium hydroxide solution to obtain a Co3O4@vacancy-type ZIF-8 electrode sheet; and electrochemically depositing it in an iridium-containing potassium hydroxide solution to obtain the Co3O4@IrOx catalyst. The Co3O4@IrOx catalyst exhibits excellent hydrogen production capacity through water electrolysis.
Absstract of: US20260078508A1
The present invention discloses a nickel oxide-based iron-iridium bi-electrocatalytic catalyst, its preparation method and application, belonging to the technical field of catalytic materials. In the present invention, a nickel oxide material is prepared as a nickel oxide working electrode, and a mixed solution of an iron precursor, an iridium precursor, and an OH- source is used as an electrolyte. Iron-iridium bimetal is deposited on the nickel oxide working electrode by electrochemical deposition to obtain a nickel oxide-based iron-iridium bi-electrocatalytic catalyst. The preparation method provided by the present invention realizes the multi-scale dispersion of two metal elements, iron and iridium, on the surface of the nickel oxide support. This multi-scale structure not only provides abundant catalytic active sites, enabling the catalyst to more efficiently adsorb and activate reactants during the reaction process, but also significantly enhances the electron transfer efficiency, thereby improving the catalytic activity of the catalyst. In addition, the synergistic effect of iron and iridium optimizes the electronic structure of the catalyst, further improving its catalytic performance.
Absstract of: WO2026057209A1
The invention relates to an apparatus (10) for producing hydrogen from water by means of electrical current, the apparatus comprising: a plurality of electrolysis devices (11), each electrolysis device (11) having at least one water supply connection (13), at least one water discharge connection (14), and at least one hydrogen discharge connection (15), each electrolysis device (11) being connected, via its at least one water supply connection (13), to a water supply line (16), via its at least one water discharge connection (14) to a discharge line (17) for water and oxygen, and via its at least one hydrogen discharge connection (15) to a discharge line (18) for hydrogen; a housing or frame (19) in which the electrolysis devices (11) are arranged; an inert gas generation device (20) which is designed to generate inert gas in situ within the apparatus (10), wherein each electrolysis device (11) and/or the discharge line (18) for hydrogen and/or a device (22) arranged in the hydrogen discharge line (18) for processing the hydrogen and/or the discharge line (17) for water and oxygen and/or a device (23) arranged in the discharge line (17) for water and oxygen for removing oxygen from the discharged water and/or the housing or frame (19) can be flushed with inert gas generated by the inert gas generation device (20).
Absstract of: WO2026059452A1
The present invention relates to a cell, an electrode and a method for producing hydrogen. The cell comprises a first and second electrode, wherein the first electrode is constituted by a cathode constituted by a Ni-SGPA material deposited on a substrate and the second electrode is constituted by an anode and a reference electrode, an electrolyte comprising H2SO4, and an electric power supply for applying a pulsed voltage.
Absstract of: US20260078513A1
A method of operating an electrolyzer system includes operating the electrolyzer system in a steady state mode by providing steam, heat and electric power to at least one stack of electrolyzer cells to electrolyze the steam and generate a hydrogen containing product stream that is provided to a hydrogen processor; and operating the electrolyzer system in a hot isolated standby mode by stopping the provision of the steam to the at least one stack of electrolyzer cells, stopping the provision of the hydrogen containing product stream to the hydrogen processor, recycling the hydrogen containing product stream through the at least one stack of electrolyzer cells while providing the heat to the at least one stack of electrolyzer cells, and not providing external hydrogen from outside the electrolyzer system to the at least one stack of electrolyzer cells.
Absstract of: WO2026058474A1
This water electrolysis system is provided with: a hydrogen production device unit that comprises a water electrolysis stack unit that includes one or more water electrolysis stacks that produce oxygen and hydrogen through an electrolytic reaction; a power source that supplies direct-current power to the one or more water electrolysis stacks; a pure water supply piping system that supplies pure water; an oxygen outflow piping system that causes oxygen produced by the water electrolysis stack unit to flow out to the outside; a hydrogen outflow piping system that causes hydrogen produced by the water electrolysis stack unit to flow out to the outside; an insulation unit that electrically insulates between the hydrogen production device unit and the ground; electrically insulating first insulated piping that is disposed in part of the pure water supply piping system; electrically insulating second insulated piping that is disposed in part of the oxygen outflow piping system; and electrically insulating third insulated piping that is disposed in part of the hydrogen outflow piping system.
Absstract of: WO2026057149A1
The invention relates to the field of photocatalytic hydrogen generation using sunlight and water. It addresses the technical problem of efficiently splitting water into hydrogen and oxygen using a specially designed photoelectrode. The photoelectrode comprises a semiconductive photo-harvester containing metal silicide, an oxidation cocatalyst with magnesium tin oxide, and a reduction cocatalyst of cobalt, nickel, and manganese alloys. The manufacturing method includes preparing a silicon-based photosensitive material, applying protective and anti-reflective coatings, and bonding the cocatalysts using techniques like sputtering. The photoelectrode is used in a transparent container filled with water and exposed to sunlight to generate hydrogen and oxygen, which can be collected and stored for energy applications, such as fuel cells. This invention aims to provide a renewable and environmentally friendly method for hydrogen production, overcoming challenges related to material stability and water impurities.
Absstract of: US20260078501A1
A water electrolysis system having: a membrane-electrode assembly; a first separator in contact with a hydrogen electrode of the membrane-electrode assembly; a hydrogen flow passage provided between the first separator and the hydrogen electrode; a second separator in contact with an oxygen electrode of the membrane-electrode assembly; an oxygen flow passage provided between the second separator and the oxygen electrode; and a cooling device that cools the hydrogen electrode such that a temperature of the hydrogen electrode becomes lower than a temperature of the oxygen electrode.
Absstract of: US20260078505A1
A method of forming a gas diffusion material layer (GDL) includes depositing a metallic layer over a porous polytetrafluoroethylene (PTFE) layer, oxidizing 3,4-ethylenedioxythiophene (EDOT) over the metallic layer, and forming a porous poly(3,4-ethylenedioxythiophene) (PEDOT) layer over the porous PTFE layer. The porous PEDOT layer directly contacts the porous PTFE layer. The resulting PEDOT-PTFE GDL combines electrical conductivity with hydrophobicity and gas permeability, enabling efficient electrochemical conversion processes, particularly carbon dioxide reduction reaction. The PEDOT-PTFE GDL can be used in electrochemical systems comprising an electrochemical reactor and a catalyst layer supported on the PEDOT-PTFE GDL, to provides stable, selective, and efficient CO2 reduction performance across alkaline, neutral, and acidic electrolytes. Compared with carbon-based GDLs, the PEDOT-PTFE electrodes exhibit reduced hydrogen evolution, high product selectivity, and durability under high current operation.
Absstract of: US20260078510A1
According to an embodiment, an electrolysis device includes a cathode for reducing a reduction target to generate a reduction product, an anode for oxidizing an oxidation target to produce an oxidation product, an electrolyte layer provided between the cathode and the anode, and the electrolyte layer including an electrolyte layer material containing at least one selected from the group consisting of a heat-resistant polymer, a solid acid, a solid acid salt, and a molten salt, and a first ion conductive material, and a control layer that is provided at least one of between the cathode and the electrolyte layer and between the anode and the electrolyte layer, and that includes a porous material and a second ion-conductive material supported in at least a part of pores of the porous material, wherein 0≤A≤B is satisfied, where A is an area of the second ion conductive material on a surface of the control layer on the cathode side or/and the anode side, and B is an area of the second ion conductive material on a surface of the control layer on the electrolyte layer side.
Absstract of: WO2026059202A1
The present invention relates to a super-anaerobic dual-function water electrolysis electrode based on a non-noble metal-non-metal mixed catalyst and a manufacturing method therefor. According to the present invention, by reducing the size of gas bubbles, which are generated during a water electrolysis reaction, to be easily separated from the electrode surface and at the same time, to maximize the active surface area of a catalyst, a super-anaerobic water electrolysis electrode having excellent performance can be provided.
Absstract of: US20260077337A1
A photocatalyst has a perovskite type crystal, the photocatalyst has, present on a surface, a stepped structure including a terrace and a step, and an occupancy ratio of a projected area of the stepped structure to a total projected area in an observation image of the surface is 20% or more. It is preferable that the terrace is formed of a {100} facet, and the step is formed of the {100} facet or a {110} facet.
Absstract of: WO2026057993A1
A process for the catalytic cracking of a liquid ammonia feedstock to produce a cracked gas stream, comprising the steps of i) heating the liquid ammonia feedstock to an intermediate temperature by heat exchange with a liquid heat exchange medium to produce a cooled liquid heat exchange medium; and ii) using the cooled liquid heat exchange medium to provide cooling to one or more downstream processes.
Absstract of: AU2025268573A1
The present invention relates to the technical field of the electrolysis of water, and specifically relates to a low-hydrogen-permeability proton exchange membrane, and a preparation method therefor and the use thereof. The proton exchange membrane comprises a Pt-containing additive layer and a matrix membrane, wherein the Pt-containing additive layer is composed of a Pt additive and a fluorine-containing proton exchange resin, the Pt-containing additive layer comprises an array layer and a flattening layer, the thickness ratio and the active-component ratio of the array layer to the flattening layer are respectively within the ranges of 1:(0.5-30) and 1:(1-50), and the array layer is composed of arrays arranged in order and an array layer resin coating the arrays. In the low-hydrogen-permeability proton exchange membrane provided by the present invention, by providing the Pt-containing additive layer consisting of the array layer and the flattening layer, the specific surface area of the Pt-containing additive layer is effectively increased by means of the arrays in the array layer, thereby achieving the efficient utilization of an additive; moreover, the hydrogen permeability improvement effect is further improved by controlling the thickness ratio and the active-component ratio of the array layer to the flattening layer and the parameters of the arrays.
Absstract of: EP4711506A1
Provided are an electrochemical cell and an electrochemical device that are easily manufactured and capable of retrofitting. The electrochemical cell includes: a first plate and a second plate between which an anode chamber and a cathode chamber are respectively formed on respective opposing inner surface sides thereof; and a sealing portion provided between the first plate and the second plate, in which the sealing portion includes plural frame bodies disposed at intervals from an inner side to an outer side, and plural sealing members disposed between the plural frame bodies and disposed in a compressed state between the first plate and the second plate. The electrochemical device includes the electrochemical cell.
Absstract of: JP2026049210A
【課題】従来のＣｏ酸化物助触媒と比較して、水の酸化に対する活性が高い可視光応答光触媒用の助触媒、助触媒を含む光触媒材、光触媒材を含む分散液、分散液を含む組成物、分散液の乾燥物または組成物の硬化物である塗膜、および塗膜を有する基材を提供する。【解決手段】コバルトと、鉄およびニッケルの少なくとも１種と、を含む、可視光応答光触媒用の助触媒。イリジウムをドープしたチタン酸ストロンチウム粒子と、前記チタン酸ストロンチウム粒子に担持した助触媒と、を含む、光触媒材。【選択図】なし
Absstract of: EP4711504A1
An ink 1a for water electrolysis electrode catalyst includes a catalyst 11, a support 15, an organic polymer 12, and a solvent 13 including water. The catalyst 11 includes at least one transition metal. The support 15 supports the catalyst 11 and includes a transition metal. The organic polymer 12 includes a water-insoluble polymer 12b and a nonionic water-soluble polymer 12a.
Absstract of: WO2024230958A1
An electrochemical device (10'), with a cell stack consisting of a plurality of cell stack elements, with a force application unit (13) which exerts a force on the cell stack in order to press the cell stack elements of the cell stack fluid-tightly in sealing regions (17) of the cell stack, wherein the force application unit (13) is designed in such a manner that the force for pressing the cell stack acts on the cell stack and therefore on the sealing regions (17) of the cell stack depending on the operating state of the electrochemical device (10').
Absstract of: EP4711483A1
The present invention provides a heat-resistant alloy that is excellent in nitriding resistance and high-temperature creep rupture strength. The heat-resistant alloy of the present invention comprises, in mass %, C: 0.2% to 0.6%, Si: greater than 0% to 2.5% or less, Mn: greater than 0% to 2.0% or less, P: 0.03% or less, S: 0.03% or less, Ni: 33.0% to 50.0%, Cr: 24.0% to 50.0%, with the remainder being Fe and impurities, and optionally including: Nb: greater than 0% to 1.8% or less, Rare Earth Elements: greater than 0% to 0.5% or less, Ti: greater than 0% to 0.5% or less and/or Zr: greater than 0% to 0.5% or less, W: greater than 0% to 2.0% or less and/or Mo: greater than 0% to 0.5% or less.
Absstract of: CN121443774A
The present invention relates to a method of synthesizing a transition metal catalyst consisting of electrodeposition on a substrate electrode from an electrolyte solution comprising at least one transition metal precursor wherein the electrodeposition is carried out at a deposition current density of 500 to 2000 mA/cm2. The invention also relates to a transition metal catalyst characterized in that it is stable on a base electrode at a current density of at least 400 A/cm2 for at least 30 minutes.
Absstract of: WO2024231175A1
The present invention concerns composite casing structures for electrolytic cells wherein each casing structure is made of a plurality of casing components, optionally made of at least two different materials, which are subsequently joined together to form a structure suitable to house one or more of the following elements: electrodes, separators, bipolar elements, elastic elements and/or current collectors. The casing structure may be advantageously employed in electrolysers for high pressure alkaline water electrolysis.
Absstract of: GB2700815A
A hydrogen extraction system for extracting hydrogen from a liquid electrolyte 102 comprising at least one isotopologue of lithium hydride (LiH), the system including an electrolysis cell 100 comprising an anode 108 for generating hydrogen from the liquid electrolyte 102, a cathode 110 spaced apart from the anode 108, and a solid-state electrolyte 112 comprising a lithium-containing high entropy oxide (HEO) material physically isolating the cathode 110 from the liquid electrolyte 102 and conducting lithium ions from the liquid electrolyte 102 to the cathode 110. Use of a HEO comprising solid-state electrolyte in the electrolytic extraction of hydrogen from a liquid electrolyte comprising at least one isotopologue of lithium hydride, and a method of extracting hydrogen from a liquid electrolyte comprising at least one isotopologue of lithium hydride using the extraction system are defined. Further specified is a tritium breeding system comprising the hydrogen extraction system and a breeder blanket, the breeding system configured to supply liquid electrolyte comprising at least one tritium-containing isotopologue of lithium hydride to the electrolysis cell from the breeder blanket and to return liquid electrolyte to the breeder blanket from the electrolysis cell following electrolysis of the at least one tritium-containing isotopologue of lithium hydride. Figure 1
Absstract of: CN121311631A
Composite proton exchange membranes are described. The composite proton exchange membrane comprises three layers, wherein the three layers comprise a proton exchange membrane layer, a continuous nonporous organic-inorganic composite coating layer and a continuous nonporous cross-linked polyelectrolyte multilayer coating. Catalyst coated membranes incorporating the composite proton exchange membranes and methods of making the composite proton exchange membranes are also described.
Absstract of: WO2026059005A1
A reaction cell for an ammonia electrolysis reaction and an electrochemical hydrogen extraction system including same are disclosed. Specifically, a reaction cell (10) for use in an ammonia electrolysis reaction is provided, the reaction cell (10) comprising: an anode (100) comprising a first metal; a cathode (200) comprising a second metal; and a separator (300) positioned between the anode and the cathode and comprising a cation exchange membrane (310). The present invention provides a hydrogen production technology based on anhydrous ammonia electrolysis through cation exchange, thereby enabling production of high-purity, high-pressure hydrogen with low energy consumption.
Absstract of: EP4711497A1
A method is described for detecting the presence of hydrogen in the oxygen stream generated by a PEM cell, wherein the PEM cell comprises a membrane permeable to H<sup>+</sup> ions , a first inlet conduit for water, a second outlet conduit for hydrogen, and a third outlet conduit for the generated oxygen. The hydrogen and the oxygen being produced by the molecular dissociation of water inside the PEM cell.In the method the temperature of a catalyst placed in contact with said oxygen stream, is detected.
Absstract of: EP4711495A1
The present invention relates to an electrolyser cell stack (100) for producing a hydrogen-based e-fuel, including an electrochemical system (10) with a plurality of electrolyser cells for an electrochemical reaction of water with electric power, an electrical system (20) for supplying electric power to the stacked electrolyser cells, and a compression system (30) with compression plates (33) for compressing at least the electrochemical system (10) in a stacking direction (D). According to the invention, the electrochemical system (10) is divided into at least two parallel stacked sub-stacks (11) of the electrolyser cells arranged within an area (A) of the compression plates (33), for a common compression of all sub-stacks (11) by the same compression system (30).
Absstract of: FI20246132A1
The application relates to a method and an apparatus for forming a feedstock for a steam cracking process. Hydrogen gas (4) and a feed (1) comprising at least carbon dioxide are fed to a first reactor (2) in which the feed reacts with the hydrogen to form a synthesis gas (3) comprising at least carbon monoxide, and the synthesis gas is supplied to a second reactor (6) in which the synthesis gas is treated in the presence of a synthesis catalyst to form a hydrocarbon composition (7) comprising at least naphtha range hydrocarbons. Undesired hydrocarbons, unreacted gases and/or water are separated from the hydrocarbon composition (7) and a fraction of the hydrocarbon composition (8) which comprises at east naphtha range hydrocarbons is formed. The fraction of the hydrocarbon composition is treated by a hydrotreatment (10) in which hydrogenation and hydrodeoxygenation reactions are carried out in the presence of at least one hydrotreatment catalyst in one or more reactors for modifying the fraction (8) to form a modified hydrocarbon composition (11), and the feedstock is formed from the modified hydrocarbon composition.
Absstract of: KR20260037813A
본 발명은 탄소 섬유 기판, 상기 기판 상에 코팅된 전도성 고분자층, 상기 전도성 고분자층 상에 형성된 나노 섬유층을 포함하며, 상기 나노 섬유층은 니켈 코발트 옥시하이드록사이드를 포함하는 전기화학 촉매에 관한 것으로서, 보다 상세하게는, 탄소 섬유, 전도성 고분자 및 니켈 코발트 옥시하이드록사이드를 포함함으로써 바인더가 필요하지 않고 수소 발생 반응, 산소 발생 반응 및 요소 산화 반응에 모두 사용될 수 있는 다기능 전기화학 촉매에 관한 것이다.
Absstract of: EP4711036A1
A system can include a catalytic reactor heated using magnetic induction to perform a magnetically induced decomposition reaction. The catalytic reactor can include a housing coupled with a feedstock source to receive a flow of an inorganic compound in gaseous form that can flow through the catalytic reactor. The housing can include a metal-based catalyst selected to decompose the inorganic compound into one or more reaction products within a predefined temperature range. The metal-based catalyst can include a heating agent that can increase in temperature when exposed to a magnetic field. A coil can be positioned around the housing to provide the magnetic field to heat the metal-based catalyst using magnetic induction to be within the predefined temperature range.
Absstract of: JP2026049668A
【課題】高純度の水素ガスを製造できる装置を提供する。高純度の水素ガスを製造できる方法を提供する。【解決手段】陰極と、前記陰極の一方側に対向して配されている陽極と、前記陰極と前記陽極の間に配されている固体電解質部材とを有する水素ガス製造装置であって、前記陰極の他方側に水素ガス回収通路が配されている水素ガス製造装置。【選択図】図３
Absstract of: WO2025028897A1
The present invention relates to a catalyst for decomposition of ammonia and a method for decomposition of ammonia. The catalyst comprises a carrier and a catalytically active component supported by the carrier, the catalytically active component comprising; i) ruthenium as a first metal; ii) a second metal; and iii) a third metal, wherein the second metal and the third metal are each independently at least one selected from the group consisting of lanthanum (La), cerium (Ce), aluminum (Al), and zirconium (Zr).
Absstract of: ES2992538A1
Hydrogen fuel cell obtained by equipment with ionization by means of solar energy characterized by being constituted by a fuel cell (CD) and a hydrogen generation equipment, where the elements of the set are the following: Fuel cell (50), constituted by an external perimeter profile in cylindrical form that contains two sheets resistant to oxidation, spirally wound on themselves, of variable extension: external anode membrane (51), internal cathode membrane (52) and between them an electrolyte (53) in a closed circuit (57), with an external cooling device (58) and a more external catalytic membrane (59), being located at the end of the membranes (51) and (52) the electricity outputs (+) (55) and (-) (56) produced and, where the hydrogen is constituted by an attached hydrogen generating equipment. (Machine-translation by Google Translate, not legally binding)
Absstract of: CN121669316A
本发明属于催化材料技术领域，公开了一种稀土掺杂型催化剂及其制备方法和在氧析出反应中的应用。该稀土掺杂型催化剂的制备方法，包括以下步骤：在保护气体氛围下，将四氨基对苯醌、氯化铁、稀土盐、溶剂混合，然后加入泡沫镍，升温进行反应，分离得到稀土掺杂型催化剂；稀土盐包括铈盐、铒盐或镧盐。该稀土掺杂型催化剂具有良好OER催化活性、高稳定性，且不含贵金属，低成本，而且性能还优于商业RuO2。这有利于催化剂的广泛应用。
Absstract of: KR20250043804A
The present invention discloses a catalyst electrode for water electrolysis, comprising: a metal foam; and a composite transition metal chalcogenide heterostructure formed on the metal foam. The catalyst electrode for water electrolysis can exhibit improved electrochemical catalytic activity in both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in water electrolysis reaction, can efficiently produce hydrogen with lower energy supply than existing noble metal electrodes, and can be used in both anion exchange membrane water electrolyzer and solar cell-water electrolysis system.
Absstract of: WO2024248706A1
Method and device for the production of hydrogen gas by splitting a media flow containing sodium ions or other metal ions in an aqueous solution, wherein the ion-splitting effect of a magnetic field is enhanced by the arrangement of a controllable electric field (E) generated between electrodes (9, 10) by means of a voltage source (13) which extends within the magnetic field (2) and the force direction of which coincides with the direction of the force that the magnetic field (2) imposes on the ions in the media flow. The electric voltage source (13) is connected in series with the electrodes (9, 10).
Absstract of: WO2025053532A1
The present invention relates to a membrane electrode assembly manufacturing method comprising the steps of: (S1) forming a first catalyst layer on the other surface of a separation membrane having a first carrier film attached to one surface thereof; (S2) attaching a second carrier film to the other surface of the separation membrane on which the first catalyst layer is formed; (S3) removing the first carrier film attached to one surface of the separation membrane; and (S4) forming a second catalyst layer on one surface of the separation membrane from which the first carrier film is removed, wherein the second carrier film includes a first area corresponding to the first catalyst layer on the other surface of the separation membrane, and a second area, which is the remaining area that excludes the first area, and the second area of the second carrier film is coated with an adhesive on a surface facing the other surface of the separation membrane on which the first catalyst layer is formed.
Absstract of: CN119024088A
The invention provides a test system and method for evaluating an electrode for a hydrogen production electrolytic bath in a laboratory, and the test system at least comprises an electrode clamp which is used for clamping an electrode to be evaluated; the heat exchanger is connected to the electrode clamp, and electrolyte is preheated through the heat exchanger and then input into the electrode clamp; and a heating unit connected to the electrode holder to heat the electrode holder. According to the test system and method for the electrode for the hydrogen production electrolytic cell in the laboratory, the temperature of the electrode clamp and the electrolyte in the electrode clamp can be accurately controlled, the accuracy of the test result is improved, the energy consumption of the test system can be reduced, and the test efficiency is improved.
Absstract of: TW202508703A
The present disclosure relates to a method for preparing a nickel-based phosphide catalyst for oxygen evolution reaction in alkaline water electrolysis anode using sodium hypophosphite(NaH2PO2) substitution and pyrolysis.
Absstract of: TW202513891A
The present disclosure relates to an electrode and a method for preparing the same. According to the present disclosure, an electrode for anion exchange membrane water electrolysis that can achieve improved electrochemical performance and also has excellent durability can be provided.
Absstract of: WO2025017013A1
The present invention relates to an electrode comprising or consisting of an electrocatalyst, the electrocatalyst comprising a metal boride, wherein the metal boride comprises at least one element M1 selected from Ti, Zr and Hf, and at least one element M2 selected from Co, Ni, Ru, Rh, Pd, Ir and Pt; and the metal boride contains more than 10 atomic % of M2. The present invention also provides an electrode obtainable by subjecting the electrode to an electrocatalytic reaction. It also relates to an electrolyzer comprising said electrode. It is also concerned with a method for producing an electrode, and use of an electrode in an electrocatalytic reaction.
Absstract of: EP1000000A1
The invention relates to an apparatus (1) for manufacturing green bricks from clay for the brick manufacturing industry, comprising a circulating conveyor (3) carrying mould containers combined to mould container parts (4), a reservoir (5) for clay arranged above the mould containers, means for carrying clay out of the reservoir (5) into the mould containers, means (9) for pressing and trimming clay in the mould containers, means (11) for supplying and placing take-off plates for the green bricks (13) and means for discharging green bricks released from the mould containers, characterized in that the apparatus further comprises means (22) for moving the mould container parts (4) filled with green bricks such that a protruding edge is formed on at least one side of the green bricks.
Absstract of: CN121219226A
The present specification relates to a system for catalytic cracking of ammonia to produce hydrogen, the system comprising: a main ammonia cracking reactor, the primary ammonia cracking reactor includes one or more reaction tubes containing an ammonia cracking catalyst and a fuel combustion zone surrounding the one or more reaction tubes to provide thermal energy to support cracking of ammonia in the one or more reaction tubes to produce a primary hydrogen-containing gas stream; and an auxiliary ammonia cracking reactor for cracking ammonia to produce an auxiliary hydrogen-containing gas stream, the system configured to direct the auxiliary hydrogen-containing gas stream to both the ammonia cracking catalyst within the one or more reaction tubes of the main ammonia cracking reactor and the combustion zone of the main ammonia cracking reactor, to at least partially fuel the primary ammonia cracking reactor.
Absstract of: CN121675119A
本发明涉及纺织科学技术领域，公开了一种制氢用PPS纱线及其面料的制备方法，所述纱线制备方法包括：对PPS短纤维开松并喷洒非离子抗静电油剂混合液；采用轻定量、慢速度原则进行梳理，并经过两道并条工艺提升均匀度；经粗纱后，在紧密纺细纱机上牵伸加捻制成单纱；将2‑6根单纱合股并施加反向捻得到PPS股线。面料制备方法采用前述股线为经纬纱，整经并精确控制上机张力，在剑杆或喷气织机上以平纹组织制成克重为300‑500g/m2的织物。本发明通过系统性工艺优化，制得的PPS纱线具有毛羽少、强度高、条干均匀的优点，其织物结构稳定、孔隙均匀，特别适用于制氢用隔膜等高性能工业领域。
Absstract of: CN121675013A
本发明公开了一种富铁钼双金属氧化物电催化剂及其制备方法和应用，属于新能源材料与电催化技术领域，制备方法包括以下步骤：将泡沫镍、含铁源和钼源的前驱体溶液充分溶解混合，进行微波水热处理，再将所得产物进行洗涤和真空干燥，制备得到所述富铁钼双金属氧化物电催化剂。即本发明利用微波快速成核实现铁钼双金属氧化物在泡沫基底上的原位构筑，通过钼限域掺杂诱导晶格畸变，形成高密度活性位点与强结构稳定性；催化剂在碱性析氧反应中仅需309 mV过电位即可驱动> 2 A cm‑2电流，并在> 500 mA cm‑2下稳定运行超120小时，显著突破高电流电解水制氢中阳极催化剂活性与耐久性瓶颈。
Absstract of: CN121674999A
本发明公开了一种纳米粒子电催化剂、其制备方法及应用。本发明的制备方法：将NiCl2·6H2O、四丁基氯化膦和乙二醇混合加热得到低共熔溶剂DESs；所得DESs置于微波反应器中进行微波反应，得到所述纳米粒子电催化剂。该方法具有工艺简单、反应迅速（仅需分钟级）、成本低廉且易于工业化放大等显著优势。所制备的Ni3P‑Ni12P5异质结构纳米粒子具有形貌均一、结晶度良好等特点，在电催化析氢反应中表现出优异的催化活性和稳定性。特别地，该微波辅助一步合成法避免了传统多步工艺的复杂性，为高性能电催化剂的大规模制备提供了新思路。
Absstract of: CN121689231A
本发明提供了一种基于交流频率调制的离网制氢系统综合效率优化方法，属于新能源制氢技术领域。包括以下步骤：电解槽性能评价体系建立；性能指标权重获取；改进TOPSIS法划分工作区间；交流频率信息传递及电解槽功率自适应控制。相比现有技术，本发明用频率信号传递系统状态信息，无需依赖通信，解决了通信故障影响系统稳定性的问题。除此之外，结合电解槽工作区间设计制氢功率自适应控制策略，考虑了电解槽工作状态的影响，对于多种天气工况均适用。
Absstract of: CN121687239A
一种碱性电解系统氧中氢预测方法、系统、介质及设备，方法中，基于气液分离器未分离溶解氢、气液分离器未分离气态氢、电解槽饱和扩散和电解槽过饱和扩散机制对系统氧中氢的贡献，得到碱性电解系统氧中氢预测的计算总公式，根据碱性电解系统在不同碱液循环流量工况下的实验数据，标定待拟合系数；根据碱性电解系统在不同系统压力工况下的实验数据，标定待拟合系数；根据碱性电解系统在不同工作电流工况下的实验数据，标定待拟合系数；根据碱性电解系统在不同温度工况下的实验数据，标定待拟合系数和；输入碱性电解系统的温度、压力、碱液循环流量和电流实验数据，计算碱性电解系统氧中氢以实时输出不同运行工况下的系统HTO。
Absstract of: EP4711496A1
The electrochemical reaction device includes: an electrochemical reaction structure including a cathode, an anode, a diaphragm having a first surface on the cathode and a second surface on the anode, a cathode flow path, and an anode flow path; a first flow path through which a first fluid containing a reducible material to the cathode flow path flows; a second flow path through which a second fluid containing water to the anode flow path flows; a third flow path through which a third fluid containing the reduction product from the cathode flow path flows; and a fourth flow path through which a fourth fluid containing water and oxygen from the anode flow path flows. The diaphragm has concentration gradient in which a concentration of a chemical species decreases from the second surface to the first surface, the chemical species being configured to decompose, capture, or inactivate an active oxygen specie.
Absstract of: CN121669287A
本发明提供了一种亲水性富氮氮化碳纳米片的制备方法，该方法为：将5‑氨基四氮唑和氯化钾通过研磨混合均匀，在空气气氛下，升温至550℃，恒温煅烧，自然冷却至室温，得到煅烧后的粉末，加入水，搅拌分散，通过透析除去盐，得到样品的水溶液进行冷冻干燥，得到亲水性富氮氮化碳纳米片。还提供了应用，该亲水性富氮氮化碳纳米片用于光催化产氢。本发明的亲水性富氮氮化碳纳米片一步合成，合成周期短，产量较高，可以通过调节氯化钾的投入量调节富氮氮化碳的亲水性，用于与光催化产氢。
Absstract of: CN121674994A
本发明公开了一种通过电化学刻蚀提高Mn基高熵合金催化剂电解水析氧反应性能的方法，属于电化学领域。将基底置于包含Fe、Co、Ni、Mn、Mo五种金属的均匀混合盐溶液中进行水热反应，得到高熵合金前驱体，煅烧，得到高熵合金；然后将高熵合金置于(NH4)2SO4溶液中，电化学刻蚀处理，从而实现Mn基高熵合金催化剂析氧反应性能的提高。本方法简单，效果明显，可以获得具有良好的微观形貌的Mn基高熵合金材料，显著增加催化剂的比表面积，提高Mn基高熵合金材料的电解水析氧反应性能。
Absstract of: CN121669247A
本发明公开了一种用于分解水制氢的xM%Co/CemLa1‑mO2‑δ催化剂及其制备方法，制备方法包括：将硝酸铈六水合物与硝酸镧六水合物溶于去离子水，滴加碳酸铵溶液，经恒温搅拌、静置陈化、过滤洗涤、干燥得La‑Ce前驱体粉末；再将硝酸钴溶液浸渍于前驱体粉末，干燥后得到含Co‑La‑Ce的前驱体粉末，高温煅烧制得目标催化剂。本催化剂钴负载诱导氧空位形成，强化了Ce3+/Ce4+循环，加速氧物种迁移，且抑制金属团聚；镧掺杂形成缺陷介电结构，钴颗粒作微波热点，90%以上微波能转化为热能，10s内升温至550℃以上，适配间歇式微波制氢；本催化剂可完全分解水制氢无副产物，减低碳排放，在2.45GHz微波场下制氢效率高，适用于氢气生产、燃料电池等领域，应用前景广泛。
Absstract of: CN121674987A
本发明公开了一种电解水制氢用防止水污染的高效气液分离装置，涉及电解制氢气液分离技术领域，包括：AEM制氢设备以及安装在其上的第一组件，AEM制氢设备包括换热组件、循环水箱、AEM电解槽、接口面板以及气液分离组件；混合产物气流驱动正向叶片部件旋转，其弧形扭曲叶片的“螺旋加速”效应可进一步增强离心力场强度，弧形叶面对气流动能的捕捉效率提升，确保叶片稳定高速旋转；正向叶片部件通过联动锥齿轮传动带动反向叶片部件反向旋转，反向叶片的锯齿形倾斜结构与气流形成剪切角，可高效破碎未完全分离的液滴团聚体，锯齿边缘对中心涡流的“切割”作用减少微小液滴逃逸率，使气液分离效率整体提升，氢气纯度升高。
Absstract of: CN121669274A
本发明属于复合材料制备领域，公开了一种H‑ZISv/Au‑Ag HAPs复合材料及其制备方法和应用，解决现有光催化剂的光催化析氢性能差的问题。H‑ZISv/Au‑Ag HAPs复合材料为空心Au‑Ag合金纳米粒子负载在含硫空位的空心ZnIn2S4纳米笼上形成的，是一种新型的双空心等离子体肖特基异质结光催化剂。该材料通过协同多光散射/反射效应与定向电荷转移，促进载流子的大量生成；且具有高效的热电子激发及卓越的光热转换性能。优化后的肖特基结、等离子体近场增强以及双腔体约束所产生的协同效应，提升了光热辅助光电化学反应。该催化剂在AM 1.5G光照、25℃条件下具有16 mmol g‑1 h‑1的氢气生成速率和优异的稳定性。
Absstract of: CN121674991A
本发明属于电催化水分解技术领域，涉及一种自支撑W‑NiCoP/NF复合材料及其制备方法与应用。将钴盐、对苯二甲酸、乙酸以及泡沫镍进行第一溶剂热反应，获得缺陷型Co‑MOF/NF；将缺陷型Co‑MOF/NF浸入至钨酸盐溶液后进行第二溶剂热反应，获得缺陷型W‑Co‑MOF/NF前驱体；将缺陷型W‑Co‑MOF/NF前驱体与磷源在惰性气氛下进行磷化热处理，即得。本发明通过分步溶剂热与气相磷化策略，成功在泡沫镍基底上构建了具有丰富缺陷结构的钨掺杂镍钴双金属磷化物，实现了双金属协同效应与缺陷工程的有机结合，使得制备的自支撑复合材料具有更多的活性位点、更优的电子结构调控效果以及更好的稳定性。
Absstract of: CN121675007A
本发明提供了一种基于磁控溅射的镍铁基碱性水分解催化剂的制备方法，包括以下步骤：S1）将导电基体进行预处理；S2）利于磁控溅射技术在预处理后的导电基体表面依次沉积镍铁基合金层和碳层；S3）重复步骤S2）至少1次；S4）开启脉冲偏压电源对步骤S3）得到的材料进行脉冲处理，再进行低温退火，得到镍铁基碱性水分解催化剂。本申请还提供了镍铁基碱性水分解催化剂及其应用。本申请制备的镍铁基碱性水分解催化剂，具有机械稳定性，高比表面积、活性位点密度高的特点，从而提高了催化剂在碱性水分解应用中的催化活性，并且本申请提供的制备方法简单。
Absstract of: CN121669949A
一种高活性氮掺杂碳负载CoRu纳米合金的制备方法，用于增强增强pH通用型析氢，其特征在于，包括以下步骤：将盐酸多巴胺溶解于含有H2O2和CuSO4·5H2O的水溶液中，经磁力搅拌形成均匀混合物。将碳布经乙醇预润湿后，浸入上述多巴胺溶液中10分钟，取出后用去离子水洗涤三次，经真空干燥得到聚多巴胺修饰的碳布，记为PDA/CC。将所得PDA/CC浸入含有Co(NO3)2·6H2O和RuCl3的20 mL水溶液中6小时，实现金属离子吸附。随后将样品洗涤并干燥，在管式炉中于N₂气氛下、700℃煅烧2小时，得到自支撑型氮掺杂多孔碳负载CoRu合金材料，记为CoxRu@CN/CC。通过出了一种基于活性离子捕获与原位碳热还原的合成策略，通过构建氮掺杂碳的钴钌合金纳米结构及强金属‑载体协同效应，实现高效氢溢流与稳定活性位点的创建，从而突破传统电催化剂在宽pH范围内高活性与高稳定性难以协同的性能瓶颈。
Absstract of: CN121669281A
一种用于氨分解制氢的整体式催化剂及其制备方法和应用，所述整体式催化剂包括蜂窝载体、涂覆在蜂窝载体上的涂层材料、均匀分散于涂层材料表面的活性贵金属Ru纳米颗粒；所述蜂窝载体为堇青石载体或碳化硅载体或金属蜂窝载体，蜂窝载体的蜂窝孔密度为300‑750目；所述涂层材料为氧化铝、氧化钛、氧化锆、氧化铈中的一种或几种，涂层材料负载量为120‑240 g/L；所述活性贵金属Ru纳米颗粒的总负载量为0.37‑1.23 wt.%。本发明的整体式催化剂兼具低温高活性、低背压、高稳定性等优点。
Absstract of: CN121674990A
本发明提供一种过渡金属掺杂硫催化剂的制备方法及其析氧应用，涉及催化剂技术领域，包括下述步骤：S1、将乙酰丙酮铁、乙酰丙酮钴、乙酰丙酮镍、乙酰丙酮钼按物质的量分别为0.5‑4 mmol混合，得到第一混合物；S2、将所述第一混合物加入含15‑100mL十八烯的聚四氟乙烯反应釜内衬中，混合均匀后，加入正十二硫醇和油胺，得到第二混合物；其中，正十二硫醇的加入量为5‑10mL，油胺的加入量为5‑10mL；S3、将所述第二混合物投入50‑100mL反应釜，在180‑250℃下一次反应6‑12h，投入2cm×2.8cm‑5cm×5cm的泡沫镍，在180‑230℃下二次反应2‑12h；S4、反应结束后，用正庚烷、乙醇冲洗泡沫镍的表面，真空干燥，得到黑色表面的负载型催化剂FeCoMo‑Ni3S2/NF。本发明能够实现催化材料从实验室样品到小试尺度的面积放大制备。
Absstract of: CN121669273A
本发明提供一种铜掺杂硫化锌镉/铬掺杂钒酸铋中空球复合光催化剂及其制备方法，以及该光催化剂在分解水制氢中的应用。所述材料由如下方法制备：(1)利用水热法制备铜掺杂硫化锌镉纳米粒子；(2)利用水热法制备铬掺杂钒酸铋中空球；(3)将铜掺杂硫化锌镉修饰于铬掺杂钒酸铋中空球表面得到铜掺杂硫化锌镉/铬掺杂钒酸铋中空球复合光催化剂。本发明制备的铜掺杂硫化锌镉/铬掺杂钒酸铋中空球复合光催化剂易于合成，原料来源广泛，具有高催化活性和稳定性，在光催化制氢测试中，3小时内的光催化制氢量可以达到49.1 mmol·g‑1。
Absstract of: CN121669209A
本发明公开了一种铈镧钆三元稀土合金催化剂及其制备方法和应用，属于稀土合金纳米材料合成技术领域，该催化剂采用简便的微乳液法结合一步煅烧工艺制备而成，将三种稀土金属盐溶解加入到到微乳液中，加入氢氧化钾反应得到凝胶前驱体，煅烧凝胶前驱体成功得到具有高结晶度的三元稀土合金纳米粒子。本申请制备工艺简便高效，产物收率高，采用的微乳液结合一步煅烧的合成路线操作简单、反应周期短，有利于实现高产量制备；本发明突破了传统认知中稀土元素难以单独作为催化活性主体材料的局限，拓展了稀土材料在催化领域的应用范围。
Absstract of: CN121675003A
本发明公开了一种催化剂、其制备方法及应用，属于催化剂技术领域。该催化剂为以铜纳米线为基底、多元金属纳米团簇负载在铜纳米线上形成的级联结构纳米催化剂；多元金属纳米团簇与铜纳米线基底的功函数差值为0.05eV以下。本发明应用于电解水/海水制氢方面，解决如何在不使用昂贵贵金属的前提下，开发出一种能同时兼具高本征活性、优异导电性和长期运行稳定性的氢溢流型析氢催化剂，突破现有材料“性能”、“动力学”与“成本”不可兼得的困局，催化剂具有优异的析氢活性和稳定性。
Absstract of: CN121669499A
本发明公开了一种碱性电解水制氢复合隔膜涂布装置，属于隔膜涂布技术领域，包括用于将涂布液涂抹到载膜上的涂抹机构，涂抹机构上设置有用于将载膜和待涂布的基膜送入的送入机构和用于将载膜和基膜进行贴合以将涂布液均匀涂抹在基膜两面的涂布机构；本发明设置的涂抹机构通过设置两个反向转动的涂布辊，并利用齿轮系统确保其同步性，该装置能够将涂布液从两个液腔中同步、等量地转移至两个载膜的内表面，随后，带有涂布液的载膜与基膜在贴合轮处精准汇合，实现了基膜两侧涂布液的同步、均匀施加，这种设计从根本上避免了传统单面涂布或分步涂布可能存在的两面涂层厚度不均、性能差异大的问题，有效保证了复合隔膜两侧理化性能的一致性与可靠性。
Absstract of: CN121672594A
本发明涉及LDH材料制备技术领域，公开一种阴离子掺杂CoFe基LDH材料的制备方法，包括如下步骤：S1、先将纯净泡沫镍置于丙酮、HCl溶液中清洗，再用无水乙醇和去离子水冲洗，干燥处理；S2、将Co源与Fe源溶解在去离子水中搅拌得到A；S3、将S1得到的材料浸入不锈钢高压釜中的溶液A内；S4、高压釜密封反应后，取出样品，用去离子水冲洗3次，干燥得到催化剂CoFe‑LDH；S5、将CoFe‑LDH与含阴离子的溶液进行阴离子掺杂，反应后清洗干燥得到CoFe‑LDH‑NO2‑产物。本发明调控工艺简单、易于操作、重复性强且对环境友好，并且可通过市面上普遍的阴离子掺杂方法合成不同的双金属LDH催化剂，优化其催化性能。
Absstract of: CN121672474A
本发明属于电化学能源材料技术领域，涉及一种生物炭电极及其制备方法与应用，所述生物炭电极的原料包括以下重量份的组分：水热生物炭2‑6份；导电炭黑1‑3份；聚四氟乙烯1‑3份；所述水热生物炭由小麦秸秆、水稻秸秆或玉米秸秆经水热反应制备而成。本发明的生物炭电极具有成本极低且绿色可持续；电催化活性高，性能接近商用活性炭催化剂；稳定性优异，在恒定电流为100mAcm‑2工作85小时后才出现电压显著升高的情况；且制备工艺简单、可规模化，具有极高的商业化应用前景。
Absstract of: CN121669310A
本发明提供了一种4BX交联给受体异质结纳米颗粒的制备及其光催化产氢应用，属于光催化领域。本发明提供了一种4BX交联给受体异质结材料，所述4BX交联给受体异质结材料包括4BX交联的给受体异质结基体；所述4BX交联的给受体异质结基体的制备原料包括给体、受体和交联剂；所述交联剂包括4BX。本发明含4BX的交联剂插入到给受体异质结基体和小分子的C‑H键中，从而在纳米颗粒内部形成贯穿整个颗粒的三维共价交联网络，实现了从热力学亚稳态到共价稳固态的根本性跨越，并将给体与受体组分牢固锁定，增强了分子间相互作用，并成功保留了纳米尺度的本体异质结互穿网络结构。
Absstract of: CN121672727A
本发明涉及富氢水制备领域，具体为一种高效制备富氢水的水壶，包括外壳，所述外壳内部设置有清水槽和富氢水槽，清水槽和富氢水槽的下方连接制备槽，制备槽内部一侧设置有气压卡块，制备槽的两侧设置有清理板与阻水板，制备槽的底部两侧设置有升降板，两侧升降板之间设置有控制板，控制板的上方设置有矩形凹槽状的固定滑槽，升降板上方设置有与固定滑槽相同的矩形凹槽，制备槽下方与控制板对应的位置设有升降槽，升降槽的一侧设置有镁块槽，镁块槽内部设置有夹持件，夹持件一端夹持着镁块，且镁块与固定滑槽相适配，清理板的上方设置有矩形的固定卡槽；本发明可对镁块进行挂刷，将镁块上反应产生的氢氧化物进行清理，便于后续的反应发生。
Absstract of: CN121684529A
本发明提出一种基于联邦安全强化学习的绿氢综合能源园区协同调控方法，包括步骤：1、获取所述异构制氢集群的运行参数；步骤2、根据获取的异构制氢集群运行参数，针对碱性电解槽ALK与质子交换膜电解槽PEM的不同响应特性，分别建立涵盖电化学反应、瞬态热动力学演化及气体纯度演化过程的非线性多物理场模型；步骤3、根据步骤2中建立的模型，针对可再生能源的不确定性波动，基于多情景鲁棒预测构建系统的鲁棒安全运行约束；步骤4、根据建立的鲁棒安全运行约束，构建集成安全防御机制的多智能体强化学习奖励函数，生成本地分布式运行策略；步骤5、根据步骤4中生成的本地分布式运行策略，利用联邦学习机制实现异构制氢集群的全局协同控制。
Absstract of: CN121669286A
本发明公开了一种高结晶度氮化碳胶体及其制备方法和应用。本发明在含有空气的密闭环境中，将盐酸胍与硫氰酸钾混匀，并于520～575℃下煅烧后，加水分散即得。本发明采用特定的原料盐酸胍与硫氰酸钾，经特定工艺制得的产物具有较高的结晶度、亲水性与稳定性，进而具有优异的光催化性能，尤其在分解水制氢的催化中，5 h内的平均产氢活性高达235.4μmol.h‑1（为体相氮化碳的17.1倍）。
Absstract of: CN121675018A
本发明涉及一种高韧性碱性电解水制氢用复合隔膜及其制备方法，所述复合隔膜由主体聚合物、增韧聚合物、造孔剂、亲水性无机填料和增强骨架组成。本发明实现了复合隔膜在高温、碱性环境下服役寿命长、面电阻低，且制备工艺简洁、成本可控，有效解决了传统复合隔膜在制氢过程中易弯折开裂的难题。
Absstract of: CN121675019A
本发明涉及吸氢机控制技术领域，公开了一种电解水制氢系统及制氢方法；通过调取用户的呼吸生理参数，并结合炎症因子指数以及制氢环境参数得到电解制氢特征，并获取吸氢机智能控制方法，利用电解制氢特征和吸氢机智能控制方法构建电解制氢调控模型，本发明基于处理后的用户炎症因子指数结合呼吸生理参数及制氢环境参数来构建吸氢机制氢线性判别分析模型，基于吸氢抗炎症作用，结合处理用户多重强相关生理参数得到电解制氢特征，根据测试集中的炎症因子指数综合修正模型，使得模型更加精准智能地得出吸氢机实时智能控制方法，降低常规模型输出控制方法的错乱率，获得的吸氢机智能控制方法更具操作性。
Absstract of: CN121675011A
本发明涉及一种微量贵金属掺杂材料Pt‑FeS/Co3S4@NF及其制备方法和应用；旨在提供一种用作水电解中的阴极析氢反应和阳极析氧反应时，具有电催化活性高、电化学反应速率快、过电位低等优点的催化剂，解决了现有异质结构催化剂材料所存在的高过电位等问题；其制备方法包括如下步骤S1：清洗泡沫镍；S2：将Co(NO3)2·6H2O、Fe(NO3)3·9H2O、尿素和氟化铵、去离子水加入反应釜，搅拌均匀得到混合溶液，升温至130~170℃，维持10～15h，得到FeaCob(OH)x(NO3)y·mH2O/FeO(OH)@NF粗品，干燥得到FeaCob(OH)x(NO3)y·mH2O/FeO(OH)@NF前驱体；S3：将氯铂酸均匀分散在FeaCob(OH)x(NO3)y·mH2O/FeO(OH)@NF前驱体的表面，待其自然烘干后，得到Pt‑FeaCob(OH)x(NO3)y·mH2O/FeO(OH)@NF；S4：将制备好的Pt‑FeaCob(OH)x(NO3)y·mH2O/FeO(OH)@NF和硫脲分别放在瓷舟的两端，置于管式炉中间位置，硫脲位于管式炉的上游，通入氩气，在250~350℃下硫化2～3h，然后自然冷却至室温，得到微量贵金属掺杂的材料Pt‑FeS/Co3S4@NF。
Absstract of: CN121675012A
本发明属于电催化和能源材料技术领域，具体涉及稀土元素掺杂碳包覆磷化钼双功能催化剂及制备方法。该方法包括以下步骤：1）筛选制备原料，所述原料包括稀土金属盐、四水七钼酸铵、碳源和含磷螯合剂；2）对步骤1）得到的所述原料按比例称量，并在一定量去离子水中进行均匀混合，随后在60‑100℃温度下蒸干得到预产物；3）将步骤2）得到的所述预产物进行研磨并在800‑1000℃温度下热解处理，得到稀土金属掺杂碳包覆磷化钼双功能催化剂。含磷螯合剂的引入有效实现稀土元素均匀掺入磷化钼晶格。稀土元素的引入，实现磷化钼表面电荷密度重新分布，优化反应中间吸附物的吸附能，其本身作为反应活性位点，进一步激活磷化钼析氧活性。
Absstract of: CN121672416A
本发明公开一种基于水伏效应增强光催化性能的薄膜器件及其产氢方法，其包括：PVC基底层；多条相互间隔设置的碳浆导线，覆盖于PVC基底层上；以及二氧化钛薄膜，设置于PVC基底层上的一个连续区域内，且覆盖连续区域内的全部PVC基底层以及至少两条碳浆导线。本申请以PVC为基底层，并在基底层上形成碳浆导线，再由二氧化钛薄膜连通碳浆导线以形成基于水伏效应增强光催化性能的薄膜器件，该器件在蒸发及光照条件下，可实现水伏效应与光催化过程原位耦合，提升产氢效率。
Absstract of: CN121678506A
本发明公开了一种用于碱性电解水制氢电极寿命的检测方法，包括实验设备的搭建和实验操作，实验设备包括烧杯电解槽、清洗烧杯、脉冲电源、超声清洗器、温度计、真空干燥箱和四氟板夹持件，烧杯电解槽内盛装有测试溶液A，烧杯电解槽与脉冲电源连接，四氟板夹持件上设有多个电极固定孔，每个电极固定孔内装载一个电极样品，四氟板夹持件上还设有测温孔，测温孔能固定温度计；清洗烧杯内盛装有测试溶液B，四氟板夹持件能夹持着电极样品放入测试溶液A中进行电化学反应，或者将电极样品放入测试溶液B中清洗，烧杯电解槽和清洗烧杯均能放置在超声清洗器中进行震荡操作；本方法通过在烧杯电解槽内进行高电密反复启停测试，预测出实际电极的使用寿命。
Absstract of: CN121675016A
本发明公开了一种贵金属掺杂过渡金属氧化物电催化剂及其制备方法和应用，属于电催化剂领域，本发明以金属有机框架（MOF）作为自牺牲模板，通过通过分步掺杂与可控热解工艺得到贵金属掺杂过渡金属氧化物催化剂，实现了贵金属原子在过渡金属氧化物晶格中的均匀分散，有效调控了材料的电子结构，提高了其导电性和活性位点数量。本发明的方法有效地提升了过渡金属氧化物作为电催化剂的催化性能，且制备流程简单，设计的反应条件温和，显著降低了贵金属用量，体现出显著的技术进步性和工业应用价值。
Absstract of: CN121669256A
本发明公开了一种WO3‑NiO/ZnO载氧体及其制备方法和应用，属于氨制氢技术领域。其技术方案包括以下步骤：1）ZnO载体的合成：将乙酸锌溶解于水中，调节pH，搅拌，过滤洗涤，干燥煅烧得到ZnO；2）NiO/ZnO的制备：将ZnO分散于水中，加入六水合硝酸镍、尿素反应；所得沉淀在室温下老化，过滤，并洗涤，然后干燥；最后，煅烧，得到NiO/ZnO；3）WO3‑NiO/ZnO载氧体的制备：将NiO/ZnO分散于水中，加入六水合硝酸钨，室温沉淀，过滤、洗涤，干燥，得到的固体进行煅烧，并二次煅烧，得到载氧体。本发明制备的载氧体用于催化氨制氢具有好的催化活性、选择性和稳定性。
Absstract of: CN121675010A
本发明涉及碱性电解水制氢技术领域，尤其涉及一种镍铁钼三元金属氢氧化物纳米片及其制备方法和应用。本发明提供的镍铁钼三元金属氢氧化物纳米片，具有独特的“掺杂‑缺陷”双功能协同体系，实现了“金属元素协同掺杂”与“缺陷位点增强活性”的双重作用，为其优异的催化性能奠定了基础。同时，由纳米花组装而成的褶皱纳米片形态以及超薄的纳米片微观结构，不仅增大了镍铁钼三元金属氢氧化物纳米片的比表面积，还为析氧反应过程中的物质传输提供了便利通道，灵活的结构也让镍铁钼三元金属氢氧化物纳米片在催化条件下能够进行一定的自我调节，更好地适应反应环境，增加活性物种并优化原子配位。
Absstract of: CN121674997A
针对碱水电解槽析氧电极构筑领域，现有方法制备的析氧催化电极存在活性差、稳定性不足，不足以满足碱水电解制氢工业的要求。本发明公开了一种序构功能化的析氧电极的制备方法，其具体流程如下：（1）粗化、除油、除氧化物层；2）三阶段脉冲电镀；3）磁控加热致密化处理4）有氧刻蚀。
Absstract of: CN121674988A
本发明公开了一种用于电解制氢的自适应密封控制装置及控制方法，所述自适应密封控制装置包括液压油缸、一对大梁以及沿所述大梁的纵向依次间隔设置在一对所述大梁之间的活动端板和固定端板；活动端板和固定端板的两侧分别与两个大梁滑动连接，且固定端板的两侧与两个大梁的端部之间设置有弹性缓冲组件，弹性缓冲组件用以限制所述固定端板不脱离所述大梁，并在受压后向固定端板提供反弹力；液压油缸设置在大梁的另一端，其活动端与活动端板固定连接；活动端板远离固定端板的一端设置有锁紧机构，锁紧机构用以将所述活动端板与所述大梁固定。本发明可保证在较大的热‑机械波动载荷下将预紧力自适应控制在设计范围内，提高控制精度。
Absstract of: CN121673502A
一种咪唑鎓基离子交换聚合物及其制备方法和在电解水中的应用，涉及离子交换膜技术领域，解决了现有阴离子难以在保证高碱稳定性的同时提升电化学性能的问题。将大位阻咪唑型单体、靛红单体、芳香单体以及酮类单体加入容器中，加入二氯甲烷，搅拌溶解，冰水浴下滴加三氟甲烷磺酸，室温下反应得到聚合物溶液，乙醇中析出，洗涤干燥。酮类单体为N‑甲基‑4‑哌啶酮或3‑奎宁环酮时，将聚合物溶于二甲亚砜，碱性加热条件下与卤代化合物进行季铵化反应。将聚合物在盐酸溶液中离子交换3次后烘干，再溶于极性溶剂，在玻璃板上流延浇铸成膜；聚合物膜在碱性溶液中浸泡得到离子交换膜。本发明可用作阴离子交换膜电解水隔膜，具备显著的商业化潜力。
Absstract of: CN121675008A
一种多钼酸晶体衍生的电极材料的制备方法及在电解水析氢中的应用，它涉及一种电极材料的制备方法和应用。本发明的目的是要解决MoS2基催化剂的边缘活性位点少、导电性差及易团聚的问题。方法：一、制备氧化石墨烯溶液；二、制备MoS2‑rGO@CC；三、电沉积Ru制备Ru/MoS2‑rGO@CC复合材料。所述多钼酸晶体衍生的电极材料在电解水析氢中应用。本发明在已构建的MoS2‑rGO@CC三维导电骨架上，采用电沉积方法，利用MoS2边缘及还原氧化石墨烯缺陷处的成核优势，实现Ru纳米颗粒的尺寸可控、均匀负载；Ru与MoS2之间的金属‑半导体界面进一步优化了电子结构，提升了复合材料的电化学活性与稳定性。
Absstract of: CN121674978A
本发明涉及硫化氢制氢技术领域，公开了一种电解硫化氢制氢的方法和系统，包括：将硫化氢和氢气分别通入电解池中，进行电解反应，得到氢气和硫磺；其中，所述电解池包括固体电解质层，固体电解质层将电解池分隔成阳极室和阴极室，所述阳极室包括阳极，所述阴极室包括阴极；所述阳极包括钙钛矿氧化物阳极材料和第一质子导体；所述固体电解质层包括第二质子导体；所述第一质子导体和第二质子导体分别选自钙钛矿型质子导体。本发明创造性地提出了将质子导体用于H2S电解制氢的电解装置中，能够兼具高效、稳定、低能耗的制氢特性，实现了高效制氢与硫磺联产。
Absstract of: CN121675000A
本发明涉及一种Fe2O3/FeS纳米片异质结构电催化剂、其制备方法及应用。本发明的制备方法：将六水合氯化铁、硫源和乙二醇加热混合，得到低共熔溶剂DESs；将低共熔溶剂DESs置于微波反应器中加热，之后用清洗剂进行洗涤，干燥，得到所述Fe2O3/FeS纳米片异质结构电催化剂。本发明所提供的制备工艺简单，条件温和，制备成本低，可工业化生产。得到的异质结构Fe2O3/FeS纳米片电催化剂具有优异的电催化活性。
Absstract of: CN121675017A
本申请属于光电化学分解水制氢应用领域，更具体地，涉及一种金属‑卟啉聚合物/钒酸铋复合光阳极及其制备方法和应用。本发明通过电聚合方法，首次在BiVO4表面成功原位聚合了聚过渡金属‑5,10,15,20‑四（四二苯氨基苯基）卟啉催化剂，成功使得过渡金属锚定的分子聚合物催化均匀分散在BiVO4复合光阳极，显著的提高了BiVO4的水氧化动力学和光生电荷转移效率，促进了光电催化的性能，并呈现了良好的稳定性。
Absstract of: CN121675041A
本发明提供了一种多元合金析氢电极及其制备方法，涉及析氢材料制备技术领域。一种多元合金析氢电极的制备方法，包括以下步骤：采用两电极电镀法，以导电基体作为阴极置于电镀液中，进行电镀；电镀液中包括：pH缓冲剂、络合剂、铁源、钴源、钼源和镍源；电镀两电极电镀法的电镀温度为20~50℃；络合剂包括柠檬酸三钠和酒石酸钾钠中的至少一种。本发明通过复合电镀方法，在导电镍基金属基体表面构建一层成分可控、结构致密的镍基多元合金析氢镀层。解决了现有技术中存在的析氢电位高、稳定性差、镀层结合力弱的问题，制备得到低能耗、长寿命的碱性制氢电极。
Absstract of: WO2025078381A1
The various embodiments of the present invention disclose a water electrolyser using alkaline medium, comprising: a first end plate and a second end plate and a plurality of cells stacked in-between the first and the second end plate. Each cell comprises an anode cell frame and a cathode cell frame, each cell frame further comprises a central opening, at least one inlet channel transversing through the cell frame, and at least one inlet pathway grooved in the cell frame for connecting the inlet channel to the central opening. The inlet pathway comprises an inlet orifice <b>characterized by</b> a minimum cross-sectional area in the inlet pathway. The cross-sectional area of the inlet channel in the stack is greater than the sum of the cross-sectional area of the plurality of inlet orifices in the stack by at least a predetermined factor, the predetermined factor being larger than 1 and smaller than or equal to 4.
Absstract of: CN120004436A
The invention relates to the technical field of industrial solid waste comprehensive treatment, and discloses a water treatment method and system after secondary aluminum ash hydrogen production, and the method comprises the following steps: collecting hydrolysate after secondary aluminum ash hydrogen production to obtain high saline-alkaline ammonia nitrogen hydrolysate; carrying out ammonia-nitrogen separation on the high-salt-alkali ammonia-nitrogen hydrolysate to obtain a gas phase and a first-stage liquid phase; dissolving carbon dioxide in the first-stage liquid phase until a specified pH value is reached to obtain a second-stage liquid phase; dissolving carbon dioxide in the second-stage liquid phase until the specified pH value is reached to obtain a third-stage liquid phase; adding an extracting solvent into the third-stage liquid phase, dissolving carbon dioxide until the specified pH value is reached, and extracting and separating to obtain a fourth-stage liquid phase of an organic phase and a fourth-stage liquid phase of an inorganic phase; evaporating moisture of a fourth-stage liquid phase of the inorganic phase; and carrying out back extraction separation on the fourth-stage liquid phase of the organic phase to obtain an inorganic liquid phase and an organic liquid phase. By adopting the method, aluminum hydroxide and various valuable salts can be efficiently recovered, and the obtained product is rich and high in value.
Absstract of: WO2025021544A1
The invention relates to a cell frame (100) configured to be integrated in an electrolyzer. The frame is forming a closed shape having an inner contour (InnCont) that defines an opening (Op) extending in an extension plane (ExtP1). The inner contour is presenting at least two steps (St1, St2, St3, St4, St5, St6) each comprising a first surface (S1) perpendicular to the extension plane and a second surface (S2) parallel to the extension plane. The respective second surfaces of two (St1, St3, St5) of the steps is configured to support two respective bipolar plates (BP-1, BP-21, BP-22).
Absstract of: TW202511178A
To provide: an ammonia-hydrogen mixed fuel production apparatus capable of stably obtaining hydrogen from ammonia even when there is a change in the required ratio of fuel; and a fuel supply system. An ammonia-hydrogen mixed fuel production apparatus 1010A comprises: an oxygen separation device 13 that separates oxygen (O2) 12 at a desired concentration from air 11; a reforming reactor 15 that converts ammonia (NH3) supplied from a raw material supply unit 14 into hydrogen (H2) by using the oxygen having the desired concentration from the oxygen separation device 13; and a gas component analyzer 17 that measures the concentration of one or both of hydrogen and ammonia in a reformed gas 16 from the reforming reactor 15.
Absstract of: US2025263322A1
Methods, systems and devices for PFAS destruction including adding a sulfite salt to an aqueous solution containing PFAS and then irradiating the aqueous solution with light at 222 nm. The method may include adding a base to the aqueous solution in an amount sufficient to raise a pH of the aqueous solution including PFAS to about 10 or more. It may also include adding a halide salt such as a bromide salt or an iodine salt, and further adding a carbonate. Greater than 90%, or greater than 99%, of the PFAS in the solution may be destroyed by irradiating the aqueous solution in this way.
Absstract of: CN121653760A
本发明公开了一种具有提纯净化功能的管道检测用制氢设备，涉及制氢设备技术领域，包括制氢箱、集氢罐、过滤提纯设备、检测装置、冷却装置和水泵，制氢箱内设有多安装腔及连接结构，电极电解电解液产生氢气后，经过滤装置滤除杂质与水分，再通过提纯装置去除残存微量氧气及水分，控制设备通过储气罐与控制阀动态调节气体流通速率，匹配氢气产出与提纯速率；检测装置基于可汽化液体、滑动变阻器实现温度监测，联动冷却装置及水泵完成电解液温控，避免温度骤升骤降。
Absstract of: CN121653691A
一种分区点状碱性电解水制氢极板流道，它涉及水电解制氢技术领域。本发明解决了现有的碱性电解槽流道结构中，由于电解液流动不均匀、存在流动死区，导致气体产物局部累积、气泡滞留电极表面，进而引起局部过热、电压升高和能耗增大的问题。本发明流道本体沿电解液流动方向被依次划分为六个功能区，区域Ⅰ为阶梯状排布的正方形单元，区域Ⅱ为尺寸较小的菱形单元，区域Ⅲ至Ⅴ为纵置矩形单元，其中区域Ⅳ与区域Ⅲ错列布置，区域Ⅴ与区域Ⅳ顺列布置，区域Ⅵ为菱形单元。这些单元的形状、尺寸与排布相配合，共同提高了流道内电解液流动的均匀性。本发明可用于碱性水电解制氢装置的极板中，能有效提升制氢效率并降低能耗。
Absstract of: CN121653708A
本发明属于电催化领域，尤其涉及一种过渡金属氮化物CuInP2Nx、制备方法、应用。本发明将Cu、In、P、S置于真空环境中，于600‑750℃下反应2‑8天制备得到CuInP2S6，将CuInP2S6进行纳米化处理得到CuInP2S6纳米片；CuInP2S6纳米片在氨气氛围下进行氮化，得到过渡金属氮化物CuInP2Nx。原料不含贵金属，成本低廉且易获得；过渡金属氮化物CuInP2Nx的制备过程简单，设备条件容易满足。将本发明得到的CuInP2Nx用于电催化分解水的阳极析氧反应(能够取得良好的催化效果，达到商用IrO2水准；且长期使用后性能未发生明显衰减，稳定性明显优于商用IrO2。
Absstract of: CN121653749A
本发明公开了一种双齿配体支撑的共价有机框架析氢催化剂及其制备方法和应用，将1,3,5‑三甲酰基间苯三酚与邻苯二胺加入到有机溶剂Ⅰ中混合均匀，脱气后加入酸催化剂进行反应，反应结束后将得到的滤固经有机溶剂Ⅱ洗涤并干燥，得到共价有机框架，将其与金属盐加入到有机溶剂Ⅰ中混合均匀，脱气后加入酸催化剂进行反应，反应结束后将得到的滤固经有机溶剂Ⅱ洗涤并干燥，得到金属掺杂共价有机框架，将其与双齿配体加入到有机溶剂Ⅰ中混合均匀，脱气后加入酸催化剂进行反应，反应结束后将得到的滤固经有机溶剂Ⅱ洗涤并干燥，即为所要制备的双齿配体支撑的共价有机框架析氢催化剂。本发明制备方法简易，合成周期短，制备成本低，对环境非常友好。
Absstract of: CN121653755A
本发明涉及能源转换与存储技术领域，公开了一种电解水制氢的动态调节方法、系统及装置，包括：接收下游实时氢气需求信号、实际产氢速率和电解槽健康状态向量；基于所述信号及历史数据，利用氢气需求预测模型，预测未来氢气需求序列；根据该预测序列，结合电解槽性能模型，通过求解一个优化函数，确定最优目标产氢速率；基于该最优目标产氢速率作为设定值，执行闭环控制算法，生成调节控制指令；以及，在一定情况下控制制氢任务从主电解槽组平滑切换至备用电解槽组。本发明通过集成需求预测、动态优化与智能诊断，实现了对制氢过程的前瞻性精细调节，显著提升了能源利用效率、系统响应速度以及氢气供应的连续性与可靠性。
Absstract of: CN121653721A
本发明涉及催化电极制备加工技术领域，具体涉及一种利用飞秒激光实现微结构调控的一体化凝胶复合电极制备方法，包括S1：配制金属盐凝胶溶液；S2：在电极基底上涂覆凝胶溶液，形成凝胶薄膜；S3：利用飞秒激光处理基底表面的凝胶薄膜；S4：用去离子水冲洗电极基底表面，获得一体化凝胶复合电极。实现了催化剂与基体结合紧密，不易脱落，延长电极使用寿命。
Absstract of: CN121653686A
本发明涉及电解槽技术领域，尤其涉及一种具有隔膜固定结构的电解槽及隔膜固定方法。电解槽包括极框、隔膜和流道压片；所述极框上具有安装电极片的电极承载面以及孔道面，所述孔道面高于所述电极承载面，且位于电极承载面的径向外侧，孔道面上开设有环形凹槽，所述环形凹槽沿极框的轴线方向布置，环形凹槽的径向内侧形成环形凸条；所述隔膜安装在电极片上，隔膜的外圈弯折形成折边结构，所述折边结构嵌入所述环形凹槽内；所述流道压片位于所述隔膜的径向外侧，并抵接在所述折边结构的径向外侧。隔膜在电解槽整个生命周期内能够与电极板保持恒定位置，从而提升电解槽的长期运行稳定性与安全性。
Absstract of: CN121653701A
本发明属于电催化材料改性技术领域，具体涉及一种粗糙蜂窝状泡沫镍铁催化剂及其制备方法和应用。本发明提供的粗糙蜂窝状泡沫镍铁催化剂的制备方法，包括以下步骤：将预处理后的泡沫铁和复合盐溶液混合，于50～70℃进行水热反应，然后清洗，即得；其中，复合盐溶液是将氯化钠、碘化钠、氯化镍溶于水中制备得到。本发明提供的制备方法，在水热反应中同时引入氯和碘离子进行协同调控，不仅改善了泡沫铁的多孔蜂窝状结构，还克服了单一氯离子引入时的腐蚀问题，尤其是有效增加了表面粗糙度和活性位点，显著提升了材料的析氧催化性能，实现了形貌和析氧催化活性的双重优化，能够为开发新型高效自支撑电催化剂提供新的途径。
Absstract of: CN121648905A
本发明提供了一种双S型异质结复合材料及其制备方法与应用，所述异质结复合材料包括TiO2纳米片，所述TiO2纳米表面负载有Na+‑Bi2O3纳米颗粒。本发明在{101}/{001}晶面共暴露的锐钛矿TiO2纳米片特定晶面上定向生长Na+‑Bi2O3纳米颗粒，构建了具有双S型异质结结构的TiO2{101}/Na+‑Bi2O3双功能光催化剂，可解决传统单S型异质结电荷传输路径单一和复合率高的问题，同时突破三元双S型异质结制备工艺复杂和界面可控性差的局限，从而实现光生载流子的高效分离与迁移。本发明的异质结复合材料具有光催化分解水制氢的优异活性，此外其在协同光催化产氢与四环素降解应用中也展现出优异性能。
Absstract of: CN121653710A
本发明属于催化剂材料技术领域，提供一种自支撑氮氧化钛催化剂的制备方法及其应用。所述制备方法包括以下步骤：1）将碳布通过三电极体系进行氧化处理；2）通过水热反应在碳布表面生长氧化钛纳米阵列；3）将所得氧化钛纳米阵列通过氮化反应制备自支撑氮氧化钛L；4）将氮氧化钛L置于双氧水取出后进行微波加热得到自支撑氮氧化钛阵列催化剂。本发明所制备的自支撑氮氧化钛催化剂呈现紧密结合的方式排列，可暴露丰富的催化活性位点，通过调节氮化反应可调控氮氧比进而优化催化剂的电子结构，从而表现优异的电解水析氢性能；该方法具备操作简便、成本低、可控性强等优点，适用于大规模生产，在电解水制氢工业中展现出广阔的应用潜力。
Absstract of: CN121653723A
本发明属于电解海水技术领域，具体涉及一种适用于电解海水的木质素碳基高熵合金复合材料及其制备方法。本发明以可再生木质素为碳源，先经模板碳化‑酸蚀工艺制备多孔活性炭载体，再采用脉冲焦耳热技术实现高熵合金的快速负载，通过瞬时高温‑快速冷却完成合金纳米颗粒原位生长，无需长时间高温保温，制备工艺简便高效、参数易控，适合规模化生产；所制复合材料形成单相固溶体结构，合金颗粒分散均匀，活性位点多、电子传输效率高；在真实海水电解中OER催化性能优异，过电位低、塔菲尔斜率小，100h稳定性测试无衰减，抗氯离子毒化能力与耐久性远超商用RuO2催化剂，应用前景广阔。
Absstract of: CN121653737A
本发明属于电解水催化剂技术领域，公开了一种Ni‑Ho‑MOFs复合催化剂及其制备方法和应用。所述复合催化剂是将镍源、钬源、有机配体加入溶剂中磁力搅拌，再将溶液pH值调至5~6，制得MOFs前驱液，在80~150℃进行水热反应制得。将该复合催化剂负载到基体上制得负载Ni‑Ho‑MOFs复合催化剂的电极。本发明的Ni‑Ho‑MOFs复合催化剂具有较好的析氢效率和稳定性，提高了水电解制氢的电解效率，可用于碱式电解水制氢气领域。
Absstract of: CN121655960A
本申请提供了一种用于制备不同氘丰度水样的装置，该装置包括进料单元，用于提供天然水，天然水包括氘水和氢水；电解制氢单元电解天然水生成标气，标气包括氢气和氘气；水氢液相催化交换单元，包括在第一方向上依次连通的第一进料口、催化交换柱和第二进料口，第一进料口用于将天然水传输至催化交换柱，第二进料口用于将氘气传输至催化交换柱。催化交换柱催化氢水和氘气发生氢同位素交换反应，得到沿第一方向上氘丰度依次增大的水样。催化交换柱包括沿第一方向依次设置的至少两个出料口，每个出料口与至少一个积液器连接，每个出料口输出的水样的氘丰度不同。本申请的装置通过液相催化交换联合电解的方法，可以同时获得不同氘丰度的水样。
Absstract of: CN121653732A
本发明属于电催化材料技术领域，公开了一种锡掺杂非晶态羟基氧化镍铁电催化剂及其制备方法与应用。本发明提供了合成锡掺杂非晶态羟基氧化镍铁电催化剂的方法，摒弃贵金属元素，以铁、锡等廉价金属为主要原料，结合低温水热法与快速浸泡工艺，显著降低能耗与设备投入，避免传统高温煅烧或复杂溶剂热步骤，工艺流程可控性强，适合规模化生产。本发明不仅制备出了电催化活性高、稳定性优异的锡掺杂非晶态羟基氧化镍铁电催化剂，无高污染副产物，且泡沫镍基底可直接作为电极使用，省去后续负载工序，大幅缩短制备周期，具备良好的工业推广前景。
Absstract of: CN121653712A
本发明公开了一种镍铁基析氧催化电极的制备方法及应用，镍铁基析氧催化电极的制备方法包括：选用镍基底为阴极、纯铁材料为可溶性阳极并进行预处理，且所述纯铁材料的尺寸大于所述镍基底；将镍盐溶液和添加剂混合搅拌均匀并调节pH，得到电镀液；将所述电镀液转移至电镀槽并将作为可溶性阳极的纯铁材料和作为阴极的镍基底浸入电镀液中，对所述镍基底进行恒电流电沉积并在所述镍基底表面形成镍铁基催化层；将恒电流电沉积得到的镍基底清洗并烘干，得到镍铁基析氧催化电极。该镍铁基析氧催化电极的制备方法能够保证镍铁基催化层与镍基底的稳定连接，提高了催化层的性能。
Absstract of: CN121653722A
本发明涉及催化剂技术领域，发明公开了一种自支撑多尺度多孔NiCrFeAlZn高熵合金全解水产氢催化剂及其制备方法，在泡沫NiCrFeAl合金表面通过电镀锌、退火和腐蚀锌原位构筑多孔高熵合金；泡沫NiCrFeAl合金作为基底载体的同时为多孔高熵合金的原位构筑提供金属来源；基底与高熵合金层间的无缝一体化结合可以为NiCrFeAlZn高熵合金催化剂提供优异的电解水传质效率，高熵合金效应可以产生丰富的高活性位点，大孔结构可以显著提高催化剂在碱性溶液中的长期催化稳定性与耐腐蚀能力；该催化剂在碱性介质中均展现出优异的析氢、析氧以及全水分解电催化活性和稳定性，并可以在安培级电流密度下实现长期稳定的全水电解制氢，同时具有制备工艺经济、简便、高效，适合大量制备的特点。
Absstract of: CN121653689A
一种碱性电解水制氢系统，其包括电解槽、氢侧分液器、氢侧洗涤器、纯水管路、第一监测装置和控制装置。电解槽包括氢侧出口。氢侧分液器包括氢侧混合液入口、氢侧分离气出口和氢侧回流液入口，氢侧出口与氢侧混合液入口连通。氢侧洗涤器包括氢侧洗涤入口、第一回流口和第一纯水入口，氢侧洗涤入口与氢侧分离气出口通过第一管路连通，第一回流口与氢侧回流液入口连通。纯水管路设置有纯水调节阀，纯水管路与第一纯水入口连通。第一监测装置设置于第一管路，用于监测第一管路的流体中碱的质量浓度。控制装置与第一监测装置以及纯水调节阀信号连接，并配置为当第一监测装置的数值大于或等于第一质量浓度时，增大纯水调节阀的开度。
Absstract of: CN121648845A
本发明公开了一种耦合氨分解的正压防爆系统及控制方法。该系统包括依次连接的氨气供应模块、正压防爆柜、第一纯化模块、第二纯化干燥模块、钯触媒反应器、纯化干燥模块和氮气储罐。氨气在防爆柜内反应器中被催化分解为氢氮混合气，经纯化分离后，氮气及残余氢气进入钯触媒反应器与空气反应除氢，最终获得高纯氮气存储并回用于维持防爆柜正压。该系统创新性地实现了脱附气中氢气与氮气的综合利用，通过增压机和钯触媒反应器协同调压，精确控制防爆柜压力。采用低温催化剂及优化设计的方管式反应器结构，热效率高、能耗低、体积紧凑，安全可靠，适用于爆炸性危险环境。
Absstract of: CN121653680A
本发明公开了一种ALK电解槽的槽模块结构、槽模块的控制方法和系统，包括：氧气先导瓶的一端通过氧气压力管线与电解槽连接，氧气先导瓶的另一端通过氧分离器压力进先导瓶管线与氧分离器连接，氧气先导瓶的另一端通过氧先导瓶泄压管线与外部连接；氢气先导瓶的一端通过氢气压力管线与所述电解槽连接，氢气先导瓶的另一端通过氢分离器压力进先导瓶管线与氢分离器连接，氢气先导瓶的另一端通过氢先导瓶泄压管线与外部连接；每个阀门分别设置于不同管线上，用于控制每条管线的连通状态。本发明利用氢氧先导瓶和若干管线构建的槽模块结构，在低功率时隔离无需启动的电解槽，实现AKL单槽模块独立运行和停机操作，延长ALK电解槽寿命。
Absstract of: CN121653718A
本发明涉及电解水制氢技术领域，尤其是涉及一种富含Pt‑C键的催化剂及其制备与应用。本发明首先将含Pt原料浸渍在碳材料上，后处理后得到Pt‑C前驱体；然后将上述得到的Pt‑C前驱体研磨后置于水蒸气氛围中，利用惰性气体产生的等离子体进行低温还原处理，得到富含Pt‑C键的催化剂。本发明提供的方法简单、处理温度低、处理速度快、电子能量高、步骤简单、安全可靠、不使用有毒试剂；所制备得到的富含Pt‑C键的催化剂可在全pH范围下应用于电催化产氢，远优于现有商用铂催化剂。
Absstract of: CN121653754A
本公开提供了一种制氢系统的控制方法、装置、电子设备、介质及程序产品，控制方法包括：基于混合预测模型获取风光出力预测功率；构建制氢系统多状态模型；基于风光出力预测功率融合制氢系统多状态模型，构建多级优化框架；基于多级优化框架获取制氢系统中各电解槽的制氢分配量。本公开基于风光出力预测功率融合制氢系统多状态模型，构建多级优化框架；并基于多级优化框架获取制氢系统中各电解槽的制氢分配量，提高了风光出力预测精度低和系统运行效率，降低了运行维护成本。
Absstract of: CN121653746A
本发明属于材料合成及电催化领域，涉及一种简单的四元合金氧化物的制备方法及其在电化学碱性析氢、析氧反应中的催化应用。先将含镍盐、钴盐、铁盐和钌盐的金属盐溶液与有机配体溶液充分混合后，加入载体，进行水热反应，得到四元金属有机配合物前驱体；再将金属有机配合物前驱体在惰性气体保护下进行热解处理得到四元金属合金氧化物。通过有机配体对金属离子的预分散与配位作用，在相对较低温度下实现了四元金属的均匀合金化；以镍、钴、铁为主体结构，掺入少量贵金属钌形成多元合金氧化物，减少了钌的用量，降低了成本，且制备的四元合金氧化物具有更高的OER、HER活性和稳定性，本发明制备方法简单，成本低，具备良好的工业化应用前景。
Absstract of: CN121653748A
本发明公开了一种电催化剂及其制备方法和应用，属于电催化分解水制氢技术领域。所述电催化剂为镍铁合金/氧化镍铁/羧甲基聚苯胺/泡沫铁（NiFe‑O@c‑PANI/IF）；该电催化剂微观结构呈纳米片状。该电催化剂的制备方法是：首先把乙酸镍、硫酸铵、苯胺溶解在水中，电沉积反应30 min后，烘干；后加入溴乙酸溶液浸泡6 h；便得到复合材料NiFe‑O@c‑PANI/IF。以该复合材料为电催化剂，用于催化OER反应，反应活性高，稳定性好。以本发明所制备的NiFe‑O@c‑PANI/IF同时作为阳极和阴极，组成电解池（NiFe‑O@c‑PANI/IF||NiFe‑O@c‑PANI/IF）用于电解水，取得了良好的催化效果；同时该电解池电解水的催化稳定性好，在经历了1100 h i‑t测试后，电解水的性能没有明显降低。
Absstract of: CN121653758A
本发明涉及电解制氢技术领域，特别涉及一种电解制氢系统承压自动排水的方法，所述方法包括：同步获取目标系统氢气侧和氧气侧的阀门状态数据和压力数据，构成氢气侧状态数据集和氧气侧状态数据集；基于氢气侧状态数据集，通过氢气侧排水控制策略，监控阀门状态并与系统压力协调控制；基于氢气侧排水和氧气侧排水之间的耦合关系，建立协调排水策略并结合自适应排水时长控制策略，形成整体排水策略，以提高目标系统的整体运行效率。
Absstract of: CN121651455A
本公开涉及一种镍铁双金属氢氧化物催化剂及其制备方法与应用，在所述催化剂的XRD图中，仅在2θ为30~40°之间有非晶态峰包，且在所述催化剂的Raman图中，在460~480 cm‑1和540~550 cm‑1处分别存在特征峰。本公开的催化剂该镍铁氢氧化物催化剂为非晶态，催化剂形貌呈现纳米片状颗粒，且具备NiOOH的活性物质，在碱性电解水析氧反应中具有较高的活性和优异的稳定性。
Absstract of: CN121653750A
本发明涉及一种碳负载高熵金属/高熵金属化合物复合催化剂的制备方法，属于电催化材料领域。结构特征在于：高熵金属颗粒原位锚定在生物质炭材料表面，并经热氧化处理形成高熵金属/高熵金属化合物复合相，均匀负载于碳载体上，所述方法包括以下步骤：将生物质材料浸渍于高熵金属化合物盐溶液，经冷冻干燥得到碳负载高熵金属合金前驱体材料；随后将前驱体材料在惰性气氛下进行高温热处理，得到碳负载高熵金属合金复合材料；最后通过热氧化处理，制备得到碳负载高熵金属/高熵金属化合物复合催化剂。该方法所制备的催化剂具有高熵金属/高熵金属化合物均匀锚定于生物质炭表面的复合结构，有效调控了碳载体的微观形貌并暴露出丰富的活性位点。其在酸性电解水析氢反应中表现出优异的催化活性和长期稳定性，且制备工艺简便、成本低廉，在能源转换与催化领域具有良好的应用前景。
Absstract of: CN121653714A
本发明公开了一种基于2‑甲基咪唑配位效应制备的自支撑电极及其衍生方法与应用，本发明先将泡沫镍（NF）经盐酸处理后，去除了NF表面氧化物。再通过水热反应使得2‑甲基咪唑N的孤对电子与Ni的3d空轨道发生配位效应，在泡沫镍表面形成配体层，避免Ni在空气中以及电解液中的氧化。最后，高温碳化使得2‑甲基咪唑在NF表面演化成碳氮层（CN），获得自支撑电极NF@CN。CN层的引入增加了非金属活性位点，提高了自支撑电极NF@CN的反应活性，使得NF@CN在电解水中展现出良好的电化学性能。同时，NF表面形成的CN层缓解了电极在酸性或中性电解液中的氧化溶解。此外，在CN和Ni的协同作用下形成了高导电性的三维网络，并增大电解水的反应动力学。
Absstract of: CN121653678A
本发明涉及电解海水制氢技术领域，具体涉及一种应用于海洋场景下的封闭式电解水制氢系统及方法。本发明包括密封壳体，以及设置于密封壳体内的电解制氢管路、氧侧分离管路、氢侧分离管路、电解冷却管路和消氢除湿管路；消氢除湿管路，包括位于氧侧分离管路和氢侧分离管路之间的风机、消氢装置，消氢装置的一端通过管路与氧气排放口相连，另一端通过电磁阀与氮气瓶相连；消氢除湿管路还包括氢气浓度报警器和氧气浓度报警器；本发明集成电解制氢、氧/氢侧分离、电解冷却、消氢除湿等多管路；各管路协同运作，实现气液高效分离、温度精准控制、安全消氢除湿，形成完整且高效的制氢体系，能稳定适应海洋复杂环境，保障制氢过程安全、持续、稳定进行。
Absstract of: CN121653711A
本发明公开了一种镍铁基催化电极的制备方法及应用，该镍铁基催化电极的制备方法包括：将第一纯镍材料作为阴极，第二纯镍材料作为阳极并对所述第一纯镍材料进行预处理；将镍盐溶液、铁盐溶液和添加剂混合搅拌均匀并调节pH至酸性，得到电镀液；将所述电镀液转移至电镀槽并将所述第一纯镍材料和第二纯镍材料浸入电镀液中，在20至30 ℃温度下，以20至60 mA/cm2的电流密度对所述第一纯镍材料恒电流电沉积20至40 min，以在所述第一纯镍材料表面形成镍铁基催化层；将表面形成镍铁基催化层的第一纯镍材料清洗并烘干，得到镍铁基催化电极。该制备方法通过控制电沉积电流密度及时间可以有效地避免因铁沉积量过多导致催化层性能不佳的问题。
Absstract of: CN121653713A
本发明公开了一种双功能电极的制备方法、电极及应用，其中制备方法，包括以下步骤：（1）电镀液配置：以去离子水为溶剂，依次加入硫酸镍、硫酸铵、氯化铵、硫代硫酸钠，搅拌均匀后调节pH值至4.5‑5.5；（2）电极预处理：取用双面喷砂的镍丝网作为阴极，再依次除油、去除氧化层；（3）电化学沉积：将预处理后的阴极与镍基拉伸网阳极放入电镀液中，阴阳极分别连接电源负极与正极，室温下以5‑20mA/cm2的电流密度恒电流沉积30‑90min，得到双功能电极。本发明通过优化电镀共沉积工艺制备NiS合金，利用多硫化物保护层的双重抗铁机制，实现高电化学活性与抗铁吸附性能的统一，降低电解槽能耗，延长运行寿命。
Absstract of: CN121653705A
本发明属于电解池技术领域，具体涉及一种用于电解池析氧的复合微孔层结构及其制备方法，包括依次层叠设置的基底层、气泡脱离层、气泡生长层、气泡形核层和驱除气泡层；气泡脱离层与电解池的阳极侧腔口连接；气泡形核层与气泡生长层的内部设置有连续的分支状孔喉；气泡形核层为周期性结构，其中：谷部形成优先形核区域，且底部与孔喉相连；驱除气泡层设置于气泡形核层上优先形核区域以外的位置；驱除气泡层朝向电极界面设置。与现有技术相比，本发明解决现有技术中无法充分解决气泡积聚带来的负面影响。本方案的复合微孔层结构具有增强电极界面反应并促进生成物排出的特点，可实现电解池高效析氧并促进氧气以小气泡形态快速排出。
Absstract of: CN121653702A
本发明公开一种电解水制氢电极的制备方法和应用。本发明将基底材料作为阴极在含镍电镀液中进行电镀，然后作为阳极在酸性溶液中进行电化学/化学刻蚀；其中，酸性溶液中的氢离子浓度为0.1‑1mol/L；电化学/化学刻蚀的电流密度为0.1~5mA/cm2，时间为30~120s。本发明采用电镀+刻蚀工艺，合成了具有微球状镍催化剂的制氢电极，不仅通过电镀使催化剂和基底具有高结合力，使催化剂不易脱离，还通过阳极电化学刻蚀+化学刻蚀工艺刻蚀，使微球增加表面积，提高其电催化活性，能够有效降低电解槽能耗。
Absstract of: CN121648823A
本发明公开了一种利用铝复合粉末和氢氧化钠制备氢气的装置，包括氢气发生器，所述氢气发生器的内部设有分级反应池；所述氢气发生器的上方设有储液罐和储粉罐，所述储液罐和储粉罐分别通过带单向阀的管道连接至反应池；所述氢气发生器的顶部通过带单向阀的管道与氢气缓冲罐连接，所述氢气缓冲罐设有连接至发动机的带电控单向阀的加料管；所述氢气发生器的底部通过带电力可控阀的管道与接收罐连接。本装置整体结构简单，体积小，具体可根据发动机的体量，制备成不同体积大小的装置，易于更换和维修，且该制氢工艺所需的原料成本低、铝的理论产氢量高、制氢速率快且可控、产氢效率高，能够满足发动机燃烧的动态需求。
Absstract of: CN121648829A
本发明公开了一种磁感应加热驱动氨分解快速冷启动的系统、工艺及催化剂，属于氢能制备技术领域。所述系统包括气路单元、装有磁性钴基催化剂的催化剂床、检测单元、磁感应加热装置和氢燃料电池集成单元。所述催化剂以Al2O3为载体，负载金属钴纳米颗粒，具有高饱和磁化强度。系统工作时，磁感应加热装置产生交变磁场，使催化剂自身快速生热，可在10秒内达到氨分解反应温度，实现“秒级”冷启动。同时，该催化剂对氨分解具有高活性，氨转化率接近100%。本发明解决了传统氨分解系统启动慢、能耗高的难题，特别适用于氨动力车辆、便携式燃料电池等需要快速即时制氢的移动场景。
Absstract of: CN121653759A
本发明公开了一种制氢系统动态协同控制方法及系统，通过中央控制器对负荷、温度、压力、液位、气体浓度等多参数进行融合判断，实现各子系统间的协调联动，防止因某一项调节滞后或过冲导致整体失衡，显著提高系统在变工况下的稳定性和抗干扰能力，制氢系统动态协同控制方法不仅提升了设备运行的安全性、稳定性与智能化水平，还为大规模、高效率、低成本的绿色制氢提供了可靠的技术支撑。
Absstract of: CN121653724A
本发明涉及电解水制氢技术领域，特别是涉及一种电解水析氧催化剂的制备方法、产品及应用。电解水析氧催化剂的制备方法包括以下步骤：将2‑甲基咪唑与钴盐和铁盐混匀研磨，之后碳化，得到所述电解水析氧催化剂。本发明成功通过一锅热解法制备了铁钴双金属碳基催化剂，其独特的单原子‑合金纳米粒子协同结构通过铁钴间的电子调控作用优化了反应路径，显著提升了析氧反应（OER）的活性和稳定性。本发明催化剂在1.0 M KOH中表现出低于商用RuO2的过电位和更高的催化活性，同时兼具良好的稳定性与低成本优势。铁钴协同效应源于电子结构优化、合金纳米粒子与单原子在反应中的互补作用以及合金纳米粒子对单原子位点的稳定作用。
Absstract of: CN121653692A
本发明公开了一种多组集装组合撬装式制氢系统及控制方法，涉及制氢技术领域，包括制氢集装箱、电气集装箱、控制集装箱、辅助集装箱、储能应急单元和氮气置换单元。本发明中控制集装箱采用阶梯式调控策略，实现了柔性启停与协同调控，降低电流骤变和温度波动对电解槽的损害，延长部件寿命。间歇待机模式可减少完全停机后冷却与重启的制氢系统设备损耗，实现停机和重启快速切换，满足每日间歇运行需求。同时在长周期停机时，无需排出碱液，氮气置换与充氮保压流程的自动化执行，能够避免碱液浪费与人工操作成本，恢复运行时，也无需重新配碱与长时间预热，大幅缩短重启周期，降低能耗与运维工作量，从而提高制氢的效率。
Absstract of: CN121662191A
一种碱性水电解系统多参数动态性能预测方法、系统、介质及设备，方法中，根据电解单体内部结构和反应机理建立电解单体的电化学、相平衡、两相流模型；根据电解堆内部流道结构，建立电解堆流道的相平衡、两相流模型；根据气液分离器的物理结构及其工作原理，建立气液分离器的气液分离、容积、相平衡、两相流模型；根据连通器内部流道结构，建立连通器的热力学、相平衡、两相流模型，并根据管网的流道结构和流动机理，建立管网的流量分配模型；将建立的各模型进行耦合，形成覆盖电解槽、气液分离器、连通器及管网的全系统多物理场耦合模型，基于动态响应特性预测结果，对氧中氢的生成机制进行动态贡献量化分析。
Absstract of: CN121653733A
本发明提供了一种自支撑钼/氮化钼复合催化剂的制备方法，所述制备方法主要包括以下步骤：1）以高温回流反应在碳布上生长氧化钼纳米阵列作为前驱体；2）将氧化钼纳米阵列进行氮化反应得到氮化钼；3）将氮化钼在氢气和氩气的混合还原气氛下进行涡流加热还原反应，使氮化钼部分还原为钼单质，即制备得到自支撑钼/氮化钼复合催化剂。本发明所制备的自支撑钼/氮化钼复合催化剂中钼和氮化钼之间以异质界面的形式共存，存在丰富的异质界面。同时金属钼单质的引入也加快了钼/氮化钼复合催化剂的电子传输速率，从而增强电解水过程的析氢反应动力学。该方法制备的复合催化剂在电解水制氢领域具备广阔的应用前景。
Absstract of: CN121653725A
本发明属于碱性电解水析氧反应技术领域，尤其涉及一种高熵合金催化剂及其制备方法和应用，催化剂以碳为载体，记作FeCoNiWCd/C。所述高熵合金催化剂的制备方法，包括如下步骤：S1：将碳载体分散于溶剂中，在冰水介质中超声均匀后，再将Fe、Co、Ni、W、Cd五种金属的盐溶液依次加入到溶剂中，继续超声得到均匀悬浊液；S2：将S1获得的悬浊液转移至高压微射流分散仪进行分散，随后将其转移至蒸发仪中进行干燥；S3：将S2中的粉末进行研磨后在管式炉中进行热分解还原，冷却至室温即得到催化剂FeCoNiWCd/C。本发明方法通过高压微射流分散促进碳载体上合金的均匀分布，得到的高熵合金粒径较小且具有较大的比表面积和优异的电催化性能。
Absstract of: CN121653751A
本发明公开了一种基于改性氧化铈的碱性电解水制氢隔膜及其制备方法，涉及碱性电解水制氢隔膜技术领域。通过酸溶液对二氧化铈进行改性处理，然后将其分散于聚砜树脂、N‑甲基吡咯烷酮、聚乙烯吡咯烷酮的混合溶液制备得到铸膜液。将聚苯硫醚网浸润铸膜液中，通过刮涂确定厚度，然后预蒸发，通过去离子水中进行相转化，清洗，获得所述隔膜。本发明工艺简单，所制备隔膜表面均匀平整，在强碱性电解环境中兼具高化学惰性、亲水特性、保障氢氧根离子高效迁移通道，且具备低面电阻。
Absstract of: CN121653684A
本申请记载了一种隔膜及其制备方法、电解水装置以及应用。隔膜的制备方法包括以下步骤：在支撑层的一侧表面或两侧表面形成铸膜液的液膜；对形成有所述液膜的所述支撑层进行相转化处理，固化所述液膜，制备复合膜，将所述复合膜置于助交联溶液中进行助交联处理，制备所述隔膜；其中，所述助交联溶液包括助交联剂。本申请提供的隔膜通过优化制备流程，在复合膜制备完成后浸入助交联剂溶液的后处理可以优化复合膜各层结构间界面相容性，可以提高隔膜的耐高温的稳定性。
Absstract of: CN121653727A
本发明涉及一种快速制备高性能自支撑析氢催化电极的方法，属于电解水制取氢气技术领域，该制备方法包括：首先对基底材料进行酸洗、醇洗和水洗等预处理步骤，然后在一定温度和压力条件下，将预处理后的基底材料浸入前驱体溶液中进行化学反应，施加适当时间的超声处理，使其充分反应，随后取出进行洗涤干燥。本技术方案可快速、低成本和大批量的制备电解水析氢电极材料，同时条件温和、效率高，所制备电极具有高催化析氢活性，有望推动碱性电解水制氢技术的商业化发展。
Absstract of: CN121653703A
一种杂多酸锚定硫化镍自支撑电极的制备方法和应用，它涉及能源材料技术领域。本发明的目的是要改善硫化镍的碱性析氧反应性能，解决硫化镍催化剂存在活性位点对OER关键中间体*OH的吸附能力弱，导致水分子活化效率低、中间体转化慢，催化活性与反应动力学受限的问题。方法：一、制备多酸FeMo6；二、泡沫镍预处理；三、制备Ni(OH)2/NF；四、POM晶粒陈化；五、制备POM@Ni3S2/NF。本发明通过FeMo6与Ni3S2的强静电锚定，优化电子结构、提升*OH吸附能力，有效提升了硫化镍电极材料的催化活性和稳定性，其制备工艺无需复杂设备、原料成本低，为非贵金属OER电催化剂的规模化应用提供支撑。
Absstract of: CN121651362A
本发明公开一种多孔活化生物炭和负载铂的生物炭基催化剂及其制备方法和应用。该多孔活化生物炭以红花秸秆为原料，所述多孔活化生物炭具有丰富的多孔结构和层状堆叠形貌，所述多孔活化生物炭以无定形碳结构为主，所述多孔活化生物炭的比表面积为1500‑3300m2/g；所述多孔活化生物炭的孔容积为0.6‑1.6cm3/g，所述多孔活化生物炭中的平均孔径不大于3nm。与传统催化剂碳载体（如炭黑、石墨烯、碳纳米管等）相比，本发明以农业废弃物红花秸秆为原料，通过炭化与活化制备的多孔生物炭材料具有成本低、环境友好、可持续性强等优点。
Absstract of: CN121653761A
本发明涉及PEM电解水制氢领域，为解决现有技术难以满足PEM电解槽长期运行监测的需求的问题，提供一种PEM电解槽的寿命判断方法、系统、介质及设备。一种PEM电解槽的寿命判断方法适用于PEM电解槽处于额定工况且密封正常的情况，包括根据氢气中氧气的瞬时值及氧气中氢气的瞬时值分别与相应设定瞬时值阈值进行比较，来判断是否异常；根据氢气中氧气的瞬时值及氧气中氢气的瞬时值的异常情况，触发相应寿命计算步骤。其能够为部件维护提供依据，同时保障生产安全。
Absstract of: CN121653709A
本发明公开了一种负载过渡金属催化剂的纳米刻蚀银电极及其制备方法和应用，属于电催化材料技术领域，制备方法包括：（1）清洗银基片，利用HNO3对清洗后的银基片进行刻蚀处理，得到刻蚀银电极；（2）向可溶性钴盐和可溶性铁盐的混合溶液中滴加碱溶液，待混合溶液完全沉淀后将溶液pH值调至10~11，在加热条件下反应，制备得到FeCoOOH；（3）使FeCoOOH溶解于乙醇后，将得到的溶液滴加至步骤（1）的刻蚀银电极上，得到所述的负载过渡金属催化剂的纳米刻蚀银电极。本发明方法制得的产品电极催化性能优异，实现了SPR效应诱导的OER性能增强。
Absstract of: CN121648906A
本发明涉及材料制备领域，具体为一种利用掺杂增强Bi4Ti3O12铁电材料光生电荷空间分离的制备方法，解决当前原始Bi4Ti3O12电荷分离效果较差的问题。具体为，按设定比例称取NaCl和KCl作为熔融盐，加入Bi2O3与TiO2为反应物，通过改变熔融盐的种类或者加入其他氧化物来实现不同元素的掺杂，提高Bi4Ti3O12光生电荷空间分离效果。本发明通过熔盐法制备，操作简单、成本低廉，所得产品形貌规则，具有较高的产率和纯度，且光生电荷空间分离效率较高，具备大规模应用的潜力。
Absstract of: CN121662192A
一种电解系统氧中氢检测滞后时间的预测方法、系统、介质及设备，方法中，基于电解槽和槽出口管道的传输滞后时间、气液分离器的气体置换滞后时间、氧中氢检测管路的传输滞后时间、氧中氢检测仪固有滞后时间构建电解系统氧中氢检测滞后时间预测的计算总公式；根据电解槽和槽出口管道的结构尺寸和运行参数计算电解槽和槽出口管道的传输滞后时间；根据气液分离器的结构尺寸和运行参数计算气液分离器的气体置换滞后时间；根据氧中氢检测管路的结构尺寸和运行参数计算氧中氢检测管路的传输滞后时间；根据监测数据的延迟特性确定氧中氢检测仪的固有滞后时间，最后求和得到电解系统氧中氢检测滞后时间。
Absstract of: CN121653726A
本申请公开了一种镍合金包覆铜骨架催化电极及其制备方法。其中，方法包括：对三维多孔泡沫铜基底依次进行溶液原子层沉积成核、自催化放大沉积处理，获得包覆有非贵金属镀层的沉积样品；对沉积样品进行退火热扩散处理，获得退火样品；退火过程中，三维多孔泡沫铜基底中的铜原子向非贵金属镀层扩散，使非贵金属镀层转化为固溶体过渡层，固溶体过渡层中的铜原子浓度由内向外递减；对退火样品依次进行化学脱合金、电化学选择性脱合金处理，溶解固溶体过渡层中的铜富集位点形成贯通纳米孔道，获得镍合金包覆铜骨架催化电极。该方法获得的结构稳定性好，材料表面能暴露高密度晶界与氧空位，显著提升电荷传输效率与活性位点密度，提高催化性能。
Absstract of: CN121653730A
本发明涉及催化剂技术领域，具体公开了一种稀土改性镍铁层状氢氧化物‑氧化物的催化剂材料及其制备方法，催化剂材料的化学式为：NixFe1‑yRey ‑LDH/NixFe1‑yReyOx+3/2/NF(x=2‑4;y=0.01(x+1)‑0.1(x+1))，其中Re为稀土元素，x是Ni2+的摩尔数，y是稀土元素的摩尔数，1‑y是Fe3+的摩尔数；所述催化剂材料具有层状微观结构的阴离子插层的粘土材料。本发明通过采用水热‑烧结‑水热的制备方法制备催化剂材料，制备出具有稳定二维层状结构的催化剂材料，这种结构能够有效防止催化剂在反应过程中的团聚和结构崩塌，从而保持长期稳定的高活性运作。
Absstract of: CN121653700A
本发明涉及一种用于碱性电解水制氢的电极及其制备方法、装置。其中的制备方法包括以下步骤，S1：提供金属电极基底，并对其进行预处理，以形成第一电极基底；S2：将第一电极基底置于抽真空的反应腔中的电极托盘上，通入惰性气体并形成等离子体，对第一电极基底进行表面活化处理，以形成第二电极基底；以及S3：向反应腔中通入含掺杂元素的反应性气体并形成等离子体，对第二电极基底进行表面掺杂处理，在其表面上形成掺杂层，以形成第三电极基底；由此形成电极。本发明提供的制备方法能够实现对电极表面掺杂层厚度的纳米级精准调控，从而改善电极性能。
Absstract of: CN121653752A
本发明公开了一种碱性电解水制氢系统氧中氢含量的优化控制系统及方法，优化控制系统在碱性电解水制氢系统上对应设置冷却水流量调节阀、碱液换热器、碱液循环泵、加热器、碱液流量计、碱液流量调节阀、温度变送器、压力变送器、氧中氢检测仪表、氧气出口薄膜调节阀、真空脱气装置、控制器，对碱性电解水制氢系统运行过程中的关键工艺参数电流密度、碱液流量、槽温、系统压力进行整体调控，同时协同处理碱液循环系统中碱液溶有的氢气气泡，使最后输出的氧中氢含量进一步大幅度降低，显著提高系统降低氧中氢含量的效率，保证系统安全性的同时，提高系统的性能。
Absstract of: CN121653688A
本申请公开了一种制氢系统，属于电解制氢技术领域。制氢系统，包括：电解槽；第一通路，第一通路包括第一加热器和用于储存纯水的储罐，第一加热器用于给流经其上的纯水加热，第一通路可选择性地与电解槽连通；第一气液分离器，第一气液分离器的进口和出口均可选择性地与电解槽连通；其中，制氢系统具有第一工作模式，在制氢系统处于第一工作模式的情况下，第一气液分离器的进口和出口均被配置为与电解槽断开，第一通路被配置为与电解槽连通且第一加热器工作。根据本申请的制氢系统，可在电解槽冷启动时提高电解槽升温效率，同时减小第一加热器加热过程中的能耗，并在制氢系统处于待机状态时，可维持电解槽的温度。
Absstract of: EP4711499A1
An electrochemical half-cell operates to form a gas at a solid surface which may be an electrode. The electrolyte liquid contains an additive, which is a high molecular weight flexible linear polymer or a viscoelastic linear surfactant. A flow path through the half-cell is configured to compel flow of liquid through the half-cell to make a succession of changes of direction. The electrolyte liquid is pumped through the half-cell at rate which is sufficient that the additive and flow path configuration put the flowing electrolyte in a state of elastic turbulence which causes bubbles of gas to detach from the surface on which they are formed while they are still small, freeing the surface area for further reaction. The half-cell may be part of an electrolyser making hydrogen and oxygen from water.
Absstract of: CN121653690A
本发明公开了一种电解水制氢紧固装置及其使用方法，属于电解水制氢技术领域，包括第一均压杆和第二均压杆，第一均压杆和第二均压杆分别平行对称设置在电解槽待紧固的两端外侧，第一均压杆的两端安装有第一连杆组件，第二均压杆的两端安装有第二连杆组件，第一连杆组件和第二连杆组件以电解槽对称设置，第一连杆组件和第二连杆组件之间设有驱动机构，驱动机构能够带动第一连杆组件和第二连杆组件相对运动。本发明解决了传统液压紧固方法成本高、预紧力不均及效率低下的问题，实现对电解槽的均匀、精准、高效的压紧并进行紧固作业，保障电解槽的密封安全。
Absstract of: CN121653734A
本发明提供了一种自支撑碳氧化钼催化剂及其制备方法和应用，所述制备方法主要包括以下步骤：1）加热不锈钢网；2）将不锈钢网在尿素和含钼盐溶液中进行淬火反应引入钼源和碳源；3）交替加热不锈钢网和淬火过程，得到生长含碳的氧化钼纳米片作为前驱体；4）将含碳的氧化钼纳米片前驱体在惰性气氛保护下，通过闪蒸焦耳技术进行快速瞬时加热处理，获得自支撑碳氧化钼催化剂。本发明提供的自支撑碳氧化钼催化剂呈现二维超薄纳米片结构，该纳米片富含氧缺陷具备超亲水能力，能有效增强水分子的吸附并降低析氢反应中间体转化的能量势垒。该方法工艺流程短，制备效率高，适合规模化工业生产，在电解水制氢领域展现出巨大的发展潜力。
Absstract of: CN121653745A
本申请提供的金属原子负载层状氧化锰电催化剂的制备方法，将前驱体溶液与泡沫镍进行水热反应，反应结束冷却至室温，将反应后的泡沫镍干燥处理，得到层状氧化锰电催化剂；将层状氧化锰电催化剂置于金属盐电解液中进行电化学沉积以获取金属原子负载层状氧化锰电催化剂，本申请通过异种原子在氧化锰表面形成金属负载来提升催化剂电催化活性、选择性和稳定性是一个有效的途径。金属负载可进一步调控层间距和电子结构，暴露更多活性位点，通过双金属协同和电子结构调控，可以优化反应动力学；本发明采用水热法结合电沉积法制备金属原子掺杂针状氧化锰电催化剂，制备方法相对更加简单。另外，本申请还提供了金属原子负载层状氧化锰电催化剂及应用。
Absstract of: US20260070783A1
The disclosure relates to systems and methods for the production of hydrogen (H2) from ammonia (NH3) in a membrane reactor that include using ammonia as a sweep gas. Ammonia is converted to hydrogen and nitrogen (N2), and the hydrogen is separated from the nitrogen and unreacted ammonia by passing the hydrogen through a hydrogen-permeable membrane while using ammonia as a sweep gas. The ammonia sweep gas can be separated from the permeated hydrogen and continuously recycled.
Absstract of: JP2026043786A
【課題】太陽光パネルから安定的に電流を取り出して水素を製造することが可能な水素製造システム、水素製造方法、及びプログラムを提供する。【解決手段】太陽光パネル１の出力特性における最大電力点を推定する推定部２１と、最大電力点を基準として、ＭＰＰＴ制御の動作範囲を設定する設定部２２と、太陽光パネル１の出力電力を取得して、電圧を出力するＤＣ／ＤＣ変換器２４と、ＤＣ／ＤＣ変換器の出力電圧にて水を電気分解する電気分解セル３と、太陽光パネル１の動作点が最大電力点に近づくように、ＤＣ／ＤＣ変換器２４の出力電圧を制御する制御部２３を備える。制御部２３は、動作点が動作範囲内であるときには、第１の変動電圧ΔＶでＤＣ／ＤＣ変換器２４の出力電圧を制御し、動作点が動作範囲外であるときには、第２の変動電圧ΔＶ/ｎでＤＣ／ＤＣ変換器２４の出力電圧を制御する。【選択図】 図１
Absstract of: US20260071333A1
The problem addressed by the invention is that of specifying a process for producing lithium hydroxide that is very energy-efficient. The process should in particular manage without using thermal energy. As a raw material, the process should be able to process Li-containing waters that arise when used lithium-ion batteries are digested. The LiOH produced by the process should be of sufficiently high purity that it can be used directly for the production of new LIBs. The process should achieve a high throughput and have a low space requirement so that it can be combined with existing processes for reprocessing used LIBs or for producing new LIBs to form a closed, continuous production cycle. The process according to the invention is an electrolytic membrane process that is operated using an LiSICon membrane. A particular aspect of the process is that the electrolysis is operated up to the precipitation limit of the lithium hydroxide.
Absstract of: US20260070025A1
Calcined or pyrolyzed metal compounds immobilized in membranes based on ionic liquids and/or eutectic solvents. The invention relates to new catalytic membranes synthesized from ionic liquids or deep eutectic solvents and oxidized or pyrolyzed immobilized metal compounds in the membranes. The use of these new catalytic membranes in oxidation/reduction reactions, for application in fuel cells and in water electrolyzers for hydrogen production, is described.
Absstract of: US20260071342A1
There is provided a system comprising burning facility (101); a synthetic fuel production facility (102); a hydrogen production facility; and an oxygen production facility (114); wherein the oxygen production facility (114) is configured to feed the produced oxygen to the burning facility (101) for combustion of fuel at the burning facility (101) using the produced oxygen, and the burning facility (101) is configured to produce a CO2-rich flue gas based on the combustion of the fuel at the burning facility (101) using the produced oxygen, and the burning facility (101) is configured to feed the produced CO2-rich flue gas to the synthetic fuel production facility (102) for capturing the CO2 generated at the combustion in a fuel synthesis.
Absstract of: US20260071341A1
A hydrogen production system includes: an electrolysis module that supplies steam to a hydrogen electrode including a metal component and produces hydrogen through steam electrolysis; a hydrogen storage facility that stores generated hydrogen; a steam supply unit that supplies steam to the hydrogen electrode; a regulation unit that regulates a supply amount of the hydrogen supplied from the hydrogen storage facility to the hydrogen electrode and a supply amount of the steam supplied from the steam supply unit to the hydrogen electrode; and a control device for controlling the regulation unit to switch a heating medium supply state in which a heating medium is supplied from a heating medium supply unit to the hydrogen electrode to a steam supply state in which steam is supplied from the steam supply unit to the hydrogen electrode, in response to the electrolysis module exceeding a first switching temperature when activating the electrolysis module.
Absstract of: US20260074251A1
A fuel cell system including a fuel cell module having an anode inlet configured to receive an anode inlet stream including fuel and an anode outlet configured to output an anode exhaust stream including carbon dioxide and steam, a solid oxide electrolysis cell module configured to receive waste heat and a first portion of the anode exhaust stream from the solid oxide fuel cell module and output an electrolysis output stream including hydrogen and carbon monoxide, wherein at least a portion of the electrolysis output stream is redirected to become a component of the anode inlet stream of the fuel cell module, and a controller configured to operate the solid oxide electrolysis cell module at an endothermic current density
Absstract of: AU2026201233A1
WO 2021/168125 PCT/US2021/018596 The present invention provide a method for manufacturing hydrogen, comprising: deploying a hydrodynamic pump to an ocean, the hydrodynamic pump including an inertial water tube comprising a constricting feature to pressurize ocean water, a pressurized fluid reservoir partially filled with ocean water transported from the ocean to the pressurized fluid reservoir via the inertial water tube, a turbine energized by a flow of pressurized ocean water exiting the pressurized fluid reservoir, an electrical generator coupled to the turbine, an electrolyzer, and a hydrogen tank; transmitting electrical energy from the electrical generator to the electrolyzer to generate hydrogen; and storing the hydrogen in the hydrogen tank. eb e b
Absstract of: WO2026052984A1
The present invention relates to a multipurpose generator for producing gaseous oxygen and hydrogen, water and electricity, comprising a spherical reactor with two external branches of operatively connected components, namely a warm air flow branch and a cold air flow branch. The warm air flow branch contains: a water inlet connected to a vaporiser associated with a water vapour fan device having a non-return valve that channels said flow to a water vapour intake pipe connected to a diffuser. The cold air flow branch comprises: a cold air mass inlet connected to a cold air circulation intake pipe associated with a cooler in turn coupled to a cold air fan having a non-return valve that channels said flow to a pipe connected to a fluid inlet diffuser distributing the cold air mass to the reactor. The invention also comprises two radially opposite electrical connectors.
Absstract of: US20260071336A1
A system for producing hydrogen gas comprising: a heat exchanger module; the heat exchanger comprising: a warming module; and a boiler; a converter module; the converter module comprising a superheater, vaporizer, and/or compressor; an electrolyzer in communication with the converter module; and the electrolyzer in communication with the heat exchanger module. A method for producing hydrogen gas comprising: passing a working fluid into a heat exchanger module comprising warming module and a boiler to form a vapor-phase working fluid; passing the vapor-phase working fluid into a converter module comprising a superheater, vaporizer, and/or compressor to form a converted working fluid; passing the converted working fluid into an electrolyzer to form hot hydrogen gas and hot oxygen gas; passing the hot oxygen gas and/or hot hydrogen gas into the heat exchanger module.
Absstract of: WO2026054606A1
The present invention relates to a porous water electrolysis separation membrane using a boron nitride compound. More specifically, the porous water electrolysis separation membrane comprises a porous polymer support and a boron nitride compound inserted into the inside of the porous polymer support or formed on a surface thereof. The water electrolysis separation membrane according to the present invention as described above exhibits excellent heat resistance and stability and has smaller pore sizes, thereby reducing the permeability of hydrogen and oxygen and achieving high hydrogen gas purity. In addition, with a reduced thickness, the water electrolysis separation membrane exhibits low sheet resistance and thus increases current density to improve electrolytic cell efficiency.
Absstract of: US20260070826A1
A produced water stream in a GOSP is pretreated to remove total suspended solids, emulsified oil, total organic carbon, chemical organics and inorganics, and biodegradable matter. The pretreated produced water stream is further processed to remove hydrogen sulfide gas, which is split in an electrolysis cell to produce hydrogen, sulfur, and water. Following this, bromine gas is removed. The pretreated produced water stream, after the removal of hydrogen sulfide and bromine gas, is further treated using CO2 to produce several minerals. The pretreated produced water stream, after mineral production, is desalinated to produce fresh water and a reject stream. Several valuable chemicals are produced from the reject stream. This process recovers valuable minerals and chemicals from a produced water stream in a GOSP.
Absstract of: WO2026051918A1
The aim of the present invention is to provide an alkaline water electrolysis membrane having good gas barrier property, which can maintain hydrophilicity during operation in long-term electrolysis, inhibit the reduction in ion permeability caused by bubble attachment, and improve the hydrogen production efficiency during the long-term operation of an alkaline electrolytic cell. The alkaline water electrolysis membrane is an electrolysis membrane capable of inhibiting the reduction of hydrophilicity thereof during long-term use and achieving a high production yield of hydrogen. The electrolysis membrane comprises: a porous support, and a porous resin containing a surfactant.
Absstract of: WO2026053545A1
This water splitting device produces hydrogen through irradiation with light and comprises: an electrolytic cell filled with an electrolyte solution and a water splitting cell immersed in the electrolyte solution. The water splitting cell has: a laminate in which an anode electrode, a hole transport layer, a perovskite battery layer, an electron transport layer, and a cathode electrode are stacked in this order; and an electrically insulating protective material that covers the outer periphery of the laminate. Two or more perovskite battery cells are connected in series in the perovskite battery layer.
Absstract of: DE102024208694A1
Elektrolysesystem zur elektrolytischen Spaltung von Wasser, mit einer Elektrolysezelle (1), die zwei Reaktionsräume (2; 3) aufweist, die durch eine semipermeable Barriere getrennt sind, wobei ein Reaktionsraum (2; 3) mit einer Ablaufleitung (9) verbunden ist, durch die Wasser und Gas aus dem Reaktionsraum (2; 3) abgeführt werden. Von der Ablaufleitung (9) zweigt ein Steigrohr 20 ab, in dem ein Gassensor (17) angeordnet ist, der die Konzentration eines Gases im Steigrohr (20) detektiert.
Absstract of: US20260070784A1
A hydrogen generating device may include a water supply device for cartridges; a first hydrogen supply valve provided in a first hydrogen supply passage through which hydrogen gas is supplied from the first cartridge to a buffer tank; a second hydrogen supply valve provided in a second hydrogen supply passage through which hydrogen gas is supplied from the second cartridge to the buffer tank; and a main hydrogen supply passage for supplying hydrogen gas from the buffer tank to outside. For switching a hydrogen supply source from the first cartridge to the second cartridge, a controller may perform: a first process to stop supplying water to the first cartridge and supply water to the second cartridge with the second hydrogen supply valve closed, and a second process to open the second hydrogen supply valve to supply hydrogen gas from the second cartridge to the buffer tank.
Absstract of: US20260074250A1
A corrosion-resistant system, a carbon-free power generation system, and a fuel cell system are provided. The corrosion-resistant system includes an ammonia supply unit; a first conduit connected to the ammonia supply unit; an ammonia decomposition unit comprising a chamber connected to the first conduit; and a second conduit connected to the chamber, wherein an operating temperature of the chamber is 410° C. or lower, the first conduit and the chamber comprise at least one selected from the group consisting of carbon steel, low alloy steel, stainless steel and a nickel-based alloy, and the second conduit comprises a nickel-based alloy (NT) satisfying Equation 1: T≤15 μm.
Absstract of: US20260070782A1
Disclosed are an ammonia supply system, a hydrogen production system, a carbon-free power generation system and a fuel cell system. The ammonia supply system includes an ammonia supply unit; an ammonia demand unit; a connection line that connects the ammonia supply unit and the ammonia demand unit; a hydrogen supply unit; and one or more first hydrogen supply lines that connect the hydrogen supply unit and the connection line, and are configured to supply a hydrogen gas stream, wherein the connection line includes a first pipe controlled to an average temperature of 410° C. or lower and a second pipe controlled to an average temperature of greater than 410° C., and the second pipe includes a nickel-based alloy (NT) satisfying Equation 1 below.T≤15µmEquation1
Absstract of: WO2026054416A1
A method for producing a catalyst for ammonia decomposition according to an embodiment of the present invention comprises the steps of: preparing an aqueous metal precursor solution and a porous support; and forming a metal-support composite by supporting a metal of the aqueous metal precursor solution on the surface of the porous support using a cyclic voltametric electrodeposition method, wherein the content of the metal may be 0.3-3.0 wt% on the basis of the total weight of the catalyst for ammonia decomposition. A catalyst for ammonia decomposition according to another embodiment of the present invention comprises: a porous support; and a metal supported on the surface of the porous support using a cyclic voltametric electrodeposition method, wherein the content of the metal may be 0.3-3.0 wt% on the basis of the total weight of the catalyst.
Absstract of: WO2026054554A1
The present invention relates to an electrode for water electrolysis and a method for manufacturing same, the electrode comprising a metal substrate and a catalyst layer formed on at least one surface of the metal substrate, wherein the catalyst layer includes CoxFeyO4 (0≤x≤4, 0≤y≤3) and satisfies formula 1.
Absstract of: US20260070031A1
An ammonia decomposition reactor, a hydrogen production apparatus and a method for producing hydrogen are provided. The ammonia decomposition reactor may include a first chamber and a second chamber, wherein an operating temperature of the first chamber is 410° C. or lower, the first chamber includes at least one selected from the group consisting of carbon steel, low alloy steel, stainless steel, and a nickel-based alloy, and the second chamber includes a nickel-based alloy (NT) satisfying Equation 1 below.T≤15μmEquation1
Absstract of: JP2026043978A
【課題】水素生成光触媒を用いて、可視光照射下においても水を効率的に水素と酸素に分解できる方法を提供すること。【解決手段】本発明の光による水分解方法は、一種類の光触媒を含み、酸化還元能を有する化合物が溶解した水溶液に対して光を照射する方法である。【選択図】図３
Absstract of: JP2026043516A
【課題】水電解を用いて発生させた酸素および水素から高純度水素および高純度酸素を効率よく製造することが可能な高純度水素および高純度酸素の製造方法および製造装置を提供する。【解決手段】原料純水３の脱気手段３２と、高分子電解質膜を用いる水電解により酸素と水素とを発生させる電解手段３３と、酸素精製手段３５と、水素精製手段３７と、酸素精製手段３５で用いる吸着剤の再生時に流通したパージガスを原料純水３の脱気手段３２に供給する手段を備える。【選択図】図１
Absstract of: JP2026043106A
【課題】セルスタックの集積率を向上させるとともに高温環境の下でセルスタックに圧縮荷重を安定的に負荷させる水素製造技術を提供する。【解決手段】水素製造装置１０は、加熱炉１２の内部の架台１５に固定されるガス流路１１と、ガス流路１１を上下方向から挟み込むように集積される複数のセルスタック２１（２１ａ，２１ｂ，２１ｃ，２１ｄ）と、最下部に位置するセルスタック２１ｄの下部プレート２３に下先端が固定されかつその上部プレート２２を貫通するとともにその他のセルスタック２１（２１ａ，２１ｂ，２１ｃ）の下部プレート２３及び上部プレート２２を貫通する複数のタイロッド２５と、各々のタイロッド２５の上先端を結束する結束プレート２６と、結束プレート２６に設けられ最上部に位置するセルスタック２１の上部プレート２２を付勢する付勢手段３０と、を備える。【選択図】図３
Absstract of: JP2026044182A
【課題】親水性無機粒子の充填性に優れる水電解用隔膜支持体を提供すること。そして、当該水電解用隔膜支持体の提供を通し、水電解の過程で発生したガスを透過しづらくできるという効果や、イオン透過性を向上できるという効果が、効率よく向上している水電解用隔膜を提供すること。【解決手段】本発明の水電解用隔膜支持体は、構成繊維にポリフェニレンサルファイド繊維を含む不織布を備える。そして、本発明にかかる不織布は、繊維の絡合のみにより構成繊維同士が結合している。そのため、本発明にかかる水電解用隔膜支持体が備える不織布は、熱融着するため構成繊維が変形している箇所や、バインダなどにより構成繊維同士が結合している箇所を有していない。その結果、当該不織布は繊維間隙が意図せず閉塞していないものであり、本発明によって親水性無機粒子の充填性に優れる水電解用隔膜支持体を提供できる。【選択図】なし
Absstract of: JP2026043878A
【課題】非貴金属系でアンモニア分解活性を示すアンモニア分解触媒、その製造方法、アンモニアの分解方法、水素製造方法、又、水素製造装置を提供する。【解決手段】アンモニア分解触媒は、複合酸化物、これに担持された非貴金属粒子を含む。複合酸化物は、ＡｘＭｇ１－ｘＯｙ（但し、Ａはアルカリ金属元素及びＭｇを除くアルカリ土類金属元素からなる群より選択される少なくとも１種の元素であるアルカリ系金属元素、０＜ｘ≦０．1、ｙは複合酸化物が電気的に中性を保つのに必要な酸素原子の数）の組成で表される。非貴金属粒子の非貴金属は、Ｃｏ、Ｎｉ、Ｆｅ、又は、これらの合金である。アンモニア分解触媒の製造方法は、準備した上記複合酸化物に上記非貴金属を含む非貴金属前駆体を含浸させて得た含浸体を、不活性ガス雰囲気下にて熱処理し、得られた熱処理物を、水素を含む還元雰囲気下、還元温度３００℃～８００℃で水素還元処理する。【選択図】図４
Absstract of: WO2026050788A1
The invention relates to a device (1) for electrochemically compressing and/or purifying hydrogen, the device comprising a first cell stack (2) having a first electrochemical cell (3) with a first half-cell (4) and a second half-cell (5), wherein the first half-cell (4) and the second half-cell (5) are separated from one another by a first membrane (6), wherein the first membrane (6) comprises a semipermeable first membrane layer (9a) adjacent to the first half-cell (4), a semipermeable second membrane layer (10a) adjacent to the second half-cell (5), and a porous transport layer (11a), disposed in a sandwich-like manner between the first membrane layer (9a) and the second membrane layer (10a), for transporting water by capillary action, wherein the porous transport layer (11) is fluidically coupled to a water reservoir by means of a transport structure (12) such that the first membrane layer (9a) can be humidified with water from the water reservoir.
Absstract of: WO2026050789A1
The invention relates to a device (1) and a method for electrochemically compressing and/or purifying hydrogen, the device (1) comprising a first half-cell (2), a second half-cell (3), and a membrane (5) separating the first half-cell (2) and the second half-cell (3), wherein the membrane (5) comprises a semipermeable first membrane layer (10) adjacent to the first half-cell (2) and a porous transport layer (11) for transporting water by capillary action, wherein the porous transport layer (11) is fluidically coupled to a water reservoir (14) by means of a transport structure (12) such that the first membrane layer (10) can be humidified with water from the water reservoir (14).
Absstract of: WO2026054154A1
According to one embodiment, a vehicle hydrogen generator having a hydrogen generation amount adjustment device may comprise a PEM water electrolysis stack for generating hydrogen by electrolyzing water, wherein the PEM water electrolysis stack includes: a water tank for storing water for generating hydrogen through electrolysis; an electrolysis cell for generating hydrogen by electrolyzing the water provided from the water tank; a water separator which removes moisture contained in the hydrogen provided from the electrolysis cell and which provides the removed moisture to the water tank; and a control unit electrically connected to the electrolysis cell and the water tank.
Absstract of: CN121368648A
The present invention relates to an electrolysis system comprising: a tank adapted to contain water or an aqueous solution; the electrolysis array comprises a conductive plate; the temperature-resistant cathode is close to but separated from the cathode end of the electrolysis array; a cell anode proximate but spaced apart from opposing anode ends of the electrolysis array; wherein a cathode terminal and an anode terminal of the electrolysis array are electrically connected to a cathode terminal and an anode terminal of a first power source adapted to provide direct current (DC) power thereto, respectively; the temperature-resistant cathode and the tank anode are electrically connected to a negative terminal and a positive terminal of a second power source adapted to provide DC power thereto, respectively; and at least the temperature resistant cathode is adapted to generate a plasma arc in the water or aqueous solution between the end of the temperature resistant cathode and the closest plate in the electrolysis array.
Absstract of: WO2026053829A1
Provided is a device capable of producing high purity hydrogen gas. Provided is a method capable of producing high purity hydrogen gas. This hydrogen gas production device comprises a cathode, an anode disposed facing one side of the cathode, and a solid electrolyte member disposed between the cathode and the anode, the hydrogen gas production device being provided with a hydrogen gas recovery passage disposed on the other side of the cathode.
Absstract of: WO2026050800A1
The invention provides a membrane electrode assembly for an electrochemical hydrogen compressor, the membrane electrode assembly comprising a proton exchange membrane arranged between an anode and a cathode, wherein the anode comprises an electrocatalyst for dihydrogen oxidation and the cathode comprises an electrocatalyst for proton reduction, and wherein the proton exchange membrane comprises a semicrystalline polymeric matrix comprising a hydrophilic polymer and particles of an inorganic metal compound dispersed in the semicrystalline polymeric matrix.
Absstract of: AU2024328562A1
A reaction medium according to the present invention is characterized by having a chemical structure in which Mn is introduced into a composite iron oxide. It is preferable that this reaction medium is used in a method for producing hydrogen by thermally decomposing water. It is preferable that this reaction medium contains a composite metal oxide of Fe, Co, Ni, and Mn, contains a composite metal oxide of Fe, Ni, Mg, and Mn, or contains a composite metal oxide of Fe, Co, Mg, and Mn. A treatment method according to the present invention includes: a first step for thermally reducing the reaction medium; and a second step for bringing the thermally reduced reaction medium into contact with an object to be treated, thereby oxidizing the reaction medium and decomposing the object to be treated.
Absstract of: TW202436694A
A hydrogen generator with extractable filter includes a water tank, an electrolysis module configured in the water tank, a filtering device coupled to the water tank, a humidifying module vertically configured above the water tank, an integrated passageway module vertically configured above the humidifying module, and a condenser configured on the integrated passageway module. The electrolysis module is configured to electrolyze water contained in the water tank to generate gas comprising hydrogen. The humidifying module includes a humidifying chamber and a gas passage isolated from the humidifying chamber. The filtering device is disposed in the gas passage to receive and filter the gas comprising hydrogen generated by the electrolysis module. The condenser is configured to condense the gas comprising hydrogen outputted by the filtering device. The integrated passageway module includes a gas input channel for guiding the gas comprising hydrogen outputted from the condenser into the humidifying chamber.
Absstract of: AU2024265029A1
A system and method for transporting and distributing hydrogen, reducing the risk of hydrogen leakage, maintaining a record of provenance, and measuring and recording its purity level as it flows from source to destination to assure it complies with a predetermined range of values. The system includes a hydrogen delivery line made from metallic or non-metallic pipe that may be placed inside a safety pipe such that a channel is formed between an exterior of the hydrogen delivery line and an interior of the safety pipe. A sweeper gas or liquid may be injected into the channel to purge any hydrogen that might escape from the hydrogen delivery line, and one or more sensors may be used to detect and avoid the presence of an unacceptable level of hydrogen, or to stop the flow of hydrogen and remediate the problem well before a safety or environmental risk can occur.
Absstract of: CN120835942A
An electrochemical cell stack (1) comprising a plurality of electrochemical cells (2) separated from one another by bipolar plates (5) wherein each electrochemical cell (2) consists of two half-cells (3, 4) having a membrane (6) as a common component, which membrane is held by a multi-piece support frame (7), according to the invention, the multi-part support frame (7) consists of two frame elements (16, 17) of different widths, each of which is stacked on one another from belonging to one half-cell (3, 4) and by inserting a plurality of layers of sheet devices (9) overlapping the membrane (6), on the inner side of each frame element (16, 17) facing the interior of the respective half-cell (3, 4), the frame elements (16, 17) are each provided with a seal (14, 15) which contacts the bipolar plate (5), and the two seals (14, 15) which are offset from each other due to different cross-sectional shapes of the frame elements (16, 17) each contact an outer layer (18, 20) of the sheet device (9).
Absstract of: EP4707230A1
Disclosed is a process for oxidizing a metal and for generating hydrogen and carbon monoxide comprising the steps:i) introduce an organic compound containing carbon and covalently attached thereto hydrogen, a particulate metal selected from the group consisting of silicon, magnesium, iron, titanium, zinc, aluminum or alloy containing two or more of these metals and an oxidant into a reaction chamber, andii) react the organic compound, the particulate metal and the oxidant from step i) in the reaction chamber to generate heat, electromagnetic radiation, oxidized metal, hydrogen and carbon monoxide.The reactor contains a reaction chamber for reacting organic compound, particulate metal and oxidant. Via feed lines the reactants are introduced into the reaction chamber. One or more metering devices are present for metering the amount of reactants introduced into the reaction chamber. In the reaction chamber a flame is generated by the reaction of the reactants. The reaction of metal fuel with oxidant results in an oxidized metal and in the generation of thermal and radiant energy, hydrogen and carbon monoxide. The thermal and radiant energy generated by the oxidation reaction is recovered by using one or more heat exchangers.
Absstract of: KR20260034269A
원자력으로부터의 전력으로 물을 수전해하여 핑크 수소 및 핑크 산소를 생산하는 핑크 수소 생산 시스템 및 천연가스를 열분해하여 청록 수소를 청록 수소 생산 시스템을 포함하는 수소 생산 통합 시스템을 제공한다. 상기 시스템은 상기 핑크 수소 생산 시스템의 부생성물인 핑크 산소가 상기 청록 수소 생산 시스템에 필요한 열 에너지를 생산하는데 이용되고, 상기 청록 수소 생산 시스템에서 배출되는 폐열이 상기 핑크 수소 생산 시스템에서 수전해되는 물에 공급되어 공정 효율성 및 에너지 효율이 우수한 수소 생산 시스템이다. 상기 수소 생산 통합 시스템을 활용한 수소 생산 방법은 고순도의 수소를 제공할 수 있다.
Absstract of: EP4707432A1
The invention relates to an electrolysis arrangement comprising an electrolyzer for performing the electrolysis of an electrolyte, wherein a biphasic flow containing a gas flow and a liquid electrolyte flow is produced in the electrolyzer, and a separator downstream of the electrolyzer and comprising a vessel with a receiving chamber for receiving the biphasic flow from the electrolyzer, wherein the separator is configured to separate the gas flow and the liquid electrolyte flow in the receiving chamber. An explosion damper is arranged within the receiving chamber
Absstract of: EP4707231A1
A process and apparatus for the production of hydrogen, wherein the process comprises the steps of: introducing an ammonia feed (2) into a catalytic cracker (10) under conditions effective for producing a cracked stream (12) ; drying the cracked stream with a temperature swing adsorption (TSA) unit (20) comprising at least two adsorbent beds (A, B) to form a dry cracked stream (22); introducing the dry cracked stream into a coldbox (30), wherein the cold box encloses a heat exchanger and a partial condensation vessel, wherein the heat exchanger is configured to cool the dry cracked stream, wherein the partial condensation vessel is configured to produce a nitrogen enriched stream (34) and a hydrogen enriched stream (32); and introducing the hydrogen enriched stream (32), after warming in the heat exchanger, to a pressure swing adsorber (PSA) unit (40) to form a hydrogen product stream 42 and a PSA off-gas (44).
Absstract of: EP4707429A1
The present application relates to the field of electrolysis hydrogen production technologies, and discloses a water electrolysis hydrogen production system and a method and an apparatus for controlling gas purity in a water electrolysis hydrogen production process, to implement separate control of flow rates at a hydrogen-side inlet and an oxygen-side inlet of an electrolyzer. The water electrolysis hydrogen production system includes an electrolyzer, a hydrogen gas-liquid separation unit, and an oxygen gas-liquid separation unit. A liquid outlet of the hydrogen gas-liquid separation unit is connected to a first pipeline, a liquid outlet of the oxygen gas-liquid separation unit is connected to a second pipeline, the first pipeline and the second pipeline converge and connect to one end of an alkali electrolyte return main pipeline, and the other end of the alkali electrolyte return main pipeline is connected to an oxygen-side pipeline and a hydrogen-side pipeline. The hydrogen-side pipeline is connected to a hydrogen-side alkali electrolyte flow channel inlet of the electrolyzer, and the oxygen-side pipeline is connected to an oxygen-side alkali electrolyte flow channel inlet of the electrolyzer. The hydrogen-side pipeline and the oxygen-side pipeline are respectively provided with a flow rate detection assembly and a flow rate regulation assembly. A hydrogen-side gas outlet of the electrolyzer is connected to the hydrogen gas-liquid separation unit, and an oxygen-side gas o
Absstract of: CN121629478A
本发明公开一种用于析氧反应的多金属磷化物异质结电极的制备方法，包括采用多种非贵金属盐为前体，通过电化学还原法，在导电基底上沉积得到均匀的多金属磷化物组分活性镀层，其中多种金属磷化物结合形成磷化物异质结结构，其与导电基底紧密结合构成自支撑电极材料。本发明的电极材料具有普适性，操作简单、组分可控的优点，在电解水析氧的反应中展现出了优异的催化活性和广阔的应用前景。
Absstract of: CN121629443A
本发明公开了一种镍铁铬催化电极的制备方法及应用，该制备方法包括将镍盐溶液、铁盐溶液和铬盐溶液及添加剂混合并调节pH得到电镀液；将作为阴极的第一纯镍材料和作为阳极的第二纯镍材料放入电镀液，对第一纯镍材料进行脉冲电沉积得到NiFeCr基底；以NiFeCr基底为工作电极，饱和甘汞为参比电极，光镍网为对电极，硫酸为电解质，对NiFeCr基底进行阳极氧化，得到表面具有Ni/Fe‑Cr2O3钝化层的NiFeCr‑A基底；以NiFeCr‑A基底为工作电极，饱和甘汞为参比电极，光镍网为对电极，氢氧化钾为电解质，对NiFeCr‑A基底进行碱性电化学刻蚀，使得Cr3+浸出，Ni、Fe被氧化并与OH‑反应形成NiFe‑OOH层，得到镍铁铬催化电极。该制备方法能避免多金属体系重构过程中元素不受控浸出的问题，确保镍铁铬催化电极的稳定性。
Absstract of: CN121629460A
本发明公开了一种自支撑三金属CC@M‑trimental/PBA材料及其制备方法。该方法先使用聚苯乙烯微球在导电基底上生长CC@PS微米阵列，然后通过电沉积的方法得到CC@PS‑trimental纳米阵列，接着通过浸泡的方法得到CC@PS‑trimental/PBA，最后通过将聚苯乙烯微球模板溶解。该材料是具备独特的大孔特性的自支撑电极，且材料表面具有方块状的PBA物质。本发明提出的方法简单安全，所得产品比表面积高，结构稳固性好，导电性能好且荷质传递速度快，在电催化水解中表现出优异的催化活性，具备良好的应用前景。
Absstract of: CN121626697A
本发明涉及氢能装备智造技术领域，尤其是涉及一种制氢电解槽乳突板的抓取装置及其使用方法，包括箱体，所述箱体上设置有夹持机构，所述夹持机构包括若干夹持组件，每个所述夹持组件包括支撑板、夹板、上楔形块和下楔形块，所述支撑板滑动设置在箱体上，所述下楔形块设置在支撑板上，所述上楔形块位于下楔形块上方且两者的楔形面相对应设置，所述夹板设置在支撑板上，若干所述夹持机构上的夹板相对设置并围合呈夹持区，使用时，通过调节机构对每个夹持组件上的夹板位置进行调节，使得若干个夹持组件之间围合呈所需形状板材的夹持，提高了抓取机构的适用性，同时，配合锁定机构确保在板材抓取过程中，将夹板和支撑板之间锁定，确保板材抓取稳定可靠。
Absstract of: JP2026040917A
【課題】複数の電解モジュールを起動する際に昇圧機によるエネルギ消費の無駄を少なくして、システム全体の効率をより向上させる。【解決手段】電解システムは、電解セルと燃焼部とをそれぞれに含む複数の電解モジュールと、それぞれ対応する電解モジュールの電解セルと燃焼部とに燃料ガスを供給可能な複数の燃料供給系と、複数の電解モジュールの水素極で生成された生成水素を昇圧機により昇圧してタンクに回収する回収ラインと、回収ラインにおける昇圧機の上流側から生成水素を複数の燃料供給系のそれぞれに還流させる還流ラインと、を備える。【選択図】図１
Absstract of: CN121629437A
本发明公开了一种用于电解槽内部电极支撑及气液配流结构的双极板，包括圆形基板和外周上的环形边框，圆形基板厚度小于环形边框厚度且设置于环形边框厚度方向的中部，圆形基板表面设置有直L形导电筋条和圆弧L形导电筋条；直L形导电筋条沿电解液流动方向布置，直L形导电筋条底部设置有V型导流结构；圆弧L形导电筋条设置在V型导流结构与圆形基板底边之间；V型导流结构对应的圆弧L形导电筋条上设置有导流口。本发明能够优化电解液在双极板上的流量分布，促进电解液在双极板上的侧向流动和电解液传质速率，使得电解液流动均匀性和出氢效率提高，同时达到降低隔膜温度，防止隔膜损伤，减小电解槽能量损失的效果。
Absstract of: CN121629436A
本申请提供一种气体扩散层及其制备方法以及电解水制氢装置。气体扩散层包括导电基底及结合在导电基底上的微孔层，微孔层的材料包括石墨化碳材、富氧空位添加剂和耐碱性聚合物。气体扩散层通过在导电基底上设置微孔层，其中微孔层包括石墨化碳材、富氧空位添加剂和耐碱性聚合物，石墨化碳材具有石墨的三维有序结构，使其具有高化学稳定性和抗氧化性，同时富氧空位添加剂可以提供氧空位，石墨化碳材和富氧空位添加剂相互配合从而增强微孔层抵抗碳氧化腐蚀的能力；耐碱性聚合物作为粘结剂将石墨化碳材和富氧空位添加剂粘接在一起并粘接在导电基底上，使得气体扩散层在碱性环境下也具有良好的抗腐蚀性能，延长气体扩散层的使用寿命。
Absstract of: CN121626944A
本发明涉及纳米材料制备技术领域，尤其涉及一种制备钠米CoP的工艺流程，所述工艺流程选用粒径约为20nm的钴粉及选用粒径约为30µm的红磷粉末，在真空手套箱中，使用精密电子天平按照摩尔比1:1的比例准确称量纳米钴粉和红磷粉末，手套箱提供无氧环境，防止原料氧化，在真空手套箱内，使用适当的搅拌工具将称量好的纳米钴粉和红磷粉末混合均匀，混合过程中注意控制搅拌速度和时间；之后将混合后的粉末在手套箱内密封至金属管中，将金属管在管式炉内在惰性气氛下加热至700‑1000K，保温2h。最后降至室温后取出样品，研磨，获得20‑50nm的磷化钴颗粒，本发明提供了一种纳米CoP的制备工艺及应用方法，该工艺流程简单，制备得到的纳米CoP颗粒细小，催化性能高。
Absstract of: CN121629432A
本发明公开了一种双极板密封结构及其监控方法，其中，双极板密封结构包括双极板，在双极板上设有水封线，密封垫片设置在相邻的双极板之间，且通过压合双极板与水封线形成第一级密封；在密封垫片的外侧设有固定环，在固定环上设有若干第一压力传感器和第二压力传感器；第一压力传感器设置在固定环与双极板的接触面上，其用于监测双极板在压合时的压紧力和均匀性；第二压力传感器设置在固定环的内环面，用于监测双极板在运行时的密封状态。本发明通过在密封垫片外侧设置固定环和压力传感器，实现了对压合压紧力和密封状态的实时监测，具有能够实时监测双极板压合时的压紧力和均匀性，以及运行时的密封状态，从而提高密封可靠性和设备安全性的优点。
Absstract of: CN121629463A
本发明属于制氢用隔膜技术领域，具体涉及一种碱性电解水制氢用复合隔膜及制备方法和应用。该复合隔膜的支撑网上覆盖有机‑无机复合涂层，其特点在于，该有机‑无机复合涂层至少含有有机聚合物粘结剂、无机亲水颗粒和氢键有机框架材料。该复合隔膜利用氢键有机框架材料可显著降低隔膜孔径，降低面电阻和碱失率，并提高气密性。
Absstract of: CN121629430A
本发明的课题在于提供一种能够抑制电力成本并且抑制氧电极的电位降低的水电解系统。一种水电解系统，其具有氢电极及氧电极，所述水电解系统具备：电压测定部，其在水电解系统停止时，测定作为氧电极相对于氢电极的电位差的电压；及供氧部，其在所测得的电压降低至预先设定的阈值的情况下，向氧电极供给包含氧的气体。
Absstract of: CN121622448A
本发明公开了一种利用电解水制氢来促进伤口愈合的便携装置，包括制氢机构、输送机构、连接机构和贴敷部；制氢机构包括相互连通的电水解制氢组件和存储组件，电水解制氢组件包括外壳，外壳分隔为阳极室和阴极室，阳极室和阴极室相连，且阳极室和阴极室的连接处设有质子交换膜，质子交换膜的两侧均设有催化电极，外壳的顶面设有单向流通组件，单向流通组件和阳极室连通，阴极室连通存储组件；输送机构为管状，连接存储组件及连接机构，输送机构内设有对氢气输送的气体通断控制装置；连接机构连接输送机构和贴敷部。能够在安全可控的条件下实时生成氢气，并可将氢气精准、定向地输送至创面区域。
Absstract of: US20260071340A1
A catalyst for water electrolysis electrode, a method for preparing the catalyst, and a water electrolysis electrode including the catalyst are provided. A catalyst for water electrolysis electrode according to an embodiment of the present disclosure includes a carbon structure doped with a first element and a second element, and an alloy nanoparticle doped with the first element. The alloy nanoparticle is supported on a surface of the carbon structure, and the first element is iron (Fe).
Absstract of: DE102025116656A1
Das vorliegende System verwendet einen Wasserelektrolysestapel, um Wasser in Wasserstoff und Sauerstoff aufzuspalten. Der Wasserstoff wird an der negativen Elektrode abgeleitet und in einem Wasserstofftank gespeichert, während der Sauerstoff an der positiven Elektrode abgeleitet und in einem Sauerstofftank gespeichert wird. Die gespeicherten Gase können bei Bedarf in den Elektrolysestapel zurückgeführt werden. Sensoren messen die Wasserstoff- und Sauerstoffkonzentration in dem abgeleiteten Fluid, und eine Steuerung vergleicht diese Messwerte mit sicheren Grenzwerten. Ist die Konzentration zu hoch, werden Ventile automatisch eingestellt, um den Durchfluss der gespeicherten Gase zu steuern. Zusätzliche Komponenten wie ein Ejektor und Druckregler tragen zu einem effizienten Betrieb bei und verhindern eine gefährliche Gasansammlung.
Absstract of: CN121629528A
本发明属于水电解制氢用隔膜材料技术领域，具体涉及一种水电解制氢隔膜用PEEK纤维及隔膜基布和用途。该PEEK纤维采用特定冷却和拉伸工艺制备，具有高强度等优势；该基布采用特定织造结构制成且进行了浅磺化处理。由该PEEK纤维及基布制备的隔膜具有强度高、耐久性优良且面电阻和气密性良好的优势，实现了低电阻、高气密性、高强度与长寿命的统一，既适于作为质子交换膜水电解制氢设备的制氢隔膜，也适于作为碱性阴离子交换膜水电解制氢设备的制氢隔膜。
Absstract of: CN121629462A
本发明属于电解水制氢用隔膜技术领域，具体涉及一种PPS包芯纱制备的碱性电解水制氢用隔膜及用途。该隔膜的芯纱为沟槽深度/纤维当量半径大于0.05的十字形或三叶形PPS长丝，外包纱为磺化度10%~12%的短纤，包芯纱芯部占比为60~70wt%，将包芯纱在特定条件下蒸纱后进行织造，然后轻度磺化处理即可制得。该隔膜无需复杂的热轧定型工艺即可显著提高气密性且可显著改善面电阻等指标，具有良好的产业应用价值，且可进行后续亲水无机纳米颗粒负载改性。
Absstract of: CN121635571A
本申请公开了一种脱氧装置的温度控制方法、装置及脱氧装置，属于水电解制氢技术领域。所述方法包括：获取脱氧装置的气体出口端的当前出口温度；基于所述气体出口端的目标出口温度和所述当前出口温度，控制所述脱氧装置的加热器的加热温度；其中，所述目标出口温度在所述脱氧装置进行脱氧工作的第一目标时段内呈阶梯式变化。该方法可以在基于目标出口温度和当前出口温度，对加热器的加热温度进行控制时，避免超调现象，且在保证加热器的加热温度稳定的同时，可以保证气体出口端的气体温度稳定，从而保证稳定控制整个脱氧装置的温度。
Absstract of: CN121629434A
本发明涉及一种用于阴离子交换膜电解水的三明治结构泡沫电极及其制备方法。所述三明治结构泡沫电极具有三明治式的夹层结构，用通式M1M2M1‑NC表示，具体为表面修饰了氮掺杂碳（NC）材料的由两片泡沫金属M1夹一片泡沫金属M2组成的三层泡沫金属结合体（M1M2M1）。与现有技术相比，本发明所制备的M1M2M1‑NC三明治结构泡沫电极中，泡沫金属同时作为结构基底和催化活性位点；表面外延生长的NC包覆层在优化电子传输通道的同时可有效缓解催化剂材料的脱金属溶解问题，有利于延长催化电极的使用寿命；此外，本发明还具有催化活性高、稳定性好，制备方法简单、便捷，可有效降低工业应用成本等优点。
Absstract of: CN121627071A
本申请公开了一种铁镍钼羟基氧化物及其制备方法和应用。提供的铁镍钼羟基氧化物的制备方法包括如下步骤：将钼酸铵、氯化镍和水混合进行反应，制备含钼酸镍的悬浊液；将三氯化铁水溶液与含钼酸镍的悬浊液混合，制备含铁离子修饰钼酸镍的悬浊液；将含铁离子修饰钼酸镍的悬浊液与尿素水溶液混合，进行水热反应，通过固液分离得到中间产物；将中间产物与碱溶液混合，进行刻蚀，制备铁镍钼羟基氧化物。提供的铁镍钼羟基氧化物的制备方法，通过调控原料的混合顺序，解决了传统水热法制备铁镍钼羟基氧化物易产生的无序堆叠和元素偏析，导致活性低、稳定性低的问题，提供的制备方法产量高，能够大规模的制备铁镍钼羟基氧化物，易于产业化。
Absstract of: CN121628179A
本发明公开了一种磁场调控镁铁双金属氢氧化物有序碱性隔膜及制备方法。属于碱性电解水制氢技术领域。针对现有复合隔膜中功能填料无序分布、离子传导通道不通畅的问题，本发明提出磁场辅助构筑定向结构的新方法。该方法在聚合物溶液中，以氯化镁和氯化铁为原料原位合成具有磁性的镁铁双金属氢氧化物，在施加特定方向外加磁场的基板上刮涂成膜，利用磁场力驱动镁铁双金属氢氧化物定向排列，经干燥固化得到复合隔膜。通过该工艺，在隔膜内部成功构筑沿厚度方向贯穿的定向离子传输通道。该方法工艺简单、效果显著，制得的隔膜具有优异的离子电导率和电解性能，为高性能碱性隔膜的制备提供新思路。
Absstract of: CN121633200A
本发明提出了一种电解水用质子交换膜电极的评价方法及评价系统，所述评价方法至少包括以下步骤：提供多个质子交换膜电极；对所述质子交换膜电极进行不同的性能测试，获得多个性能测试数据；对各所述性能测试数据进行数据处理，获得多个性能指标数据；以及基于多个所述性能指标数据，评价所述质子交换膜的综合性能。通过本发明提出的电解水用质子交换膜电极的评价方法及评价系统，能够为质子交换膜电极的性能测试提供统一、全面且客观的行业标准，还能对质子交换膜电极进行综合评价，为电解水用电解电极的选择提供可靠性参考。
Absstract of: CN121629438A
本发明属于催化剂技术领域，公开了一种单原子自旋催化剂及其制备方法和应用。该单原子自旋催化剂，包括磁性元素‑NC基底，以及负载在所述磁性元素‑NC基底上的重金属。本发明的单原子自旋催化剂通过引入强自旋轨道耦合(SOC)重金属(如Ta)与Fe单原子形成间接键合结构(Fe‑N‑Ta)，协同调控Fe的自旋态和自旋极化，显著降低氧中间体的能垒，具有良好的氧析出反应催化效果。
Absstract of: CN121629459A
本发明公开了一种金属原子掺杂针状氧化锰电催化剂及其制备方法和应用，涉及电催化剂技术领域。所述方法采用一步水热法直接在碳纸基底上生长金属原子掺杂的针状氧化锰，制备过程仅需混合前驱体金属离子化合物和高锰酸钾、水热反应和后处理，无需多步合成或复杂插层。本发明通过异种原子掺杂(如Ru、Ni、Co等)诱导晶格畸变和氧空位形成，稳定催化剂表面的活性位点并增加活性位点的数量，从而优化了电子结构和反应动力学，提高催化剂的的电催化活性。
Absstract of: CN121623864A
本申请公开了一种锥状阵列光催化光热双层凝胶及其制备方法与应用，属于氢能制备技术领域。将第一原料混合物填充至模具的阵列结构空腔中，静置形成光催化层前驱体；将第二原料混合物填充至模具的基底层空腔中，静置形成光热层前驱体；对光催化层和光热层前驱体进行冻融循环处理，使其形成具有多孔结构的结构稳定的凝胶材料；进行脱模及后处理，得到一体化结构的光催化光热双层材料；光催化层为从光热层表面突出的阵列结构。本申请通过独特的结构设计，实现了光热层与光催化层的紧密耦合，无需疏水处理即可物理隔离水体与催化剂，有效避免了海水成分干扰，在保证高产水速率的同时，实现了无牺牲剂条件下的高效、稳定光催化制氢。
Absstract of: CN121629450A
本发明属于电化学析氧催化剂材料技术领域，涉及一种氮化硼修饰碳纸负载金属自支撑析氧催化剂的制备方法及应用。该方法通过超声辅助浸渍将二维氮化硼纳米片均匀负载于碳纸表面，构建稳定的导电支撑层。将Fe和Ni在表面活性剂作用下溶解于水中，搅拌至完全溶解，以处理后碳纸作为工作电极，铂片和饱和甘汞电极作为对电极和参比电极，进行电沉积，冲洗，干燥后得到氮化硼修饰碳纸负载金属自支撑析氧催化剂。本发明利用BN进行界面调控增强镍铁催化剂与碳纸基底之间相互作用、优化电子传递；同时为活性组分提供锚定位点，抑制催化剂团聚，提升体系稳定性。该方法简单、低成本、环保，制得的NiFe-BN/CP自支撑催化剂具有高活性、高稳定性。
Absstract of: CN121629431A
本发明属于电解水制氢技术领域的电解水制氢用流道结构。多道下凹组合条（1）上按间隙设置多个下凹部（3），多道上凸组合条（2）上设置多个上凸部（4），每道下凹组合条（1）侧面和相邻一道上凸组合条（2）侧面连接，每道上凸组合条（2）侧面和相邻一道下凹组合条（1）侧面连接，下凹组合条（1）上的每个下凹部（3）水平方向对准上凸组合条（2）上的对应上凸部（4），多道下凹组合条（1）的对应下凹部（3）和多道上凸组合条（2）的对应上凹部（4）形成多道流道直通孔（5）。本发明所述的电解水制氢用流道结构，成本低、加工方式简易，能够有效提供传质通道，降低部件间的接触阻抗，提高电解槽整体性能。
Absstract of: CN121629474A
本发明提供一种涂层件的制备方法、质子交换膜水电解槽及部件，包括采用电刷镀方式，在质子交换膜水电解槽导电部件的表面进行电化学沉积；其中，电刷镀被配置为：仅在导电部件表面预设的目标区域形成贵金属或贵金属合金涂层，目标区域为导电部件表面在微观尺度上的粗糙峰区域，使得当导电部件在质子交换膜水电解槽中间隔地与其他部件压合装配时，粗糙峰区域能够与其他部件形成微观点接触；通过控制电刷镀的施镀区域，使贵金属或贵金属合金涂层优先覆盖于粗糙峰区域，而避免在导电部件表面的除粗糙峰区域之外的区域或非接触区域形成功能性涂层。本发明提高涂层附着力，减少贵金属浪费，提升生产效率，增强部件抗腐蚀性和导电性，延长电解槽寿命。
Absstract of: CN121629440A
本发明公开了一种机械稳定性强的磷化镍泡沫网的制备方法及其在电解水产氢的应用，制备步骤为：原材料装载；气氛清洗及保护性气体通入；煅烧获得机械稳定性强的磷化镍泡沫网；组装电解水产氢装置。本发明的制备方法通过降低煅烧温度以及缩短煅烧时间，降低了制备过程中的成本和时间，并且泡沫网表面形成磷化镍的同时也保留了泡沫网内部的金属镍，使得磷化镍泡沫网表现出高催化活性和强机械稳定性，比现有技术具有显著的技术优势。
Absstract of: CN121629455A
本发明属于电催化技术领域，具体涉及一种Ru基负载型HER催化剂的制备方法和应用。所述催化剂为KTN负载的Ru基催化剂，Ru高度分散在KTN基底中，形成负载型Ru/KTN结构。催化剂通过控制在不同温度和气氛中退火，使Ru均匀负载在载体表面，同时优化了高价态Ru含量。通过调节水热时间及前驱体比例，得到了复合型异质结载体，大大提高了氧化物载体的导电性。协同作用显著增强其在碱性环境下的HER活性与耐久性，同时大幅降低贵金属Ru的使用量，具有优异的性价比和工业化应用前景。
Absstract of: CN121629442A
本发明公开了一种电解水制氢阳极电极及其优化方法，涉及电解水制氢技术领域。该阳极电极包括基底和经硫化处理的非贵金属基催化层，非贵金属合金/化合物选自FeNi合金、FeNi层状双氢氧化物中的至少一种；优化方法通过将非贵金属基阳极基材置于保护性气氛的加热设备中，引入硫源进行高温硫化后冷却实现。本发明可在维持阳极催化活性的同时显著提升其耐碱性与结构稳定性，工艺简易可控、与现有生产流程兼容，可实现米级尺寸电极的均匀优化，为电解水制氢技术工业化推广提供支撑。
Absstract of: CN121633013A
本发明属于氢气检测传感技术领域，具体涉及一种用于水中氢气探测的光纤氢气传感器。所述光纤氢气传感器由解调仪和氢敏光纤组成，所述氢敏光纤自内而外由光纤、包覆在光纤外的WO3/Pt层和包覆在WO3/Pt层外的ePTFE疏水透气膜组成。本发明提供的光纤氢气传感器体积小，克服了传统氢气传感器不适合电解水制氢槽小室内狭小空间的缺点。利用疏水透气薄膜克服了传统光纤氢气传感器在电解槽环境中受水影响造成的光谱抖动，异常干扰问题。本发明的氢气传感器针对电解水制氢槽小室内和出水口及氧气出口中氢氧气体混合无法有效测量氢气浓度的问题提出了实时且稳定的定量手段。
Absstract of: KR20260033150A
본 발명은 티타늄 소스의 수열 반응을 통하여 탄소섬유(CC) 상에 TiO2 나노로드 어레이(NRs)를 합성하여 TiO2 NRs/CC를 준비하는 단계; TiO2 나노로드 어레이가 형성된 탄소섬유를 수소, 메탄 및 아르곤 가스 분위기 하에서 열처리하여, 상기 탄소섬유 상에 Ti4O7 나노로드 어레이를 형성하여 Ti4O7 NRs/CC를 준비하는 단계; 및 상기 Ti4O7 NRs/CC를 작동전극으로 하는 3전극 시스템에서, 니켈염 화합물, 몰리브덴염 화합물, 인산염화합물 및 백금염 화합물을 포함하는 전해질 용액의 전착에 의하여 백금(Pt) 및 인(P)이 이중 도핑된 Ni4Mo으로 코팅된 Ti4O7 나노로드 어레이(Pt, PNi4MoTi4O7 NRs/CC)를 합성하는 단계를 포함하는 수분해 및 Mg/해수 배터리용 촉매의 제조방법을 제공한다.
Absstract of: CN121629466A
一种水电解系统多参数动态性能预测方法、系统、介质及设备，方法中，根据电解堆内部结构和反应机理建立电解堆的电化学、相平衡、两相流和热力学模型；根据气液分离器的物理结构及其工作原理建立气液分离器的气液分离、容积、相平衡、两相流和热力学模型；根据换热器和加热器的内部结构和流动机理建立换热器和加热器的热力学、相平衡、两相流模型；根据管网的流道结构和流动机理建立管网的流量分配模型；形成覆盖电解堆、气液分离器、换热器、加热器及管网的全系统多物理场耦合模型；利用全系统多物理场耦合模型同步预测不同宽功率波动工况下系统内氧中氢浓度、氢中氧浓度、温度、压力、流量、气相分压及液相饱和度的动态响应特性。
Absstract of: JP2026039612A
【課題】貴金属以外の材料で形成され、耐久性が向上した触媒を提供する。【解決手段】触媒は、Ｈｆ（ハフニウム）とＮｂ（ニオブ）とＺｒ（ジルコニウム）とを含み、さらに、Ｔｉ（チタン）と、Ｖ（バナジウム）と、Ｔａ（タンタル）と、Ｍｏ（モリブデン）と、Ｗ（タングステン）とのうちの少なくとも２種類の金属を含む合金で形成され、合金に含まれる金属元素の種類数をＸとしたとき、合金に含まれる各金属元素のモル分率は、（１００／Ｘ－４）％以上（１００／Ｘ＋４）％以下である。【選択図】図１
Absstract of: CN121195089A
The invention relates to an electrolyser (1) for producing hydrogen from an alkaline electrolyte. The electrolyzer (1) comprises a first header (11) and a second header (12) between which a plurality of base cells (20) and a plurality of bipolar plates (5, 5 ', 5' ') are stacked. Each bipolar plate (5) separates two adjacent base cells. According to the invention, each of the bipolar plates (5, 5 ', 5' ') comprises two plate-like parts (5A, 5B) coupled together and configured to define one or more internal cavities (66) for the circulation of a cooling fluid. Furthermore, each bipolar plate (5, 5 ', 5' ') comprises an inlet section (SI) and an outlet section (SV) for an inlet and an outlet, respectively, of the cooling fluid in the one or more inner cavities (66).
Absstract of: US20260002270A1
An enclosure adapted for a hydrogen and oxygen generating apparatus arranged in a movable has an interior and an interior surface and an exterior surface whereby the hydrogen and oxygen generating apparatus comprises at least one electrolyser stack adapted for electrolysing water to hydrogen product gas and oxygen product gas and accompanying gas and electrolyte handling equipment. The exterior surface of the enclosure comprises at least a heat insulating, flexible polymer cover element which is attached to a metal frame.
Absstract of: CN121610809A
本发明公开了一种电解脱硫废水析氯制氢系统及工艺，属于电催化处理废水技术领域。本发明的电解脱硫废水析氯制氢系统包括脱硫废水供给单元、阴极液供给单元、电解单元、资源回收单元、再生水回用单元以及控制单元；电解单元包括阳极室、阴极室以及将阳极室和阴极室隔开的复合膜组件，脱硫废水供给单元与阳极室连通，阴极液供给单元与阴极室连通；电解单元还包括膜污染控制组件，膜污染控制组件包括邻近复合膜组件设置的机械刮刷件，以及驱动机械刮刷件沿复合膜组件表面移动的升降驱动机构。本发明有效解决了高硬度脱硫废水电解过程中膜结垢严重与系统抗负荷波动能力差的技术难题，实现了废水的稳定高效处理与资源化利用。
Absstract of: WO2025048510A1
The present invention relates to a separator in which an anode catalyst layer is coated on one surface of a porous substrate, and an electrochemical cell comprising same, the separator allowing ions to smoothly move through pores of the porous substrate and exhibiting low overpotential due to having the anode catalyst layer coated on one surface thereof.
Absstract of: WO2025039019A1
The present invention relates to an electrolysis system (10), comprising: - an electrolysis cell stack (100) with a cathode portion (110) which has a cathode supply portion (112) and a cathode discharge portion (114), and with an anode portion (120) which has an anode supply portion (122) and an anode discharge portion (124), - an anode gas port (202) fluidically coupled to the anode supply portion (112) by means of an anode supply connection (200) for supplying anode gas to the anode portion (120), - an anode discharge port (316) fluidically coupled to the anode discharge portion (124) by means of an anode discharge connection (300) for discharging anode exhaust gases produced by the electrolysis cell stack (100), - a cathode supply port (502) fluidically coupled to the cathode supply portion (112) by means of a cathode supply connection (500n) for supplying cathode gas to the cathode portion (110), and - a cathode discharge port (612) fluidically coupled to the cathode discharge portion (114) by means of a cathode discharge connection (600) for discharging synthesis gas produced by the electrolysis cell stack (100).
Absstract of: CN121609364A
本发明公开了一种氨基功能化金属有机框架插层MoS2复合材料的制备方法及其应用，包括以下步骤：将氨基功能化金属有机框架Ni‑Val和四硫代钼酸铵在水及还原剂的存在下进行水热反应，得到所述氨基功能化金属有机框架插层MoS2复合材料；该氨基功能化金属有机框架Ni‑Val的化学式为{Ni(L‑Val)(H2O)3(CH3COO)}，其中L‑Val为4‑吡啶甲醛修饰的缬氨酸配体。本发明通过将氨基金属有机框架Ni‑Val作为添加剂加入四硫代钼酸铵水热还原反应中，显著扩大了产物中MoS2的层间距，提高了活性位点的暴露程度，同时引入的过渡金属Ni及氨基可提供更多的活性位点，协同提高复合材料电催化性能。由上述复合材料作为电催化剂用于电催化析氢，达到10mA cm‑2电流密度的过电位可低至138mV，表现出优异的电催化活性。
Absstract of: CN121610806A
本发明属于电解液制备技术领域，尤其涉及一种电解液及应用、输送装置和输送方法。该电解液包括K+；电解液还包括浓度为0.05~0.25mol/L的Zn2+、浓度为5~40μmol/L的Fe3+、浓度为5~50mmol/L的PO43‑、浓度为1.6~34mmol/L的Cr2O72‑、浓度为2.2~22mmol/L的VO43‑；电解液还包括不可避免的杂质，杂质包括Ca2+和/或Mg2+，电解液中Ca2+的浓度≤0.01mol/L，Mg2+的浓度≤0.1mol/L。本发明电解液同时包含上述离子，可以改善现有电解液导致电池电阻上升、电压升高和电流密度下降等情况，进而减少气体测混以及提高气体纯度。
Absstract of: CN121612123A
本发明公开了一种水基基础雷管，包括：水基基础雷管密封罐体，所述水基基础雷管密封罐体一端固定套设有水基基础雷管密封罩，所述水基基础雷管密封罩一端固定穿设有雷管电解负电极，所述水基基础雷管密封罩中部固定穿设有水基基础雷管点火装置，所述水基基础雷管密封罩另一端固定穿设有雷管电解正电极；本发明中通过分别在雷管电解负电极和雷管电解正电极上连接电解电路，在水基基础雷管点火装置上连接点火引爆电路，首先通过雷管电解负电极和雷管电解正电极电解雷管内部电解液，接着通过水基基础雷管点火装置通电，通过点火装置桥丝实现引爆，如此结构雷管在使用时无论是在生产、运输、存储还是安装各个环节都更加安全。
Absstract of: CN121613053A
本发明涉及碱性电解水制氢技术领域，尤其涉及一种在线检测碱性电解系统气液分离器分离效果的方法，包括以下步骤：从氢氧分离器气相出口管路引出气液混合流体，以内置旋流结构与定时反吹执行防堵型富集处理，避免碱液残留堵塞，得到可测量液相；检测采样气体与可测量液相瞬时流量并计算实时夹带率；对可测量液相电导率检测确定分离状态，基于该状态校核实时夹带率，后续结合夹带率变化率、功率预测数据执行分级控制，按预设周期更新控制阈值并记录参数快照供回退。本发明实现分离效果连续在线监测与双向验证，达成分离实时感知，可视化界面展示参数、配置离线存储与故障报修功能，有效改善传统监测滞后性与系统盲运行问题。
Absstract of: CN121610833A
本发明公开了一种高性能低成本碱性电解水复合隔膜及其制备方法。本发明包括亲水支撑网布基底和外部高亲水涂层；所述外部高亲水涂层包括聚合物、无机亲水填料、增强纤维填料和水溶性分散剂。本发明通过在复合隔膜的浆料中引入聚苯硫醚纤维、玄武岩纤维、高耐碱玻璃纤维、尼龙纤维、聚丙烯纤维等绝缘、不溶于有机溶剂且具有较好的耐高温碱液的材料，这些纤维材料可以起到“增强筋”作用，在复合隔膜中可以承担一部分的拉伸力，增强复合隔膜涂层韧性，能明显提升复合膜的抗拉强度、耐弯折及涂层耐摩擦性。
Absstract of: CN121610831A
本发明公开了一种多孔煤基碳纤维负载钴/氮化钴/铈氧化物复合催化剂的制备方法及其在电解水制氢中的应用，属于电解水催化剂技术领域，该复合催化剂以分级多孔煤基碳纤维为载体，其内部封装有铈氧化物，其外部负载有钴/氮化钴活性组分。制备方法包括以下步骤：采用静电纺丝技术将不溶性三氟化铈作为铈源和可溶性聚乙烯吡咯烷酮作为造孔剂封装在纤维内部，经预氧化后通过水热法在其表面生长Co‑MOF，同时由可溶性的聚乙烯吡咯烷酮在水热反应过程中的去除对纤维造孔，再经低温氮化、高温碳化处理得到多孔煤基碳纤维负载钴/氮化钴/铈氧化物复合催化剂。该催化剂具有分级多孔结构、电解水催化性能。
Absstract of: CN121610834A
本发明涉及固体氧化物电解池制氢技术领域，具体公开了一种用于电解水制氢的SOEC设备的控制系统及方法。该系统包括多频阻抗获取单元和动态区间匹配与协同控制器。方法的核心在于：同步获取表征电解质体相状态与电极界面状态的不同频段交流阻抗参量；根据电堆实时直流工作状态，动态确定一个在多维阻抗状态空间内的优化运行区间；通过比对阻抗参量与该动态区间的相对位置，生成协同控制指令，同时按差异化权重调节直流电源、加热装置及气体供给装置，驱使电堆状态进入并保持在目标区间内。本发明利用阻抗参量直接反映电堆内部综合状态，实现了全局、快速的自适应协同控制，能够提升SOEC系统运行的效率、稳定性与耐久性。
Absstract of: CN121610810A
本公开涉及一种水电解制氢装置及电子设备，涉及电解技术领域，用于实现水电解制氢设备在宽负荷功率波动范围下稳定运行、压力可控；水电解制氢装置包括：电解槽、控制器、气液分离模块、压力检测单元和至少两个并联设置的调节阀；电解槽的输出端与气液分离模块连接，压力检测单元设置在气液分离模块上，控制器的输入端与压力检测单元连接，控制器的输出端与调节阀连接；至少两个并联设置的调节阀设置在气体排放管路上；压力检测单元用于检测气液分离模块的压力信号，并将压力信号转换为电信号；控制器用于接收电信号，并比较是否大于预设压力设定值；若是，控制调节阀开度增大；若否，控制调节阀开度减小。
Absstract of: KR20260030406A
본 발명의 일 실시예인 암모니아 BOG 감축 시스템은 암모니아를 저장하는 암모니아 저장 탱크; 상기 암모니아를 분해하여 수소 및 질소를 생성하는 개질부 및 상기 개질부에서 생성된 가스를 배출하는 덕트부를 포함하는 암모니아 분해 장치; 상기 덕트부에서 배출된 가스를 이용하여 과열 증기를 생산하는 증기 발생부; 상기 증기 발생부에서 생산된 과열 증기를 이용하여 전기를 생산하는 증기 터빈; 및 상기 암모니아 저장 탱크에서 발생한 암모니아 BOG(Boiled-off gas)냉매와 열교환시켜, 상기 암모니아 BOG를 액화시키는 열교환기를 포함할 수 있다.
Absstract of: CN121614734A
本发明涉及电解水制氢技术领域，公开了一种碱性电解系统过滤器故障诊断方法，实时采集过滤器前后压差、循环泵出口流量和循环泵电机功率，经滤波后计算各参数变化率及预设时间窗口内标准差，构建多维特征向量。采用阈值逻辑进行初步判别，区分轻度、中度、重度堵塞、滤芯破裂及传感器故障。同时以当前运行电流值为索引，从覆盖额定电流10%～100%的多工况特征模板库检索相似工况模板，计算加权欧氏距离确定智能匹配结果。本发明通过实时采集过滤器前后压差、构建包含变化率与标准差的多维特征向量，使系统能够准确区分轻度堵塞、中度堵塞、重度堵塞、滤芯破裂及传感器故障，避免传统单一压差监测的误报与漏报。
Absstract of: CN121610828A
本发明公开了一种钴铁双金属氧化物催化剂及其制备方法与应用，属于电催化材料技术领域。本发明将含有钴源、铁源的金属盐溶于水中，得到钴铁双金属盐溶液；将其与碳悬浮液混合均匀，蒸发溶剂得到负载于碳源上的FeCo金属盐前驱体；氮气保护下，对前驱体施加恒电流，通入体积分数1~5% H2O/N2混合气，热处理得到通过水热‑静电场协同制备的CoFe2O4/C纳米复合材料，即钴铁双金属氧化物催化剂。本发明制备出具有低结晶度、小颗粒尺寸、高电化学活性面积、丰富表面氧物种、高比例高价态活性位点以及快速电荷传输能力的CoFe2O4/C纳米复合材料，从而显著提高了析氧反应的催化活性和稳定性。
Absstract of: KR20260030254A
본 발명에 따른 액관을 구비한 수전해 시스템은, 수전해 스택과, 양극측 기액분리기와, 음극측 기액분리기와, 제어부를 포함한다. 특히, 상기 양극측 기액분리기 내에 저장된 물과 상기 음극측 기액분리기 내에 저장된 물을 연통시키는 액관을 더 포함한다. 여기서, 상기 액관은, 수평방향으로 연장되는 가로관과, 상기 가로관의 제1단부로부터 위쪽으로 연장되어 상기 양극측 기액분리기 내에 저장된 물에 연통하는 제1경사관과, 상기 가로관의 제2단부로부터 위쪽으로 연장되어 상기 음극측 기액분리기 내에 저장된 물에 연통하는 제2경사관으로 구성된다.
Absstract of: CN121607174A
本发明公开一种光催化剂以及制备方法和应用。所述光催化剂包括掺杂有磷的氮化碳载体和负载在所述载体上的钛酸锶。本发明的光催化剂利用钛酸锶与氮化碳之间的协同作用，调节活性中心的电子及化学结构，同时促进光生电荷产生及迁移。同时，本发明的光催化剂表面被磷修饰，可以进一步促进反应物H2O分子的吸附和活化。本发明的光催化剂价格便宜，制备工艺简单，重复性好，易于进行规模放大生产。
Absstract of: CN121610819A
本发明公开了一种质子交换膜电解水制氢膜电极及其制备方法和应用，属于电解制氢技术领域，该膜电极包括：质子交换膜以及形成于其两侧的阴极催化层和阳极催化层；阴极催化层和阳极催化层是通过将低温的阴极催化剂浆液和阳极催化剂浆液分别直接涂布于质子交换膜表面，依次经负压预干燥和高温热处理后形成的固化层；低温的范围为‑5℃至3℃。该膜电极具有高性能、低贵金属负载的特性，整个过程不采用转印膜和喷涂，膜电极制备效率高、流程短、操作简单、综合成本低。
Absstract of: CN121610830A
本发明属于氢电极材料技术领域，特别涉及一种自支撑多元非贵金属析氢电极、制备方法及其应用。一种自支撑多元非贵金属析氢电极，其特征在于，包括导电基体和包覆在所述导电基体表面的多元非贵金属催化剂层，所述多元非贵金属催化剂层包括Ni、Co、Fe、Cu、Cr、Ce、La、Yb中的金属元素中的至少两种。本申请限定了催化剂层的金属元素选择范围。通过多元非贵金属的协同作用提升催化性能，选择的多种金属元素均适配碱性电解环境，从材料根源上保障了电极的热力学稳定性。“包覆”的连接方式替代了传统粉体催化剂的涂覆方式，无需添加粘结剂和导电剂，既简化了结构设计，又能增强催化剂层与基体的结合力，避免催化剂脱落。
Absstract of: CN121610835A
本发明涉及电解水制氧技术领域，公开了一种电解水制氧调控系统，该系统包括：氧气浓度检测模块、二氧化碳浓度检测模块、电解水制氧模块、在线电化学阻抗谱测量单元和控制模块。所述控制模块基于实时二氧化碳浓度计算二氧化碳浓度变化率；并基于该变化率是否满足预设的稳态判据，来调度在线电化学阻抗谱测量单元执行电化学阻抗参数的测量；还基于该变化率和实时氧气浓度，计算总目标产氧速率，并据此调节向电解水制氧模块输送的电能。本发明通过前馈‑反馈双环控制，解决了调控响应滞后与精度不高的问题；并通过自适应EIS测量与模型更新，克服了电解槽性能衰减导致的能效低下。
Absstract of: KR20260030253A
본 발명은, 기액분리기와 결합된 스크러버를 포함하는 수전해 시스템에 관한 것이다. 수전해 시스템은, 수전해 스택과, 기액분리기와, 스크러버와, 물탱크와, 제어부를 포함한다. 여기서, 상기 스크러버와 상기 기액분리기와 상기 물탱크는, 펌프의 입력측과 상기 물탱크를 연결하며 제1밸브가 설치된 제1배관; 상기 펌프의 출력측과 상기 스크러버를 연결하며 제2밸브가 설치된 제2배관; 상기 펌프의 출력측과 상기 기액분리기를 연결하며 제3밸브가 설치된 제3배관; 상기 펌프의 입력측과 상기 스크러버를 연결하며 제4밸브가 설치된 제4배관에 의해 결합된다. 상기 제어부는, 상기 스크러버의 내부세척수의 레벨이 미리설정된 하한 이하이면, 상기 물탱크의 물을 상기 스크러버로 공급하고, 상기 스크러버의 내부세척수의 레벨이 미리설정된 상한 이상이면, 상기 내부세척수를 상기 기액분리기로 배출하고, 상기 기액분리기의 내부에 저장된 물의 레벨이 하한 이하이면, 상기 물탱크의 물을 상기 기액분리기로 공급하도록, 상기 제1 내지 제4밸브 및 상기 펌프의 동작을 제어할 수 있다.
Absstract of: CN121610805A
本发明属于电解水技术领域，具体涉及一种使用镍基催化剂电解水制氢耦合氕氘分离的方法。所述方法包括：使用镍基催化剂材料用作析氢反应电极，所述镍基催化剂包含镍元素。本发明发现，采用含镍元素的镍基催化剂作为析氢反应电极用于电解水/海水制氢耦合氕氘分离副产重水具有优异的氕氘分离性能，分离比普遍可达3以上。调控后的镍基催化剂对氕氘吸附选择性强，更容易吸附氕生成氢气，从而将氘富集在电解液中，在产氢同时副产重水，分离比可达8.3。
Absstract of: CN121610816A
本公开涉及一种电解槽集群系统、控制方法、控制器及存储介质。所述系统包括：多个电解单元、第一气液分离单元、第二气液分离单元和碱液循环设备；多个所述电解单元通过主气管道连接所述第一气液分离单元，多个所述电解单元用于电解水制氢，所述第一气液分离单元用于所述系统的气体和碱液分离；多个所述电解单元通过辅气管道连接所述第二气液分离单元，所述第二气液分离单元用于目标电解单元的气体和碱液分离；所述碱液循环设备通过碱液管道连接所述多个电解单元、所述第一气液分离单元和所述第二气液分离单元，用于所述系统的碱液循环。本公开实施例能够实现故障电解槽的快速无影响脱离系统以及新电解槽的快速无缝接入系统。
Absstract of: CN121606791A
本发明公开了一种持续高效氢氧气吸入治疗仪，包括壳体：壳体的内腔设置有氢氧制造机构，壳体的顶部设置有氢氧气排出端遮挡的防护机构；本发明通过在壳体顶部设置由连接组件、封堵组件及弹性组件构成的防护机构，闲置时保护套可紧密封堵接入孔，有效避免灰尘、异物侵入氢氧气排出端；防护机构采用医用级液态硅胶制成的保护套，搭配第二弹簧驱动的弹性支撑结构，避免意外触碰造成的损坏，还能防止排出端污染影响治疗气体纯度；使用时仅需拉伸并旋转即可带动封堵组件移位，弹性组件的自适应调节不阻碍气体输出，既保证防护效果又不影响使用便捷性，有效延长设备核心排气部件的使用寿命，使用安全性与耐用性大幅提升。
Absstract of: CN121607177A
本发明属于催化材料技术领域，具体涉及一种碳纳米管桥联氮化碳/钛酸铁材料及其制备方法和应用。本发明提供了一种碳纳米管桥联氮化碳/钛酸铁材料，包括C3N5、Fe2TiO5和CNT；CNT“桥联”在C3N5和Fe2TiO5之间。本发明巧妙地结合了S型异质结与高导电性CNT的优势，S型异质结的内建电场负责驱动光生电子和空穴向相反方向分离，而CNT桥梁则为分离后的电子提供了极低电阻的迁移通道，协同提升了光催化性能。
Absstract of: CN121610822A
本发明公开了一种PdPt双金属烯催化剂，所述催化剂的微观结构包括纳米片，所述纳米片具有线缺陷、点缺陷和孔洞，所述PdPt双金属烯由Pd和Pt两种元素合金化所构成，本发明具有活性较高和稳定性较高的特点。本申请还公开了PdPt双金属烯催化剂的制备方法和应用。
Absstract of: CN121610823A
本发明公开了一种废弃PET瓶衍生钌基三元金属氧化物的制备方法及其催化酸性电解水析氧的应用，以废弃PET瓶为碳源，在金属盐的化学配位作用下构建双金属的MOF材料，并通过引入钌元素以及煅烧法制备了Co和Mn均匀分布于RuO2晶相结构的Co,Mn共掺杂的RuO2材料。本发明由废弃PET瓶通过MOF路径形成钌基三元金属氧化物，借助于MOF中配体实现氧化物形貌的调整，相比于纯金属盐制备的钌基三元金属氧化物粒径大幅降低，分散度大幅提升，从而提高了电解水析氧性能。
Absstract of: CN121610820A
本发明公开了一种无定形金属氢氧化物及其制备方法与应用，首先利用成核反应器快速成核，使金属盐溶液与含氧酸根溶液共沉淀，获得无定形前驱体；再通过阴离子交换处理，最终得到具有长程无序结构的无定形金属氢氧化物催化剂。本发明方法具有工艺简单、连续、可控、无需高温煅烧、能耗降低、可规模化制备催化剂的特点，利用本方法制备的无定形金属氢氧化物催化剂不仅具有优异的催化活性，结构稳定性，而且在电解水耦合5‑羟甲基糠醛氧化反应中具有优异的选择性和法拉第效率。
Absstract of: CN121610825A
本发明公开了一种基于碳球限域多酸辅助制备钼基氮化物催化剂及其方法和应用，属于电解水制氢催化材料技术领域。该方法以葡萄糖为碳源，通过水热法合成碳纳米球，并引入多酸（如磷钼酸）作为钼源，形成内置钼源的碳球复合结构；随后与过渡金属盐溶液复合，经干燥、研磨得到均相前驱体；最后在氨气气氛中氮化处理，使金属物种原位转化，得到分级结构的钼基氮化物纳米球。本发明方法通过调控金属比例与氮化工艺，实现对材料组成、晶相与孔结构的精确调控，所得催化剂具有分级多孔结构、高导电性与充分暴露的活性位点，在电解水析氢和析氧反应中均表现出高催化活性与稳定性，适用于能源转化领域，具备良好的规模化应用前景。
Absstract of: CN120659908A
A hydrogen generating battery includes a pair of input electrode plates, a pair of output electrode plates, an additional X-plate electrode positioned adjacent the pair of output electrode plates, and a plurality of intermediate electrode plates disposed between the pair of input electrode plates and the pair of output electrode plates. The plasma torch is spaced apart from and inductively coupled to the pair of input electrode plates. A pulsed DC voltage is applied to the plasma torch and the X-plate, while a lower pulsed DC voltage is applied to the pair of input and output electrode plates such that hydrogen gas is generated from the aqueous solution in which the battery is immersed.
Absstract of: US20260062820A1
In a method for connecting a pair of electrolyser stacks with electrolyte, electric current and gas drain piping, each pair of stacks of the electrolyser: through interconnection endplates are supplied with alkaline electrolyte at elevated pressure by common electrolyte supply pipes and further, through the interconnection endplate drain off oxygen gas containing electrolyte, and hydrogen gas containing electrolyte, to common gas separation vessels for oxygen and hydrogen respectively, pull first electrically interconnected current injection electrodes adjacent to interconnection endplates to zero electrical potential through a zero potential conductor, and supply second current injection electrodes placed adjacent to distal endplates with electric current at potentials equally higher and lower respectively than the zero potential at the first electrodes.
Absstract of: WO2026046719A1
The invention relates to a method for catalytically producing methanol from biomass by means of electric current, wherein in a first stage, O2 and H2 are produced from water by electrolysis, wherein in a second stage, the biomass is converted into formic acid by means of an aqueous solution of a first catalyst in a first reaction vessel (R1), wherein the first catalyst reduced in the catalytic reaction is converted back into its initial state by oxidation, wherein for the oxidation thereof the oxygen produced in the first stage is introduced into the solution in the first reaction vessel (R1), wherein the solution with the formic acid resulting therein is transferred to a second reaction vessel (R2), wherein methanol is added to the solution during transfer into the second reaction vessel or in the second reaction vessel (R2), wherein the second reaction vessel (R2) is designed as a rectification column which optionally contains an acidic second catalyst which catalyses esterification of the methanol with the formic acid, wherein the second catalyst is present in solid form as a bed or in liquid form as an acid, wherein a reactive distillation is carried out in the second reaction vessel (R2) and the resulting methyl formate is transferred into a tank (T), wherein in a third stage, the methyl formate is evaporated from the tank (T) and is transferred to a third reaction vessel (R3) and there is hydrogenated with the H2 from the first stage by means of a third catalyst which c
Absstract of: WO2026045877A1
The present application provides an electrolytic cell, an anode catalytic material, a preparation method therefor, and a use thereof. The anode catalytic material in the present application comprises: a substrate, which is an alloy comprising nickel and iron elements; and a nickel-rich oxide layer, which covers the surface of the substrate, wherein the nickel-rich oxide layer comprises nickel oxide and/or nickel hydroxide, and the mass content of nickel element in metal components of the nickel-rich oxide layer is greater than 70%. The anode catalytic material uses a nickel-iron alloy as a substrate, and the addition of iron element can effectively reduce the oxygen evolution overpotential of the substrate material; the nickel-rich oxide layer covering the surface of the substrate can passivate the substrate, and inhibit the dissolution of metal ions, preventing collapse of the skeleton structure of the alloy substrate, thereby maintaining mechanical stability; when the nickel-rich oxide layer is used as an anode, the thickness of the nickel-rich oxide layer does not increase significantly, thus not affecting the catalytic performance thereof; the nickel oxide and/or nickel hydroxide contained in the nickel-rich oxide layer and nickel iron hydroxide which may also be contained therein are also used as active components, thereby further ensuring the catalytic activity of the material.
Absstract of: WO2026045952A1
An aluminum composite material for hydrogen production by hydrolysis, comprising an aluminum-based core and a composite layer formed on the surface of the aluminum-based core. The aluminum-based core comprises, by mass fraction: 90-95% of aluminum and the balance being a magnesium-sodium alloy. The composite layer comprises a carbon-based skeleton attached to the surface of the aluminum-based core and a titanium-iron oxide formed on the carbon-based skeleton. According to the composite material, the aluminum-based core can be prevented from reacting with oxygen to generate an aluminum oxide thin film, thereby increasing the hydrogen yield and hydrogen production rate of the aluminum composite material during hydrogen production. The present invention also relates to a preparation method for and a use of the aluminum composite material for hydrogen production by hydrolysis.
Absstract of: AU2024337380A1
An electrolyzer stack in which gas passages (16C, 16D) and thin and long shunt-current reducing liquid passages (16A, 16B) are provided inside a gasket that is a combination of a first and a second gasket part (12A, 12B) for ease of assembly.
Absstract of: US20260062819A1
There is disclosed a water electrolysis stack in which a current collector, a cathode cell frame, a membrane electrode assembly, and an anode cell frame are sequentially stacked and fastened by a fastening member, wherein the water electrolysis stack has one or more through holes through which the current collector, the cathode cell frame, and the anode cell frame pass, the anode cell frame has a counter bore continued from the through hole and has a greater size than the through hole, and the fastening member includes a head seated on the counter bore, a shaft extending from the head and passing through the through hole, and a hook provided along an outer circumferential surface of one end portion of the shaft and protruding outward from the through hole to provide a compression force in a stacking direction.
Absstract of: US20260063249A1
A system for compressing, storing and providing gas, in particular hydrogen, having a compressing device, a storage device, an expansion machine and a refrigeration machine, in particular an absorption-type refrigeration machine, wherein the system is configured to compress received gas by means of the compressing device, in particular in multiple stages, and to store the compressed gas in the storage device, wherein the system is configured to refrigerate the compressing device using the refrigeration machine and the expansion machine.
Absstract of: US20260066320A1
A method for generating power or producing hydrogen from a carbon source, the method including a chemical conversion step of making, in a chemical conversion unit, a mixture obtained by mixing a solution containing an intermediate medium with a carbon source to react at a temperature at which chemical exergy of the carbon source exceeds chemical exergy in a reduced state of the intermediate medium to reduce the intermediate medium while oxidizing the carbon source, an electrochemical conversion step of bringing the intermediate medium reduced at the chemical conversion step into contact with an anode of a battery structure in an electrochemical conversion unit including the battery structure, and bringing oxygen or air into contact with a cathode of the battery structure to generate power, or bringing water into contact to produce hydrogen, and a reuse step of returning a solution containing the intermediate medium after the electrochemical conversion step to the mixture, and an energy conversion system.
Absstract of: US20260062823A1
A method of preparing bismuth vanadate particles is described. The bismuth vanadate particles prepared via ultrasonication and hydrothermal treatment exhibit controlled morphology (e.g., octahedral shape) and crystallinity (e.g., tetragonal crystal symmetry). A photoelectrode containing bismuth vanadate particles and a method of using the photoelectrode in a photoelectrochemical cell for water splitting is also provided.
Absstract of: US20260063069A1
A raw material fluid treatment plant is provided with a raw material reaction apparatus for reacting a raw material fluid to form a reaction gas. The raw material reaction apparatus includes preheaters and a reactor. The preheaters are heat exchangers that perform heat exchange between a second heat transfer medium and the raw material fluid to heat the raw material fluid. The reactor is a heat exchanger that performs heat exchange between a first heat transfer medium differing from the second heat transfer medium and the raw material fluid having been heated by the preheaters to heat and react the raw material fluid.
Absstract of: US20260062816A1
A method of operating an electrolyzer system includes electrolyzing water into oxygen and inlet hydrogen using a polymer electrolyte cell (PEC) module including PECs, providing the inlet hydrogen to solid oxide electrolyzer cell (SOEC) modules that each include at least one SOEC stack, providing steam to the SOEC modules, and electrolyzing the steam to generate oxygen and a main product stream containing hydrogen.
Absstract of: WO2026047671A1
The invention provides a method of storing and producing energy with the aid of a liquid hydrogen carrier (LHC) as a fuel material in a unified regenerative fuel cell having bifunctional electrocatalyst on its oxygen electrode. A fuel cell system comprising the unified regenerative fuel cell and a fuel supply and regeneration installation for the LHC is also provided.
Absstract of: WO2026050250A1
Methods of producing a product, such as methods that include irradiating a susceptor material with electromagnetic radiation, and contacting the susceptor material and a fluid to produce the product. The irradiating of the susceptor material may produce an electric current, a field, and/or generate heat, which can effect a chemical reaction of the fluid or a component thereof. Apparatuses and systems, which include a susceptor material disposed in a container.
Absstract of: WO2026047273A1
An object of the invention is a solid oxide steam electrolysis system comprising a steam feed (1), a gas recycle device (10) that supplies hydrogen from feed-in line (51) to the steam feed (1), and flow rate of the hydrogen from the gas recycle device (10) is being configured to control the partial pressure of hydrogen in the inlet of the cathode compartment from fuel gas supply structure (22) of the solid oxide electrolysis stack structure (30). A first heat management system (20) is being configured to heat the steam-hydrogen gas mixture in line (21) to 400 - 900 °C and is being configured to supply the gas from fuel gas supply structure (22) to the cathode compartment of the solid oxide electrolysis stack structure (30) to reduce steam into hydrogen and oxygen ions by a first controlled current from a power source (70). In the system the hydrogen-steam mixture in product gas line (23) being fed to the first heat management system (20) transferring energy to the inlet gas mixture from line (21), and the hydrogen-steam mixture from the first heat management system (20) in fluid line (24) being fed through a second heat management system (40) where the gas mixture is partly condensing and producing two-phase hydrogen-water-steam mixture to line (41). The steam flow rate in fuel gas supply structure (22) to the cathode compartment of the solid oxide electrolysis stack structure (30) is being controlled based on the first controlled current of a power supply (70). The steam fl
Absstract of: WO2026048903A1
A titanium porous body according to the present invention comprises a powder sintered body and is formed in a sheet shape having a thickness of 200 μm or greater. In the titanium porous body, holes present in a cross-section extending along the thickness direction have an average aspect ratio of 3.2 or higher, the aspect ratio being calculated as a ratio of the thickness-direction length of a hole to the width-direction length of the hole, within a visual field measuring 200 μm × 200 μm in the cross-section.
Absstract of: US20260062824A1
The present disclosure relates to a separator plate for an electrolyser, comprising a metal layer which has a surface structuring in sections, and an elastomer coating designed as a sealing element and applied to the metal layer for sealing at least one region of the separator plate. The surface structuring comprises a plurality of channel-shaped depressions produced by laser surface treatment. The elastomer coating is arranged at least in some regions on the surface structuring. The present disclosure additionally relates to a method for manufacturing the separator plate.
Absstract of: WO2026046825A1
The invention relates to a method for ammonia synthesis, comprising: providing hydrogen and nitrogen; supplying the hydrogen and the nitrogen to an ammonia synthesis circuit (20) comprising an ammonia converter (3) in which ammonia is catalytically synthesized, wherein a reactant gas mixture is supplied to the ammonia converter (4) and a product gas mixture is discharged from the ammonia converter (6); a circulator (1) which supplies a reactant gas mixture containing the hydrogen and the nitrogen to the ammonia converter (3); and a separator (11) in which ammonia is separated from a product gas mixture of the ammonia converter (4); wherein the ammonia synthesis circuit (20) is operated in a full-load operation in which a nominal flow rate of the hydrogen is provided to the ammonia synthesis circuit (20), and wherein the ammonia synthesis circuit (20) is either transferred from the full-load operation to a partial-load operation or from a partial-load operation to the full-load operation, wherein a flow rate of hydrogen is provided to the ammonia synthesis circuit (20) in the partial-load operation which is lower than the nominal flow rate, wherein, in the partial-load operation, a bypass gas flow branches off from the reactant gas mixture between the circulator (1) and the ammonia converter (4) and is supplied to the product gas mixture between the ammonia converter (4) and the separator (11).
Absstract of: DE102024208419A1
Elektrolysesystem zur elektrolytischen Spaltung von Wasser in Wasserstoff und Sauerstoff, mit einer elektrolytischen Zelle (1), die einen Anodenraum (2) und einen Kathodenraum (3) aufweist, die voneinander durch eine semipermeable Barriere getrennt sind, und mit einem Anoden-Wasserkreislauf (4), der über einen Anodenzulauf (5) den Anodenraum (2) mit Wasser versorgt und der über einen Anodenablauf (6) Wasser aus dem Anodenraum (2) aufnimmt, wobei im Anoden-Wasserkreislauf (4) ein Gas-Wasser-Separator (8) und eine Pumpvorrichtung (9) angeordnet sind. Das Wasser aus dem Kathodenraum (3) wird in einem Kathoden-Wasserpfad (14) aufgenommen und in den Anoden-Wasserkreislauf (4) einspeist, wobei im Kathoden-Wasserpfad (14) ein zweiter Gas-Wasser-Separator (17) angeordnet ist und im Anoden-Wasserkreislauf (4) ein Ionentauscher (10) zum Entfernen von Metall-Ionen. Im Kathoden-Wasserpfad (14) ist ein Radikalfänger (20) angeordnet.
Absstract of: US20260063035A1
A lunar regolith reduction reactor system includes a housing, a crucible, and a pair of electrodes. The housing includes a base structure and a cover structure detachably connected to the base structure, a gas input port to permit input of hydrogen gas into the housing, and a gas output port to permit outgassing of water vapor and gases. The crucible is designed to hold an amount of lunar regolith in the housing. The electrodes are disposed apart from one another and adjacent the crucible, wherein the electrodes are connectable to a power source to generate an electric arc to heat lunar regolith in the crucible and initiate a reduction reaction to separate oxygen gas and reduce separated material into a molten state.
Absstract of: WO2026048255A1
A water electrolysis cell and a water electrolysis system comprising: an ion exchange membrane; a cathode-side catalyst layer disposed on one side of the ion exchange membrane; an anode-side catalyst layer disposed on the other side of the ion exchange membrane; and a metal impurity removal layer disposed between the ion exchange membrane and the cathode-side catalyst layer and/or between the ion exchange membrane and the anode-side catalyst layer.
Absstract of: US20260061384A1
An autothermal ammonia reactor includes a chamber, a hydrogen-separation membrane within the chamber, and an ammonia decomposition catalyst. The chamber receives ammonia and air. The chamber including a combustion zone, a catalytic zone, and a hydrogen zone. The catalytic zone is in thermal communication with the combustion zone. The chamber directs the air and a portion of the ammonia from the fluid inlet to the combustion zone to allow the air and ammonia to exothermically react to generate thermal energy. The chamber directs another portion of the ammonia into the catalytic zone to decompose into hydrogen and nitrogen as the ammonia is exposed to the thermal energy from the combustion zone and contacts the catalyst. The chamber directs the hydrogen from the catalytic zone, through a surface of the hydrogen-separation membrane, to the hydrogen zone to allow the hydrogen to exit the chamber through the fluid outlet.
Absstract of: WO2026048251A1
This water electrolysis device comprises: a water electrolysis stack that has a water electrolysis cell having a solid polymer electrolyte membrane disposed between a pair of separators, and that electrolyzes an electrolytic solution by using the water electrolysis cell; a power supply unit that is electrically connected to the water electrolysis stack; an electrolytic solution path that circulates and supplies the electrolytic solution to the water electrolysis cell; a first temperature sensor that is capable of measuring an inlet temperature of the electrolytic solution flowing through an inlet of the water electrolysis stack; a second temperature sensor that is capable of measuring flow-path outlet temperatures of the electrolytic solution flowing through outlets of a plurality of flow paths formed in electrolysis units of the separators; and a control unit that performs, on the basis of the inlet temperature from the first temperature sensor and the flow-path outlet temperatures from the second temperature sensor, control on the electrolysis units to regulate at least one of the flow rate, temperature, and electric current of the electrolytic solution so as to lower a temperature that has increased in a portion of the electrolysis units of the separators.
Absstract of: KR20260029968A
본 발명은 수전해 반응을 통해 수소와 산소를 생산하는 수전해 스택; 상기 수전해 스택의 작동에 필요한 에너지를 공급하는 전력 공급부; 상기 수전해 스택에서 생산된 수소와 산소를 이용하여 수소 가스 및 산소가스를 물과 분리하는 기액 분리기; 상기 수소 가스 및 상기 산소 가스를 배출시키는 압력 제어 밸브; 상기 기액 분리기의 압력을 측정하고 차압 데이터를 획득하는 차압 센서; 상기 수소 가스 및 상기 산소 가스를 배출시켜, 상기 기액 분리기의 압력을 유지시키는 역 압력 조절기; 및 상기 차압 데이터를 기초로 필요한 수소 가스 및 산소 가스의 양을 자동으로 계산하고, 계산 데이터를 기초로 상기 압력 제어 밸브 및 상기 역 압력 조절기 중 적어도 하나를 제어하는 제어부를 포함하는 수전해 시스템을 제공한다.
Absstract of: WO2026048152A1
Provided are a structure and a reduction device capable of more efficiently generating hydride ions. A structure according to an embodiment of the present invention comprises a first electrode, a second electrode, and an electrolyte. The first electrode and the second electrode are porous and allow a fluid to pass therethrough. The electrolyte is a solid disposed between the first electrode and the second electrode. The electrolyte is electrically connected to the first electrode and the second electrode. Hydride ions can move through the electrolyte.
Absstract of: KR20260029812A
본 발명의 일 측면에 따르면, (a) 니켈 폼 기판 준비단계; (b) 상기 니켈 폼 기판 및 Cu, Mn, B, P 전구체를 포함하는 전구체 수용액을 밀폐된 반응용기 내에 넣어서 수열반응법(hydrothermal approach)에 의해 상기 Ni 폼 기판에 CuMnBP 구조체를 제조하는 단계; (c) 상기 CuMnBP 구조체에 대해 후- 어닐링 공정을 수행하는 단계; 및 (d) 상기 후 어닐링 공정을 거친 CuMnBP 구조체를 침지법에 의해Ru 전구체 수용액에 침지시켜서 Ru도핑 CuMnBP 마이크로 클러스터 전기 촉매를 제조하는 것을 특징으로 하는 전기 촉매 구조체 제조방법이 제공된다.
Absstract of: KR20260029969A
본 발명은 수전해 반응을 통해 수소와 산소를 생산하는 수전해 스택; 상기 수전해 스택의 작동에 필요한 에너지를 공급하는 전력 공급부; 상기 수전해 스택에서 생산된 수소와 산소를 이용하여 수소 가스 및 산소 가스를 물과 분리하는 기액 분리기; 상기 기액 분리기의 압력을 측정하고 차압 데이터를 획득하는 차압 센서; 상기 수소 가스 및 상기 산소 가스를 배출시켜, 상기 기액 분리기의 압력을 유지시키는 역 압력 조절기; 및 상기 차압 데이터를 기초로 필요한 수소 가스 및 산소 가스의 양을 자동으로 계산하고, 계산 데이터를 기초로 상기 역 압력 조절기를 제어하는 제어부를 포함하는 수전해 시스템을 제공한다.
Absstract of: KR20260029661A
본 발명은 유입된 암모니아 기체가 유동하며, 상기 유입된 암모니아 기체를 수소 기체와 질소 기체로 분해하는 촉매 물질을 포함하는 반응부, 상기 반응부를 가열하여, 상기 반응부에서 암모니아 분해를 가능하게 하는 히터 및 상기 히터의 질화 현상을 방지하기 위하여, 상기 히터의 일부 또는 전체를 덮도록 배치되는 질화 방지용 금속층을 포함하는 암모니아 분해 장치를 제공한다. 따라서 히터의 일부 또는 전체를 덮도록 질화 방지용 금속층이 형성되어 있어서, 암모니아 분해 반응이 고온에서 장시간 동안 진행되더라도 질화 현상이 감소되고, 따라서 질화 현상에 의해 경화가 되어 내구도가 저하되는 문제를 미연에 방지할 수 있는 장점이 있다.
Absstract of: US20260066650A1
A plant network has an electrolysis plant, a power supply source, and a central supply line connected to a DC voltage output of the power supply source for feeding a direct current into the central supply line. The electrolysis plant is connected to a central DC network for a high voltage via the central supply line. The power supply source has a wind turbine as a power generator and a rectifier with a DC voltage output for the high voltage. An energy storage system can feed a direct current into the central supply line. A DC supply network controls three different DC voltage levels independently, namely, a first DC voltage for charging and discharging an electrical storage battery of the energy storage system, a DC-Bus high voltage on the central supply line, and a DC operating voltage of the electrolysis plant.
Absstract of: CN120813541A
The invention relates to a method for purifying an oxygen stream contaminated by water, hydrogen and possibly nitrogen, said method comprising contacting the oxygen stream to be purified with a zeolite-based adsorbent material comprising at least one metal in the form of a zero-valent metal, or in the oxidized or reduced form, and recovering the purified oxygen stream. The invention also relates to the use of a zeolite-based adsorbent material comprising at least one transition metal for purifying oxygen, and to the use of the oxygen thus purified in industrial processes.
Absstract of: WO2024223472A1
A method for storing hydrogen in a reactor or a synthesis loop comprising the steps of (a) providing a gaseous stream of a reaction compound; (b) providing an excess of a hydrogen stream as required for stoichiometric molar ratio of reactants to hydrogen in the synthesis loop or reactor from an electrolysis unit; (c) storing the excess of hydrogen provided in step (b) by introducing at least an amount of the hydrogen stream into the gaseous stream of a reaction compound and to provide a mixed stream of hydrogen and gaseous reaction compound with at least 25 mol % excess hydrogen than what is required for a reaction of the reaction compound with hydrogen in the hydrogen stream; (d) introducing the mixed stream into the reactor or the synthesis loop; (e) withdrawing a mixed stream of gaseous reaction product and unreacted gaseous hydrogen and reaction compound from the reactor or the synthesis loop; (f) separating the reaction product from the unreacted gaseous hydrogen and reaction compound (g) recycling all or a part of unreacted amounts of hydrogen and reaction compound to the reactor or synthesis loop.
Absstract of: CN121039328A
A solid-state oxide cell stack has at least one connection plate between the solid-state oxide cell stack and adjacent end plates, between two adjacent end plates, and/or between adjacent five solid-state oxide cell sub-stacks.
Absstract of: CN121013919A
The invention relates to a cell layer (200) for an electrolysis cell stack (60) of an electrolysis device group (51), in particular a water electrolysis device group (51), comprising a frame (250), in particular a cathode frame (250), in the main central region of which a transport structure (210) of the electrolysis cell stack (60) is accommodated, said frame (250) comprising at least one circumferentially open through-passage opening (256), in which the transport structure (210) of the electrolysis cell stack (60) is accommodated, the access through hole is used for electrolyzing an effluent product medium (56) of the cell stack (60); a fluid flow path (257) is arranged between the inner edge of the frame (250) and the outer edge of the transport structure (210) beside the product medium passage through-holes (256), the fluid flow path (257) leading to at least one of the product medium passage through-holes (256).
Absstract of: AU2024220092A1
This disclosure relates to polymer electrolyte membranes, and in particular, to a composite membrane having at least two reinforcing layers comprising a microporous polymer structure and a surprisingly high resistance to piercing. This disclosure also relates to composite 5 membrane-assemblies and electrochemical devices comprising the composite membranes of the disclosure, and to methods of manufacture of the composite membranes. 21188108_1 (GHMatters) P120981.AU.1
Absstract of: KR20260029201A
(과제) 암모니아 메타네이션을 통해 메탄 함유 유체를 효율적으로 제조하는 기술을 제공한다. (해결수단) 암모니아와 이산화탄소를 포함하는 원료 유체로부터 메탄 함유 유체를 생성함에 있어서, 암모니아 분해 활성 및 메타네이션 활성을 갖는 제1 촉매가 충전된 제1 반응기(31)에 상기 원료 유체를 공급하여 암모니아 분해 및 메타네이션을 진행시켜 중간 생성 유체를 얻는다. 이어서, 제1 반응기(31)에서 유출된 상기 중간 생성 유체를 냉각시킨 후, 메타네이션 활성을 갖는 제2 촉매가 충전된 제2 반응기(32)에 공급하여 메타네이션을 진행시켜 메탄 함유 유체를 얻는다.
Absstract of: AU2024262986A1
The invention relates to the coating of cation exchange membranes with catalytically active substances. The catalytically actively coated cation exchange membranes are used in electrochemical cells, especially in fuel cells (proton exchange membrane fuel cells - PEMFC) or in electrolysers for water electrolysis (polymer electrolyte membrane water electrolysis - PEMWE). In order to counteract the disadvantages of conventional decal processes, an alterative process for coating cation exchange membranes was sought which enables the transfer of electrocatalysts without the need for high temperatures, high pressures and PFAS-based substrates. It was surprisingly found that catalyst layers which are treated, shortly before the transfer step, with a polymer-swelling solvent conducting the cations can be transferred far more easily.
Absstract of: AU2024263112A1
The present invention relates to an electrode and in particular to an electrode suitable for gas evolution comprising a metal substrate and a catalytic coating. Such electrode can be used as an anode for the development of oxygen in electrolytic processes such as, for example, in the alkaline electrolysis of water.
Absstract of: GB2643827A
An energy storage system (60) comprises a high temperature electrolyser (70), and a battery pack (65) with cells (10) that comprise a ceramic electrolyte, means (75) to supply steam at above 400°C to the high temperature electrolyser (70), and means to carry a gas stream (77) containing hydrogen away from the high temperature electrolyser (70). The system (60) includes means (78, 82) to maintain the battery pack at an operating temperature above 170°C by use of heat from the high temperature electrolyser (70). The system (60) may be used in conjunction with a renewable energy source (62) of variable power output.
Absstract of: WO2024223362A1
The invention provides an electrochemical stack (1) comprising a plurality of electrochemical cells (2) oriented horizontally and arranged between a top plate (4) and a bottom plate (3) of the stack (1), wherein the top plate (4) and the bottom plate (3) are braced relative to one another by a bracing means (5). At least one connection for supplying gaseous and/or liquid media to or removing them from the electrochemical cells (2) is provided on the top plate (4). The top plate (4) has suspension means (17) configured to fasten the electrochemical stack (1) to a frame (15), wherein the bottom plate (3) is free-floating. The mounting assembly for mounting the electrochemical stack comprises a frame (15), on which the electrochemical stack (1) rests with its suspension means (17) such that the bottom plate (3) is free-floating and the electrochemical cells (2) are oriented horizontally.
Absstract of: CN121399056A
The invention relates to a method for producing hydrogen and magnetite from water and iron in the presence of a ferrous (II) salt catalyst. The invention also relates to the use of the obtained iron as indirect hydrogen storage.
Absstract of: MX2025012716A
An electrochemical device including: - at least one electrochemical cell, - two fluid lines, - a pre-heating unit for preheating at least one of the fluids before feeding the at least one fluid to the system, a load device for electrically oading the at least one electrochemical cell, - temperature sensors, - pressure sensors for detecting a pressure and/or a differential pressure, the device comprises a control management system. The control management system : - is configured to keep a temperature gradient between the inlet side and the exhaust side of at least one fluid line below a predefined system critical temperature gradient and/or to control a minimum temperature and/or a maximum temperature cross the electrochemical device compared with a pre-defined temperature reference; and/or - is configured to control the di f ferential pressure between the two fluid lines; and/or - is configured to control the pressure drop of at least one fluid line; and/or - is configured to control at least one maximum pressure and/or at least one minimum pressure of the fluid in the electrochemical device compared to a pre-defined pressure reference.
Absstract of: AU2024324493A1
A membrane-electrode assembly for a water electrolyser is provided. The membrane- electrode assembly comprises a polymer electrolyte membrane with a first face and a second face; an anode catalyst layer on the first face of the membrane, the anode catalyst layer comprising an oxygen evolution reaction catalyst; and a porous web of polymer fibres in contact with the anode catalyst layer, the polymer fibres comprising a conductive metal additive.
Absstract of: CN121588869A
本发明涉及无机功能材料制备技术领域，是一种无定形硫化钼负载氧掺杂石墨相氮化碳催化剂及其制备方法和应用，将所需量前驱体尿素煅烧得到g‑C3N4，再复烧，得到O‑C3N4，将合成的(NH4)2Mo2S12·2H2O负载于O‑C3N4上，将Mo2S12/O‑C3N4进行煅烧，得到无定形硫化钼负载氧掺杂石墨相氮化碳催化剂。本发明首次通过浸渍法将Mo2S122‑纳米团簇负载在石墨相氮化碳上，并通过原位热解将Mo2S122‑纳米团簇原位转化为无定形硫化钼a‑MoSx，a‑MoSx与石墨相氮化碳以成键的方式紧密结合，可用于光催化制氢，使光催化剂的产氢活性大幅提高，析氢表现也足够稳定。
Absstract of: CN121588912A
本发明属于功能纳米催化材料的制备领域，提供了一种快速制备金属掺杂SiO2@TiO2基光子晶体催化微球的方法，包括S01.将去离子水、硝酸加入无水乙醇中，得溶液A；S02.将钛酸四丁酯、金属乙酰丙酮盐加入无水乙醇，得溶液B；S03.将溶液A滴入溶液B中，获得TiO2前驱体分散液；S04.将二氧化硅纳米颗粒分散在TiO2前驱体分散液中，制得SiO2@TiO2前驱体分散液；S05.将SiO2@TiO2前驱体分散液作为分散相，经微流控芯片中的连续相剪切后，得到SiO2@TiO2基液滴；S06.将SiO2@TiO2基液滴，经过烘干、洗涤、煅烧、过氧化氢改性后制得。本发明提供的方法成功解决了高性能光子晶体催化微球制备中存在的尺寸不均、结构不可控、工艺复杂、难以批量生产等关键技术难题，能够极大的提升制备效率和产率。
Absstract of: CN121593092A
本发明提供一种能够抑制电解质膜的进一步劣化的水电解系统。水电解系统具有氢极、氧极、以及位于氢极与氧极之间的电解质膜，并且进一步具备：劣化检测部，其检测电解质膜的劣化状况；以及氢调压部，在水电解系统启动时，氢调压部根据检测出的所述劣化状况，对在氢极中产生的氢的压力的上升速度和压力的上限值中的至少一方进行调整。
Absstract of: CN121593106A
本发明涉及具有中空结构的RuNiFe金属气凝胶的制备方法及其应用，属于电催化技术领域。采用一步还原法制备了具有核壳结构的NiFe金属气凝胶前驱体，通过精确调控Ni、Fe的投料比实现了对前驱体结构的优化。在此基础上，进一步通过电偶置换法合成了具有中空结构的RuNiFe金属气凝胶。合成方法简单，制备及原料成本低廉，适合大规模应用。本发明中Ru的引入与NiFe非晶合金的协同作用全方位提高了该催化剂析氧性能，中空结构增加纳米颗粒表面的活性位点和比表面积。
Absstract of: CN121593101A
本申请公开了一种制氢系统和制氢站场，属于电解水制氢领域。制氢系统包括：第一电解槽和对应的第一循环泵、第二电解槽和对应的第二循环泵、配液器、气液分离器以及换热器；配液器的出口与第一电解槽和第二电解槽的进液口相连；第一电解槽和第二电解槽的气液出口与气液分离器的进口相连；换热器的第一路的进口与气液分离器的液相出口相连；其中，第一循环泵的进口与换热器的第一路的出口相连，第一循环泵的出口与第一电解槽的进液口及配液器的进口相连。本申请可以缩短待启动第二电解槽从启动到进入正常工作状态的时间，同时对已启动第一电解槽的多余热量进行回收利用，减少了能源浪费。
Absstract of: CN121593099A
本发明提供一种电解水制氢余热绿氢制备系统及方法，属于制氢技术领域。该系统包括：电解水制氢模块、软化水处理模块、余热回收模块、金属裂解制氢模块、氢气后处理模块；所述余热回收模块包含软化水碱液换热器和蓄热罐；所述电解水制氢模块包含制氢装置、循环冷却水碱液换热器、碱液循环泵和电解槽；所述电解水制氢模块通过软化水碱液换热器与余热回收模块连接；所述软化水处理模块、余热回收模块、金属裂解制氢模块、氢气后处理模块依次连接。本发明与常规技术相比从本质上降低了常规电解水制氢系统中余热资源浪费的问题，降低了电解水制氢系统中循环冷却水的冷负荷需求，提升了能源的利用率，降低了绿氢的综合制备成本。
Absstract of: CN121588900A
本发明属于催化剂材料技术领域，具体涉及一种氧缺陷氧化钨/三嗪骨架催化剂及其制备方法与应用。本发明采用4,4’‑联苯二腈和双氰胺进行环加成反应，然后与双氰胺进行热聚合反应，再通过高温煅烧，得到共价三嗪骨架；以钨酸钠二水合物为钨源，柠檬酸和葡萄糖为表面活性剂，通过水热反应，得到三氧化钨前驱体，随后在惰性气氛下进行第一次煅烧，再在氧化性气氛中进行第二次煅烧，得到氧空位掺杂的三氧化钨纳米片；将共价三嗪骨架与氧空位掺杂的三氧化钨纳米片在水中进行自组装，制得氧缺陷氧化钨/三嗪骨架催化剂。本发明构建具有可控氧空位浓度的WO3与联苯型COF的S型异质结催化剂，实现了高效的一步双电子光催化ORR制备H2O2。
Absstract of: CN121591171A
一种纳米金属氧化物及氢气的制造方法，包含有以下步骤：步骤A、备一第一反应器，将一金属材料、一醇类化合物与一第一触煤置入于该第一反应器内，并进行加热，以反应生成金属醇盐化合物，在此同时即产生大量氢气；步骤B、备一第二反应器，待步骤A中该第一反应器内的该金属材料反应完全后，将第一反应器内的剩余溶液导入至该第二反应器中，再加入一第二触煤及控制定量的水，经过适当加热后，形成为呈粉体状的纳米金属氧化物；借以达到生产成本大幅降低、安全性提高、普及氢燃料电池、碳排量极低、能定义为“绿氢”、减少储存成本及风险的功效。
Absstract of: CN121593134A
本发明提出了一种基于气控背压阀的水电解制氢装置及控制方法，能够解决新能源发电耦合工况下，水电解制氢设备因产氢/产氧量动态波动导致的系统压力失控、氢氧侧液位失衡问题。包括：电解槽，气液处理器和控制柜，电解槽用于向气液处理器提供电解液，控制柜用于控制气液处理器的系统压力稳定。本发明仅通过氧侧气控背压阀控制氧侧分离器排放氧气的量，进而控制系统压力达到设定压力目标；通过氢侧的气控背压阀调节氢侧分离器排放氢气的量，使氢侧分离器内的氢气压力始终跟随氧侧分离器内的气体压力，从而控制液位平衡。
Absstract of: CN121593127A
本发明提供了一种强机械稳定性碱性的电解水制氢隔膜，由增韧内核和亲水耐磨防刮层组成，增韧内核由支撑基网两侧涂覆铸膜液而成；亲水耐磨防刮层由待交联物质发生交联反应而成。制备该方法包括：制备铸膜液、增韧内核、喷涂溶液、超声喷涂结合交联固化处理。本发明旨在解决传统复合隔膜在运输、组装及长期运行中涂层脱落的问题，提升隔膜使用寿命与电解系统安全性。通过“内部增韧+表面耐磨”的双层协同优化的方式，交联形成的三维网状结构的亲水耐磨防刮层可以避免涂层脱落，同时交联型聚乙烯醇或交联型聚乙二醇含羟基，赋予隔膜良好的亲水性，有利于保持低电阻和高气密的优势，可满足碱性电解水制氢系统长期稳定运行需求。
Absstract of: CN121595957A
本发明公开了一种绝缘电阻在线监测装置及方法，应用于通过直流电源供电以处于工作状态的水电解槽，装置包括：信号采集模块、信号处理模块及监测模块；信号采集模块与水电解槽、信号处理模块连接，信号处理模块与监测模块连接；信号采集模块隔离采集水电解槽的泄漏电流并传输至信号处理模块，信号处理模块根据泄漏电流确定水电解槽的绝缘电阻，并根据绝缘电阻生成用于指示水电解槽绝缘状态的反馈信号，监测模块根据反馈信号工作。通过信号采集模块和信号处理模块在水电解槽工作时实时监测其绝缘电阻，同时用户还可通过监测模块的工作状态确定此时水电解槽的绝缘状态是否异常，替代传统的离线监测手段。
Absstract of: CN121593093A
本发明提供一种耐久性高的水电解小室。水电解小室具备树脂制的框体。框体具备开口部、和配置于开口部的周围的氧排出用的歧管孔。水电解小室具备配置于开口部的内部的膜电极接合体。水电解小室具备第一隔膜以及第二隔膜。第一隔膜以及第二隔膜经由框体以及膜电极接合体而相互对置，并通过框体而相互接合。框体的划定开口部和歧管孔的内周面具有水的接触角为100°以上的疏水性。
Absstract of: CN121588755A
本发明提出一种用于制备多元金属氧化物纳米复合物的装置及制备多元金属氧化物纳米复合物的方法，属于金属粉末的专用装置或设备领域。该装置包括：前体反应气发生模块，用于制备多元金属前体反应气，多元金属前体反应气包括主金属前体反应气和多种掺杂金属前体反应气；氧化气发生模块用于制备臭氧；扰流混合模块，用于接收多种掺杂金属前体反应气并预混合；反应掺杂模块，使主金属前体反应气、掺杂组分与臭氧发生气相氧化掺杂反应，生成多元金属氧化物纳米复合物，用于催化电解水制氢，掺杂组分为预混合的掺杂金属前体反应气或金属单原子；热分解模块，当掺杂组分为金属单原子时接收并加热预混合的掺杂金属前体反应气，使其热解得到金属单原子。
Absstract of: CN121593120A
本发明属于功能材料技术领域，特别涉及一种三维亲水电极材料及其制备方法和应用。首先通过水热和磷化反应在泡沫镍基底上得到磷化钴纳米线阵列，之后在纳米线阵列上生长ZIF‑67，高温碳化后得到钴氮碳/磷化钴/泡沫镍三维电极材料。该电极材料表现出优异的亲水特性，以及析氢和尿素电氧化性能。与现有技术相比，该电极在尿素辅助海水电解制氢中大幅降低了电解电位，避免了氯氧化反应的发生，提高了电解效率，有利于推动高效无氯海水电解制氢技术的发展。
Absstract of: CN121591251A
本发明公开了一种二氧化钛纳米棒/异金属MOFs异质结材料及其制备方法与应用，属于光电化学海水制氢技术领域，本发明采用可溶性镍盐、可溶性镉盐或可溶性钴盐和钼酸铵作为金属源，在TiO2纳米棒表面原位生长出球形异金属MOFs，经后续酸蚀刻与退火处理，获得氧缺陷调控的异金属MOFs材料（即二氧化钛纳米棒/异金属MOFs异质结材料），该材料在OER过程中发生原位重构，自发形成阴离子保护(MoO42‑)的活性氢氧化物(NiOOH)，展现出卓越的稳定性，在高氯离子环境（3.5wt%‑7wt% NaCl）中仅出现微小法拉第效率损失（1.2‑2.3%），为利用海水实现工业规模太阳能制氢提供了可扩展路径。
Absstract of: CN121593130A
本发明属于水电解制氢技术领域，具体涉及一种电解槽功率实时调节方法、设备及制氢系统。本发明通过在电解槽处于可进行功率调节的状态下，计算为电解槽分配的初始目标功率与电解槽的当前功率的差值的绝对值；若所述差值的绝对值大于电解槽的最大调节步长，则当所述初始目标功率大于当前功率时，计算当前功率与所述最大调节步长之和；当所述初始目标功率小于当前功率时，计算当前功率与所述最大调节步长之差；并将计算得到的数值作为更新目标功率；根据更新目标功率对电解槽进行功率调节；解决了传统的电解槽控制方式导致电解槽不能安全可靠运行的问题。
Absstract of: CN121591248A
本发明提供了一种球形多面体钛酸锶单晶颗粒及其制备方法与应用。所述球形多面体钛酸锶单晶颗粒的制备方法包括：混合钛源、锶源、形貌调控剂、铝源和碱液，超声分散后得到混合溶液；对混合溶液进行水热反应，而后进行洗涤和干燥处理，得到所述球形多面体钛酸锶单晶颗粒。本发明采用水热法，利用钛源、锶源和铝源，制备得到了规则的球形多面体钛酸锶单晶颗粒，实现了(100)、(110)与(111)等多个不同取向的微小晶面的有效暴露，将其用于光催化领域，可以在太阳光照条件下，显示出高效的光解水产氢速率。
Absstract of: CN121593098A
本申请实施例提供一种电解制氢方法及系统，其中，电解制氢方法包括：对制氢装置的制氢量与氢气应用端的动态用氢需求进行对比，得到对比结果；制氢装置基于核电池装置和光伏发电装置产生的电能进行制氢；其中，制氢量是基于制氢装置的电解制氢功率计算得到的；电解制氢功率至少包括最小电解制氢功率，核电池装置的电能输出功率不小于制氢装置的最小电解制氢功率；响应于对比结果表征制氢量不等于动态用氢需求，对光伏发电装置的输出功率或动态用氢需求进行调整，直至制氢量等于动态用氢需求。如此，基于氢气应用端的动态用氢需求，对系统的制氢量进行了动态调整，可以有效平衡供需关系。
Absstract of: CN121591247A
本发明提供了一种圆角多面体钛酸锶单晶颗粒、钛酸锶催化剂及其制备方法。所述单晶颗粒的制备方法包括：将钛酸锶、铝源、铈源和助熔剂混合后得到混合物料；对混合物料进行熔融处理后依次进行降温、洗涤和干燥，得到所述圆角多面体钛酸锶单晶颗粒。本发明提供的钛酸锶单晶颗粒是一种具有圆角的二十六面体结构，具有（100）、（110）与（112）融合圆角晶面；该颗粒圆角处更容易负载助催化剂，使得催化颗粒具有更高的光催化性能；所述钛酸锶催化剂具有优异的光解水产氢效率。
Absstract of: CN121593100A
本申请公开了一种碱性电解系统及其温度控制方法，涉及电解制氢领域，包括：在电解回路处于升温运行状态时，第一开关阀和第三开关阀导通，第二开关阀和第四开关阀关断，换热介质循环泵将换热介质储存容器中的饱和换热介质的蒸汽泵入电解回路的碱液换热器，在电解回路处于降温运行状态时，第二开关阀和第四开关阀导通，第一开关阀和第三开关阀关断，换热介质循环泵将换热介质储存容器中的饱和换热介质泵入碱液换热器。本申请利用饱和换热介质的相变等温特性，通过饱和换热介质相变为蒸汽，实现对降温运行时电解回路的热量收集，并在升温运行时，通过蒸汽相变为饱和换热介质，实现对电解系统的加热，降低了碱性电解系统的运行能耗。
Absstract of: CN121593126A
本申请公开了一种OER电催化剂的制备方法及其应用，属于催化剂制备技术领域。制备方法包括如下步骤：S1、将含有Ru元素前驱体、Ir元素前驱体、溶剂的混合液，加热蒸发去除溶剂，得到前驱体粉末；S2、将步骤S1的前驱体粉末加入到熔融态金属盐中，反应得到所述OER电催化剂。该催化剂为二维钌铱氧化物纳米片材料，通过该方法制备的电催化剂富含晶界，能够提供丰富的催化反应活性位点，从而在酸性析氧反应中展现出优异的电催化性能。此外，该制备方法工艺流程简单，可实现大规模制备，具有广泛的工业应用前景。
Absstract of: CN121593111A
本发明属于电解水制氢能源转换技术领域，具体涉及一种多孔网状纳米硫化镍电催化剂及其制备方法。多孔网状纳米硫化镍电催化剂的原料包括泡沫镍和镍的硫化物；所述泡沫镍通过挂浆法制得，使用的浆料包括以下质量百分数的组分：30‑40％镍粉、3.0‑3.5％粘结剂、0.4‑0.45％分散剂，余量为水。本发明的多孔网状纳米硫化镍电催化剂通过泡沫镍硫化处理制备，催化剂材料表面呈现纳米多孔网状设计，比表面积大且活性位点多，作为电解水析氢催化剂具备低成本、高活性的性能优势，以该催化剂设计的电解水制氢设备能够实现低电耗、高容量、高效率的产品优势。
Absstract of: CN121587544A
本发明涉及富氢水杯技术领域，更具体的涉及一体式保温富氢水杯，包括杯体，所述杯体上设置有杯把和杯盖，所述杯体内设置有制氢上模块，所述制氢上模块上设置有安装开口，所述安装开孔内依次设置有制氢上硅胶圈、制氢上钛片和制氢下钛片，所述制氢上钛片和所述制氢下钛片之间设置有制氢离子膜，所述制氢下钛片下方设置有制氢下硅胶圈，所述制氢下硅胶圈下方设置有制氢模块硅胶圈，所述制氢模块硅胶圈下方通过制氢固定螺丝安装有制氢下模块。解决了现有内部结构多采用分离式设计导致电解产生的副产物氧气处置不完善以及氧气排放通道、压力不平衡的技术问题。
Absstract of: CN121588852A
本发明提供一种碳/氮基燃料分解制氢催化剂及其制备方法和应用，所述制备方法，包括：S1，将镍源和载体前驱体溶于水中，加入络合剂和硝酸，搅拌，得到前驱体溶液；S2，将前驱体溶液加热至燃烧，收集并研磨燃烧后的产物，得到前驱体粉末；S3，将前驱体粉末煅烧，得到单金属催化剂；S4，将钌源溶于水中，采用得到的钌源溶液对所述单金属催化剂进行表面浸渍，然后烘干，得到所述碳/氮基燃料分解催化剂。所述制备得到的催化剂具有高催化活性、低成本等优势，可以用于氨气或甲醇的分解制氢，具备大规模工业化应用潜力。
Absstract of: CN121593113A
本发明公开了一种改性四氧化三钴催化剂及其制备方法与应用，所述催化剂包括载体泡沫镍和负载在载体上的钨与氯共掺杂的四氧化三钴纳米片W,Cl‑Co3O4，所述催化剂以氯化钴和钨盐为前驱体，先通过水热反应得到泡沫镍负载的钨掺杂的碱式氯化钴纳米片W‑Co2(OH)3Cl2，随后通过煅烧将Co2(OH)3Cl2原位转化为泡沫镍负载的钨与氯共掺杂的四氧化三钴纳米片W,Cl‑Co3O4。本发明通过在四氧化三钴中引入氯和钨，提高了电催化氧气析出的活性和稳定性，用于电催化海水分解阳极催化剂，具有优越的电催化氧气析出的活性和稳定性。
Absstract of: CN120787177A
The invention provides a ruthenium catalyst for ammonia decomposition reaction and a production method thereof. The ruthenium catalyst exhibits a conversion rate of almost 100% at a reaction temperature of 550 DEG C, even further exhibits a conversion rate of 93.6% or more at 500 DEG C, and also exhibits a conversion rate of about 60% or more at a low reaction temperature of 450 DEG C, so that the catalyst has excellent ammonia decomposition activity and low manufacturing cost, and can be used in the field of catalytic cracking. And therefore, the method is economical for ammonia decomposition processes even in large-scale decomposition processes at relatively low temperatures.
Absstract of: CN121575431A
本发明涉及一种自支撑镧钼钴硼双功能全解水催化剂及其制备方法与应用，属于电催化材料技术领域。所述方法包括将镧盐、七钼酸铵与四水合乙酸钴按设定摩尔比溶于含硼酸与柠檬酸钠的水溶液中，再加入少量硫酸，加热形成均匀电解液；以泡沫镍为工作电极，在‑300至‑200mA cm‑2的电流密度和20-50℃条件下电沉积100-200分钟，得到负载于泡沫镍上的镧钼钴硼材料。该催化剂具备自支撑结构，无需粘结剂，制备过程简单、成本低且环境友好，在析氢反应与析氧反应中均表现出高催化活性与优异的稳定性，适用于高效全水分解系统。
Absstract of: CN121575436A
本发明涉及电催化剂技术领域，具体公开了一种双位点催化剂及其制备方法与应用，本发明提供一种电解水阳极催化剂制备方案，该方案采用温和的低温水热法及乙二醇原位热还原工艺，成功构建了催化位点‑质子传输位点的双位点协同体系，片状磷酸氧铌载体提供了较大的比表面积和优异的质子导电性，确保质子能够迅速传导至电解液中，避免了质子积累带来的负面效应，有效抑制了局部微环境酸化导致的金属铱溶解与脱落，维持催化剂的热力学稳定性，将金属铱纳米颗粒负载在片状磷酸氧铌载体上，金属铱作为反应活性位点，提供了高效的析出反应活性，磷酸氧铌载体作为质子导电位点，协同金属铱提高了反应效率，二者的协同作用显著提升了催化活性和稳定性。
Absstract of: CN120857975A
The invention discloses a catalyst for ammonia dehydrogenation, a preparation method thereof and a method for preparing hydrogen by using the catalyst. The disclosed catalyst for ammonia dehydrogenation comprises a clay, and an alkali metal and ruthenium impregnated in the clay.
Absstract of: AU2024321116A1
The present invention relates to a methanation method comprising providing an electrolyser system, the electrolyser system (20) comprising an electrolyser (10) that has at least one electrolyser cell (11), at least one fuel input (14) through which fuel enters the electrolyser (10) and at least one offgas output (46) from which offgas exits the electrolyser (10), the method further comprising supplying fuel to the at least one fuel inlet, the fuel comprising at least water and either or both carbon dioxide and carbon monoxide, operating the electrolyser system (20) by powering the electrolyser cell (11) with electricity to electrolyse the fuel in the at least one electrolyser cell (11) such that a part of the water splits into hydrogen and oxygen, wherein the electrolyser (10) is operated at a temperature at or in excess of 150 degrees C, and methanation occurs to the carbon dioxide and/or carbon monoxide in the electrolyser (10). The gas mixture can be released from the at least one offgas output (46) and then passed through a gas separation process to separate at least the methane from the gas mixture. The present invention also relates to an electrolyser system (20) configured to operate using the above method. The electrolyser system (20) comprises a fuel fluid flow path connecting a fuel inlet and a fuel outlet. The method may comprise providing to the fuel inlet a fuel gas containing water and a source of carbon selected from one or more of CO and CO2, operating the ele
Absstract of: KR20240154110A
The present invention relates to a method for preparing a complex metal catalyst in the form of a tri-metal of ruthenium, yttrium, and potassium by using a thermally transformed delta-alumina support and to a method for preparing hydrogen through an ammonia cracking reaction using the same. An ammonia cracking catalyst according to the present invention adjusts the ratio of ruthenium/potassium + yttrium, along with a thermally transformed alumina support in a specific phase, even when using a low content of ruthenium metal, minimizes the contents of chlorine and nitrogen compounds, which are impurities in the catalyst, and localizes active metals in the catalyst, thereby achieving a very high ammonia conversion rate and hydrogen production efficiency even at low temperatures, compared with a catalyst having the same content of the ruthenium metal.
Absstract of: MA73371A1
A Solid Oxide Cell stack has at least one connection plate between the solid oxide cell stack and an adjacent end plate, two adjacent end plates and/or between adjacent solid oxide cell sub-stacks.
Absstract of: CN121574352A
本发明公开了一种含有偶极诱导体的阴离子交换膜及其制备方法和应用，其属于高分子膜技术领域，其中，该阴离子交换膜含有刚性扭曲偶极诱导芳基单体Ar1和刚性扭曲芳基单体Ar2。本发明提供的阴离子交换膜具有良好的超高离子导电率和良好的尺寸稳定性，可以促进水电解的高效稳定进行，这是因为该阴离子交换膜的微孔结构能够有效地促进离子的传输，其中包含的全刚性聚合物主链可以限制阴离子交换膜的溶胀，可应用于碱性电解水。
Absstract of: CN121575428A
本发明提供一种可稳定连续独立产生双气泡的双电极结构及制备方法，双电极结构包括外部绝缘管、电极线、内部绝缘管、导线和密封体；内部绝缘管中有第一电极线，外部绝缘管中设有第二电极线，第一电极线和第二电极线平行，第一电极线和第二电极线的第一端连接导线，第一电极线和第二电极线的第二端与外部绝缘管端面平齐并密封，第一端处外部绝缘管、导线以及内部绝缘管之间的间隙设置密封体；内部绝缘管的第一端和第一电极线的第一端均置于密封体中，两根电极线在外部绝缘管内绝缘；在电极表面产生微米级单气泡，防止电解液渗漏导致的短路或腐蚀，从根源上杜绝了电极表面多气泡的产生，保障了电极在同一时刻只产生单气泡，并延长了装置使用寿命。
Absstract of: CN121575432A
本发明属于电极技术领域，公开了一种具备电解水催化功能的钛基抗结垢阴极制备方法，步骤如下：在钛网基底表面构建微结构；在微结构上负载过渡金属催化剂；在具有催化功能的微结构材料表面涂覆惰性涂层。这种阴极表面的惰性涂层会阻碍电子与水分子接触，使仅未被惰性涂层覆盖的微结构尖端充当晶体的初始成核位点。当晶体生长至微米级时，其与微结构尖端的附着力会减弱。同时，电解水产生的气泡会沿惰性涂层生长，并在微结构尖端附近破裂，推动晶体自发脱落，避免沉淀在电极表面堆积。同时微结构上负载的金属阳离子如Ni2+、Co2+可以降低电解海水的过电位。这两种性质使得该阴极可以应用于海水中镁资源的提取。
Absstract of: CN121575440A
本发明属于电极材料技术领域，特别涉及一种双单晶CoS@CoSe2异质结电极及其制备方法和应用。所述异质结电极的结构为在碳布表面原位均匀生长单晶CoS纳米块，并于CoS纳米块表面外延生长单晶CoSe2纳米棒。所制备的双单晶CoS@CoSe2异质结电极在碱性OER测试中表现出卓越的性能。在1 M KOH电解液中，仅需115 mV的极低过电位即可驱动10 mA cm‑2的电流密度。
Absstract of: CN121575439A
本发明属于催化材料技术领域，具体涉及一种珊瑚状铁钴镍铝钼高熵合金催化材料及其制备方法，以及该材料在碱水析氧反应中的应用。本发明通过精准调控电解液中铁、钴、镍、铝、钼五种元素的浓度比例，采用直流恒电流共沉积法，在洁净镍网表面直接生长出铁钴镍铝钼高熵合金珊瑚状结构（简称FeCoNiAlMo HEA）。制备的FeCoNiAlMo HEA催化电极具备较高的反应活性和快速的传质速率，而且表现出优异的稳定性，同时在大电流密度下展现出优异的催化效果；本发明通过组分和结构双重调控，解决传统高熵材料应用中需要粘结剂的使用导致传质受阻和稳定性不足的难题，为解决工业化电极大电流密度下性能较差的痛点提供了新的解决方案。
Absstract of: CN121584757A
一种基于多状态协同调度的光伏制氢并网系统及方法，涉及新能源综合利用领域。解决现有因光伏发电的间歇性和波动性导致电解槽运行不稳定、能源综合利用率低及经济效益不佳等问题，所述系统包括光伏发电单元、储能单元、至少一个电解槽单元、储氢单元以及一个控制器。控制器实时监测光伏发电功率、储能单元充电状态和储氢单元储氢状态，并根据预设的多状态协同调度策略执行以下操作：依据光伏功率阈值分级启动电解槽单元；利用储能单元平滑光伏功率波动，为电解槽稳定供电；并且，基于储能单元达到上限或储氢单元达到上限这两个独立的触发条件，动态地将系统富余电能并网售卖。本发明还适用于集成光伏发电、电化学储能、电解水制氢领域。
Absstract of: CN121574362A
本发明涉及一种高温固相制备酰胺键桥连有机聚合物产氧光催化剂的方法，包括以下步骤：将芳香多元胺单体与芳香多元酰氯单体混合后进行高温处理，冷却，即得；高温处理的温度T满足T1≤T≤T2，高温处理的时间为10~60min，其中，T1为高于芳香多元酰氯单体的熔点且不低于260℃的温度，T2为比芳香多元胺单体的起始分解温度低20℃以上的温度。本发明采用一步高温固相法，通过将反应温度调控在T1与T2之间，利用芳香多元酰氯单体熔融自成溶剂的特性作为反应介质，使得氨基与酰氯基团直接、快速地缩合生成酰胺键，合成周期短；同时，该反应温度条件能够为分子链运动与有序排列提供充足能量，形成高结晶度的聚合物网络，从而表现出较好的光解水产氧性能。
Absstract of: CN121575443A
本发明公开了一种复合电极材料及其制备方法，属于电解水析氢催化剂合成技术领域。本发明的复合电极材料的制备方法，包括以下步骤：将煤质炭、导电剂和粘结剂配制成浆料，涂敷在电极基材上，然后以阶梯型递增电压进行电沉积，得到复合电极材料。本发明制备的复合电极材料具有较低的过电位，电催化性能良好，且具有优异的电催化稳定性。
Absstract of: CN121571065A
本发明涉及新能源制氢技术领域，具体是一种动力装置废热供能的甲酸液相/汽相梯级制氢系统。该系统可充分利用氢燃料电池发动机等动力装置运行过程中的废热，加热甲酸制氢反应液，提高反应液温度进而强化甲酸分解制氢性能，甲酸所产氢气经纯化后进入氢动力装置，为氢动力装置提供氢气来源。
Absstract of: CN121575447A
本发明公开了一种自支撑异质结构电催化析氧电极及其制备方法和应用，涉及电解水制氢技术领域。通过一种简单的两步水热方法直接在泡沫镍上生长一种新型的纳米棒（Ni3S2）负载高活性纳米簇（FeS/MoS2）异质结构的三维复合材料。第一步合成的短棒状Ni3S2有利于反应物（H2O、OH‑）的吸附和中间体（如O*、OOH*）的形成，而第二步合成的FeS/MoS2/Ni3S2@NF，其中FeS提供了大量的活性位点，MoS2优化了异质结构电子结构。FeS/MoS2/Ni3S2@NF具有较小的电荷转移电阻和优异的电催化性能。在1M KOH溶液中具有优异的OER性能，并保持了较长的工作寿命，在析氧电池中具有应用前景。
Absstract of: CN121575454A
本发明涉及电解水制氢技术领域，具体为一种具有低耗能干燥舱的电解水制氢设备，包括制备机构和循环机构，所述循环机构设在制备机构的左侧，所述制备机构包括储存组件、输送组件和电解组件，所述输送组件设在储存组件的顶部，所述电解组件设在储存组件的内侧，所述循环机构包括导流组件、干燥组件、冷却组件、散热组件、导热组件和回收组件，所述导流组件设在输送组件的左侧，所述干燥组件设在导流组件的内侧。本发明提供了一种具有低耗能干燥舱的电解水制氢设备，具有对含有水蒸气的氢气进行低能耗干燥除湿的结构，因此可以采用低能耗的方式为氢气中的水蒸气进行干燥除湿，提高了长期对氢气中水蒸气干燥除湿稳定性的优点。
Absstract of: CN121575437A
本发明公开了一种PdPtCu三元金属烯催化剂，所述催化剂的表面具有晶体、非晶、线缺陷、点缺陷和孔洞，所述PdPtCu三元金属烯由Pd、Pt和Cu三种元素合金化所构成，本发明具有活性和稳定性较高的特点。本申请还公开了PdPtCu三元金属烯催化剂的制备方法和应用。
Absstract of: CN121571185A
本发明公开了一种用于光热氨分解制氢的MoN/Mo2C复合材料的制备方法及应用。该方法将以MoCl5·7H2O与尿素为原料，在氮气气氛中煅烧得到Mo2C，随后通过氨气和氦气的混合气体气氛条件下热得到MoN/Mo2C复合材料。该类复合材料在带有凸透镜聚焦的光源照射下有着优异的氨分解产氢效率。该催化剂在光照作用下不仅能够产生大量的热能，同时生成载流子能够有效地参与催化过程，极大程度地降低反应活化能，光热催化产氢效率远高于其在相同温度下未光照条件下的性能。该发明所涉及的催化剂合成方法简便易放大，光热催化氨分解制氢的方法具有条件温和，能耗低，效率高等特点，具有良好的应用前景。
Absstract of: KR20260026808A
수소 생산 시스템이 제공된다. 본 발명의 일 측면에 따른 수소 생산 시스템은 물과 유기 연료를 이용하여 수소 혼합 유체를 생산하는 제1 수소생성기와, 상기 제1 수소생성기로 유입되는 상기 물과 상기 유기 연료를 가열하는 하나 이상의 히터를 포함하는 제1 수소생성부; 상기 제1 수소생성부에 상기 유기 연료를 공급하는 연료공급부; 상기 제1 수소생성부에 상기 물을 공급하는 물공급부; 및 상기 수소 혼합 유체로부터 수소 기체를 분리하는 흡착부;를 포함하되, 상기 제1 수소생성부는 상기 제1 수소생성기의 하류에 제1 열교환부를 더 포함하고, 상기 제1 수소생성기로 공급되는 상기 물은 상기 제1 열교환부를 경유하여 상기 수소 혼합 유체와 열교환한 후에 상기 제1 수소생성기로 공급될 수 있다.
Absstract of: CN121574674A
本发明涉及质子交换膜电解槽装配技术领域，本发明公开了一种质子交换膜电解槽密封垫片装配用粘接剂及其制备方法，粘接剂包括质量分数如下的原料：原胶5%‑40%、乳化剂1%‑10%、增粘剂2%‑10%和溶剂40%‑90%组成。将原料在20℃‑50℃的环境下充分搅拌，搅拌混合均匀即得到本申请的粘接剂。本发明的粘接剂粘结强度高的同时粘性低、固化时间短，相较传统的粘结剂具有显著的优势；同时，使用方法操作简单、易于点胶，适配各种自动化操作过程，应用本申请的粘接剂能够解决低表面能橡胶和钛金属件难以固定的问题，提升密封垫片搭接效率和搭接稳定性。
Absstract of: CN121575483A
本发明提供了一种钛酸锶单晶颗粒及其制备方法与应用。所述钛酸锶单晶颗粒的暴露晶面包括(100)晶面和(111)晶面；且所述钛酸锶单晶颗粒呈锥形多面体结构。本发明提供的钛酸锶单晶颗粒呈锥形多面体结构，暴露晶面只有(100)晶面和(111)晶面，且每个颗粒的(111)晶面暴露比例和面积更大，使得本发明提供的钛酸锶单晶颗粒具有更高的光量子利用率。
Absstract of: CN121575423A
本发明涉及富氢水制备及氢氧混合供气技术领域，公开了一种可浸入式亲水性多孔钛PEM电解槽，包括阳极端板和阴极端板，阳极端板和阴极端板通过若干紧固螺丝和若干紧固螺母可拆卸连接；电解堆体，位于阳极端板和阴极端板之间，且电解堆体两端与阳极端板和阴极端板之间进行绝缘隔绝；电解堆体两端分别从阳极端板和阴极端板伸出，且分别与外部电源的正极和负极连接。本发明彻底省去传统PEM电解槽的密封结构、输气管道及外部水泵，不仅具备结构极致简化、成本低廉、氢气溶解效率高的优势，更通过明确的材料选型与工艺设计实现“富氢水制备‑氢氧混合供气”一体化，大幅提升高原户外使用的便捷性与实用性。
Absstract of: CN121574680A
本发明公开了一种具有催化水解离功能胶黏剂的制备方法及应用，属于新能源领域，一种具有催化水解离功能胶黏剂的制备方法，包括以下步骤：S1：将丙烯酸、丙烯酸甲酯、NN‑亚甲基双丙烯酸酰胺、乳化剂、以及纯水进行充分搅拌，升温至40‑60℃，搅拌时间为0.5‑2h，得单体溶液，S2：将引发剂溶解于纯水中得溶液A，且将金属离子化合物溶解于纯水中得溶液B，S3：采用缓慢连续滴加的方式向单体溶液中滴加溶液A和溶液B，滴加时间为0.5‑2h，升温至50‑75℃，反应1‑5h，得到具有催化水解离功能胶黏剂。本发明制得的胶黏剂通过内部活性催化粒子，显著降低了水分子解离的活化能垒，促进电解制氢过程中水的解离效率，进而提高制氢能效。
Absstract of: CN121575449A
本申请设计制氢技术领域，提供电解水制氢隔膜及其制备方法和电解水制氢装置。电解水制氢隔膜，包括基材层和多孔亲水层。其中，多孔亲水层设置于基材层的至少一侧表面，多孔亲水层中分散有多个改性无机颗粒，改性无机颗粒包括无机颗粒以及包覆于无机颗粒至少部分表面的改性材料。改性材料中含有的硅氧烷主链以及聚醚链段和烷基链段，不仅改善了无机颗粒与有机聚合物之间的相容性，而且实现了隔膜的高离子电导率、优异的气体阻隔性、良好的机械强度和长期运行稳定性。
Absstract of: CN121584591A
本发明公开考虑温度‑压力‑水影响的质子交换膜电解槽自适应调频控制方法，包括以下步骤：1）基于PEMEL动态运行特性，构建考虑温度、压力和含水量耦合效应的PEMEL动态模型，为调频控制策略设计提供精确的模型基础；2）剖析PEMEL在不同稳态运行点下的调频性能；3）剖析PEMEL的温度、压力、含水量对其最大制氢功率的影响机理；4）提出PEMEL在温度、压力、含水量影响下的调频功率补偿方法；5）基于模糊控制理论及PEMEL的运行点实时状态，设计PEMEL的虚拟惯量和一次调频参数自适应整定机制，研究PEMEL自适应调频策略。本发明通过考虑温度‑压力‑水影响的PEMEL自适应调频控制策略实现PEMEL调频性能的精准感知与动态优化控制。
Absstract of: CN121577725A
一种模拟阴离子交换膜水电解槽产生反向电流的方法及反向电流对电极影响的加速应力测试应用，它涉及电化学技术领域。产生反向电流的方法：在恒定电解状态下，停机瞬间施加0V，阳极电位会跨越平衡电位，出现‑1.0 V vs. RHE的瞬时反向极化信号，随后快速衰减并趋近于零，表明反向电流已被成功诱发。加速应力测试方法：在不同电流密度下分别运行，每个电流密度下运行后需要重新停机、再启动的操作，重复循环上述操作。本发明实现了对AEMWE阳极失效过程的实时追踪与定量评估，明确了阳极在反向电流条件下的活性衰减路径与惰性覆盖层形成过程，为波动工况下AEMWE电极可靠性评估提供了借鉴。
Absstract of: CN121571061A
本发明涉及制氢设备技术领域，具体为一种结合等离子体与催化剂的氨裂解制氢装置，催化单元包括固定设置在底板上的支架，且其中一组支架上固定设置有控制器，控制器上固定设置有用于添加原料的存料器，底板上固定设置有转化器，存料器与转化器之间通过连接管连通，输料管二的另一端与转化器相连通，催化单元用于对氨气进行裂解反应，氨气通过转化器和输料管一输送至装置的反应罐内，设置在底板上的调节器能够保持氨气输送的稳定性和安全性，同时设置在输料管一上的结合器能够保持反应过程中氨气的稳定性，支撑框架上的混合器能够搅拌催化剂能够保持与溶液的充分接触，增加表面羟基数量，增强与活性组分的结合力。
Absstract of: US20260055524A1
Low-cost and earth abundant, Ni1-xMox alloy nanocrystals, with sizes ranging from 18-43 nm and varying Mo composition (0.0-11.4%), were produced by a colloidal chemistry method for alkaline HER reactions. For a water splitting current density of −10 mA/cm2, these alloys demonstrate over-potentials of −62 to −177 mV, which are comparable to commercial Pt-based electrocatalysts (−68 to −129 mV). The cubic Ni0.934Mo0.066 alloy nanocrystals exhibit the highest activity as alkaline HER electrocatalysts, outperforming commercial Pt/C (20 wt %) catalyst.
Absstract of: US20260055526A1
There are provided system for preparing lithium hydroxide from an aqueous composition comprising a lithium compound and use of the system thereof to prepare lithium hydroxide, the system comprising an electrochemical cell, a pH probe and at least one inlet for receiving acid or base for maintaining pH. For example, the lithium compound can be lithium sulphate and the aqueous composition can be at least substantially maintained at a pH having a value of about 2 to about 4.
Absstract of: US20260055516A1
A water electrolysis cell includes a membrane-electrode assembly, a frame body made of resin that is provided along a peripheral edge of the membrane-electrode assembly, and a first separator and a second separator that face each other through the membrane-electrode assembly and the frame body and are joined to each other by the frame body. An outer peripheral portion of the membrane-electrode assembly is extended to between a first face of the frame body and the first separator. A surface of the first face includes an antioxidant.
Absstract of: WO2026042828A1
Problem To provide a water electrolysis method and a water electrolysis system with which water electrolysis can be highly efficiently performed under non-extreme pH conditions. Solution Provided is a water electrolysis method in a buffer solution having a pH of 7 to 12, wherein the buffer solution is composed of an electrolyte solution containing at least one cation species selected from the group consisting of alkali metal cations and at least one anion species selected from the group consisting of borates and carbonates, and the electrolyte solution contains 0.1 to 6.0 mol/kg of phosphate ions.
Absstract of: WO2026039871A1
The present disclosure relates to hydrogen storage mediums comprising sodium borohydride, magnesium oxide, and magnesium which release hydrogen when contacted with a proton source. The present disclosure also relates to methods of producing hydrogen storage mediums.
Absstract of: US20260054981A1
A method for hydrogen production may comprise: feeding a steam stream and a natural gas stream to a methane reforming unit to produce a gray hydrogen gas and CO2 stream; feeding the gray hydrogen and CO2 stream to a CO2 capture unit to produce blue hydrogen; feeding a water stream and electricity to an electrolyzer unit to produce a green hydrogen gas and oxygen; and collecting the blue hydrogen from the CO2 capture unit and the green hydrogen from the electrolyzer unit. A hydrogen production system may comprise: a methane reforming unit; a CO2 capture unit; and an electrolyzer.
Absstract of: WO2026040290A1
A hydrogen evolution electrocatalyst, a preparation method therefor, and the use thereof. The hydrogen evolution electrocatalyst comprises a nickel foam substrate, a Ni3S2 nanosheet layer and a graphdiyne coating layer; at least part of the outer surface of the nickel foam substrate is provided with the Ni3S2 nanosheet layer; nickel atoms in the Ni3S2 nanosheet layer come from the nickel foam substrate; at least part of the outer surface of the Ni3S2 nanosheet layer is provided with the graphdiyne coating layer. The hydrogen evolution electrocatalyst has the characteristic of high catalytic activity.
Absstract of: DE102024207916A1
Die vorgestellte Erfindung betrifft eine Bipolarplatte (100) für ein Elektrolysesystem (200),wobei die Bipolarplatte (100) umfasst:- einen Grundkörper (101) mit einer ersten Seite (103) und einer der ersten Seite (103) gegenüberliegenden zweiten Seite (105),wobei zumindest auf der ersten Seite (103) eine Vielzahl Kanäle (107) von einem ersten Ende zu einem dem ersten Ende gegenüberliegenden zweiten Ende der Bipolarplatte (100) verlaufen,wobei zwischen jeweiligen benachbarten Kanälen (107) Leitpfade (109) ausgebildet sind, undwobei jeweilige Kanäle (107) eine Anzahl Öffnungen (111) umfassen, die dazu konfiguriert sind, durch die Kanäle (107) strömendes Fluid in die Leitpfade (109) zu leiten.
Absstract of: KR20260026365A
본 발명에 따른 촉매 구조체 제조 방법은, 전도성 집전체를 준비하는 단계, 전이금속 및 칼코겐 원소를 포함하는 촉매층 소스를 준비하는 단계, 상기 전도성 집전체 상에 상기 촉매층 소스를 코팅하여 예비 촉매층을 포함하는 예비 촉매 구조체를 제조하는 단계, 및 상기 예비 촉매 구조체, 알칼리 금속 전극, 및 전해질을 이용한 전기화학적 양이온 주입 방법으로, 상기 예비 촉매 구조체의 상기 예비 촉매층을 촉매층으로 전환시켜 상기 촉매층을 포함하는 상기 촉매 구조체를 제조하는 단계를 포함하고, 전기화학적 양이온 주입 과정에서, 과전압의 방전에 의해 상기 촉매층의 결정 구조가 반도체 특징을 갖는 결정 구조에서 금속 특징을 갖는 결정 구조로 전환되는 것을 포함할 수 있다.
Absstract of: US20260055519A1
An electrolysis apparatus operation system includes an electrolysis apparatus, a control unit, a target state-of-health value input unit, and a control parameter calculating unit. The electrolysis apparatus has a plurality of electrolytic stacks in which a plurality of electrolytic cells that produce hydrogen by electrolyzing water are stacked. The control unit controls a controlled subject based on a control parameter that affects state-of-health of the controlled subject. The target state-of-health value input unit allows a system user to input a target state-of-health value that is a target value for state-of-health. The control parameter calculating unit calculates a control parameter of the controlled subject based on the target state-of-health value. The controlled subject is the electrolysis apparatus.
Absstract of: US20260055517A1
Microorganisms and bioprocesses are provided that convert gaseous C1 containing substrates, such as syngas, producer gas, and renewable H2 combined with CO2, into nutritional and other useful bioproducts.
Absstract of: US20260055518A1
Herein discussed is a method of producing hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode, wherein the membrane is both electronically conducting and ionically conducting; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia; (c) introducing an oxidant to the anode; and (d) introducing a second stream to the cathode, wherein the second stream comprises water and provides a reducing environment for the cathode; wherein hydrogen is generated from water electrochemically; wherein the first stream and the second stream are separated by the membrane; and wherein the oxidant and the second stream are separated by the membrane.
Absstract of: US20260055523A1
The technology generally concerns novel aerogels of mixed metal oxides and uses thereof as electrocatalysts.
Absstract of: US20260054247A1
The invention relates to a device, stacked plate reactor and to a method for investigating chemical processes to be carried out simultaneously or almost at the same time on a large number of functional element variations of the process parameters.
Absstract of: US20260055522A1
Provided herein is a hydrogen gas production assembly includes a hydrogen gas production device, a container including an aqueous electrolyte solution, a storage container for storing produced hydrogen gas an input providing the aqueous electrolyte solution from the container to the hydrogen gas production device and an output for transferring produced hydrogen gas from the hydrogen gas production device to the storage container.
Absstract of: AU2024327448A1
The present invention relates generally to the production of a desalinated, filtrated or other way treated water simultaneously with generation of renewal energy source, in particular hydrogen, using osmotic and/or gauge pressure driven filtration processes and systems. The co-generation of hydrogen 11 from water 8 produced during pressure driven water desalination/filtration processes, such as reverse osmosis, forward osmosis, pressure retarded osmosis or ultrafiltration. A small part of feed, raw saline solution and/or permeate involved in a desalination/filtration processes is subjected to electrolysis thereby splitting the water to produce hydrogen. This is achieved by the provision of novel RO type semi- permeable membranes and UF type membrane that incorporate electrodes 9, 10 within the membrane to allow splitting of the water via electrolysis.
Absstract of: AU2026200812A1
22418031_1 (GHMatters) P121123.AU.1 The present application relates to water electrolyzers, including water electrolyzers incorporating anion exchange membranes. The present applications also 5 relates to materials incorporated into water electrolyzers and approaches for manufacturing water electrolyzers, as well as methods of using water electrolyzers. eb e b
Absstract of: AU2024257970A1
Process for synthesis of ammonia wherein: ammonia make-up gas (7) containing hydrogen and nitrogen is reacted in an ammonia converter (15) under ammonia forming conditions thus obtaining an ammonia-containing effluent (8); a first hydrogen portion contained in the ammonia make-up gas (7) is produced by reforming a hydrocarbon source (1) in a reforming process (100); a second hydrogen portion (19) contained in the ammonia make-up gas (7) is produced separately from said reforming process (100), by using at least a renewable energy source (SE, WE); a part of said hydrogen (19) produced in step (c) is stored in a hydrogen storage (103); hydrogen (20) from said hydrogen storage (103) is used to fully or partially replace said second hydrogen portion (19) when said renewable energy source (SE, WE) is fully or partially unavailable. Said process comprising the steps of: assessing an expected flow rate of the hydrogen (19) produced in step (c); adjusting a flow rate of the hydrocarbon source (1) so that a flow rate of the first hydrogen portion in said ammonia make- up gas (7) is in a desired ratio with respect to said expected flow rate; detecting an actual amount, e.g., a filling level, of said hydrogen in said hydrogen storage (103); detecting an actual flow rate of hydrogen produced using the renewable energy source (SE, WE), and adjusting a flow rate of the hydrogen (20) from said hydrogen storage (103) depending on said actual amount detected in said hydrogen storage (103) and
Absstract of: WO2024217840A1
A method for producing green hydrogen by electrolysis in a hybrid power plant (10), which comprises at least: - a wind turbine (11 ) with a rotor (11.1), a drive-train and a generator; multiple photovoltaic modules (12), - an electrolysis unit (15) for producing hydrogen by electrical power generated by the wind turbine (11) and/or the photovoltaic modules (12), an internal electrical power grid interconnecting the generator, the photovoltaic modules (12) and the electrolysis unit (15) within the power plant (10) and - a control unit (16); wherein a) electrical energy is generated by using the photovoltaic modules (12) and/or wind turbines (11 ); b) cloud coverage and/or solar radiation is measured by at least one weather sensor (14) which is located in a windward position remote of the power plant (10) and which is connected to the control unit (16) via a data link; According to a first aspect of the invention the wind turbine (11) is used as kinetic energy storage and according to another aspect of the invention the wind turbine (11) is used as an energy absorber by increasing inertia of the rotor (11.1).
Absstract of: US20260028730A1
Conventional control schemes for electrolyzers focus on maximizing electrical efficiency, which describes the relationship between the electrical energy consumed and the gas produced by the electrolyzer. However, the cost associated with high electrical efficiency may be unnecessarily expensive. In one embodiment presented herein, a model is used to determine the cost (or profit) associated with a gas produced by the electrolyzer at each of a plurality of operating conditions. The control system can select the operating condition to use based on which operating condition is associated with the lowest cost (or highest profit), even though that operating condition may not be associated with the highest electrical efficiency.
Absstract of: EP4699691A1
Provided is a reduction device that can be manufactured inexpensively and easily, has a wide reaction field, can achieve a reduction reaction even with low energy light such as visible light, and has a long catalyst life. The reduction device of the present disclosure includes diamond particles. It is preferable to contain the diamond particles as a diamond particle dispersion liquid. The diamond particles preferably contain nanodiamond particles having a particle size of 1 µm or less. The diamond particles preferably include detonation nanodiamond particles.
Absstract of: CN120835863A
A process for catalytic cracking of ammonia, the process comprising: supplying an ammonia feed gas to one or more heated catalyst-containing reaction vessels disposed within an ammonia cracking reactor; and cracking ammonia in the ammonia feed gas in the one or more catalyst-containing reaction vessels to produce a hydrogen-containing stream wherein the reaction vessel or each of the reaction vessels has a wall comprised of at least a first alloy and a second alloy wherein the first alloy is more resistant to nitriding than the second alloy, and the second alloy provides mechanical support for the first alloy, and wherein at least a portion of the wall adjacent the catalyst is comprised of the first alloy.
Absstract of: GB2643493A
A method for the production of hydrogen gas comprising (i) providing a DC electrical power supply, (ii) providing a plasma reactor with chamber 105, plasma torch 135 with a plasma cathode extending in to the chamber, a plasma anode extending into the chamber, and first and second spray systems which extend into the chamber, (iii) establishing a DC electric potential between the cathode and anode to generate and sustain a reaction zone about a plasma arc, (iv) providing a spray of hydrogen containing feedstock into the reaction zone from the first spray system whereby a mixture of gases comprising hydrogen gas is formed in the chamber by decomposition of the feedstock, and (v) providing a spray of water into adjacent to the reaction zone from the second spray system, wherein the water spray cools and dilutes the mixture of gases formed in step (iv). A plasma reactor comprising a chamber, plasma torch comprising a plasma cathode extending into the chamber and multi-functional device with plasma anode extending into the chamber, first spray anode with first annual passage surrounding the anode and providing a spray of hydrogen containing feedstock, and a second spray system with second annual passage surrounding the first passage and providing a spray of water.
Absstract of: EP4699693A1
A semiconductor catalyst is provided, which exhibits an effect of accelerating a reduction reaction by visible light irradiation and is excellent in durability. The semiconductor catalyst of the present disclosure includes thin film containing nitrogen-containing diamond particles in a plane direction and a height direction. The semiconductor catalyst can be produced by, for example, fixing, on a substrate having a positive or negative charge, nitrogen-containing diamond particles having a positive or negative charge, the positive or negative charge of the nitrogen-containing diamond particles being opposite to that of the substrate, and laminating, on the fixed nitrogen-containing diamond particles, nitrogen-containing diamond particles having a positive or negative charge, the positive or negative charge of the laminated nitrogen-containing diamond particles being opposite to that of the fixed nitrogen-containing diamond particles. The step of laminating is performed at least once after the step of fixing.
Absstract of: CN120813538A
A process for catalytic cracking of ammonia, the process comprising: supplying an ammonia feed gas to one or more heated catalyst-containing reaction vessels disposed within an ammonia cracking reactor; and cracking ammonia in the ammonia feed gas in the one or more catalyst-containing reaction vessels to produce a hydrogen-containing stream wherein the ammonia feed gas is fed to the or each reaction vessel at a pressure of at least 10 bar wherein the or each reaction vessel is heated to a temperature of at least 500 DEG C, and wherein the or each of the reaction vessels has a wall comprising or consisting of an alloy selected to resist both nitriding and creep deformation without failure at said temperature and pressure over an operating period of at least 1000 hours, 5000 hours, 10,000 hours, 50,000 hours or 100,000 hours.
Absstract of: WO2024218486A1
Oxygen evolution catalyst materials are provided with a pyrochlore-type structure and with (i) calcium and / or sodium as A-site elements of the pyrochlore-type structure; (ii) iridium and / or ruthenium as first B-site elements of the pyrochlore-type structure; (iii) niobium and / or tantalum as second B-site elements of the pyrochlore-type structure; and (iv) a molar ratio of A-site elements: first and second B-site elements is in the range of and including 0.8: 1 to 1:1.
Absstract of: AU2024256387A1
The invention relates to a method (100) for producing hydrogen (103), wherein feed water is subjected to electrolysis (10) with a cathode gas (101) being obtained, wherein the cathode gas (101) contains hydrogen, oxygen and some of the feed water, wherein a process gas flow (102) is formed using at least some of the cathode gas (101), wherein the process gas flow (102) contains at least some of the hydrogen, oxygen and feed water contained in the cathode gas (101), and wherein, in the process gas flow (102), at least some of the oxygen is subjected to an oxidative catalytic reaction with some of the hydrogen to form oxidation water, and wherein at least some of the feed water and the oxidation water in the process gas flow (102) are removed from the process gas flow (1029 in a water removal process. The catalytic reaction and the water removal process are carried out using one or more process units (41, 42), wherein the one process unit (41, 42) or each of the plurality of process units (41, 42) has a first adsorptive drying bed (4a), by means of which at least some of the feed water is removed from the process gas flow (102), a catalytic bed (4b) which is arranged downstream of the first drying bed (4a) and by means of which the catalytic reaction is carried out, and a second adsorptive drying bed (4c) which is arranged downstream of the catalytic bed and by means of which at least some of the oxidation water is removed from the process gas flow (102). The invention also pro
Absstract of: GB2700654A
An apparatus 1 for generating hydrogen includes a housing 10 containing a cylindrical first electrode 11 surrounding a part-conical or frusto-conical second electrode 12. Each of the first and second electrode is for submersion within water located within the housing. The first electrode may be an anode and the second electrode may be a cathode. The housing may be fabricated from or include glass or a glass body may be provided within the housing. The glass may be a borosilicate glass or heat tempered glass. The housing may be cylindrical or cuiboid. The distance between a lowermost portion of the housing and an uppermost portion of the housing may be at least three times greater than the height of the anode. The anode may be fabricated from a metal such as stainless steel which may have a protective coating. The anode may comprise a mesh, such as an unwelded mesh, for example with a mesh size of 149 to 841 µm. The cathode may be formed of stainless steel coated with a second metal. The surface of the cathode may be patterned or textured. The anode and cathode may be retained away from the walls of the housing. Figure 1
Absstract of: GB2700593A
A process for controlling an ammonia cracking plant comprising a fired ammonia cracking reactor 1, may comprise the steps of: decreasing a flow of ammonia feedstock 11 to the catalyst containing reaction tube inlets, and decreasing the heat output of a fuel combustion zone of the reactor. The obtained cracked gas from the outlet of the reaction tubes may be cooled 2, increased in pressure 3, and heated 4 before recirculating the cracked gas to the inlet of the reaction tubes and passing it through the reaction tubes. An ammonia plant in a turn down state may have operated said process. The process is intended to place the ammonia cracking plant into a turndown state which enables it to rapidly return to normal operation without wasting ammonia feedstock or hydrogen. A process may return the plant from turndown by increasing ammonia feedstock flow and heat output and obtaining cracked gas. Figure 2
Absstract of: WO2024218273A1
A method for storing hydrogen in a plurality of subsea storages in a system. The system comprising an electrolyser source (100) for producing hydrogen at a source pressure; a downstream compressor (200) for compressing the hydrogen from the source pressure to a compressed higher pressure; and a plurality of storages (300) each for storing compressed hydrogen at the compressed higher pressure and each being subsea. The method comprising at least the steps of: producing hydrogen (1000) by the electrolyser source (100) at the source pressure; passing the hydrogen (2000) to the plurality of storages (300) through a bypass line (210) around the compressor (200); and storing the hydrogen (3000) in at least one of the plurality of storages (300) at a first pressure below the compressed higher pressure. A system for storing hydrogen in a plurality of subsea storages, the system comprising: an electrolyser source (100) for producing hydrogen at a source pressure; a downstream compressor (200) for compressing the hydrogen from the source pressure to a compressed higher pressure; a plurality of storages (300) each for storing compressed hydrogen at the compressed higher pressure and each being subsea; and a controller (400) for controlling the electrolyser source (100), the downstream compressor (200), and valves (310) to the plurality of storages (300). The controller (400) is configured for controlling the system in, at least, two alternative ways: A) passing the hydrogen, produced by
Absstract of: SE2350468A1
An electrode (200) for a proton exchange membrane water electrolyzer, the electrode (200) comprising a plurality of elongated nanostructures (220) arranged on a substrate (210). The elongated nanostructures (220) are attached to the substrate (210) at a respective first end and extend along a direction perpendicular to a plane of extension of the substrate (210). The plurality of elongated nanostructures (220) are coated with a conformal protective layer (230), and a catalyst layer (240) is arranged on the conformal protective layer. The catalyst layer (240) comprises a plurality of nanoparticles (241), the nanoparticles (241) forming a continuous coating on at least a part of the surface of the plurality of elongated nanostructures (220).
Absstract of: CN120897885A
A method for reacting aluminum with water, the method comprising the steps of: adding aluminum metal to an aqueous solution comprising potassium hydroxide at a concentration between 0.1 M and 0.4 M and a surfactant; stirring the mixture of the previous step; and collecting the generated hydrogen. A composition for use in such a method for reacting aluminum with water, the composition comprising potassium hydroxide and a surfactant.
Absstract of: WO2024165389A1
The present invention relates to a pyrogenic process for manufacturing metal oxides or metalloid oxides wherein a metal precursor and/or a metalloid precursor is introduced into a flame formed by burning a gas mixture comprising oxygen and hydrogen, wherein at least a part of the hydrogen has been obtained from electrolysis of water or an aqueous solution, using electrical energy, at least a part of which has been obtained from a renewable energy source, and wherein at least a part of the thermal energy of the flame is transferred to a first heat transmission medium by means of at least one exchanger, thereby heating the first heat transmission medium to a maximal temperature in the range between 80 and 150 °C.
Absstract of: CN121556074A
本发明提供了一种钌基电解水制氢电极材料的激光制备方法及其应用。所述方法将十二羰基三钌溶液喷到导电载体上，通过SEM发现十二羰基三钌的形貌为不规则的块状团聚体。再使用直接激光划线技术进行碳化处理。通过SEM，XRD等表征发现十二羰基三钌的形貌发生了剧烈的变化，从原来的不规则的块状团聚体转变为网络状的结构，形成了高活性的钌单质纳米颗粒，具有高效的催化活性。该方法将钌基化合物材料通过直接激光划线技术碳化处理成电极材料，具有良好的催化活性和稳定性，且本发明方法简单易行、成本低，可以批量生产。
Absstract of: US20260027556A1
A catalyst for decomposition of ammonia, and a method for decomposition of ammonia in which a decomposition reaction of ammonia is performed in the presence of the catalyst, the catalyst including a carrier, and catalytically active components supported on the carrier, where the catalytically active components include i) ruthenium (Ru) as first metal; ii) lanthanum (La) as second metal: and iii) one or more of aluminum (Al) and Cerium (Ce) as third metal, and the catalyst has a porosity of 25% or more. The catalyst exhibits very high ammonia conversion rates, has little pressure difference between the front end and back end of the reactor, has high catalyst strength, and catalyst layer temperature difference is very small.
Absstract of: CN121556063A
本发明实施例提供了一种电解槽塑料极框结构，包括：A极框，其包括两个能够对接形成框体结构的第一子极框，一个第一子极框的两端分别设有第一氢侧进液口和第一氢侧出气口，另一个第一子极框的两端分别设有第一氧侧进液口和第一氧侧出气口；B极框，其包括两个能够对接形成框体结构的第二子极框，一个第二子极框的中部区域分别设有第二氢侧进液口和第二氢侧出气口，另一个第二子极框的中部区域分别设有第二氧侧进液口和第二氧侧出气口；极板，其为平板结构且周侧设有密封槽，极板在周侧关于极板中心线对称的设有成对设置的极耳，在极耳中心的厚度方向开设有用以安装电阻丝的开孔，极板分别安装在A极框形成的框体结构内和B极框形成的框体结构内。
Absstract of: CN121556070A
本发明提供了一种高熵尖晶石电极材料及其制备方法、固体氧化物电解池，上述高熵尖晶石电极材料具有尖晶石晶体结构，化学通式为RO4；其中，R由Mg、Mo、Sc、Co、Mn、Fe、Ni、Cu、Al、Zn、Cd、Cr以及In中的5种或5种以上元素组成，且R中各元素的化学计量系数xi均满足0.25≤xi≤1。本发明以5种及以上特定金属元素构建R组分，且各元素计量系数控制在合理区间，不仅能形成均匀致密的单相尖晶石晶体结构，更通过高熵混合效应降低体系吉布斯自由能，显著提升材料热力学稳定性，从而消除传统尖晶石材料在固体氧化物电解池中应用时存在的相分解问题，有利于固体氧化物电解池的稳定工作。
Absstract of: CN121556079A
本发明属于纳米材料合成技术领域，涉及一种铁掺杂磷化钴空心纳米笼析氢催化剂及制备方法。该催化剂为Fe掺杂CoP纳米颗粒与氮掺杂碳的复合多孔材料，微观上包覆氮掺杂碳的Fe掺杂CoP纳米颗粒均匀负载于尺寸为200nm的十二面体多孔氮掺杂碳上。其制备方法包括三步：（1）六水合硝酸钴与2‑甲基咪唑在甲醇中室温反应，离心得ZIF‑67前驱体；（2）ZIF‑67与铁氰化钾在乙醇‑去离子水中油浴回流，离心干燥得CoFe‑PBAs前驱体；（3）CoFe‑PBAs在氩气保护下400℃退火2h，制得目标催化剂。该催化剂全pH范围析氢活性优异，酸性、碱性、中性体系中0.01Acm‑2过电位分别为61mV、133mV、188mV，质子交换膜电解槽实现1.0Acm‑2电流密度仅需1.91V，且200h运行电压衰减率低至0.1mVh‑1。本发明制备工艺简单、成本低，催化剂活性与稳定性突出，适用于工业绿氢制备场景。
Absstract of: CN121556080A
本发明公开一种稀土元素掺杂钌氧化物催化剂的制备方法及其应用，所述制备方法包括如下步骤：（1）将稀土金属盐、钌金属盐、盐酸多巴胺和Tris‑HCl缓冲剂溶于水中得到混合溶液，经原位聚合反应，固液分离、干燥后得到粉末前体；（2）将步骤（1）得到的粉末前体进行高温煅烧，得到稀土掺杂氧化钌催化剂。本发明通过将稀土金属盐与钌盐前体分散在原位构筑的多孔碳基底上，通过自牺牲模板法，在高温条件下氧化生成了稀土元素掺杂氧化钌纳米片。本发明方法具有高效且无污染的特点。本发明的稀土元素掺杂钌氧化物作为酸性电解水阳极反应的催化剂，展现出了优异的催化活性和广阔的应用前景。
Absstract of: CN121556067A
本发明属于电催化技术领域，具体涉及一种Ti网基底上负载锰钌氧化物复合电极材料及其制备方法和应用，所述制备方法主要为：将经过预处理后的Ti网基底置于含有锰盐、醋酸盐、硫酸盐的电解液中，对Ti网基底进行电沉积，接着放入马弗炉进行退火，得到Ti/MnOx；然后，将其放入钌盐溶液中进行数次浸泡和干燥，再放入马弗炉中退火，得到Ti/MnOx‑RuOy。本发明制备方法具有工艺简单方便，反应条件温和，成本经济的优势，所制得的复合电极材料，用作电解水阳极时具有优异的酸性OER性能和稳定性。
Absstract of: CN121556066A
本发明公开了一种复合物催化电极材料，包括：(CoNiFe)OOH纳米多孔结构以及吸附在(CoNiFe)OOH纳米多孔结构上的MoO42‑阴离子，通过MoO3/CoNiFe复合物前驱体经电化学氧化获得，其中，MoO42‑阴离子对(CoNiFe)OOH的阳离子催化位点进行锚定。本发明在碱性电解质条件下，由MoO3原位反应生成的MoO42‑阴离子吸附在(CoNiFe)OOH上，MoO42‑阴离子可以通过静电引力作用锚定(CoNiFe)OOH中的阳离子催化位点Co，Ni和Fe，降低金属阳离子在电解质溶液中的溶解，保证了电极的析氧催化稳定性。
Absstract of: CN121556082A
本发明属于电催化材料技术领域，公开了一种CeO2/NiCo2O4异质结析氧反应电催化剂及其制备方法。该电催化剂通过在NiCo2O4纳米片阵列表面构建由氮掺杂碳量子点与CeO2组成的复合保护层，利用吡啶氮捕获溶出钴离子、CeO2氧空位促进其再整合，实现界面动态自修复。所述氮掺杂碳量子点嵌入CeO2层中并与NiCo2O4直接接触，协同抑制钴流失并维持结构完整性。本发明通过构建具有动态离子捕获与自修复能力的CeO2/氮掺杂碳量子点复合界面层，成功解决了NiCo2O4基析氧反应电催化剂在强氧化性工况下因钴离子溶出导致的结构失稳与性能衰减问题，在绿色氢能电解水技术领域具有重要的应用价值与产业化前景。
Absstract of: CN121556068A
本发明适用于电解水制氢催化剂技术领域，提供了一种中熵普鲁士蓝类似物衍生硫化物催化剂及制备方法，包括以下步骤：将Ni(NO3)2·6H2O和C6H5Na3O7·2H2O溶解在去离子水中，磁力搅拌形成溶液A；将K3Co(CN)6和K3Fe(CN)6溶解在去离子水中，磁力搅拌形成溶液B；将溶液B加入到溶液A中，室温搅拌，得到混合溶液；将混合溶液水浴加热，搅拌；对混合溶液进行离心处理，分离得到沉淀，多次洗涤后再真空干燥过夜，得到FeCoNi‑PBA前驱体；将FeCoNi‑PBA前驱体与过量硫粉分别置于两个瓷舟内，放置于管式炉的下游和上游，在氩气气氛下，升温后，保温处理，得到中熵硫化物，命名为FeCoNi‑S。本发明制备得到具有丰富缺陷、高比表面积的双功能催化剂，实现高效、稳定的电解水制氢和制氧。
Absstract of: CN121556056A
本发明公开了一种制氢模块用管路布置系统，包括制氢箱体组件，所述制氢箱体组件内设置有水箱系统，所述水箱系统上连接有进水系统、排水系统、水循环系统，所述水箱系统还连接有排氧气系统，所述水循环系统上连接有制氢系统，所述制氢系统与水箱系统连接，所述制氢系统上设置有氢气风冷系统，所述氢气风冷系统上连接有气液分离系统，所述气液分离系统上连接有排氢气控制系统、水箱系统。本发明的有益效果是，本技术方案的管路布置系统，布局合理，实用性较高，且运行稳定，运用此管路布置系统，实现了稳定制氢作业，有效提高了制氢作业的效率，同时方便对制氢过程进行灵活配置。
Absstract of: CN121556051A
本发明涉及核能、新能源与化工交叉技术领域，公开了一种基于核能的零碳系统，包括：淡水子系统；CO2捕集子系统从空气中捕集CO2气体；高温电解子系统接收从CO2捕集子系统传输的CO2气体以及从淡水子系统传输的水蒸气，以电解制取混合的合成气；核能子系统为淡水子系统供热和供电，使得淡水子系统产生水蒸气，且为CO2捕集子系统和高温电解子系统供电；化工原料合成子系统接收高温电解子系统传输的合成气，以制取化工原料。本申请直接利用核能子系统的热能和电能，将核能和化工生产有机结合，实现能源的多能互补和梯级利用，提高能源利用效率，扩大能量来源，降低碳排放，构建零碳系统。
Absstract of: CN121568290A
本发明公开了一种带状束氢离子源及系统，带状束氢离子源包括离子源基座、离子源弧室和水冷组件，所述水冷组件用于对离子源弧室进行冷却，所述离子源弧室包括弧室底板和弧室顶板，所述离子源弧室内设有灯丝以及相对布置的阴极组件和反射极组件，所述灯丝用于加热阴极组件以发射电子，所述阴极组件与反射极组件处于同一电位，所述弧室底板安装在离子源基座上，所述弧室顶板上开设有带状口。本发明具有氢气电离效率高、氢离子束稳定性好的优点。
Absstract of: CN121551028A
本申请属于催化剂制备技术领域，具体涉及一种硫空位Co3O4/CdIn2S4‑Vs复合材料及其制备方法和应用。该方法将CdIn2S4纳米材料置于H2O2溶液中搅拌，洗涤，干燥，得到具有S空位的CdIn2S4‑Vs纳米材料；然后和Co3O4置于无水乙醇中，搅拌，洗涤，干燥，即得。本发明通过H2O2对CdIn2S4进行刻蚀，构建出具有表面硫空位的CIS‑Vs，其表面硫空位起到电子捕获阱的作用，促使CdIn2S4的光生电子快速转移，从而显著提高光生载流子分离效率。该复合材料的最佳光催化产氢速率达到10.378 mmol h‑1g‑1，是纯CdIn2S4的43倍，循环实验后性能仍能保持在93%。
Absstract of: CN121551027A
本发明公开一种光催化制氢用Cs‑WO3‑X/Zn0.5Cd0.5S复合催化剂及其制备方法和应用，属于可见光谱响应的光催化材料制备技术领域。本发明将CsCl3、WCl6和CO(NH2)2溶解于乙醇进行水热反应得到Cs‑WO3‑x粉末；将CdCl2·2.5H2O、ZnCl2和Na2S·9H2O溶解于水中，然后加入Cs‑WO3‑x粉末室温搅拌，离心、洗涤、干燥得到Cs‑WO3‑X/Zn0.5Cd0.5S复合催化剂。本发明所制备的Cs‑WO3‑X/Zn0.5Cd0.5S复合异质结催化剂集合了单一Cs‑WO3‑X和单一Zn0.5Cd0.5S的优点，并且构建了异质结形成内建电场，异质结抑制了载流子复合，提高了光吸收率，提高了析氢产率。
Absstract of: CN121556091A
本发明提供一种PEM电解水产氢效率测试装置，包括：PEM电解腔以及排气端，所述PEM电解腔设有三组，其三组PEM电解腔规格相同，与现有技术相比，本发明具有如下的有益效果：通过进出水端向电解腔注入去离子水至规定液位，启动电源后，电解过程产生的氢氧气体经排气端分排收集，同时通过外置抽流泵实时监测底部沉淀水体，本发明还提供一种PEM电解水产氢效率测试装置的测试方法，本发明方法具有如下的有益效果：侧封板与内支撑杆构成的密封结构确保电解腔气密性，双极板阵列配合质子交换膜实现高效产氢，而侧测试罐内的氢气浓度传感器可精准监测气体纯度，外置抽流泵则有效排除气泡干扰，多腔并联设计不仅降低单次测试误差。
Absstract of: CN121556078A
本发明涉及一种卤离子掺杂的镍铁氢氧化物析氧催化剂及其制备方法，所述卤离子掺杂镍铁基氢氧化物结构特征为：卤素离子在镍铁基氢氧化物层板内配位，其原子数占总原子数的20～40%之间；镍与铁的原子数比为4：1～1：4之间；除镍和铁外，所添加的其他阳离子原子数占总原子数的0～20%之间；卤离子掺杂的镍铁基氢氧化物纳米片层交联生长，形成有序的中空阵列，其片层厚度为10～100 nm；晶系为三斜晶系，空间群为R‑3m。该催化剂亦可在泡沫镍、泡沫镍，镍网、不锈钢网、泡沫铁、铁网等载体上进行生长。大电流密度下，该催化剂具有较低的析氧过电位和塔菲尔斜率，具有优异的循环稳定性，在碱性电解槽中展现出不俗的应用潜力。
Absstract of: CN121556050A
本发明公开了一种用于碱性电解水的改性电解液，包括：碱性电解质溶液以及添加在碱性电解质溶液中的钼酸盐、硒酸钠以及氢氧化锂，通过将钼酸盐、硒酸钠以及氢氧化锂加入到碱性电解质溶液中并对其进行搅拌溶解，以生成改性电解液。通过上述方式，本发明一种用于碱性电解水的改性电解液，能够在电极表面形成NiMo、NiMoSe等金属化合物，使电极的物质组成及表面形貌结构发生变化，暴露出更多的活性位点，提升电极的电解效率。
Absstract of: CN121556089A
本发明提供了一种降低电解槽停机后高电位的方法，属于电解水制氢技术领域。本发明采用特定放置方式的电解槽进行产氢运行，所述电解槽的放置方式为侧式放置，即电解槽的膜电极朝向为竖直方向，使运行过程中产生的气体在浮力作用下上浮至总管口侧积聚，且气体积聚位置不位于膜电极的活性区，并结合两步吹扫方式，可显著加快气泡排出速度，大幅缩短吹扫时间，有效解决了大电流密度下电解槽停机后高电位问题。
Absstract of: CN121558979A
本发明涉及电解制氢安全领域，特别是一种电解制氢设备的监测装置，包括进气管构件，所述进气管构件包括外壳，外壳直接与制氢设备的氢气产物排出管道相连接，从管道中抽取少量氢气产物进行检测，所述外壳的内壁设置有监测管道，氢气产物会进入监测管道接受监测，所述监测管道的侧面设置有保温副管道，保温副管道为氢气产物保温，防止其快速降温生成冷凝水对监测传感器造成干扰或污染，所述保温副管道的一端设置有防护网，防护网与保温副管道固定连接，保温副管道与吸湿构件形成双重防潮防护：保温副管道有效延缓氢气产物的降温速度，抑制冷凝水生成，避免冷凝水附着在监测传感器表面影响其感应性能；吸湿构件进一步吸附氢气中残留的水分。
Absstract of: CN121556055A
本发明涉及低成本电解水制氢技术领域，具体为一种智能自适应宽负荷低电耗低成本电解水制氢设备，支撑单元包括固定设置在所述底板上的支撑杆，所述底板上固定设置有支撑台，且所述支撑台上固定设置有用于电解反应的反应罐，所述支撑杆上固定设置有定位架，同时控制台内的集成智能化运维系统，实时监测气体纯度与设备状态，精准动态管理系统热平衡、压力平衡和液位平衡，在装置使用过程中能够通过运料管进行各个原料的运输，设置在底板上的存储罐能够对反应过程中产生的氢气进行存储，设置在防护壳上的缓冲罐能够保证装置内的气压处于一个稳定的区间，保证反应过程的正常进行。
Absstract of: CN121556062A
本发明涉及质子交换膜电解水装置阳极催化剂领域，具体地公开了指一种适用于高电流密度酸性析氧反应的IrRu/TiOxNy纳米带阵列结构薄膜电极及其制备方法。本发明选择具有多孔结构和良好化学/机械稳定性的商用Ti毡作为基底，通过水热法在Ti毡上原位生长钛酸钠纳米带阵列，然后经过离子交换和热氮化处理分别制备得到氢钛酸纳米带阵列和TiOxNy纳米带阵列，最后利用湿化学还原法将IrRu纳米合金颗粒负载在TiOxNy纳米带阵列表面，获得具有纳米带阵列结构的IrRu/TiOxNy薄膜电极。本发明制备的IrRu/TiOxNy纳米带阵列结构薄膜电极，避免使用了粘结剂和导电添加剂，具有优异的高电流密度催化活性。
Absstract of: CN121557875A
本发明公开了一种碱性电解槽密封垫片厚度监测系统及监测方法，包括：图像采集设备，其安装在碱性电解槽的径向外侧；控制系统，其与图像采集设备电连接，包括图像预处理模块，其接收图像数据并对其进行去噪和增强处理；特征提取模块，其提取各极框、密封垫片的边缘特征，得到特征数据；角度畸变矫正模块，其根据拍摄角度误差对各密封垫片的特征数据进行矫正；厚度计算模块，其建立单位特征数据与实际尺寸之间的对应关系，并以此为依据计算各密封垫片的实际厚度数据；输出储存模块。本发明通过图像采集设备与控制系统的多个模块配合实现对各密封垫片厚度变化的实时、精确、自动化监测，解决了传统人工测量方式劳动强度大、误差大及不安全的问题。
Absstract of: CN121556092A
本发明属于电解水制氢技术领域，公开一种集成汽水分离的PEM电解纯水制氢系统，包含原水预处理、超纯水精制、两级超纯水检测回流、PEM电解反应、集成式气液分离、氢气提纯及中央控制模块，系统通过集成多级气液分离单元与智能对比检测通道，实现气液高效分离与精准回流调控；两级超纯水检测回流模块保障水质并实现水资源循环利用；中央控制模块实现全系统自动化监测与联动控制。该系统可提升电解效率与氢气纯度，保障运行稳定安全，提高水资源利用率。
Absstract of: CN121554752A
本发明公开了一种含不同配位模式金属节点的金属有机框架催化剂及其合成方法和应用。所述金属有机框架催化剂的合成方法包括如下步骤：S1，使三氮唑有机配体L与M1和M2金属源试剂进行水热反应得到母体框架，所述母体框架具有八面体位点和四面体位点，M1金属节点占据八面体位点中心，M2金属节点占据四面体位点中心；S2，采用醛基辅助修饰配体H配位取代四面体位点的M2‑Cl形成M2‑O。本发明的金属有机框架催化剂基于三氮唑有机配体与金属M构建的M‑TZ框架，具有结构明确、孔道可调、电子结构灵活等特点，在碱性及外加电压条件下可通过动态重构形成富含氧空位、键长优化和自适应活性位点的活性相，显著提升析氧反应活性和稳定性。
Absstract of: CN121566547A
本发明涉及可再生能源风光发电、水电解制氢技术领域，具体涉及一种离网的风光互补制氢发电系统及方法：包括风力发电模块、光伏发电模块、碱性电解水模块、电力智能分配模块、储能模块和电力负载模块，风能发电模块和光伏发电模块共同作为电能来源，为碱性电解水模块及电力负载模块供电。在风光发电负荷充足时，碱性电解水模块以额定功率运行，同时将多余电能存储至储能模块；当风光发电负荷不足，无法满足碱性电解水模块的最低负荷需求时，储能模块为碱性电解水模块提供补充电能，确保其以最低负荷持续运行，同时向电力负载模块供电，通过电力智能分配模块动态调控风能、光伏、储能及负载之间的能量分配，实现高效能源管理。
Absstract of: CN121556049A
本发明属于新能源制氢与生物质资源利用的技术领域，具体的涉及一种解耦电解水制氢的方法。该方法基于具有可逆氧化还原特性的过渡金属配合物，通过构建阳极侧“电化学-化学”反应的闭环通路解耦电解水，有效避免了传统电解水中高能耗的析氧过程，降低了系统运行电压和安全风险。在该方法体系中，过渡金属配合物作为氧化还原媒介，持续参与阴极水还原析氢和阳极氧化的电子转移过程，生成的高价态物种随后在电解液中被生物质还原，从而实现价态循环与持续电子传递；而生物质则同步实现了高价值转化。具有能耗低、安全性高、产物附加值高的优势，适用于分布式绿氢制备与生物质资源梯级利用。
Absstract of: CN121556090A
本申请涉及一种制氢系统的电解液温度控制方法、装置和设备。制氢系统中包括：光伏单元、储能单元、电解槽单元、连接电解槽单元的电解液循环回路，以及目标DC‑DC变换器，目标DC‑DC变换器与电解液循环回路之间的距离小于预设距离，目标DC‑DC变换器包括：连接于光伏单元与储能单元之间的DC‑DC变换器，和/或，连接于储能单元与电解槽单元之间的DC‑DC变换器，方法包括：获取电解槽单元中的电解液实时温度；根据电解液实时温度所处的目标温度范围，确定与目标温度范围对应的目标工作模式；基于目标工作模式控制目标DC‑DC变换器工作。采用本方法能够优化能源利用效率。
Absstract of: CN121551047A
本发明公开了一种用于甲醛溶液重整制氢的光催化剂及其制备方法，属于催化剂制备与氢能技术交叉领域。所述光催化剂是具有不同Mn和Ni摩尔比的双金属结构材料，所述光催化剂分子式为MnxNiy/C3N4。其制备方法是通过加入不同比例的醋酸锰和氯化镍调节催化剂中Mn和Ni的投料比，将混合物在含C3N4的去离子水中均匀分散后，滴加硼氢化钠溶液并持续搅拌以获得前驱体，随后在氢气氛围中进行煅烧处理后得到。该光催化剂可同步实现甲醛降解与稳定产氢，其产氢速率可达134.53 mmol·h‑1·g‑1。本发明光催化剂在无牺牲剂的温和反应条件下展现出优异的光催化甲醛重整产氢性能，既能突破传统催化剂对牺牲剂的依赖性难题，又能通过甲醛的高效转化实现污染物降解与清洁能源制备的双重效益。
Absstract of: CN121551024A
本发明提供了一种氧化铈负载的PtPdRhRuNi高熵合金团簇催化剂及其制备方法和应用，属于催化剂技术领域。该催化剂包括载体氧化铈和负载于所述载体上的PtPdRhRuNi高熵合金团簇。经测试，本发明提供的氧化铈负载的PtPdRhRuNi高熵合金团簇催化剂具有较好的循环稳定性；并且该催化剂在氨硼烷水解制氢反应中具有优异的催化性能。
Absstract of: CN121556088A
本发明公开了一种用于碱性水电解的复合隔膜及其制备方法和应用，属于复合膜技术领域。本发明中的复合隔膜采用高分子聚合物网格作为支撑层，可以提高复合隔膜的机械强度；另外，采用金属氧化物/层状双金属氢氧化物复合材料作为亲水无机填料，可以优化复合隔膜孔结构及增强复合隔膜的亲水性。本发明中所得复合隔膜较金属氧化物复合隔膜和层状双金属氢氧化物复合隔膜具有更优异的综合性能，应用在碱性水电解槽可达更好的电解性能。
Absstract of: CN121556073A
本发明公开了一种三维多孔铂碳HER催化剂的制备方法，包括以下步骤：一、对Na3C6H5O7·2H2O、CH4N2O和NH4Cl混合溶液进行雾化干燥，得到前驱体粉末；二、前驱体粉末进行高温热解，得到热解产物；三、热解产物进行酸洗，得到三维多孔载体；四、三维多孔载体进行铂负载，得到固体粉末；五、固体粉末进行热还原，得到三维多孔铂碳HER催化剂。本发明成功制备出具有多级孔结构的三维多孔铂碳HER催化剂，其均匀分布的活性位点与丰富的孔径结构协同作用，显著改善了HER过程的传质效率和反应动力学，从而有效提升了电催化析氢性能，该制备方法工艺简便、产物纯度高且易于规模化制备，展现出良好的应用前景。
Absstract of: CN121556081A
本发明公开了一种Cu/Cu2O/Bi2WO6三元Z型异质结光电催化材料及其制备方法和应用，制备方法包括：制备Bi2WO6粉末，并通过电沉积在碳纸表面得到一层均匀、垂直生长的Bi2WO6纳米片阵列，通过电沉积在附有Bi2WO6纳米片阵列的碳纸表面沉积Cu2O得到Cu2O/Bi2WO6薄膜；将沉积有Cu2O/Bi2WO6薄膜置于管式炉中在惰性气氛中，在150～300°C下退火处理，随后在空气中室温放置12～24 h，使其表面状态自然氧化达到稳定，获得Cu/Cu2O/Bi2WO6三元Z型异质结光电催化材料，本发明的Cu/Cu2O/Bi2WO6三元Z型异质结光电催化材料具有高效的光电转换效率、优异的稳定性和宽光谱响应特性，在其作为阴极和阳极的全解水体系中表现出优异的光电催化全解水效率。
Absstract of: CN121556054A
本发明涉及小型制氢机技术领域，具体为一种用于家庭治疗的小型制氢机，加工单元包括固定设置在所述外壳内的蓄水罐，所述外壳内固定设置有支撑板，所述支撑板上固定设置有电解器，所述加工单元用于对水进行电解反应处理，启动装置，通过设置净化腔室上的水泵使其能够提供一个稳定的吸力，并且水源能够被净化腔室内的除杂管进行净化除杂，处理过后的水源再通过长管输送至装置的蓄水罐中进行存储，并且通过设置在蓄水罐外壁上的催化剂罐对蓄水罐内的溶液进行进一步的除杂加工，再通过软管一输送至装置电解器中进行电解反应，保证电解过程的高效进行，设置在电解器内的转板能够对其内部溶液含量进行实时的检测，保证装置运作时的安全性。
Absstract of: CN121556058A
本发明提供一种高温蒸汽联用固体氧化物高温电解系统及控制方法，属于高温电解制氢技术领域。蒸汽依次通过氢侧换热器和氢侧补热器调节温度后送入电解堆高温箱；氮气和氢气依次通过氢侧换热器和氢侧补热器调节温度后送入电解堆高温箱；空气依次通过空侧换热器和空侧补热器调节温度后送入电解堆高温箱；电解堆高温箱中固体氧化物高温电解堆塔电解高温蒸汽后产生的氢气依次通过氢侧换热器、气体冷却器后，部分经氢气循环泵重新通过氢侧换热器和氢侧补热器调节温度后送入电解堆高温箱；电解堆高温箱中固体氧化物高温电解堆塔电解高温蒸汽后产生的其他气体通过空侧换热器送入空侧排放组件进行排放。采用模块化集成设计，温度分区布置，解决热应力问题。
Absstract of: CN121556059A
本申请公开了一种电解制氢系统，电解制氢系统包括：ALK电解组件和AEM电解组件；ALK电解组件包括：ALK阳极反应区、ALK阴极反应区、ALK阳极气液分离罐和ALK阴极气液分离罐；ALK阳极反应区和ALK阳极气液分离罐连通，ALK阴极反应区和ALK阴极气液分离罐连通；AEM电解组件包括：AEM阳极反应区和AEM阳极气液分离罐；AEM阳极反应区和AEM阳极气液分离罐连通。在本技术方案中，能够实现ALK电解槽和AEM电解槽中的循环碱液可以相互补充，以避免电解液浓度失衡，提升制氢效率，保证电解制氢系统运行稳定性。
Absstract of: CN121556057A
本发明公开一种模块化碱性电解槽，属于电解水制氢系统领域。包括电解小室、双极板、极框、端压板，极框上部开设有碱液出口，极框下部开设有碱液入口，在电解槽外围安装有n个输电板，n为不小于3的整数，所述的输电板焊接在极框外侧，极框与BOP的连接管道设有控制开关的阀门。所述的n个输电板为一个负极输电板和4个正极输电板或者一个正极输电板和4个负极输电板。本发明提供的模块化碱性电解槽，能够达到兼顾模块独立性、均衡运行、氢气和氧气纯度高的效果。
Absstract of: CN121556069A
本发明提供了一种基于淬火工艺的镍钴铁碱性电解水催化剂，化学通式为NixCoyFezOx+y+z+1，其中0＜x+y+z≤4，且0≤x≤2，0≤y≤1，0≤z≤1，制备方法包括：镍基材的前处理、制备前驱体溶液、浸渍‑煅烧‑淬火、重复浸渍‑煅烧‑淬火。还提供了应用，该基于淬火工艺的镍钴铁碱性电解水催化剂用于电解水催化。本发明通过多金属组份的协同形成金属‑氧强键合作用以及淬火处理诱导产生的大量氧空位和表面缺陷。不仅增加了活性位点数量，还优化了电子结构，促进了水分子的吸附与解离，有效防止了活性组分在长时间运行中的溶解和脱落。
Absstract of: CN121556087A
本发明公开了一种羟基氧化铝基碱性电解水复合隔膜及其制备方法，属于隔膜制备技术领域，所述隔膜由聚砜、聚乙烯吡咯烷酮、季胺化聚乙烯醇、γ‑AlOOH粉末组成，通过γ‑AlOOH粉末的引入可以显著降低面电阻、增强阻气性、提高机械强度与尺寸稳定性、改善热稳定性与化学稳定性，通过季胺化改性可以显著增强隔膜的永久亲水性、提升隔膜离子传导效率。
Absstract of: CN121556084A
本发明提供了一种镍掺杂手性钴氧化物催化剂，化学式为L‑Co(3‑x)NixO4，制备方法：将还原剂、L‑半胱氨酸、柠檬酸钠、氯化钴、氯化镍与水混合搅拌，加入异丙醇并静置，得到镍掺杂手性钴氧化物催化剂。本发明还提供了包括BiVO4光阳极和镍掺杂手性钴氧化物催化剂的光电化学水分解用复合光阳极，镍掺杂手性钴氧化物催化剂负载在BiVO4光阳极表面，通过将L‑Co(3‑x)NixO4分散液与BiVO4光阳极混合热处理得到。本发明还提供了包括上述复合光阳极的光电化学水分解装置。本发明能够通过手性诱导的自旋选择效应实现自旋选择性电荷传输，降低了反应能垒，优化了OER路径，解决了现有技术高过电位和低光电流密度的问题，能够抑制H2O2副产物，稳定性强，无需外部磁场，为光电化学水分解提供了新思路。
Absstract of: CN121556086A
本发明公开了一种IrxCo3‑xO4/Ir‑Co3O4异质结构电催化剂及其共沉积结合缺陷调控制备方法和应用，属于催化剂制备技术领域。包括：将含铱化合物和含钴化合物溶解于去离子水中配置成前驱体溶液，并在三电极体系中进行阴极共沉积处理；然后将样品煅烧，再经等离子体处理在材料中创造丰富的阴、阳离子空位，再次进行煅烧消除氧离子空位；将处理后的样品浸渍于IrCl3溶液中，蒸干溶剂后进行热处理，制得IrxCo3‑xO4/Ir‑Co3O4异质结构电催化剂。该异质结构催化剂能够有效改善Ir活性中心周围的电子结构，强化金属‑金属氧化物载体相互作用，抑制Ir活性中心原子过度氧化，极大地提升催化剂的活性及稳定性，因此能够有效解决现有技术中贵金属基催化剂活性低、质量活性不高及稳定性差的技术难题。
Absstract of: CN121551755A
本发明公开了一种电解水氢氧焊割装置，涉及火焰焊割技术领域。该电解水氢氧焊割装置，包括反应组件、移动座、支撑组件，还包括：外壳，安装于支撑组件上，其内部设有用于氢气输送的内管，所述内管外侧设有套管，套管与内管之间的间隙形成氧气输送腔，且套管与外壳之间的间隙形成降温腔；接头，固定于外壳下端，其内设有与降温腔连通的环形腔，接头底部安装有出气嘴。通过同轴嵌套的内管、套管与外壳，隔离氢气输送、氧气输送及水雾，实现了燃料、助燃剂与冷却介质在输送阶段的完全物理分离，从根本上杜绝了可燃气体在管路内预混合的风险，将混合点严格限定在焊嘴外的安全区域，显著提升了设备使用时的安全水平。
Absstract of: CN121556083A
本发明提供了一种电氧化含氯电解质的催化剂及其制备方法和应用，所述催化剂包括原位生长在镍基底上的层状双氢氧化物‑稀土碱式碳酸盐异质结，所述镍基底为表面经过镍修饰的泡沫镍。本发明基于构建可区分Cl‑与OH‑的选择性吸附位点的策略，通过引入稀土碱式碳酸盐（RE(OH)CO3）实现对OH‑的优先吸附，从而显著增强材料在海水电解中的抗氯离子腐蚀能力。该异质结构不仅具有优于传统LDH的析氧反应活性，更在工业级电流密度下表现出卓越的结构稳定性与持续抗腐蚀性能，为推进海水电解技术的工业化应用提供了可行的材料解决方案。
Absstract of: CN121551048A
本发明提供了一种Co‑NC纳米立方体负载单金属Rh纳米催化剂的制备方法及在甲醇析氢中的应用，通过金属离子与有机配体结合制备了Co‑NC纳米立方体前驱体，再通过高温煅烧获得Co‑NC纳米立方体，随后使用还原剂硼氢化钠原位还原Rh3+金属离子，制备了Co‑NC纳米立方体负载单金属Rh催化剂，并将其应用在催化四羟基二硼与甲醇反应制氢中，其催化制氢中氢气转换频率值达到了161(L(H2)·gCat.‑1·h‑1)以上。本发明技术方案得到的纳米催化剂的优点为制备工艺简单，对四羟基二硼与甲醇反应制氢具有较高的选择性和催化活性，以及其在极低温度下仍保留较高催化活性。
Absstract of: CN121565302A
本发明公开了一种氮掺杂‑有机基团协同调控MXene非贵金属析氢电催化剂定向设计与筛选方法，其特征在于，该定向设计与筛选方法包括以下步骤：一、以氮掺杂Ti3C2O2 MXene为基底，选取有机基团进行修饰，构建吸附型协同模型；二、对步骤一中构建的吸附型协同模型的HER活性和位点可及性进行分析，筛选出最优的吸附型协同模型，得到MXene非贵金属析氢电催化剂。本发明的定向设计与筛选方法通过以氮掺杂Ti3C2O2 MXene为基底，选取有机基团进行修饰，构建吸附型协同模型，并结合HER活性和位点可及性两大指标共同筛选，有效缩短了研发周期，兼顾稳定性和活性位点密度，适用于电化学用催化剂的制备领域。
Absstract of: AU2024305585A1
The invention relates to an ion-conducting membrane (10) for an electrochemical device, said membrane comprising a layer of a material comprising: - 5% to 30% by weight of a polymer binder and - 70% to 95% by weight of a powdered ceramic, the powdered ceramic comprising ceramic doped with yttrium oxide and/or ceramic doped with cerium oxide. The invention can be used to produce a non-porous membrane for low-temperature electrolysis (0°C to 150°C).
Absstract of: WO2025105885A1
A membrane-electrode assembly includes a first catalyst electrode, a polymer electrolyte membrane covering a side surface and an upper surface of the first catalyst electrode, and a second catalyst electrode disposed on the polymer electrolyte membrane, in which at least a portion of a corner area in which the side surface and the upper surface of the first catalyst electrode are connected has a curved shape.
Absstract of: WO2025095296A1
A solid oxide cell stack fastening apparatus, in which downward pressure applied to the solid oxide cell stack is uniform throughout, includes a housing which accommodates a solid oxide cell stack and includes a first coupling part on one side thereof, and a first block which includes a second coupling part and an elastic member in contact with the solid oxide cell stack. The first coupling part and the second coupling part each have screw threads coupled to each other.
Absstract of: WO2025028396A1
A method for producing hydrogen is provided in which ammonia can be highly efficiently decomposed even with low power consumption to produce hydrogen. This method for producing hydrogen includes a step in which an ammonia decomposition catalyst including a titanium oxide represented by general formula (1) or a titanium oxynitride represented by general formula (2) is brought into contact with ammonia while being irradiated with microwaves at low output. General formula (1): ATiO3-x (A is at least one member selected from the group consisting of Ba and Sr, and x is a number represented by 0.1≤x≤2.0.) General formula (2): ATiO3-xNy (A is at least one member selected from the group consisting of Ba and Sr, x is a number represented by 0.1≤x≤2.0, and y is a number represented by 0.1≤y≤1.0.)
Absstract of: CN121550718A
本发明涉及电解水技术领域，具体为一种电解水用循环过滤装置，主要包括支撑架，支撑架顶面安装有电解槽和冷却箱，电解槽两端安装有出气管出液管和进液管，还包括：过滤机构，过滤机构设置在管道内部，振动机构，振动机构设置在管道内部，敲击机构，敲击机构设置在管道内部。通过电解槽中进行反应制氢时，外界的循环泵对电解槽中的液体进行循环，液体流动时，带动扇叶转动，扇叶带动转轴和转动条转动，转动条带动刮条和刷毛转动，刷毛和刮条对滤板侧面过滤下来的碳酸钾进行清除，碳酸钾不会堵塞滤板，提高液体从滤板处进入冷却箱再次到电解槽的效率，同时保证碳酸钾不会再次循环至电解槽中，对电极表面造成覆盖，进一步提高电解的效率。
Absstract of: PL449572A1
Przedmiotem zgłoszenia jest elektrolizer do elektrolizy wody, z elektrodami ulokowanymi poziomo, które to elektrody są w pionie poprzecinane kanałami, gdzie stosunek pola przekroju poprzecznego pojedynczego kanału do jego długości wynosi co najwyżej 0,3 i mikroporowatego separatora, między tymi elektrodami, charakteryzujący się tym, że wspomniane elektrody (1, 2) i separator (4) je oddzielający są wypukłe w stronę dna elektrolizera i elektroda górna (1) jest ulokowana w objętości, której dotną ścianę stanowi separator (4) i obie strony: górną i dolną tej elektrody, łączą kanały do cyrkulacji elektrolitu (7, 7a) i poniżej dolnej strony kraju separatora (4) są również wykonane otwory cyrkulacyjne (13, 13a), a elektroda dolna (2) jest ulokowana poniżej tych otworów.
Absstract of: KR20260024666A
본 발명은, 물을 다양한 목적으로 다양한 경로로 순환시킬 수 있는 다목적 펌프를 구비한 수전해 시스템에 관한 것이다. 상기 시스템은, 물탱크와 산소측 기액분리기를 연결하는 배관으로서 제1밸브, a합류점, 펌프, 이온교환기, b합류점, 제2밸브가 순서대로 배치된 제1배관과; b합류점과 물탱크를 연결하며 제3밸브가 배치된 제2배관과, 산소측 기액분리기와 a합류점을 연결하며 제4밸브가 배치된 제3배관과, 수소측 기액분리기와 a합류점을 연결하며 제5밸브가 배치된 제4배관을 포함한다. 여기서, 산소측 기액분리기의 수위가 제1 기준수위 미만이면, 제1 및 제2밸브를 개방하고 펌프를 동작시키고 제3, 제4 및 제5밸브를 폐쇄하고, 산소측 기액분리기 내의 물의 전기전도도가 제1 기준전도도 이상이면, 제2 및 제4밸브를 개방하고 펌프를 동작시키고 제1, 제3 및 제5밸브를 폐쇄하고, 물탱크 내의 물의 전기전도도가 제2 기준전도도 이상이면, 제1 및 제3밸브를 개방하고 펌프를 동작시키고 제2, 제4 및 제5밸브를 폐쇄하고, 수소측 기액분리기의 수위가 제2 기준수위 이상이면, 제2 및 제5밸브를 개방하고 펌프를 동작시키고 제1, 제3 및 제4밸브를 폐쇄하게 된다.
Absstract of: WO2024236080A1
There is provided a membrane electrode assembly (MEA) for an electrochemical devices, such as for fuel cells and electrolyzers, particularly for polymer electrolyte membrane (PEM) fuel cells, said membrane electrode assembly comprising a composite electrolyte membrane comprising a reinforced electrolyte layer comprising at least one porous support, the porous support being at least partially imbibed with a first ion exchange material; and a first electrode comprising a reinforced electrode layer comprising a porous support, the porous support being at least partially imbibed with a first catalyst and a second ion exchange material, wherein the composite electrolyte membrane is in contact with the first electrode. Also provided is a composite electrolyte membrane, which can be used in the manufacture of the membrane electrode assembly and a fuel cell and electrolyzer comprising such a membrane electrode assembly. A method for the manufacture of the membrane electrode assembly, and a membrane electrode assembly obtainable by such a method are also disclosed.
Absstract of: KR20260024382A
본 발명은 스테인레스 스틸 지지형 고체산화물 수전해전지 및 이의 제조방법에 관한 것으로, 본 발명에 따르면, 금속산화물 수전해전지의 제조시 스테인레스 스틸 다공성 지지체를 사용하여 고온에서의 열내구성이 뛰어나며 높은 수분 저항성을 나타내며, 양극(연료극)으로서 Ni, YSZ 및 페로브스카이트 산화물의 3가지 조성 혼합물을 사용함으로써 상기 페로브스카이트 산화물이 니켈(Ni) 입자 사이에 물리적 장벽 역할을 수행하고 전자전도성이 높고 융점이 니켈보다 높아 니켈과의 화학적 결합을 안정적으로 유지하여 니켈의 이동 및 조대화를 막고 전자전도를 향상시켜 고온에서도 니켈의 열화를 억제하여 수전해 전지 성능을 향상시킨다. 또한, 양극 제조시 기공형성제의 농도와 소성 온도를 조절하여 기공 크기 및 분포를 조절함으로써 전지 성능 향상을 더욱 증대시킬 수 있다. 또한, 상기 금속산화물 수전해전지는 슬러리를 테이프 캐스팅과 공소성을 통해 제조함으로써 제조가 용이하고, 연속 제조 공정이 가능하여 대량 생산이 가능하므로 종래 금속산화물 수전해전지를 대신하여 유용하게 사용될 수 있다.
Absstract of: KR20260024959A
본 발명은 이리듐계 촉매를 포함하는 고분자 전해질막(Polymer Electrolyte Membrane: PEM) 수전해용 전극 촉매이며, 상기 이리듐계 촉매는 코어-셀(core-shell) 입자이며, 상기 코어는 이리듐 금속을 포함하며, 상기 쉘은 이리듐주석 복합산화물을 포함하는, PEM 수전해용 전극 촉매, 그 제조방법, 상기 전극 촉매를 포함하는 PEM 수전해용 전극, 및 이를 포함하는 PEM 수전해용 셀을 제공한다. 상기 PEM 수전해용 전극 촉매는 분산성 및 내구성이 향상된다. 이러한 전극 촉매를 포함한 전극은 산소 발생 반응 (oxygen evolution reaction: OER) 활성이 개선된다. 이러한 전극 촉매를 이용하여 형성된 PEM 수전해용 전극은 산소 발생 반응 (oxygen evolution reaction: OER) 활성이 개선된다. 이러한 전극을 이용하면 셀 성능이 개선된 PEM 수전해용 셀을 제조할 수 있다.
Absstract of: KR20260024422A
본 발명은 전기화학적 활성 및 내구성이 우수한 수전해용 촉매 및 그 제조방법, 그를 포함하는 수전해 전지에 관한 것이다. 상기 수전해용 촉매 및 그를 포함하는 수전해 전지는 구조가 제어되어 있고, 알칼리성 및 산성 전해질에서 낮은 과전압에서 높은 전류밀도를 달성하기 때문에 전기화학적 활성이 우수하고, 향상된 내구성을 가지고, 그를 통해 수소의 생산에 대한 경제성과 효율성을 크게 향상시킬 수 있으며, 기존 촉매에 비해 전이금속 비율을 줄일 수 있어 그 제조비용을 줄일 수 있다. 또한, 상기 제조방법은 이온교환반응을 통해 구조를 제어할 수 있고, 상기와 같은 효과를 가지는 수전해용 촉매를 제공할 수 있으며, 제조과정에서 전이금속의 비율을 줄일 수 있어서 제조비용을 줄일 수 있다.
Absstract of: KR20260023671A
본 발명은, 배터리 방전을 이용한 수소 제조장치, 제조방법, 및 이를 이용한 탄화수소 연료 제조 시스템을 제공한다. 본 발명의 일실시예에 의하면, 상기 배터리 방전을 이용한 수소 제조장치는, 제1 방전대상 배터리 및 제2 방전대상 배터리가 전기적으로 연결되어 발생한 방전에 의하여 수전해가 이루어지는 방전 처리부; 상기 제1 방전대상 배터리가 상기 방전 처리부와 전기적으로 연결되도록 상기 제1 방전대상 배터리가 탑재되는 제1 배터리 탑재부; 상기 제2 방전대상 배터리가 상기 방전 처리부와 전기적으로 연결되도록 상기 제2 방전대상 배터리가 탑재되는 제2 배터리 탑재부; 및 상기 방전 처리부에서 상기 수전해에 의하여 발생한 수소 가스를 수용하는 수소 가스 수용부를 포함하고, 상기 제1 방전대상 배터리의 방전은, 상기 제2 방전대상 배터리에 의한 역전위 방전에 의하여 이루어질 수 있다.
Absstract of: KR20260024021A
본 발명은 수소 추출형 발전장비용 여과장치 및 그 제작방법에 관한 것으로서, 수소를 추출하여 전기를 생산하는 발전장비에서 미세 이물질의 포집 및 제거가 용이하게 이루어질 수 있게 되어 발전 효율을 향상시키는 효과를 나타낸다. 이를 실현하기 위한 본 발명은, 평탄면을 이루는 판상 구조를 이루는 가운데 다수의 타공(12)이 관통 형성된 타공판 본체(10)와; 상기 타공판 본체(10)의 저면에 스폿 용접에 의해 고정되는 매쉬망(20);을 포함하는 구성을 이루는 것을 특징으로 한다.
Absstract of: KR20260023382A
본 발명의 일 실시예에 따른 플라즈마 버너는 내부 공간을 갖는 하우징, 및 상기 하우징 내부에 삽입되며 방전 전압으로 대전된 방전극을 포함하고, 상기 하우징은 상류측에 배치된 비방전 영역과 상기 비방전 영역의 하류에 연결되며 아크가 위치하는 방전 영역을 포함하며, 상기 방전극에는 연료가 이동하는 연료 통로와 상기 하우징 내부로 연료를 분사하는 연료 분사구가 형성될 수 있다.
Absstract of: KR20260023453A
본 발명은 우수한 성능의 수전해 촉매를 제조할 수 있는 방법에 관한 것으로, 보다 구체적으로 본 발명은 니켈 전구체, 철 전구체 및 코발트 전구체를 포함하는 용액을 100℃ 이상 및 200℃ 이하의 온도에서 열처리하여 고형분을 수득하는 단계 및 상기 고형분을 동결건조하여 촉매 입자를 수득하는 단계를 포함하는 수전해 촉매의 제조방법에 관한 것이다.
Absstract of: KR20260022576A
본 발명의 일 실시예는 4차 암모늄화된 트립티센 첨가제를 포함하는 수전해용 음이온 교환막 및 이의 제조방법을 제공한다. 본 발명의 일 실시예에 따른 수전해용 음이온 교환막은 브롬화된 고분자 매트릭스 기지에 4차 암모늄화된 트립티센 첨가제를 도입하여 수전해 작동 온도 범위 내에서 추정된 수산화물 이온의 이온 전도성이 크게 향상되고 활성화에너지가 감소하여 수전해 전지의 성능을 개선하는 효과가 있다.
Absstract of: KR20260022745A
본 발명은 전기화학적 활성 및 내구성이 우수한 수전해용 촉매 및 그 제조방법, 그를 포함하는 수전해 전지에 관한 것이다. 본 발명에 따른 수전해용 촉매 및 그를 포함하는 수전해 전지는 구조가 제어되어 있고, 알칼리성 전해질에서 낮은 과전압에서 높은 전류밀도를 달성하기 때문에 전기화학적 활성이 우수하고, 향상된 내구성을 가지며, 이를 통해 수소의 생산에 대한 경제성과 효율성을 크게 향상시킬 수 있다. 또한, 기존 촉매에 비해 전이금속 비율을 줄일 수 있고 특히 백금(Pt)을 전혀 사용하지 않아 그 제조비용을 크게 줄일 수 있다는 장점이 있다. 그리고, 본 발명에 따른 수전해용 촉매는 여러 조성의 입자로 구성될 수 있어서 원하는 목적에 따라 적당한 조성을 선택할 수 있다. 나아가, 본 발명에 따른 수전해용 촉매의 제조방법은 이온교환반응을 통해 구조를 제어할 수 있고, 상기와 같은 효과를 가지는 수전해용 촉매를 제공할 수 있으며, 제조과정에서 전이금속의 비율을 줄일 수 있고 백금(Pt)을 전혀 사용하지 않아 제조비용을 크게 줄일 수 있다.
Absstract of: WO2026039480A1
A method for producing hydrogen including: performing electrolysis of a hydronium solution, the hydronium solution including: a molecule including hydrogen and oxygen; hydronium ions; hydroxide anions (OH-); a pH between -1.0 and 0.5; and a hydroxide anion OH- concentration of about 1% or less, wherein the hydronium solution is configured to maintain the same pH and the same hydroxide anion OH- concentration for at least six years. A method for producing hydrogen including: performing electrolysis of a hydronium solution, the hydronium solution including: a molecule including hydrogen and oxygen; hydronium ions; hydroxide anions (OH-); a pH between -1.0 and 0.5; and a hydroxide anion OH- concentration of about 1% or less, wherein the hydronium solution is configured to maintain the same pH and the same hydroxide anion OH-
Absstract of: KR20240160080A
The present invention relates to a catalyst composite for a hydrogen production reaction having remarkably excellent catalytic activity and durability by an interaction effect between a porous carbon body doped with nitrogen of a high graphitic structure and a specific bonding type and a hydrogen active catalyst metal. More specifically, the present invention relates to a porous catalyst composite for a hydrogen production reaction, which comprises: a hydrogen active catalyst metal; and a porous three-dimensional net-type carbon support on which the hydrogen active catalyst metal is supported and containing nitrogen, wherein 30% or more of the total nitrogen contained in the porous three-dimensional net-type carbon support is nitrogen in a pyrrolic bond state.
Absstract of: US20260049405A1
A method of operating an electrolyzer cell system includes providing a steam inlet stream to a stack of electrolyzer cells, generating a main product stream containing hydrogen and steam, and an oxygen exhaust stream in the stack, and providing liquid water into the main product stream to cool the main product stream.
Absstract of: DE102024207827A1
Die Erfindung betrifft eine Elektrolysevorrichtung (10) mit wenigstens einer Elektrolyseeinheit (12) zur Reduktion eines für die Elektrolyse vorgesehenen Mediums, insbesondere Wasser, mit einer Luftzuleitung (20) zur Zufuhr von Luft zur Elektrolyseeinheit (12), mit einer Abgasleitung (24) zur Ableitung von Anodenabgasen der Elektrolyseeinheit (12). Es wird vorgeschlagen, dass die Luftzuleitung (20) einen Verdichter (66) zur Druckerhöhung der Luft aufweist, die Abgasleitung (24) eine Turbine (74) aufweist, welche mechanisch mit dem Verdichter (66) gekoppelt ist.
Absstract of: US20260049408A1
An electrolysis system includes an electrolyzer stack and a contamination mitigation system. The electrolyzer stack includes an injection port fluidly connected with a cathode compartment of the electrolyzer stack. The contamination mitigation system is configured to remove ions from the electrolyzer stack to mitigate ion contamination in the electrolyzer stack. The contamination mitigation system includes a storage tank including formic acid therein and an injection line fluidly coupled between the storage tank and the injection port. The injection line is configured to direct the formic acid from the storage tank to the injection port for injection into the cathode compartment of the electrolyzer stack.
Absstract of: DE102024207773A1
Verfahren zum Betreiben einer elektrochemischen Anlage, die mehrere elektrochemische Stacks (11; 12; 13; 21; 22; 23; 31; 32; 33) umfasst, die elektrisch und/oder hydraulisch zusammengeschaltet sind. Dabei werden folgende Schritte durchgeführt:- Erfassen wenigstens eines Zustandsparameters jedes Stacks (11; 12; 13; 21; 22; 23; 31; 32; 33),- Bestimmen eines Degradationsgrads jedes Stacks (11; 12; 13; 21; 22; 23; 31; 32; 33) unter Verwendung der erfassten Zustandsparameter,- Ausgeben einer Empfehlung zum Austausch wenigstens eines Stacks (11; 12; 13; 21; 22; 23; 31; 32; 33) abhängig vom Degradationsgrad des Stacks, wobei die Empfehlung einen Degradationsgrad-Bereich umfasst, den der neu einzubauende Stack (11; 12; 13; 21; 22; 23; 31; 32; 33) aufweisen soll, und einen Zeitpunkt, zu dem der Austausch erfolgen sollte.
Absstract of: WO2026039285A1
Provided are compositions comprising a catalytic oxide material having the atomic formula of M1xM2yM3zM4tM5uOv; and/or a catalytic alloy material having the atomic formula of M1xM2yM3zM4tM5u, where M1, M2, M3, M4 and M5 are selected from Ru, Ni, W, Nb, Mn, Fe, Ti, Ag, V, Co, and Mo. Further provided is the use of the catalytic oxide materials and/or the catalytic alloy materials in oxygen evolution reactions.
Absstract of: WO2026036170A1
This disclosure relates to a replaceable photocatalytic cartridge for use in a reactor, and a method for producing the replaceable photocatalytic cartridge. The replaceable photocatalytic cartridge being suitable for use within a reactor that photocatalytically splits water, such as a PWS reactor. In one embodiment, the photocatalytic cartridge comprises a container that contains a substrate that is coated with photocatalytic particles, wherein, in use, the photocatalytic cartridge is configured to be removably inserted into a receiving portion of the reactor such that the coated substrate is adapted to participate in a photocatalytic reaction with H2O and solar radiation within the reactor.
Absstract of: WO2026039286A1
Provided is a catalytic mixed metal oxide material that includes Ir, O, and which has the atomic formula of M1xM2yM3zIrtOu, or M1xM2yM3z(IrM4)tOu where between one and three elements labeled as M1 through M3 is selected from the group consisting of Ru, Sr, Fe, Co, Mn, Ni, Sb, Nb, W, and Sn and M4 is selected from Ru and Sr. Further provided is the use of the catalytic mixed metal oxide material in oxygen evolution reactions.
Absstract of: JP2026027770A
【課題】燃焼器にＮＨ３と酸化剤を供給してＨ２とＮ２に分解し、精製してＨ２を効率よく製造することが可能な燃焼式アンモニア分解装置および燃焼式アンモニア分解方法を提供する。【解決手段】アンモニアおよび酸化剤が供給される燃焼器１１と、燃焼器１１が設置される燃焼炉１０と、燃焼炉１０に接続された触媒槽２０と、触媒槽２０に接続された吸着槽３１とを備え、燃焼炉１０においては、燃焼器１１にアンモニアおよび酸化剤を用いてアンモニア分解ガスを発生させ、触媒槽２０においては、燃焼炉１０から触媒槽２０に導入されたアンモニア分解ガスに含まれる未反応アンモニアを分解し、触媒槽２０が少なくとも２種類以上の触媒２１，２２により構成され、吸着槽３１においては、未反応アンモニアを吸着して回収する。【選択図】図１
Absstract of: JP2026027768A
【課題】燃焼器にＮＨ３と酸化剤を供給してＨ２とＮ２に分解し、精製してＨ２を効率よく製造することが可能な燃焼式アンモニア分解装置および燃焼式アンモニア分解方法を提供する。【解決手段】アンモニアおよび酸化剤が供給される燃焼器１１と、燃焼器１１が設置される燃焼炉１０と、燃焼炉１０に接続された触媒槽２０とを備え、燃焼炉１０においては、燃焼器１１にアンモニアおよび酸化剤を用いてアンモニア分解ガスを発生させ、触媒槽２０においては、燃焼炉１０から触媒槽２０に導入されたアンモニア分解ガスに含まれる残存アンモニアを分解し、触媒槽２０が少なくとも２種類以上の触媒２１，２２により構成される。【選択図】図１
Absstract of: JP2026027748A
【課題】燃焼器にＮＨ３と酸化剤を供給してＨ２とＮ２に分解し、精製してＨ２を効率よく製造することが可能な燃焼式アンモニア分解装置および燃焼式アンモニア分解方法を提供する。【解決手段】アンモニアおよび酸化剤が供給される燃焼器１１と、燃焼器１１が設置される燃焼炉１０と、燃焼炉１０に接続された触媒槽２０と、触媒槽２０に接続され、アンモニアと水分を凝縮して分離する凝縮槽３１と、凝縮槽３１に接続され、吸着剤が充填された吸着塔３３とを備え、燃焼炉１０においては、燃焼器１１にアンモニアおよび酸化剤を用いてアンモニア分解ガスを発生させ、触媒槽２０においては、燃焼炉１０から触媒槽２０に導入されたアンモニア分解ガスに含まれる未反応アンモニアを分解し、触媒槽２０が少なくとも２種類以上の触媒２１，２２により構成され、凝縮槽３１ではアンモニアを水に溶解して吸着塔３３に供給し、吸着塔３３では水とアンモニアに分離する。【選択図】図１
Absstract of: KR20260021885A
본 발명은 물을 전기분해하는 방식으로 그린수소 제조를 위한 전기촉매에 관한 것으로서, 양극 산소 발생반응과 음극 산소 발생반응의 두가지 방식으로 수행하는 P-doped MnO2 전기촉매에 관한 것이다. 구체적으로 본 발명은 PMnO2 전기촉매는 합리적인 비용으로 가능한 열수반응과 CVD공법으로 합성되는 것으로, 먼저 MnO2 는 열수반응으로 전처리 과정을 거친 후에 CVD 퍼니스에서 MnO2 에 인(P)을 도핑한다.
Absstract of: US20260048995A1
A method for manufacturing nano metal oxides and hydrogen includes the following steps: Step A, providing a first reactor, and placing a metal material, an alcohol compound, and a first catalyst in the first reactor and applying heating thereto for reacting to generate a metal alkoxide compound, while simultaneously generating a substantial amount of hydrogen; and Step B, providing a second reactor, and, after the metal material in the first reactor has fully reacted in Step A, transferring remaining solution in the first reactor into the second reactor, and adding a second catalyst and a controlled amount of water, and applying appropriate heating to generate nano metal oxide in powder form. As such, effects of significant reduction of production cost, enhancement of safety, widespread application of hydrogen fuel cells, extremely low carbon emissions, being defined as “green hydrogen”, and reduction of storage costs and risks can be achieved.
Absstract of: WO2026037094A1
The present invention belongs to the technical field of electrochemical catalysis. Disclosed are the preparation and use of a nickel-foam-supported layered cobalt tungsten oxide catalyst for efficient water decomposition. In the present invention, nickel foam (NF) is selected as a substrate, on which two cobalt oxides having different morphologies successively grow by means of electrochemical deposition, wherein ComCo3O4 serves as a first layer and can tightly wrap around the NF, thereby preventing the NF from anodic corrosion and dissolution in a harsh acidic medium; AcCo3O4 serves as a second layer, and nanosheet-shaped Co3O4 has good OER activity itself; in addition, the large specific surface area also provides more growth sites for a tungsten oxide; and finally, the tungsten oxide is electrically deposited on the AcCo3O4. WxOy/AcCo3O4/ComCo3O4/NF prepared by using the above method has a low overpotential and good stability.
Absstract of: AU2024285985A1
A method of producing a hydrogen stream and an oxygen stream and passing the hydrogen stream and the oxygen stream to a reverse water-gas shift reactor is described, the method comprising: providing a water stream to an electrolysis system configured to form: a hydrogen stream at a first pressure, and an oxygen stream at a second pressure; passing the hydrogen stream, a carbon dioxide stream, and the oxygen stream to the reverse water-gas shift reactor, wherein the first pressure is lower than the second pressure.
Absstract of: AU2024328340A1
Provided is an electrode exhibiting high oxygen generating electrode catalytic activity as compared with conventional electrodes using manganese-based oxide as an oxygen generating electrode catalyst.
Absstract of: AU2024327331A1
Electrolysis system, energy balancing system, method for balancing electrical power in an electrical network, computer program, controller and an electrical energy source The present invention pertains to an electrolysis system (1) and an energy balancing system (10) comprising a renewable electrical energy source (2) and the electrolysis system (1) that are electrically connected, wherein a production of electrical power of the renewable electrical energy source (2) is controlled by generator controller (5) and an absorption of electrical power by an electrolysis process (5) of the electrolysis system (3) is controlled by a main power controller (2) and an electrolysis controller (4). The electrolysis controller (4) is adapted to determine a capacity of the electrolysis system (3) of converting any additional electrical power and to transmit an indicator value (7) indicative of the electrolysis process (5) being capable or not capable of absorbing any additional electrical power to the main power controller (2) and/or to the generator controller (12) for adjusting the production and/or absorption of electrical power.
Absstract of: AU2024330634A1
The present invention refers to an electrolyser (1) for the production of hydrogen from an alkaline electrolyte. The electrolyser (1) comprises a first header (2) and a second header (3) between which a plurality of elementary cells (4) and a plurality of bipolar plates (5) are stacked. Each bipolar plate (5) separates two adjacent elementary cells. The electrolyser (1) further comprises a plurality of clamping elements (20) that mechanically connect said headers (2, 3). Each of the elementary cells (4) comprises a frame (6) defining a chamber (6A), having an anodic section and a cathodic section, in which an anodic electrode (7) and a cathodic electrode (8) are at least in part housed. Each of the elementary cells (4) further comprise a separator element (10) that separates the anodic section from the cathodic section. According to the invention, each of the frames (6) comprises first through holes (61) and each of the bipolar plates (5) comprises second through holes (51), wherein each of said first through holes (61) of one frame (6) is mutually aligned with a corresponding first through holes (61) of each of the another frames (6) and with one of said second through holes (51) of each bipolar plate (5), wherein each one of said clamping means (20) extends through said through holes (51, 61) mutually aligned.
Absstract of: TW202517835A
To provide iridium oxide suitable for proton exchange membrane-type water electrolysis, the iridium oxide having high initial activity and being excellent in stability during long-term operation. Provided is iridium oxide having a rutile structure, the iridium oxide being characterized by having: a crystallite size of 2.0 nm to 4.0 nm as calculated from a peak of a (110) plane of the rutile-structured iridium oxide determined by X-ray diffraction; and a BET specific surface area, measured by nitrogen adsorption measurement, of 70 m2/g to 120 m2/g.
Absstract of: US20260049404A1
Disclosed are a photoelectric cell with a silicon carbide electrode (4) for photocatalytic production of hydrogen, and a manufacturing method therefor. The cell has on one side of the silicon carbide electrode (4) a window (2) the incidence of light (5) and on the other side of the silicon carbide electrode (4) an aqueous electrolyte (10) and a counter electrode (6). On the side of the silicon carbide electrode (4) facing the window, the cell is electrolyte-free. The silicon carbide electrode (4) is preferably produced by coating a substrate (3) with silicon carbide (4).
Absstract of: US20260049370A1
The present invention concerns a metal material production configuration (1) and a method of direct reduction of a metal oxide material (5) holding a first thermal energy into a direct reduced metal material (16) by means of a metal material production configuration (1).The method comprises charging the metal oxide material (5), holding the first thermal energy, into a direct reduction facility (7); introducing a hydrogen, holding a second thermal energy, into the direct reduction facility (7).The invention involves reducing the metal oxide material (5) by using the first thermal energy of the metal oxide material (5) to heat or further heat the introduced hydrogen containing reducing agent (8) toward a required reaction temperature for providing a chemical reaction. A high-temperature exit gas (12) is removed from the direct reduction facility and fed to a high-temperature electrolysis unit (21) configured to produce the hydrogen.
Absstract of: AU2023460501A1
A composite separator and a preparation method therefor. The composite separator comprises a main film and an anti-contamination layer, which is arranged on one or both surfaces of the main film, wherein the anti-contamination layer comprises a first polymer, a charge agent and/or an anti-fouling agent. The composite separator can be applied to alkaline water electrolysis for hydrogen production and other electrolysis industries, and the anti-contamination layer of the composite separator can effectively prevent impurity species, especially metal ions fallen from a cathode catalyst, from being attached to the surface, which causes the sheet resistance to increase, thereby increasing the electrolytic energy consumption.
Absstract of: US20260049407A1
Provided is a carbon dioxide electrolysis device including: a carbon dioxide electrolysis cell including an anode, a cathode, an electrolyte, and a membrane disposed between the anode and the cathode. The carbon dioxide electrolysis device further includes; a supply line configured to supply gaseous carbon dioxide and water vapor to the cathode; and a discharge line configured to discharge, into the outside of the carbon dioxide electrolysis cell, the water vapor and a product produced by the electrolysis reaction of the gaseous carbon dioxide inside the carbon dioxide electrolysis cell, wherein the discharge line includes a condensation part configured to condense the water vapor discharged through the discharge line.
Absstract of: AU2026200708A1
Abstract A separator for alkaline electrolysis (1) comprising a porous support (100) and a porous layer (200) provided on the porous support, characterized in that a lateral Bubble Point of the separator, measured according to the method described in the description, is at least 0.2 bar. Abstract an b s t r a c t a n
Absstract of: WO2026038553A1
The present invention pertains to: an anion conductive film which includes a porous base material and an anion conductive polymer that is disposed, in addition to being provided inside of pores of the porous base material, on 70% or more of the area of at least one surface of the porous base material, and in which the anion conductive polymer has a constituent component (I) derived from a polyfunctional polymerizable monomer having a total of 2 or more of at least one atom selected from an oxygen atom, a sulfur atom, and a nitrogen atom at a structural part other than a polymerizable group, and the proportion of the constituent component (I) among all constituent components of the polymer is 50 mol% or more; a method for producing the anion conductive film; a membrane electrode assembly; a hydrogen production method; and a hydrogen production system.
Absstract of: TW202511539A
The present disclosure provides hydrogen carrier fluid (HCF) compositions, comprising a leanliquid organic hydrogen carrier (lean-LOHC) component comprising at least one cyclohexyl-based compound having at least one unsaturated bond, optionally in combination with one or more C4-12 alkyl alcohol, or a rich-liquid organic hydrogen carrier (rich-LOHC) component comprising at least one cyclohexyl-based compound, optionally in combination with a C4-7 ketone, a C4-6lactone or a mixture thereof; and an electrolyte component. Also provided is the use of these HCF compositions for storage and release of hydrogen, in an electrochemical reactor system.
Absstract of: AU2023443530A1
A method for forming a recombination layer includes, for example, an ionomer and a nanocrystal catalyst disposed in the ionomer. A method for forming the recombination layer may include, for example, providing an ionomer dispersion, providing a compound having a catalyst having a charge, adding the catalyst in the compound to the ionomer to form a mixture, reducing the catalyst in the compound to a metal catalyst in the ionomer, and forming the mixture with the metal catalyst into a recombination layer for a proton exchange membrane.
Absstract of: EP4696815A1
Provided is a method of manufacturing an anion exchange membrane water electrolysis system exhibiting improved durability and efficiency, along with excellent water electrolysis performance.
Absstract of: EP4696816A2
An electrolyzer stack is configured for high-speed manufacturing and assembly of a plurality of scalable electrolysis cells. Each cell comprises a plurality of water windows configured to maintain a pressure loss, temperature rise and/or oxygen outlet volume fraction below predetermined thresholds. Repeating components of the cells are configured based on a desired roll web width for production and a stack compression system is configured to enable a variable quantity and variable area of said repeating cells in a single stack. A high-speed manufacturing system is configured to produce scalable cells and assemble scalable stacks at rates in excess of 1,000 MW-class stacks per year.
Absstract of: CN120958174A
The present invention relates to an electrochemical electrode structure comprising a current collector and at least one electrode element wherein the at least one electrode element is a two-dimensionally extending electrically conductive element having an open structure. In this electrochemical electrode structure, the at least one electrode element has at least one edge with a crimped rim, at which the strip portion of the electrode element is crimped away. Furthermore, the invention relates to an electrochemical cell comprising a first electrode, a second electrode and a separator wherein the first electrode or the second electrode or both electrodes are such an electrochemical electrode structure, and to a method for retrofitting a limited-gap electrochemical cell into a zero-gap electrochemical cell using such an electrochemical electrode structure.
Absstract of: CN121013926A
The invention relates to an electrochemical electrode structure comprising at least one electrode element and a support element. Each electrode element is a two-dimensionally extending conductive element having an open structure and has a first edge portion. The support element has an elastic region extending along the surface in a main extension plane of the elastic region. The elastic region is adapted to push the at least one electrode member away from the support element in a direction at least substantially perpendicular to a main plane of extension of the elastic region. The support element has a first tongue-shaped region arranged at an edge of the support element. A first edge portion of the at least one electrode element is curved around a first tongue-shaped region of the support element, thereby attaching the at least one electrode element to the support element. Furthermore, the invention relates to an electrochemical cell and a bipolar electrode assembly, each of which comprises such an electrode element, to an electrochemical cell arrangement having a plurality of such bipolar electrode assemblies, and to a method for attaching an electrode element to a support element of such an electrochemical electrode structure.
Absstract of: WO2024214055A1
An electrolysis apparatus for the production of gaseous hydrogen and oxygen by water electrolysis is disclosed, with an electrolyzer (100) comprising a plurality of cells arranged next to each other to form a cell stack (116), wherein each cell includes an anode plate (122) and a cathode plate (124), and wherein the electrolyzer (100) further includes an anode end plate (118) and a cathode end plate (120) between which the cell stack (116) is clamped. The electrolyzer (100) has an active chamber (102) integrated therein, in which the electrolysis reaction of water contained in an electrolyte solution with which the electrolyzer (100) is fed takes place, a first liquid/gas phase separator (104) for separating oxygen gas from the electrolyte solution, and a second liquid/gas phase separator (106) for separating hydrogen gas from the electrolyte solution. The electrolyzer (100) also includes a plurality of sensors mounted on at least one of said anode and cathode end plates (118, 120) and configured to detect appropriate operating parameters of the first and second liquid/gas phase separator (104, 106).
Absstract of: AU2024249844A1
A method for thermal or thermochemical conversion of ammonia or methanol feedstocks into hydrogen (gas) in a related feedstock conversion facility (1000) is provided. The method comprises generating heated fluidic medium by at least one rotary apparatus (100), supplying a stream of thus generated heated fluidic medium into the feedstock conversion facility (1000), and operating said at least one rotary apparatus (100) and said feedstock conversion facility (1000) to carry out thermal or thermochemical conversion of the ammonia or methanol feedstocks into hydrogen at temperatures essentially equal to or exceeding about 500 degrees Celsius (°C). Facility (1000, 1000A) for production of hydrogen from ammonia or methanol feedstocks is further provided.
Absstract of: CN121537394A
本发明涉及一种自组装卟啉笼状化合物及其制备方法与应用，属于电催化水分解技术领域。一种自组装卟啉笼状化合物，其结构式如下所示。本发明通过对卟啉进行结构修饰，引入吸电子基团硝基（‑NO2），利用非贵金属锌（Zn）来调节催化剂的电子结构和表面活性位点，通过配位作用形成卟啉笼，并将其作为碱性析氧电催化剂进行应用。本发明所述自组装卟啉笼状化合物的分子结构清晰明确，制备过程中无需使用贵金属，大幅降低生产成本，对推动清洁能源技术发展具有重要意义。
Absstract of: CN121538660A
本发明公开了一种基于固体氧化物电解池电解重水制备高纯氘气的系统及方法。该系统包括重水加热装置、SOEC反应器、立式管式炉、氘气冷凝装置、外加电源和氘气存储罐。SOEC反应器位于立式管式炉中，固体氧化物电解池的两端连接外加电源。重水通过加热装置气化后直接输入到固体氧化物电解池的阴极，通过外加电压，将重水蒸汽电解为氘气，同时产生氧离子，氧离子通过电解质传输到阳极，在阳极氧化为氧气，实现重水电解制备高纯氘气的目的。该系统利用SOEC技术直接将重水蒸汽高温电解，经氘气干燥装置即可得到高纯氘气。该方法操作性强，安全风险低，易于规模化生产，解决了现有技术的重水除杂成本高，低温电解能耗高、效率低的问题。
Absstract of: CN121534738A
本发明属于光催化能源转化技术领域，具体为一种多孔蜂窝状CTF复合光催化剂及其制备方法和应用。本发明复合光催化剂由硫缺陷ZnIn2S4纳米片修饰处理得到；具体通过固相模板法构建吩噻嗪功能化三维有序大孔共价三嗪框架，并原位生长硫缺陷ZnIn2S4纳米片，形成三维有序大孔网络限域二维纳米片多级异质结构；得益于CTF‑PTZBN中吩噻嗪单元通过分子锚定作用诱导ZIS‑Sv定向生长，界面C‑S‑Zn/In键桥接形成稳定电子传输通道，随后骨架内建电场协同硫缺陷态构建电场驱动‑通道传输‑陷阱捕获三元载流子调控体系，实现光生电荷高效分离与定向迁移，成功减少光生载流子的复合。该二元复合材料表现出优秀的制氢以及苯乙烯选择性环氧化反应的性能。
Absstract of: CN121538682A
本发明属于催化能源转化技术领域，具体为一种低铱掺杂氧化钌基酸性析氧催化剂及其制备方法。本发明催化剂制备包括，将可溶性钌金属前驱体盐与其他金属前驱体盐溶解混合于乙二醇，利用乙二醇的还原性将金属离子还原为低价态；再加入碳载体作为模板，控制金属颗粒粒径；随后经溶剂热反应、热解氧化得到催化剂；其中钌为基础金属，掺入金属包含过度金属与铂族贵金属。本发明制备工艺兼顾催化效率与催化剂的合成成本，具有高度的拓展性，材料成分具有高度的可选择性。制得的催化剂利用多元素协同调控有效优化钌在水氧化反应中的反应活性与稳定性，为电解水阳极催化剂降本增效提供了新的选择，具有较好的应用前景。
Absstract of: CN121534641A
本申请涉及氨分解制氢技术领域，具体提出了一种分区声场调控的液态金属氨分解反应器及其使用方法。反应器包括反应容器、设置在反应容器内的液态金属、设于反应容器底部区域并与液态金属连通的进气口，以及设于反应容器上部并与外部连通的出气口；反应容器底板的外侧设置有第一声场单元，反应容器外壁沿液态金属高度方向的上部区域设置有第二声场单元；第一声场单元为高频声振单元，第二声场单元为低频声振单元。本申请的底部高频声场使氨气气泡在生成阶段发生界面重构与分裂，上部低频声场使其在上浮阶段获得扰动与路径延长，从而提升液态金属体系的界面刷新效率，使气液界面在整个反应过程中保持一致活化水平，提高氨分解反应的整体反应速率。
Absstract of: CN121535023A
本发明公开了一种铝灰综合回收利用的方法，包括以下步骤：S1、对铝灰进行预处理；S2、向预处理后的铝灰中加入氢氧化钠溶液和添加剂，进行制氢反应，得到氢气、氨气及含氟铝酸钠溶液；S3、向含氟铝酸钠溶液中通入二氧化碳，进行反应，得到冰晶石和滤液；S4、向滤液中加入生石灰，进行反应，得到碳酸钙和氢氧化钠，将碳酸钙经高温烧结得到CaO和二氧化碳。本发明使用危废铝灰与添加剂、氢氧化钠混合反应来制氢，制得的氢气转化率高。本发明使用危废铝灰来制备冰晶石的方法具有成本低廉、反应条件温和、氟利用率高、环保无污染等优点，且制得的冰晶石产品纯度高、性能优良。本发明实现了无害化处理、减量化排放以及经济效益的最大化统一。
Absstract of: CN121535538A
本发明公开了一种电解极板校正碾平装置，包括：底座；承载机构，用于承载极框，承载机构设于底座且包括多个承载组件；限位支撑机构，用于限位和支撑极框，限位支撑机构设于底座且包括沿周向间隔设置的多个限位支撑组件；下压机构，用于压着极框，下压机构设于底座；碾平机构，用于对极框焊缝进行碾平作业和平面度校正作业，碾平机构设于底座；上去毛刺机构，设于底座；下去毛刺机构，设于底座。本发明解决了极框加工和焊接过程中出现的变形、毛刺问题，通过将矫平、碾压、去毛刺集成于一体，可以将1.5‑2mm的焊高碾压到0.2‑0.5mm，使得焊缝内气孔被碾平，同时可以对极框的平面度进行校正，控制在1mm以内，极大地节约了人工成本和提高了产品质量。
Absstract of: CN121538677A
本发明公开了一种富含氧空位的Fe掺杂NiO电解水析氧催化剂及其制备方法与应用，包括：将镍基基底进行酸化预处理；将镍盐、铵盐和尿素溶解于溶剂中，加入预处理后的镍基基底进行水热反应，形成片状纳米阵列结构；将NiO前驱体进行退火处理，通入惰性气体以排空氧气，并在惰性气体保护下升温至退火温度后保温1~3h，在保温阶段开始时，切换为氩氢混合气保持10~30min，随后切换回惰性气体并持续至退火处理结束；将NiOx催化剂前体浸泡于铁源溶液中，经风干处理。本发明通过Fe掺杂与氧空位协同作用，在催化碱性环境中的电化学析氧反应中，表现出较好的催化活性和稳定性，具有很好的工业应用前景和商业价值。
Absstract of: CN121534788A
本发明公开了一种活化棉纤维素气凝胶负载Co‑B复合材料Co‑B/A‑CC，首先，采用溶剂交换法活化棉纤维素制得活化的棉纤维素A‑CC，然后，将A‑CC在LiCl/DMAc溶剂体系溶解得到活化棉纤维素溶液，再将CoSO4·7H2O置于活化棉纤维素溶液得到Co/A‑CC混合溶液，最后，将Co/A‑CC混合溶液注射到NaBH4水溶液中进行发泡即可得到。Co‑B/A‑CC的微观形貌为三维分层多孔框架结构，多级孔洞分布形态的尺寸涵盖微孔到宏孔；Co‑B纳米粒子作为活性物质。其制备方法包括以下步骤：1，棉纤维素A‑CC的活化；2，Co/A‑CC混合溶液的制备；3，Co‑B/A‑CC的制备。作为硼氢化钠水解制氢催化剂的应用时，在303K条件下最大产氢速率为3800‑4500mL·min‑1·g‑1，放氢量达到理论值的100％；8次回收/重复使用后，保留初始催化活性的71.7‑81.5％；活化能为Ea＝45.3‑48.9kJ·mol‑1。
Absstract of: CN121534754A
本发明涉及制氢技术领域，具体是公开一种氨分解制氢催化剂及其制备方法，所述氨分解制氢催化剂包括载体和负载在载体上的钌基活性组分，其中，所述载体为液相沉积法制备的生物炭/二氧化钛复合载体，所述钌基活性组分为钌金属。本发明通过优化复合载体组分之间的相互作用与活性金属的分散度，协同解决活性、稳定性、成本和钌活性组分的分散度等问题，显著提升氨分解制氢的效率。
Absstract of: CN121538670A
本发明公开了一种煤基碳纤维负载磷化钴自支撑催化剂的制备方法及其在电解水制氢中的应用，属于电解水催化剂技术领域。该催化剂由煤基碳纤维载体和负载于其上的磷化钴活性组分组成；磷化钴活性组分由钴基层状氢氧化物与ZIF‑67的复合前驱体经磷化处理衍生得到。具体方法为：以静电纺丝法制备的煤基碳纤维为载体，在含有六水合硝酸钴和聚乙烯吡咯烷酮的水溶液中采用电沉积法在其表面生长钴基层状氢氧化物，再通过浸渍法原位生长ZIF‑67，形成钴基层状氢氧化物与ZIF‑67复合的前驱体结构，最后经磷化处理得到煤基碳纤维负载磷化钴自支撑催化剂。该催化剂具有亲水性、电解水催化活性和稳定性。
Absstract of: CN121534743A
本发明公开了一种ZnCdS/NiO‑C异质结光催化剂的制备方法及应用，通过水热法合成ZCS粉末；以绿茶无水乙醇提取物为模板和碳源，通过热解法制备TOP‑Ni助催化剂；通过溶液自组装法将ZCS粉末与TOP‑Ni助催化剂复合，得到。本发明构建了高效的异质结界面，促进光生载流子的分离和转移，提高了光催化析氢的整体效率和可见光利用率，同时降低了光生电子‑空穴复合概率；利用绿茶无水乙醇提取物作为生物质模板诱导的助催化剂结构，提供了高比表面积和丰富的介孔通道，有利于增加活性位点并优化反应物/产物的传质过程，提升了表面反应动力学。
Absstract of: CN121538664A
本发明公开一种制氢行业碱液浓度自动测量与调节系统，涉及制氢技术领域，包括测量装置、回收装置、调节装置和PLC控制系统。测量装置通过碱液循环泵出口管道的减压阀、取样电磁阀连接密封耐压的测量容器，容器内的密度、温度、液位变送器实时传信至PLC；回收装置将测量容器内碱液经回收泵、电磁阀及止回阀抽回制氢系统分离器；调节装置通过补碱和补水装置精准补入浓碱与纯水，由PLC控制完成闭环调节。优点：该系统实现不停机带压测量，碱液回收再利用，自动化程度高且调节精准，提升生产效率、节能环保，保障制氢稳定。
Absstract of: CN121540853A
本发明公开了一种多通道电解槽产气质量测量系统及方法，包括电解槽巡检采样模块、气液处理模块、氮气供应模块、产气质量测量模块、回流模块；所述气液处理模块包括气液分离器，所述电解槽巡检采样模块包括若干电解槽，若干电解槽均通过采样管路连接到气液分离器的入口，气液分离器的底部出口通过出液管路连接到回流模块，所述氮气供应模块包括连接到气液分离器入口的氮气吹扫管路。本发明所述的多通道电解槽产气质量巡检测试方法，可实现在线切换不同电解槽产气质量巡检，可满足不同压力下的在线测试，提出了制氢系统尤其多台电解槽并机测试无法检测到单个电解槽的产气质量的解决方案。
Absstract of: CN121537570A
本发明提供了一种光催化水凝胶的制备方法，属于光催化技术领域，旨在解决传统制氢高能耗污染、现有光催化水凝胶纯度低及性能不稳定的问题。方法先分步制备CPDT‑1、CPDT‑2Br‑SO3Na、PCT‑SO3Na、Fluo‑2Br‑SO3Na、PFT‑SO3Na、PCBT‑SO3Na、PFBT‑SO3Na七种前驱体，过程通过氮气吹扫防氧化、丙酮沉淀‑重结晶‑索氏提取纯化；再将四种活性前驱体分别与丙烯酸、季戊四醇三烯丙基醚、(2,4,6‑三甲基苯甲酰基)二苯基氧化膦混合，经365nm紫外光照射聚合，制得四种光催化水凝胶。该方法条件温和、操作可控，产物纯度高、光催化性能稳定，适用于氢能制取与水污染治理。
Absstract of: CN121538683A
本发明涉及复合隔膜技术领域，具体涉及一种原位生成的碱性电解水隔膜及其制备方法。隔膜包括聚合物基体，所述聚合物基体由聚砜和/或聚醚砜构成；所述聚合物基体内部含有原位生成的层状双金属氢氧化物纳米颗粒；其制备方法包括首先将碱性前驱体加入有机极性溶剂中，将溶液pH值控制在8‑11，得到碱性极性溶液，再将聚砜或聚醚砜溶解于碱性极性溶液中，随后将金属盐前驱体加入到聚合物溶液中，使层状双金属氢氧化物在聚合物溶液中原位生成，搅拌使金属盐前驱体和聚合物搅拌混合，最终对聚合物溶液进行流延、相转化、后处理，随后固化成膜。本发明降低了隔膜的面电阻的同时还提升了复合隔膜的化学稳定性与长期运行稳定性，具有规模化生产的前景。
Absstract of: CN121534764A
本发明涉及光催化制氢技术领域，具体公开了一种磺酸化氮化碳纳米片光催化剂，其是通过将含氮前驱体进行热处理后，得到氮化碳前驱体；再将与硫酸溶液混匀后微波处理，固液分离后得到磺酸化氮化碳纳米片光催化剂；本发明制备的磺酸化氮化碳纳米片光催化剂，具有更高的比表面积，更窄的带隙能量以及更大的光响应范围，并且具有更高的光催化产H2活性，应用前景广泛。
Absstract of: CN121536888A
本发明涉及纳米材料技术领域，具体地，涉及一种二维闪锌矿结构Zn1‑yCdySe纳米片及其制备方法和应用。所述制备方法包括以下步骤：1）在保护气存在的条件下，将一价铜源溶液与CuSe纳米片溶液反应，制得立方相Cu2‑xSe纳米片；2）将步骤1）中制得的立方相Cu2‑xSe纳米片分散于非极性溶剂与磷系助剂的混合液中得前驱体溶液，将金属盐溶于极性溶剂得金属盐溶液，将前驱体溶液与金属盐溶液混合反应；其中，所述金属盐溶液含锌源与镉源；0≤x≤1；0.05≤y≤0.3。该制备方法原料易得，反应温和，条件可控，适用于工业化大批量生产；同时，制得的纳米片催化性能优异，稳定性强，在光催化水分解领域展现出优异的催化性能。
Absstract of: CN121538658A
本发明公开了一种氢气和有机酸的联产装置及方法，联产装置包括电解槽，电解槽内设置有析氢电极、氢氧化镍电极与有机物催化氧化电极，电解槽内加注有碱性电解液，析氢电极、氢氧化镍电极与有机物催化氧化电极底部均埋设于碱性电解液内，方法包含两个循环交替进行的阶段：产氢阶段，水在阴极析氢电极的电化学还原生成氢气，同时氢氧化电极被电化学氧化，生成NiOOH；有机物催化氧化阶段，有机醇在阳极有机物催化氧化电极发生电化学氧化生成相应的羧酸，以及NiOOH电化学还原生成Ni(OH)2。本发明的优点在于将具有增值效应的有机醇电氧化反应替代析氧反应，在阳极获得高价值的有机羧酸，进一步提升分步电解体系的经济效益。
Absstract of: CN121538675A
本申请属于电催化析氢技术领域，具体涉及一种金属型钴‑碳化钒异质结构复合材料及其制备方法和应用。该方法先将Zn(NO3)2·6H2O与Co(NO3)2·6H2O溶于甲醇中，然后加入2‑甲基咪唑甲醇溶液，搅拌均匀，继续加入含有MXene溶胶的甲醇/水混合液，搅拌反应，洗涤，干燥，得到前驱体，最后置于混合气氛中进行高温热解，冷却，得到所复合电催化材料。本发明采用MOF在二维V2C MXene表面原位组装，可有效控制前驱体的组成与结构，实现钴‑碳化钒异质结构在介孔碳片中的均匀分散，避免了传统金属纳米颗粒易团聚、分布不均等问题。此外，本发明合成工艺简便可控，无需复杂后处理或多步煅烧过程，适合规模化生产。
Absstract of: CN121538674A
本发明公开了一种低铂碳载量的镍钼多酸‑高分子基自支撑电催化剂的制备方法和应用，涉及电催化剂技术领域。电催化剂的制备方法，包括以下步骤：称取配制电解质溶液的各原料；包括：硫酸镍、钼酸铵、氯铂酸、硼砂、聚乙烯醇以及壳聚糖；用去离子水分别将原料混合均匀得到镍钼多酸溶液、硼砂溶液和PVA‑CS溶液，得到目标电解质溶液并用碳纸浸泡；冷冻干燥；碳化；以处理后的碳纸作为工作电极，饱和甘汞电极作为参比电极，石墨电极作为辅助电极；采用循环伏安电沉积法在碳纸上电沉积铂制得电催化剂。本发明制备的电催化剂，能够降低成本、改善碱性溶液和碱性海水的反应动力学、降低过电位以及提高稳定性，使碱性海水电解过程更加经济和高效。
Absstract of: CN121538667A
本发明公开了一种基于三电极体系的两步法电解水制氢的装置及其工艺，包括电源与两个以上串联的三电机电解池，单个三电机电解池包括电解液储罐，电解液储罐内设置有产氢催化电极、氢氧化镍电极与产氧催化电极，其中首个电解液储罐的氢氧化镍电极通过单刀双掷开关和电路分别与电源的正负极连通，其中一组电解液储罐的氢氧化镍电极与相邻另一组电解液储罐的产氢催化电极、产氧催化电极通过单刀双掷开关连通，尾部电解液储罐的产氢催化电极、产氧催化电极分别通过两组单刀双掷开关与电源的正负极连通。本发明的优点在于制氢纯度高、成本低，且易于串并联集成化和操作。
Absstract of: CN121534765A
本发明属于氨硼烷水解析氢技术领域，公开一种Co‑Co3B界面双活性位点修饰的木质炭催化剂及其制备方法和应用。所述催化剂为核壳结构并且以BNC为壳，以Co‑Co3B异质结构为核；所述催化剂具有双活性位点：Co纳米颗粒和Co3B纳米颗粒，并且Co和Co3B之间存在界面结构；其中，所述BNC为氮化硼改性木质炭且具有多孔结构。本发明创造性地设计了Co‑Co3B界面双活性位点修饰的木质炭催化剂，BNC壳的存在不仅避免了催化剂失活还限制了金属颗粒的团聚，Co3B的引入增加了活性位点，与此同时，Co和Co3B之间还存在界面结构，优化了催化剂的电子结构和配位环境，降低了反应物分子的解离能垒，提高了催化活性，该催化剂在NH3BH3水解反应性能测试中，具有优异的催化性能，其产氢速率达到了10492mL·min‑1·gCo‑1。
Absstract of: CN121538685A
本发明涉及材料测试分析技术领域，具体涉及一种水解制氢测试方法、设备及系统，通过获取若干工况下的电解槽工作电压，确定每个工况下的相对可控系数；根据每个工况下的相对可控系数和电解槽工作电压分析水解制氢反应的稳态变动趋势，确定每个工况下的运行稳态程度；通过每个工况下的运行稳态程度动态优化每个类型的运行参数值的调整步长，进而基于调整结果确定水解制氢测试对应的最优运行参数值组。本发明通过多工况数据收集全面了解系统行为，然后通过相对可控系数和运行稳态程度评估参数敏感性和系统稳定性，最后动态调整步长实现高效精确的寻优，其克服了固定步长方法的缺陷，能够快速、精确地确定最优运行参数值组。
Absstract of: CN121538668A
本发明公开了一种富含晶界的高熵金属硫化物多孔纳米管阵列催化剂及其制备方法和应用，属于催化剂领域。所述催化剂具有多孔纳米管阵列结构，包括一维多孔纳米管，所述多孔纳米管是由纳米粒子组装而成，若干所述多孔纳米管交错堆叠形成密集的多孔纳米管阵列；所述多孔纳米管尺寸为6~8μm，直径为40~80nm，且富含晶界微区结构。本发明的催化剂具有丰富的晶界结构，使得其能够提供更多高活性反应位点，同时高效催化析氧反应和硫氧化反应。
Absstract of: CN121538666A
本发明公开了一种用于可再生能源的AEM电解制氢系统及其动态控制方法，属于电解制氢技术领域，包括风光波动直连系统、动态响应控制中枢、AEM电解槽电堆以及气液分离纯化系统，通过“三阶变载策略”与“功率预测补偿”的结合，系统实现了冷启动时间小于30秒，功率在0‑100%范围内调节的响应时间小于5秒，完美适应可再生能源的秒级波动，显著提升了系统运行稳定性和寿命：优化的波浪形流场板和膜湿度闭环控制，共同确保了电堆内部反应环境的均匀和稳定，有效防止了变载工况下的膜电极损伤，显著延长了系统使用寿命，实现了与可再生能源的高效直连耦合。
Absstract of: CN121535202A
本发明属于纳米材料制备与催化领域，公开了一种具有高孔隙率的核壳结构金属气凝胶及其制备方法。所述金属气凝胶包括如下成分：还原剂，Ru盐前驱体，配体；所述金属气凝胶中，还原剂、Ru盐前驱体、配体的摩尔比为（2‑4）:1:1。本发明系统性调控反应物种类以及反应条件，通过一锅法合成具有高比表面积的单金属钌（Ru）气凝胶。随后通过调控马弗炉中的热处理时间和温度，精确调节核壳组分在气凝胶中的比例（Ru/RuO2），进而成功构建具有高孔隙率、Ru/RuO2核壳结构的金属气凝胶。实验结果表明，所制备的材料在全pH条件下均表现出优异的电催化析氢、析氧性能。本发明为设计具有核壳结构的金属气凝胶电催化剂提供了新策略。
Absstract of: CN121538681A
本发明涉及电催化技术领域，且公开了一种析氢纳米颗粒催化剂制备方法。该析氢纳米颗粒催化剂制备方法，将含氮杂环有机物与镥源在溶剂中溶解后，经稀硝酸调节pH，在反应釜中结晶后再经研磨，超声处理，于管式炉中高温处理后，制得析氢纳米颗粒催化剂。本发明制备得到的析氢纳米颗粒催化剂具有良好的催化效率，且成本低，市场前景广阔。
Absstract of: CN121541725A
本发明公开了一种集成电解水制氢与氢燃气轮机的能源系统，包括：富氧制备膜分离模块处理空气输出富氧气体，风光预测计算模块分析风速与光照数据生成电能产出曲线，电解功率分配模块据此向电解水制氢单元分配功率，富氧燃烧模拟模块计算燃烧场分布。耦合驱动控制模块采集氢气产量与燃烧效率数据，调节氢燃气轮机转速；参数监测反馈模块采集各模块参数并传输偏差值。同时，系统通过特定模型与算法优化富氧制备、功率分配、风光预测及燃烧模拟，风光预测计算、富氧燃烧模拟、耦合驱动控制模块还包含多个功能单元，运行时按六步启动各模块，该系统保障氢燃气轮机燃烧效率稳定，最终实现对高原缺氧环境下能源利用综合性能的显著提升。
Absstract of: CN121538669A
本发明属于高熵电极材料与电催化技术领域，具体涉及一种高熵磷硫化物自支撑电极材料及其制备方法和应用。所述电极材料包括导电基底和催化活性组分；所述催化活性组分为高熵磷硫化物，其由高熵普鲁士蓝类似物前驱体与磷源、硫源高温热处理制得；其中，所述高熵普鲁士蓝类似物前驱体的化学通式为M(Ⅱ)Fe(CN)6，M(Ⅱ)为Mn、Zn、Co、Fe、Ni、Cu中的至少三种；各M(Ⅱ)金属元素占全部M(Ⅱ)金属元素的摩尔百分比均为5%~35%。本发明高熵普鲁士蓝类似物前驱体与磷源、硫源高温热处理，将磷、硫元素成功引入高熵普鲁士蓝类似物骨架中。这种非金属元素掺杂能有效调节材料电子结构，显著降低析氧反应能垒，从而提升本征催化活性。
Absstract of: CN121538657A
本申请提供一种用于制备不同氘丰度标气的装置，包括：进料单元，提供天然水，天然水包括氘水和氢水；电解制氢单元，电解天然水生成标气，标气包括氢气和氘气；水氢液相催化交换单元，包括在第一方向上依次连通的第一进料口、催化交换柱和第二进料口，第一进料口用于将标气传输至催化交换柱，第二进料口用于将天然水传输至催化交换柱；催化交换柱中氘气和氢水发生氢同位素交换反应，得到沿第一方向上氘丰度依次减小的标气；催化交换柱包括沿第一方向依次设置的至少两个出料口，任意两个出料口输出的标气的氘丰度不同。本申请的装置通过液相催化交换联合电解的方法，可以同时获得不同氘丰度的标气。
Absstract of: CN121545608A
本申请公开了一种基于PEM电解水模块和EHC模块的耦合系统的水管理方法，涉及氢能技术领域。通过控制PEM电解水模块的最佳电流密度，调节进入EHC模块的水含量，使EHC模块始终运行在最佳水合状态，从而提高系统整体效率。该方法包括以下步骤：S1.建立PEM电解水模块的最佳电流密度与EHC模块的目标压比的关系模型JPEM‑r：S2.获取EHC模块的目标压比；S3.根据EHC模块的目标压比，通过JPEM‑r关系模型得到PEM电解水模块的最佳电流密度；S4.调节PEM电解水模块的实时电流密度至目标电流密度，实现对EHC系统的水管理。本申请同时公开了一种基于PEM电解水模块和EHC模块的耦合系统。本申请用于提升PEM电解水模块和EHC模块的耦合系统的性能。
Absstract of: CN121534744A
本发明公开了一种硫锌镉固溶体负载二硫化钼光催化剂及其制备方法和应用，属于光催化产氢技术领域。所述光催化剂包括Cd0.7Zn0.3S固溶体及负载在表面的MoS2；光催化剂中，MoS2的含量为5～40wt%。本发明通过采用一步水热法在Cd0.7Zn0.3S表面构筑MoS2二维助催化层，促使二者形成紧密的界面接触与肖特基结，利用这种强界面耦合作用增强相互作用力，加速光生电荷转移，使其既具备高活性又兼顾低成本，能更充分地利用太阳能驱动光催化反应，大幅提升太阳能转化效率，为高效、稳定的光催化产氢技术提供了切实可行的解决途径，具有广阔的应用前景。
Absstract of: JP2023012629A
To provide a water decomposition device capable of easily collecting generated hydrogen, the whole device being easily and compactly configured.SOLUTION: A water decomposition device (1) comprises: an electrolytic cell (5) in which an electrolytic solution (3) is housed; an oxygen generation electrode (9) which is a photoelectrode including an n-type semiconductor layer (7) immersed in the electrolytic solution (3) in the electrolytic cell (5); and a hydrogen generation electrode (13) including a hydrogen storage alloy layer (11) immersed in the electrolytic solution (3) in the electrolytic cell (5).SELECTED DRAWING: Figure 1
Absstract of: JP2026025239A
【課題】無機化合物を含む不溶化補助剤を必要とせず、かつ簡便な方法で行える水素の製造方法を提供すること。【解決手段】本開示にかかる水素の製造方法は、アルミニウム合金をアルカリ溶液に反応させて水素を製造する方法であって、アルカリ溶液は、界面活性剤を含み、界面活性剤は、アルミニウム合金に含まれる不純物を不溶化する不溶化補助剤である。これにより、無機化合物を含む不溶化補助剤を必要とせず、かつ簡便な方法で行える水素の製造方法を提供することができる。【選択図】図１
Absstract of: AU2024291792A1
The disclosure concerns a process of carbon oxides-free hydrogen production is disclosed. The process comprises the following steps: - heating a gas stream of a reacting compound including hydrogen atoms in absence of oxidizing agents, to thermally decompose the reacting compound into smaller product compounds, including hydrogen molecules, obtaining a stream of decomposition product compounds; - separating hydrogen molecules from other product compounds of the stream of decomposition product compounds; - reacting a portion of the stream of separated hydrogen molecules with a stream of an oxidizing agent, in particular oxygen or air, to obtain combustion product compounds, including steam and heat, in a stream of combustion product compounds; - providing heat obtained in the previous step to the step of heating the reacting compound; and wherein the process can comprise a step of - recovering energy from the stream of decomposition product compounds and/or from the stream of combustion product compounds. Additionally, a system of hydrogen production is also disclosed, the system being configured to operate according to the above process.
Absstract of: CN120569516A
The invention provides an electrolytic cell system (10). The electrolytic cell system comprises a heat storage unit (14) and an electrolytic cell (16). The heat storage unit (14) comprises at least one heat source feed inlet. The electrolytic cell (16) comprises at least one electrolytic cell cell (20), a steam inlet and at least one exhaust gas outlet. The exhaust outlet is connected to the heat source feed inlet to heat the heat storage unit (14). The heat storage unit (14) is configured to use its stored heat to generate steam for one of feeding into the steam inlet at a time and generating electricity or both feeding into the steam inlet at the same time and generating electricity. The invention also provides a system comprising an intermittent or variable power source (12) and an electrolytic cell system (10) as defined above. The intermittent or variable power source (12) may be configured to simultaneously or separately power the electrolysis cell (16) and heat the heat storage unit (14) via a heating element.
Absstract of: WO2026028790A1
Disclosed is a diaphragm for alkaline water electrolysis, which separates an anode chamber and a cathode chamber of an alkaline water electrolysis cell. This diaphragm for alkaline water electrolysis is provided with a polymer porous film which integrally has a sealing region that is sandwiched by cell constituent members in the alkaline water electrolysis cell, an edge region that is disposed on the outer peripheral side of the sealing region, and a separator region that is disposed on the inner peripheral side of the sealing region. The sealing region has a shape surrounding the separator region, and has a bulk part for preventing permeation of an electrolyte solution through the pores of the polymer porous film.
Absstract of: WO2026028789A1
This diaphragm for alkaline water electrolysis separates an anode chamber in which an anode of an alkaline water electrolysis tank is disposed and a cathode chamber in which a cathode is disposed, the diaphragm for alkaline water electrolysis comprising a polymer porous membrane integrally having a seal region, which is sandwiched by a tank-constituting member in the alkaline water electrolysis tank, and a separator region, which is disposed on the inner-peripheral side of the seal region. The separator region has an inter-electrode region that is smaller than the separator region and is sandwiched between the anode and the cathode, and a non-restraint region present between the seal region and the inter-electrode region. The polymer porous membrane has a frame-shaped bulk part that extends across the seal region, the non-restraint region, and the inter-electrode region.
Absstract of: WO2024252801A1
Provided is a hydrogen gas production system capable of producing, with a high recovery rate, a hydrogen gas having a deuterium D content ratio equal to or higher than that in raw material water. A hydrogen gas production system 100 according to the present invention comprises: a first tank 10 that accommodates raw material water including heavy water; an electrolysis device 30 that electrolyzes the raw material water to generate a hydrogen gas; a reservoir 50 that stores the hydrogen gas; a liquid feed device 20 that feeds the raw material water from the first tank 10 to the electrolysis device 30; and a gas feed device 40 that feeds the hydrogen gas generated in the electrolysis device 30 to the reservoir 50. In the system 100, the liquid feed device 20 is controlled so as to replenish the raw material water from the first tank 10 to the electrolysis device 30 as the raw material water remaining in the electrolysis device 30 decreases, the gas feed device 40 is controlled so as to continuously feed the hydrogen gas generated in the electrolysis device 30 to the reservoir 50 before, during, and after the replenishment, and the reservoir 50 stores the hydrogen gas generated in the electrolysis device 30 before, during, and after the replenishment.
Absstract of: US20260008042A1
The present disclosure is directed to a processing solution composition comprising a metal salt, an acid, a solvent, and a non-metal reductant. The present disclosure is also directed to a method of impregnating a porous material by covering or coating the porous material with a processing solution comprising a metal salt, an acid, a solvent, and a non-metal reductant.
Absstract of: FI20246009A1
The present disclosure relates to methods and arrangements for improving the operational flexibility of systems (200) comprising an electrolyzer (201) configured to produce hydrogen and one or more downstream hydrogen processing units (202a-d), wherein at least one of the one or more downstream hydrogen processing units has a hydrogen mass flow operating capacity more restricted than hydrogen mass flow operating capacity of the electrolyzer. The operational flexibility of the system is improved by feeding additional hydrogen from an additional hydrogen source (203) to the one or more downstream hydrogen processing units to compensate for the difference.
Absstract of: CN121518072A
本发明公开了一种聚苯硫醚隔膜‑聚四氟乙烯垫片粘接用环氧胶粘剂及其制备方法，属于碱性电解水制氢技术领域，一种聚苯硫醚隔膜‑聚四氟乙烯垫片用环氧胶粘剂，原料包括A组分和B两组分；其中，所述A组分包括环氧树脂、单官能团型苯环刚性结构稀释剂、硅烷交联改性纳米氧化锆粉末、聚苯硫醚微米级粉末、纳米碳化硅粉末、助剂；所述B组分为胺类固化剂。本发明制备的胶粘剂具有耐强碱、耐高温、对基材有高适配性和低VOC等多方面的优点。
Absstract of: CN121521680A
本发明涉及碱性电解水制氢技术领域，公开了一种多参数融合的气液分离效果在线评估方法，包括以下步骤：在气液分离器回流碱液管道上实时采集碱液质量分数浓度、流体温度、实际混合密度和质量流量信号；根据实时采集的碱液质量分数浓度和流体温度，动态计算当前工况下无气泡纯碱液的理论密度；计算所述理论密度与实际混合密度的绝对偏差；对质量流量信号进行实时噪声水平分析；根据所述绝对偏差与预设密度偏差阈值的比较结果；输出分离结果判断结果并执行相应报警或联锁控制。本发明通过在控制单元中实时根据在线测量的碱液质量分数浓度和温度动态计算无气泡纯碱液的理论密度，实现了在浓度实时变化工况下的可靠分离结果评估。
Absstract of: CN121519105A
本发明属于催化剂材料技术领域，具体涉及一种用于电解水制氢的双金属氮化物催化剂及其制备方法。所述方法为，将钒源、钛源溶于双氧水中，加入聚乙烯吡咯烷酮作为碳源，进行水热反应，得到前驱体，前驱体于氨气中进行氮化反应，即得所述双金属氮化物催化剂。所述催化剂为超薄二维多孔结构，可暴露丰富的催化活性位点，并且原位的碳基体复合提高了催化剂的稳定性。本发明可通过改变钒\钛比来调节双金属氮化物的电子结构，提高催化活性，从而表现出优异的电催化性能和良好的循环稳定性。本发明的制备方法操作简单、可控且适合规模化制备，在电解水产氢工业领域具有良好的应用前景。
Absstract of: CN121513907A
本申请属于催化剂制备技术领域，具体涉及一种ZnIn2S4/CoAl2O4复合催化剂及其制备方法和应用。该方法先将Co(NO3)3·6H2O、Al(NO3)2·9H2O、尿素和NH4F分散于水中，搅拌，转移至反应釜中，然后置于恒温烘箱中进行反应，离心，洗涤，干燥，煅烧，最后分散于甘油和水的混合溶液中，加入ZnCl2、In(NO3)·4H2O和TAA，搅拌直至形成均匀溶液后，置于油浴中加热，洗涤，干燥，即得。本发明成功制备了一种II型异质结光催化剂，并实现了高效的光催化析氢性能。其中，CAO与ZIS的结合不仅有效抑制了ZIS的团聚现象，还显著增加了材料的比表面积，提供了更多的活性位点。
Absstract of: CN121519104A
本申请属于电催化材料技术领域，公开了一种钌钴双金属掺杂的二硫化钼析氢电催化材料的制备方法，包括以下步骤：制备离子液体并用其对碳布进行亲水性改性；一锅法制备Co掺杂且负载在改性碳布上的MoS2；对Co‑MoS2/MCC在管式炉中高温退火得到富含Mo空位的催化剂；采用还原成键技术向Co‑MoS2/MCC中引入Ru，最终得到钴钌双掺杂的CoRu‑MoS2/MCC。本申请在碳布上进行离子液体亲水性改性，再负载Co掺杂的MoS2，经高温退火造取富含Mo空位的催化剂，通过还原成键技术使Ru元素掺杂其中，形成钴钌双掺杂的MoS2复合材料，将MoS2的层状结构优势与Co、Ru的高电催化活性结合起来，从而提升材料的析氢电催化性能。
Absstract of: CN121513760A
本公开属于电能转化技术领域，提供了一种二氧化碳甲烷化反应器。该反应器包括电解单元和化学催化单元，二者均设置于支撑体上；电解单元包括若干固体氧化物电解池单元，用于电解二氧化碳和水产生一氧化碳和氢气；化学催化单元用于接收一氧化碳和氢气以及电解产生的废热，以进行化学催化反应，从而制备甲烷；支撑体为NiO与氧化锆基电解质、造孔剂的混合物，氧化锆基电解质选自YSZ、ScYSZ中的至少一种。本公开的反应器使得化学催化反应在常温下即可进行，无需高压。其将电解和化学催化相结合，实现了一体化制备，有效降低了反应的能耗，将可再生能源转化为易于储存和运输的甲烷，转化率高。
Absstract of: CN121519091A
本发明公开一种双金属硫化物/三维多孔碳催化剂的制备方法和应用，涉及电解水催化剂技术领域，包括以下步骤:将三聚氰胺海绵进行清洗，得到清洁的三聚氰胺海绵;将金属盐1、金属盐2溶解于乙醇水溶液中，加入碱和苯胺单体，获得前驱体溶液;将所述清洁的三聚氰胺海绵完全浸泡在前驱体溶液中，经恒温水热反应后，依次进行洗涤、干燥，得到锚定双金属离子的三聚氰胺海绵;通入惰性气体保护，并进行高温硫化处理，得到嵌入双金属硫化物异质结构的三维多孔碳催化剂。所述催化剂包括均匀分散的双金属硫化物纳米颗粒和海绵状三维多孔碳载体，当应用于电催化分解水反应中，展现出优异的双功能催化活性和稳定性，具有广阔的应用前景。
Absstract of: CN121513937A
本发明公开了一种碳载钼基复合物和层状双金属氢氧化物共修饰的光催化剂及其制法，属于光催化分解水产氢技术领域。所述光催化剂中，碳载钼基复合物为薄壁大/介孔中空氮掺杂碳管HNC负载的Mo2C/MoO2复合物，记为Mo‑C/O，利用Mo‑C/O作为助催化剂，限制了Mo2C/MoO2复合物的尺寸；层状双金属氢氧化物为笼状NiCo‑LDH复合物，Mo2C/MoO2和NiCo‑LDH共修饰ZnCdS；ZnCdS与Mo2C/MoO2构成肖特基结，NiCo‑LDH、ZnCdS间构成II型异质结，Mo2C/MoO2、ZnCdS和NiCo‑LDH间形成级联电子传输通道。本发明双异质结构之间的协同作用不但能够扩宽光响应范围，还能进一步增强光生载流子的分离效率，提高电荷迁移的驱动力，推动电子的定向迁移，提高反应动力学，进一步提高光催化析氢性能。
Absstract of: JP2026024159A
【課題】多孔質構造を有するアルカリ水電解用隔膜において、き裂や打痕、摩耗などの軽度の欠陥が生じた場合に隔膜を補修する方法を提案する。【解決手段】高分子多孔質膜から成るアルカリ水電解用隔膜のガス遮断性を低下させる欠陥部分を溶着して当該欠陥部分の多孔質構造をバルク構造に変化させることにより、前記欠陥部分の前記ガス遮断性を回復させる。【選択図】図３
Absstract of: CN121513927A
本发明公开了碱金属与碳共掺杂的聚合物碳氮化物光催化材料及其制备方法与应用。涉及光催化材料领域。碱金属与碳共掺杂的聚合物碳氮化物光催化材料的结构中包含碱金属‑N键和C=C双键，其中碱金属为Li、Na或K。本发明通过碱金属与碳共掺杂策略，在聚合物碳氮化物（PCN）中同步引入C=C双键和碱金属‑N键（如Li-N键、Na-N键或K-N键），从根本上提升了材料的光催化性能。
Absstract of: CN121513943A
本发明涉及一种Co@BC‑PCN光热催化剂的制备方法和应用。本发明将三聚氰胺分散于一定浓度的磷酸水溶液中，然后进行水热处理使部分三聚氰胺水解为三聚氰酸，同时得到磷掺杂超分子前驱体；将此前驱体与废弃咖啡渣混合后，在氮气氛下焙烧得到由磷掺杂剥离的类石墨相氮化碳纳米片与咖啡渣生物炭组成的复合材料；进一步通过湿法浸渍‑原位还原制得Co@BC‑PCN光热催化剂。本发明通过三聚氰胺‑三聚氰酸热解自组装制备剥离的类石墨相氮化碳，结合磷掺杂和生物炭修饰来提高催化剂的比表面积，增强可见光吸收能力，减少光生载流子的复合，使得该催化剂在光热催化硼氢化钠水解产氢反应中有优异的催化性能。
Absstract of: CN121513761A
一种立式硅碳棒解水剂制氢装置，属于制氢技术领域，主要由料箱、解水剂料、供料管、电动阀、外管、反应管、落料板、硅碳棒、上盖、下盖、回收管、水箱、供水管、回收罐、蒸汽发生器、蒸汽管、电磁铁、压簧、氢气出口等组成，其特征是：料箱内装解水剂料，供料管上端接料箱中部串连两个电动阀下端接上盖进料口，反应管上端的上盖设有进料口和氢气出口内设落料板下端的下盖设有出料口和蒸汽进口，外管内置硅碳棒外设蒸汽发生器反应管从内通过。工作过程是：通电后，电磁铁振动，硅碳棒加热，解水剂料在重力和振动力作用下，由料箱内经电动阀进入反应管内，受热后与水蒸汽接触发生化学反应产生氢。氢气经氢气出口收集备用；剩余料经下盖出料口排出，由回收罐收集备用。优点有：1成本低于现有工业制氢；2无污染；3原料充足易得。
Absstract of: CN121517719A
本发明属于MOF材料领域，具体公开了一种用于光催化产生氢气的MOF材料及其制备方法和应用。所述MOF材料的分子式为Fe(anby)(SCN)2，晶体结构为有机配体与金属铁原子连接，桥联形成的规则二维网状结构；其中anby为9、10‑双(4‑吡啶基)蒽。本发明的配合物可在400nm的氙灯下，加入BIH、RuPS还有水和乙腈构建的光催化还原CO2体系中高效制氢。本发明促进了人工光合催化剂的发展，在新型能源应用和环境治理方面具有良好的发展前景。
Absstract of: CN121519102A
基于钨球限域与原位转化策略构筑的酸性电解水多金属复合电催化剂及其制备方法和应用，它涉及多金属复合电催化剂的制法及应用。它是要解决现有的多金属电催化剂在酸性电解水中的催化活性、稳定性和可扩展性差的技术问题。本发明的催化剂是由W多酸团簇构筑的粒径为200~600nm球体，RuO2纳米晶与MnCO3镶嵌在球体表面并均匀分布在球体内部。制法：一、制备W球基底；二、制备W‑Mn‑Ru前驱体；三、制备W‑MnCO3/RuO2电催化剂。它在酸性OER和HER中，在电流密度为100 mA cm‑2时的电位分别为1.489 V和‑0.145 V，可用于在绿色能源转化和储存技领域。
Absstract of: CN121513696A
一种中微量元素耦合富氢水的复合供应装置及供应方法，复合供应装置包括原料供应单元、二阶混合单元和控制单元；原料供应单元包括供液机构、供氢机构和提供中微量元素的供料机构；二阶混合单元包括混粉设备和三相混合设备；混粉设备用于将供氢机构提供的氢气与供料机构提供的粉料混合，得到气载粉体；三相混合设备设置在混粉设备下游，用于将供液机构提供的液体与所述气载粉体混合均匀，得到中微量元素耦合富氢水；控制单元，用于调控中微量元素耦合富氢水中的中微量元素和/或氢气含量。本发明的复合供应装置及供应方法在确保氢气持续稳定供应的基础上，还能够为植物供应生长所需的中微量元素，实现了氢肥的协同供应。
Absstract of: CN121519087A
本发明公开了一种基于时间序列分步化学转化的高性能雷尼镍网析氧电极，是通过分步化学浸渍法依序在基底雷尼镍网上先构筑界面稳定层，再生长催化功能层而获得；界面稳定层前驱液包含铈离子、镧离子、钇离子的至少一种；催化功能层前驱液包含主活性金属离子和协同调控元素离子，所述主活性金属离子包含镍离子和铁离子、或镍离子和亚铁离子，所述协同调控元素离子包含钴离子、锰离子、钒离子中的至少一种。本发明的雷尼镍网析氧电极具有界面稳定层与催化功能层紧密结合的梯度复合结构，在微观结构、宏观性能与长期稳定性方面都得到显著优化，且该制备工艺适用于工业大规模生产，为制约工业析氧电极发展的技术瓶颈提供了可行的解决方案。
Absstract of: CN121519107A
本发明为一种电催化析氢用非晶镍/结晶二氧化钼材料的制备方法和应用。该方法包括以下步骤：将Mo系杂多酸放置于管式炉下游，固体气氛源放于管式炉上游，然后向管式炉内通入混合气体，升温到400‑700℃热解还原0.5‑5 h，得到非晶镍/结晶二氧化钼材料；Mo系杂多酸具体为钼酸镍NiMoO4、6‑钼镍酸四铵或9‑钼镍酸六铵；固体气氛源为尿素、三聚氰胺、氯化铵或双氰胺。本发明制备简单，催化剂组分可调，析氢反应活性高。
Absstract of: JP2026024157A
【課題】アルカリ水電解用多孔質隔膜において膜の物理的強度を向上する。【解決手段】アルカリ水電解槽の陽極室と陰極室とを隔てるアルカリ水電解用隔膜は、アルカリ水電解槽において槽構成部材に挟み込まれるシール領域と、シール領域の内周側に配置されたセパレータ領域とを一体的に有する高分子多孔質膜を備える。セパレータ領域は、バルク構造の補強部を有する【選択図】図３
Absstract of: CN121519081A
本发明涉及一种再生烟气中CO2的转化方法及系统。本发明中将水送入电解水装置中进行电解，得到外部氧气和外部氢气；将所述外部氧气作为助燃气送入气体换热器与高温低压烟气换热后得到高温助燃气和低温低压烟气，将所述高温助燃气送入催化裂化再生器中进行再生烧焦，将所述低温低压烟气分为循环烟气和待转化烟气，将待转化烟气送入CO2电化学转化单元进行电化学转化反应，得到合成气和再生氧气。本发明充分提高了催化剂的再生效率、降低处理尾气中的CO2排放量，实现了处理装置的合理配置以及电解水副产氧气的高效利用，提高经济效益的同时达到了环境保护的目的。
Absstract of: CN121517656A
本发明公开了一种芘基共价有机框架材料的制备方法及其在光催化产氢反应中的应用，属于多相催化领域。本发明通过调控三苯胺数量，将具有不同含量的三苯胺单体整合到芘基共价有机框架（COF）骨架中，合成了一类新型芘基COFs光催化剂。本发明操作简单，反应条件温和，反应时间短，可重复性高，所得芘基COFs具有良好的光捕获能力和光生载流子分离特性，同时能够有效降低电子‑空穴复合，延长激发态寿命，从而提高光催化产氢的反应效率，具有潜在的应用前景。
Absstract of: CN121513942A
本发明公开了一种泡沫状磷掺杂氮化碳限域金属钴光热催化剂的制备方法和应用，属于光热催化材料制备与硼氢化物制氢领域。本发明制备方法通过盐酸与磷酸混酸溶液对三聚氰胺进行处理，再借助三聚氰胺‑三聚氰酸超分子前驱体自组装一步得到泡沫状磷掺杂类石墨相氮化碳，然后通过钴盐溶液浸渍，使Co2+在泡沫状氮化碳结构中限域吸附，最后通过NaBH4将其原位还原为金属钴，进而制得泡沫状磷掺杂类石墨相氮化碳限域钴光热催化剂。泡沫状结构有利于反应物分子的传输，限域钴为表面反应提供了更多的活性位点，磷掺杂后使氮化碳的禁带宽度降低，可增强可见光激发电子跃迁能力。
Absstract of: JP2026025107A
【課題】膜抵抗が充分に実用的なものでありながら、無機粒子の脱落を充分に抑制することができるアルカリ水電解用隔膜を提供する。【解決手段】多孔性支持体と、該多孔性支持体の片側又は両側の主面に設けられ、無機粒子及び有機樹脂を含む多孔膜と、を備えるアルカリ水電解用隔膜であって、更に、該多孔性支持体と該多孔膜とからなる本体層の片側又は両側の主面の少なくとも一部を覆う、中性又は塩基性の極性官能基を有する第１樹脂を含む被覆膜を備えることを特徴とするアルカリ水電解用隔膜。【選択図】なし
Absstract of: CN121513870A
本发明涉及一种结构化氨分解催化剂及其制备方法和反应器，该结构化氨分解催化剂包括载体，该载体由电阻丝制成，其表面由内向外依次设有氧化铝晶须层和催化层，其两端分别通过导线与电源装置电性相连。该结构化氨分解催化剂的制备方法包括：1）氨分解催化剂粉末制备；2）催化浆料制备；3）载体预处理；4）催化层涂敷。从而，可防止在弯折变形时发生催化层的脱落，提升了使用的灵活性与拓展应用场景。同时，还可以直接在载体上施加电流而进行原位焦耳加热，极大的减少传热损失，提高能量利用率，并可降低床层压降，进一步降低能耗。
Absstract of: KR20260021272A
본 발명은 전기 전도성 및 전기화학적 활성이 높으며, 동시에 내구성이 우수한 이종구조 촉매를 제조하는 방법, 이로부터 제조된 이종구조 촉매 및 이러한 이종구조 촉매를 포함하는 수전해 전극과 수전해 장치를 제공한다.
Absstract of: CN121519093A
本发明涉及一种高稳定电解水催化剂及其制备方法和应用，属于电催化技术领域。催化剂，包括碳布，碳布上负载有四元合金，四元合金包括摩尔比为（1.2~1.8）：（1.2~1.8）：（0.7~0.9）：（0.1~0.3）的镍、铁、镓和铂。碳布能够改善活性组分的分散性，并提升电子传导效率。四元合金的协同掺杂能够提升本征活性，抑制活性位点的团聚与溶解。在碱性环境下具备优秀的电化学性能，兼具高催化活性与长循环稳定性。
Absstract of: CN121513905A
本发明涉及催化领域，特别是涉及一种整体式氨分解制氢催化剂及其制备方法和用途，所述整体式氨分解制氢催化剂包括蜂窝载体和活性涂层，所述活性涂层涂覆于所述蜂窝载体上；所述活性涂层包含钌、碱金属、复合金属氧化物以及碳材料；所述复合金属氧化物包覆碳材料；所述钌和碱金属负载在复合金属氧化物包覆的碳材料上。本发明所提供的整体式氨分解制氢催化剂具有较高的低温氨分解活性、较大的产氢速率和优异的长周期稳定性，且该催化剂技术制备工艺简单，能耗低，适合大规模生产应用。
Absstract of: CN121513930A
本公开提供一种碳自掺杂氮缺陷催化剂的制备方法及碳自掺杂氮缺陷催化剂、制氢方法以及还原方法，涉及光催化剂技术领域，包括：将尿素和尿酸混合，经搅拌和煅烧处理后，得到碳自掺杂的g‑C3N4基底材料；对所述碳自掺杂的g‑C3N4基底材料在惰性气氛下进行煅烧，制得碳自掺杂氮缺陷催化剂。本公开能够提高碳自掺杂氮缺陷催化剂的光催化性能。
Absstract of: CN121519106A
本发明提供了一种用于电解水制氢的氧化钼‑碳化钼复合催化剂及其制备方法，所述制备方法主要包括以下步骤：1）将钼酸铵和尿素经水热反应得到氧化钼纳米带；2）对氧化钼纳米带进行低温一次热碳化得到前驱体MoOx/C纳米带；3）将前驱体MoOx/C纳米带进行二次微波碳化和还原热处理即制备氧化钼‑碳化钼复合催化剂。本发明所制备的氧化钼‑碳化钼复合催化剂显著增加了催化活性位点，有效调节电子结构，进而展现卓越的电解水析氢性能。该方法具有工艺简单、成本低廉、可控性好等优势，适合大规模推广应用，在电解水制氢领域具备广阔的应用前景。
Absstract of: CN121519891A
本发明涉及超基性岩石天然氢开发技术领域，是一种基于流速控制的水力激活超基性岩石自发断裂生氢方法，其利用水力压裂激活超基性岩层的水岩反应，通过水岩反应产生的矿物挤压和放热效应，使超基性岩层自发断裂，形成多级裂缝网络；之后注入含镍离子流体，所述含镍离子流体沿裂缝流动后进一步发生水岩反应，生成氢气。本发明提出的基于流速控制的水力激活超基性岩石自发断裂生氢方法，其通过精确控制含镍离子流体的注入速度，实现反应速率、裂缝扩展与氢气生成的动态平衡，流体注入速度与反应速率匹配，实现自发可控生氢。
Absstract of: CN121513919A
本发明公开了一种用于可见光光解水制氢的MXene修饰TiO2/Cd0.3Zn0.7S异质结复合光催化剂的制备方法。其包括通过氢氟酸蚀刻MAX相（Ti3AlC2）制备Ti3C2 MXene，利用水热氧化技术将TiO2纳米片原位生长并锚定在Ti3C2 MXene表面形成Ti3C2@TiO2复合材料，再通过油浴加热负载Cd0.3Zn0.7S纳米颗粒制得最终复合光催化剂。该制备方法简单、条件温和、成本低廉，无需添加表面活性剂或模板剂。所制备的复合光催化剂具有优异的光催化分解水产氢性能，析氢速率高达48.92 mmol·g‑1·h‑1，较纯Cd0.3Zn0.7S与Ti3C2@TiO2分别提升43.67倍与99.83倍，且循环稳定性良好，4次循环后活性保持95%以上，在420 nm处表观量子效率达74.6%。本发明为高效光催化体系提供了新思路，适用于太阳能转化及环境净化领域。
Absstract of: CN121521676A
本发明公开了一种用于电催化析氢材料的检测装置，本发明涉及电化学检测技术领域，包括底板，以及固定在其顶部的电解池，所述电解池的外表面固定安装有电源，所述电源的正负极均连接有导线，所述导线的端部固定安装有电极棒安装件，所述电解池顶部的两侧可拆卸安装有密封盖，所述电解池两侧分别安装有氧气收集机构与检测机构。该用于电催化析氢材料的检测装置，通过密封盖防止空气进入电解池影响实验结果，检测机构通过激光位移传感器实时检测位移件位置变化，进而计算产氢量和产氢速率，电极棒安装件稳固安装电极棒，提高了电极安装的稳定性，还能适应不同直径的电极棒，减少了接触电阻带来的测量误差，确保了实验数据的准确性。
Absstract of: CN121513890A
本发明涉及氨分解制氢的技术领域，公开了一种基于二氧化铈反相催化剂进行氨分解制氢的方法，包括如下步骤：（1）将镍前驱体、钴前驱体、铁前驱体混合作为金属前驱体，将金属前驱体和二氧化铈粉末混合，得到A溶液；配制碱溶液作为B溶液；（2）将B溶液滴加至A溶液的同时进行搅拌，滴加完成后，经离心、干燥、有氧焙烧，得到反相催化剂；（3）将氨气与反相催化剂接触反应，温度为400~500℃，压力为0.01~1MPa，得到氢气。本发明通过多元金属组分设计、界面协同构筑与制备工艺优化，形成二氧化铈小颗粒锚定和高度分散在Ni‑Co‑Fe多元金属氧化物载体的反相催化剂，从而实现高效催化活性。
Absstract of: CN121513879A
本发明公开了一种碳基氨裂解制氢催化剂的制备方法及其应用，步骤如下：对纳米洋葱碳载体进行酸洗和钾盐溶液浸渍活化两级预处理，得到活化载体K‑CNO'；采用均匀沉积沉淀法，将钴盐、镁盐、尿素与所述活化载体在水热条件下反应，经沉淀、过滤、洗涤、干燥和煅烧，制得最终催化剂CoxMg/K‑CNO'。本发明通过酸洗在CNOs表面引入含氧官能团，通过钾活化提升载体碱性和比表面积，并与活性组分Co及助剂MgO产生强协同效应，实现了Co基活性中心的高分散、强稳定性和丰富的表面碱性位点。该催化剂在氨分解制氢反应中表现出优异的低温催化活性和稳定性，在特定条件下氨转化率高达99.6%，且可在500℃下长期稳定运行。
Absstract of: CN121519089A
本发明涉及光电催化材料领域，提供了一种铁电型异质结电极及其制备方法和在光电催化领域的应用，旨在双S型异质结中引入额外的内置电场，提高光生电荷的分离和利用效率。所述制备方法包括：制备TiO2纳米管阵列，在TiO2表面生成铁电体SrTiO3，形成SrTiO3/TiO2异质结，进一步在异质结表面生成g‑C3N4，形成g‑C3N4/SrTiO3/TiO2双S型异质结。所述电极将铁电体SrTiO3分布到TiO2和g‑C3N4之间，形成双S型三元异质结电极，铁电体的内置极化电场与异质结界面电场之间形成“多场耦合”效应，提高了光生电荷的分离和转移效率，同时保持了较强的氧化还原能力，有效提高光电催化性能。
Absstract of: CN121519103A
本发明涉及一种氮硫共掺杂碳包覆CoS2析氧电催化材料及其制备方法，属于电催化材料技术领域，包括以下步骤：取钴盐溶液与钴氰化钾溶液反应制得钴氰化钴前驱体；在惰性气氛下，对钴氰化钴前驱体进行高温热处理，得到中间产物；在惰性气氛下，以硫为硫源，对中间产物进行硫化处理，制得氮硫共掺杂碳包覆CoS2析氧电催化材料。本发明方法采用廉价的过渡金属化合物作为原料，具有制备工艺简单，容易控制，便于规模化生产等优势。采用本发明方法制得的氮硫共掺杂碳包覆CoS2析氧电催化材料在碱性条件下具有优异的析氧催化活性，且化学稳定性好。
Absstract of: WO2025028379A1
Provided is an ammonia decomposition catalyst that has a high ammonia decomposition activity even at a low reaction temperature and a low reaction pressure, and has stable catalyst characteristics even when repeatedly used in reactions after being exposed to water or the atmosphere. A barium nitride according to the present invention is represented by general formula (1). (1): BaAN2-x (In general formula (1), A is at least one type of element selected from the group consisting of Si, Fe, Ni, Mo, and Zr, and x represents a numerical value represented by 0≤x<2.0.)
Absstract of: CN121519080A
本发明涉及电解水制氢技术领域，公开了一种电解水制氢用装置及方法，包括电解槽，电解槽包括槽体，槽体的两侧均安装有循环出液口和循环进液口；电解液循环单元，电解液循环单元包括安装在槽体上的净化罐；净化罐的内部设置有拦截机构，拦截机构包括设置于净化罐内部的旋转轴，旋转轴的两侧安装有拦截盘，且拦截盘之间设置有多组拦截板。本发明通过设置拦截盘和拦截板的旋转拦截机构，实现了对电解液中较大颗粒杂质的初步高效拦截过滤，并且在拦截机构转动时，可以利用流入的电解液对拦截板进行反冲洗，实现了连续、高效的自清洁功能，有效防止了过滤孔的堵塞，显著提高了电解水制氢装置的整体运行效率和稳定性。
Absstract of: CN121519090A
本发明提供了一种稀土掺杂的雷尼镍电极、制备方法及应用，步骤包括：对导电基材进行粗化处理；采用喷涂工艺，将复合粉末喷涂并沉积于所述导电基材上，得涂层导电基材；将所述涂层导电基材置于碱性溶液中进行活化处理，得所述稀土掺杂的雷尼镍电极；其中，所述复合粉末包括镍粉、铝粉、稀土组分的粉末。稀土组分的引入能够改善镍的电子结构，提高电极的导电性和催化活性，降低析氢过电位。喷涂工艺使不同粒径的粉末形成一层一层堆叠起来的致密且均匀的涂层，增强了耐腐蚀性和机械强度。本发明无需复杂的设备和高昂的成本，且稀土元素添加量较少，适合大规模工业化生产。
Absstract of: CN121519079A
本申请实施例公开一种基于三维正弦型曲线流道的流场板及质子交换膜水电解槽，流场板包括至少一条流道；流道包括若干依次排列且相互平行的流道段，相邻的流道段之间通过圆弧段交替首尾平滑连接；流道段由第一正弦型曲线流道和第二正弦型曲线流道交汇形成，在平行于流场表面的方向，第一正弦型曲线流道沿第一正弦型曲线延伸；在垂直于流场表面的方向，第二正弦型曲线流道沿第二正弦型曲线延伸，并在第一正弦型曲线流道的底面交汇形成间隔分布的凹坑，在第一正弦型曲线流道的侧面交汇形成间隔分布的侧洞。本申请实施例能够提升流体传输效率、优化气泡脱附与排放、改善温度均匀性，大幅度提升反应物的供给、产物的排出和系统的稳定性。
Absstract of: CN121519099A
本发明公开了一种P掺杂Bi4Si3O12‑Bi12SiO20异质结光电催化材料及其制备方法和应用，制备方法包括：取Bi(NO3)3·5H2O加入乙二醇中搅拌至溶解得到溶液A；取九水硅酸钠加入去离子水中，搅拌至溶解得到溶液B；将溶液B逐滴加入溶液A，搅拌至均匀得到混合溶液，加入磷酸钠，搅拌至均匀得到溶液C；调节溶液C的pH值至3~14，向溶液中加入CTAB，搅拌至均匀后填充进反应釜内衬中，置于水热烘箱中100~220 °C反应6~48 h，烘箱内温度降至室温后取出反应釜冷却，经过离心、洗涤、干燥得到粉体，即P掺杂Bi4Si3O12‑Bi12SiO20异质结光电催化材料，P掺杂Bi4Si3O12‑Bi12SiO20异质结的构建促使界面电荷转移，改善光生电荷分离，提高了长寿命电荷的产率，从而抑制了电荷重组，大幅度提高了光电催化水裂解的效率。
Absstract of: CN121519075A
本发明公开了一种制氢模块用新型结构的多功能水箱，包括箱体主体，箱体主体顶端设置有上盖组件，箱体主体底部设置有若干个辅助固定组件，箱体主体内设置有防浪组件，箱体主体前侧设置有呈上下布局的第一传感器、第二传感器、第三传感器，上盖组件上设置有鼓风机，上盖组件上位于鼓风机侧部设置有回水接口组件。本技术方案的水箱，结构设计巧妙，实用性较强，水箱强度高，且密封性好，具有一定的耐压能力，不会漏水漏气，具有水位监控，温度和电导率监控，自动进水和排水，以及气体排出等功能，运用此水箱结构，保证了制氢模块的正常工作，箱体内部的防浪板结构，有效防止了回水对内部水体的干扰，有效保证了制氢过程的稳定性和效率。
Absstract of: JP2026024144A
【課題】水電解効率を向上させる。【解決手段】水電解スタックは、互いに電気的に直列に接続され、水電解を行うアニオン交換膜型の複数のセルと、複数のセルに電解液を供給するための第１マニホールドと、複数のセルから電解液を排出するための第２マニホールドと、を有するマニホールド構造体と、を備え、第１マニホールドおよび第２マニホールドのうちの一方または両方の内壁面は、電解液よりも高い絶縁性を有する。【選択図】図１
Absstract of: CN121519108A
本发明公开了一种核壳结构二氧化钛载铱/氧化铱催化剂及其制备方法与应用，先将二氧化钛与前驱体水溶液混合经过水热反应得到水热产物，水热产物经洗涤、干燥后，再于特定气氛下煅烧后得到表面改性的二氧化钛载体；再将铱源与表面改性的二氧化钛载体于含有还原性物质的溶剂中，于避氧条件下加热反应后得到铱/改性二氧化钛中间体；将铱/改性二氧化钛中间体经酸洗和分段控温热处理得到二氧化钛载铱/氧化铱催化剂。本发明显著增强铱活性组分的分散度及其与载体的相互作用，制备工艺简单、成本可控、催化活性高且稳定性优异。
Absstract of: CN121516935A
本发明公开了一种低过电势高稳定性的NiFeCu氢氧化物的制备方法，属于电解水催化材料制备技术领域。所述低过电势高稳定性的NiFeCu氢氧化物的制备方法，包括如下步骤：将镍盐、铁盐、铜盐、聚乙烯吡咯烷酮和水混合，得到混合液；以导电基底作为阴极和阳极，在所述混合液中进行电沉积，形成所述NiFeCu氢氧化物。本发明采用“一锅”的电沉积法，在反应体系中加入PVP作为结构导向剂，将所有原料混合均匀后，通过控制电沉积的反应时间和电流密度，调节反应速率，从而控制催化材料的形貌，制备低过电势高稳定性的NiFeCu氢氧化物，适用于电解水制氢领域。
Absstract of: CN116439627A
The invention is applicable to the technical field of cleaning appliances, and discloses an integrated water tank capable of cleaning and separating, which comprises a clean water tank, a sewage tank and a water tank cover, the clean water tank contains and outputs clean water to a cleaning tool, the top wall is provided with a water outlet, and the inner wall of the bottom wall is connected with a water pumping joint; the sewage tank collects sewage output by the cleaning tool, the peripheral wall and the bottom wall of the sewage tank are closed, and only the top is open; the water tank cover can cover the clear water tank and the sewage tank from the top at the same time, a clear water outlet and a sewage inlet are formed in the water tank cover, the water tank cover is directly or indirectly connected with a water pumping pipe which is arranged in the clear water tank and communicated with the clear water outlet, and the other end of the water pumping pipe is communicated with a water pumping connector. The clean water tank and the sewage tank of the water tank can be detached independently, and the whole water tank is convenient to assemble and maintain; the clear water outlet and the sewage inlet arranged on the water tank cover are far away from the water tank electricity-taking interface, so that short circuit of the electricity-taking interface caused by water tank leakage can be avoided.
Absstract of: AU2024222987A1
A system, comprising: an electrolyzer having a plurality of electrolysis cells arranged in a cell stack, wherein the electrolysis cells are electrically connected in series and grouped into two or more cell groups, each cell group having an electrical contact at either end; an electrical circuit having one or more switches, each switch coupled between the electrical contacts of a respective one of the cell groups and configured to selectively disconnect the cell group from the cell stack by electrically bypassing the cell group via a lower resistance path, to thereby vary the number of active electrolysis cells in the cell stack; and a controller configured to determine the number of active electrolysis cells based on a variable amount of direct current (DC) electrical energy supplied to the cell stack by an electrical energy source, and to control the one or more switches based on the determination.
Absstract of: MX2025009259A
A hydrogen generation system includes: a direct current (DC) power supply providing a driver signal, a reactive circuit coupled to the power supply and configured to generate a pulse drive signal from the driver signal, at least one reaction chamber coupled to the reactive circuit and receiving the pulse drive signal wherein the chamber is configured to generate hydrogen from feedstock material utilizing the pulse drive signal, a gas analyzer coupled to the at least one reaction chamber and configured to detect the generated hydrogen, and a control unit coupled to the reactive circuit and to the gas analyzer and configured to control the reactive circuit based on the detected hydrogen. The reaction chamber includes a plurality of positively charged elements and a plurality of negatively charged elements. The elements are composed of non-dis similar metallic material.
Absstract of: WO2025012277A1
The invention relates to a method for the preparation of H2 from NH3. NH3 is introduced into a fixed-bed reactor at a gas temperature in the range from 550 to 850°C, in which fixed-bed reactor NH3 is decomposed on an NH3 decomposition catalyst partly into H2 and N2. The gas mixture obtained in this manner is discharged from the fixed-bed reactor at a gas temperature in the range from 300 to 700°C, is heated to a temperature in the range from 550 to 700°C and is then introduced into a tubular reactor in which further NH3 is decomposed on a nickel-based NH3 decomposition catalyst into H2 and N2. The gas mixture obtained in this manner is discharged from the tubular reactor at a gas temperature in the range from 550 to 750°C.
Absstract of: US20260043150A1
A photocatalytic cell of the disclosure is installed in an inclined manner at an angle of 5° or more and 45° or less with respect to a horizontal plane. The photocatalytic cell includes: a translucent member; an electrolytic solution; a photocatalytic sheet including photocatalytic particles; an injection port through which the electrolytic solution is injected into an inside of the photocatalytic cell; a discharge port through which the electrolytic solution is discharged to an outside of the photocatalytic cell; and an exhaust port through which gas inside the photocatalytic cell is discharged, at least a part of the photocatalytic sheet is immersed in the electrolytic solution, a position of the exhaust port is higher than a position of the injection port, a gap between a surface of the translucent member and a surface of the photocatalytic sheet is 5 mm or more and 50 mm or less in width, and the injection port and the discharge port allow the electrolytic solution to flow from an upper part toward a lower part in the gap between the translucent member and the photocatalytic sheet.
Absstract of: AU2026200498A1
A power generator is described that provides at least one of electrical and thermal power comprising (i) at least one reaction cell for reactions involving atomic hydrogen hydrogen products identifiable by unique analytical and spectroscopic signatures, (ii) a molten metal injection system comprising at least one pump such as an electromagnetic pump 5 that provides a molten metal stream to the reaction cell and at least one reservoir that receives the molten metal stream, and (iii) an ignition system comprising an electrical power source that provides low-voltage, high-current electrical energy to the at least one steam of molten metal to ignite a plasma to initiate rapid kinetics of the reaction and an energy gain. In some embodiments, the power generator may comprise: (v) a source of H2 and O2 supplied to the 10 plasma, (vi) a molten metal recovery system, and (vii) a power converter capable of (a) converting the high-power light output from a blackbody radiator of the cell into electricity using concentrator thermophotovoltaic cells or (b) converting the energetic plasma into electricity using a magnetohydrodynamic converter. an a n
Absstract of: DE102024122674A1
Es wird ein Verfahren zur Herstellung von Kohlenstoffmonoxid beschrieben. Das Verfahren umfasst die elektrochemische Desorption von Kohlenstoffdioxid und Sauerstoff aus einer ein Metallhydrogencarbonat enthaltenden Lösung und das Bilden von Kohlenstoffmonoxid aus dem Kohlenstoffdioxid. Das erzeugte Kohlenstoffmonoxid kann in einem Verfahren zur Bildung von Syngas verwendet werden.
Absstract of: WO2026034402A1
This electrolytic cell comprises an element provided with: an anode chamber provided with an anode; a cathode chamber provided with a cathode; a conductive partition wall provided between the anode chamber and the cathode chamber; and an outer frame that borders the conductive partition wall. The electrolytic cell is stacked with a gasket and a diaphragm interposed between cells. Sealing of an electrolytic solution is achieved by applying surface pressure between the gasket and the diaphragm and between the gasket and the outer frame. The contact ratio between the diaphragm and a first electrode, which is at least one of the anode and the cathode, is 15%-60%, and a region in which the local stress between the diaphragm and the first electrode is 0.1 MPa or more is 5% or less.
Absstract of: WO2026035442A1
A system includes at least one electrochemical device including a proton exchange membrane situated between an anode and a cathode. An oxygen separator is fluidly connected to an inlet to the anode and a hydrogen separator is fluidly connected to an outlet from the cathode. A separator tank fluidly interconnects an outlet from the hydrogen separator to an inlet to the oxygen separator.
Absstract of: US20260043153A1
Systems and methods are provided for water electrolysis. The system includes an electrolyte material configured for the exchange of anions, a first electrode including a nickel-cobalt-phosphorus-based compound, and a second electrode, wherein the first electrode and the second electrode are configured to exchange the anions through the electrolyte material.
Absstract of: WO2025012271A1
The invention relates to a plant for preparing H2 by catalytically decomposing NH3. The plant according to the invention can be operated in a start-up mode in order to heat apparatuses of the plant to an increased operating temperature using a heat-transfer medium, e.g. following interruption of a continuous operation of the plant due to maintenance work. After heating to the operating temperature, the plant according to the invention can be operated in a production mode for continuous production of H2. The invention also relates to a method for starting up a plant for preparing H2 by catalytically decomposing NH3.
Absstract of: WO2026033405A1
A process and a related plant for decomposing ammonia and synthesizing a hydrogen-rich process stream by a direct cooling performed downstream of the decomposition reactor with a stream consists of, or essentially consists of, nitrogen and/or ammonia, where the decomposition of ammonia takes place in a thermal or autothermal chemical reactor.
Absstract of: DE102024207534A1
Die Erfindung betrifft ein Fluidtransportbauteil (1) für einen Elektrolyseur, mit einer Gasdiffusionslage (2), die ein Metall aufweist und porös ist, und einer porösen Transportschicht (3), die ein Kohlenstoffpapier und/oder einen Kohlenstoffvlies aufweist, dadurch gekennzeichnet, dass die Gasdiffusionslage (2) stoffschlüssig und elektrisch leitfähig mit der porösen Transportschicht (3) verbunden ist. Zudem betrifft die Erfindung ein Verfahren zum Herstellen eines Fluidtransportbauteils (1) für einen Elektrolyseur, mit den Schritten: a) Bereitstellen einer Gasdiffusionslage (2), die ein Metall aufweist und porös ist; b) Bereitstellen einer porösen Transportschicht (3), die ein Kohlenstoffpapier und/oder einen Kohlenstoffvlies aufweist; und c) stoffschlüssiges und elektrisch leitfähiges Verbinden der Gasdiffusionslage (2) mit der porösen Transportschicht (3).
Absstract of: WO2026033095A1
The invention relates to the use of doped 3C-SiC microparticles for the solar-driven splitting of molecules.
Absstract of: WO2026033097A1
The invention relates to the use of 3C-SiC microparticles having a carbon surface, for the solar-driven splitting of molecules.
Absstract of: WO2026034682A1
Disclosed are an ammonia dehydrogenation catalyst with which hydrogen can be produced from ammonia in a high yield, and a method for producing hydrogen. The disclosed ammonia dehydrogenation catalyst includes nickel (Ni), lanthanide elements (M), and aluminum (Al).
Absstract of: US20260047229A1
Techniques for water electrolysis employing: a glass substrate layer; a transparent conductive oxide (TCO) layer including TCO electrical disconnects formed in the TCO; a photovoltaic (PV) layer including PV electrical disconnects formed in the PV layer, portions of the PV layer extending into the TCO electrical disconnects; a metal back contact (MBC) layer including MBC electrical disconnects formed in the MBC layer, portions of the MBC layer extending into the PV electrical disconnects; an insulating layer including insulating voids formed in the insulating layer to expose anode and cathode portions of the MBC layer, portions of the insulating layer extending into the MBC electrical disconnects; a metal conductor layer adjacent the insulating layer and including a metal conductor extending into insulating voids to form metal conductors electrically coupled to the exposed anode and cathode portions; catalyst coatings on the metal conductors electrically coupled to the anode and cathode portions.
Absstract of: JP2026022181A
【課題】本開示は、新たな直接空気電解法を提供することを目的とし、好ましくは、強塩基性や強酸性の溶液、及び、貴金属電極触媒を用いる必要がない、直接空気電解法を提供することを目的とする。【解決手段】アノードと、前記アノードに対向するカソードと、細孔を有する基材と、吸水性化合物と、を備え、前記基材は、前記アノードと前記カソードとの間に配置され、前記吸水性化合物は、前記基材の細孔中に存在する、電解セル。【選択図】なし
Absstract of: US20260043158A1
An electrolytic cell and an anion-exchange conductive hollow fiber tube matrix thereof are disclosed. The anion-exchange conductive hollow fiber tube matrix includes a plurality of conductive hollow fiber tubes arranged adjacent to each other in a matrix. The conductive hollow fiber tubes each have a diffusion surface and two opposite ends defined as an inlet and an outlet. An anode and a cathode of the electrolytic cell are disposed adjacent to the diffusion surface. Water in an electrolysis tank flows into the conductive hollow fiber tubes from the inlet, water molecules enter the cathode from the diffusion surface and decompose to produce hydrogen and hydroxide ions, the hydrogen is discharged from the cathode, the hydroxide ions return to the conductive hollow fiber tubes from the diffusion surface and then enter the anode from the diffusion surface to produce oxygen, the oxygen is discharged from a surface of the anode.
Absstract of: AU2024396946A1
According to exemplary embodiments of the present invention, a hydrogen production system is provided. The present invention comprises: a hydrogen generation unit configured to receive reduced iron from a reduced iron generation unit configured to generate reduced iron by reducing powdered iron ore in a reducing gas atmosphere, and to generate hydrogen from ammonia by bringing the reduced iron into contact with the ammonia; and a regeneration unit configured to receive the reduced iron from the hydrogen generation unit and to regenerate the reduced iron by reducing the reduced iron in a hydrogen gas atmosphere. According to other exemplary embodiments of the present invention, a method for producing hydrogen is provided.
Absstract of: AU2024398260A1
Provided according to exemplary embodiments of the present invention is an ammonia decomposition system capable of minimizing the generation of iron nitride, which is a by-product.
Absstract of: AU2024357053A1
Provided is a control device including: a step in which a current command value regarding current to be applied to an electrolytic stack is determined; and a step in which pure-water adjustment amount command values for adjusting the pressure or/and flow rate of water to be supplied to the electrolytic stack are determined on the basis of the current command value. The control device further includes a step A in which, when the current command value is changed from a first current command value (current command value c1) to a second current command value (current command value c2), which is a different value, and the pure-water adjustment amount command value is changed from a first pure-water adjustment amount command value (pure-water adjustment amount command value w1) to a second pure-water adjustment amount command value (pure-water adjustment amount command value w2), which is a different value, measured values of the pressure or/and flow rate are caused to reach the second pure-water adjustment amount command value from the first pure-water adjustment amount command value before a measured value of current applied from a power converter to the electrolytic stack reaches the second current command value from the first current command value.
Absstract of: WO2025051333A1
The invention relates to a plate-like element (10) of a cell stack (2) of an electrochemical system (1), having a first plate side (26), a second plate side (27), a plurality of openings (13, 21, 22, 23, 23') and a first structure (14) for forming a flow field for coolant and several further structures (14') for forming distributors for operating media on the first plate side (26). The structure (14) comprises a coolant conducting structure (15, 16) through which a first coolant path (15) and a second coolant path (16) arranged mirror-symmetrically thereto are formed, each of which have, starting from one of the openings (21), an elongate inflow portion (17), a centre portion (18) which starts from the inflow portion (17), fans out and describes at least one meandering bend (19), and an elongate outflow portion (20) which adjoins the centre potion (18) and is narrower than the centre portion (18). A longitudinal axis (30) of the inflow portion (17) of the first coolant path (15) matches a longitudinal axis (30) of the outflow portion (20) of the second coolant path (16), and a longitudinal axis (30') of the inflow portion (17) of the second coolant path (16) matches a longitudinal axis (30') of the outflow portion (20) of the first coolant path (15). The invention also relates to a cell stack (2) comprising a plurality of such plate-like elements (10) which are parallel to one another.
Absstract of: AU2024300028A1
The compression arrangement comprises a hydrogen compressor and a return circuit having an inlet, which is fluidly coupled with the discharge side of the centrifugal compressor, and an outlet, which is fluidly coupled with the suction side of the centrifugal compressor. A head-loss control valve is positioned in the return circuit. The head-loss control valve is adapted to generate a controlled head loss in the return circuit when the compressor operates at a flowrate below the surge control line.
Absstract of: WO2026033985A1
Provided is a hydrogen production system (40) which comprises: an exhaust heat reception unit (41) that receives exhaust heat generated by an external exhaust heat source (11); a water vapor generation unit (42) that generates water vapor by heating water by means of the exhaust heat received by the exhaust heat reception unit (41); a cell stack (43) that electrolyzes the water vapor generated by the water vapor generation unit (42) so as to generate hydrogen; and a replenishment unit (44) that, when the amount of exhaust heat is insufficient with respect to the amount necessary for generating the required amount of water vapor, replenishes water, water vapor, or the water vapor generation unit (42) with heat, or replenishes the cell stack (43) with water vapor from an external water vapor supply source (95).
Absstract of: US20260043154A1
An alkaline water electrolysis apparatus includes: a separation membrane including a first main surface and a second main surface opposite to the first main surface; a first electrode including a third main surface and a fourth main surface opposite to the third main surface, the third main surface being provided to face the first main surface of the separation membrane; and a first bipolar plate including a fifth main surface, the fifth main surface being provided in contact with the fourth main surface of the first electrode, wherein the first electrode consists of a first metal porous body having a three-dimensional mesh structure.
Absstract of: US20260043149A1
The following disclosure relates to an electrochemical cell or system that is configured to operate with forced water flow on the cathode side of the cell and forced water flow on the anode side of the cell. The system may include at least one electrochemical cell having a cathode, an anode, and a membrane separating the cathode and the anode. The system has the forced water flow on the cathode side of the cell to be principally in opposite direction of the forced water flow on the anode side of the cell.
Absstract of: US20260043160A1
This control device is for a hydrogen production facility and comprises: a plurality of electrolysis cells for electrolyzing water or steam; and a plurality of rectifiers for supplying DC power to each of the plurality of electrolysis cells. The control device is provided with: a degradation coefficient acquisition unit configured to acquire a plurality of degradation coefficients indicating the degrees of deterioration of the respective electrolysis cells, an individual necessary current calculation unit configured to calculate, on the basis of a total necessary current corresponding to a hydrogen generation volume required for the hydrogen production facility and the plurality of degradation coefficients, a plurality of individual necessary currents indicating necessary currents required for the electrolysis cells; and a control unit configured to control the respective rectifiers on the basis of the plurality of individual necessary currents.
Absstract of: US20260043159A1
A solid oxide electrolyzer cell (SOEC) includes a solid oxide electrolyte, a fuel-side electrode disposed on a fuel side of the electrolyte, and an air-side electrode disposed on an air side of the electrolyte. The air-side electrode includes a barrier layer disposed on the air side of the electrolyte and including a first doped ceria material, and a functional layer disposed on the barrier layer and including an electrically conductive material and a second doped ceria material.
Absstract of: US20260043151A1
A method of operating an electrolyzer system includes providing steam to a stack of electrolyzer cells through a steam filter, electrolyzing the steam into a hydrogen product in the stack of electrolyzer cells, receiving data from one or more sensors indicating that the filter requires cleaning or replacement, and cleaning or replacing the steam filter in response to the receiving the data from the one or more sensors indicating that the steam filter requires cleaning or replacement.
Absstract of: EP4692422A1
The present invention relates to an electrode for the electrolysis of, in particular, alkaline water solutions. The electrode has a 3D-knitted metal structure in the form of a net. The metal is predominantly made of nickel. The invention also relates to a corresponding electrolysis cell and its use for the electrolysis of alkaline aqueous solutions.
Absstract of: CN120981610A
The invention relates to a membrane electrode assembly (1) for a water electrolyser, comprising an anode (2), a cathode (3) and a hydrocarbon membrane (4) located between the anode (2) and the cathode (3), further comprising a first gas recombination layer (5) arranged between the anode (2) and the hydrocarbon membrane (4), in which at least one adhesion layer (6) is arranged between the gas recombination layer (5) and the hydrocarbon membrane (4), wherein the adhesive layer (6) comprises at least one ceramic material (7) and a proton-conducting polymer (8).
Absstract of: EP4691968A1
A process (100) for producing a hydrogen product (20) from a feedstock stream (10), the process (100) comprising the following steps:- performing a combustion of a fuel gas (S11) to bring a heat input to the process (100) thereby generating a flue gas (52),- pre-heating the ammonia stream (S3), said preheating being realized in a first heat exchanger (4) arranged to heat the ammonia stream by heat exchange with the flue gas,- sending the pre-heated ammonia stream (12) to a vaporizer (5) and vaporizing (S4) said pre-heated ammonia stream,- sending the vaporized ammonia (14) from said vaporizer (5) as said feedstock stream (S6) and/or sending the vaporized ammonia from said vaporizer as said fuel to said combustion (S11).
Absstract of: EP4691967A1
Die Erfindung betrifft ein Katalysatorsystem zur Spaltung von Ammoniak in Wasserstoff und Stickstoff, umfassend mindestens Rohr mit einer zentral durch das innere des Rohrs verlaufenden Achse, wobei in dem Rohr mindestens zwei koaxial angeordnete Bereiche, in Form von einem ersten Bereich entlang der zentralen Achse und mindestens einem den ersten Bereich umgebenden weiteren Bereich, ausgebildet sind, und wobei der erste Bereich ein erstes Katalysatormaterial und der mindestens eine weitere Bereich mindestens ein weiteres Katalysatormaterial enthält, dadurch gekennzeichnet, dass a) das erste Katalysatormaterial mindestens ein Metall aufweist, das ausgewählt ist aus der Gruppe bestehend aus Edelmetallen und Nicht-Edelmetalle, und b) das mindestens eine weitere Katalysatormaterial mindestens ein Nicht-Edelmetall aufweist. Das erste und das mindestens eine weitere Katalysatormaterial sind verschieden.
Absstract of: CN121359262A
The invention relates to a method for producing an assembly for an electrochemical cell, wherein the assembly comprises at least the following structural components: a first plate (10; 10 '), a proton exchange membrane (42), a first electrode (31) arranged between the first plate and the proton exchange membrane, and a first gas diffusion layer (21) arranged between the first plate and the first electrode, having the following steps: A) providing a substrate having only a part of the structural component, in particular the first plate and/or the first gas diffusion layer; b) assembling the components, wherein the assembling comprises the step of adding residual structural components; or the following steps: a) providing a substrate distinct from the structural component; b) assembling the components, wherein the assembling comprises adding structural components; wherein the bezel is formed by applying one or more layers of a molding material (70-72) to the provided substrate, the strength of the molding material being increased after said application, at least one layer of the molding material forming the bezel or at least one surrounding section of the bezel being applied prior to step B) or b). The invention also relates to an electrochemical cell, in particular a fuel cell or an electrolytic cell, to a cell stack having a cell of this type, and to a method and a facility for producing an assembly for a cell or a cell stack of this type.
Absstract of: CN121039917A
Systems and methods are provided for an electrolysis plant interconnecting a renewable energy source (22) and a power grid (20). The system includes a power source (22) and an electrolysis plant (30) including electrolysis equipment (32) connected to the power source (22) to energize the electrolysis equipment to respective operating conditions. The control system (40) is connected to the power source (22) and the power grid (20). Upon detection of a power failure or otherwise insufficient power supply of the renewable power source, the control system is configured to bring the electrolysis device to a corresponding standby condition. The electrolysis device is connected to an electrical grid to energize the electrolysis device to a standby condition. Optionally, a backup power supply (26) is connected to the control system such that the backup power supply is configured to energize the control system upon detecting that the renewable power source and the grid are simultaneously powered off or are simultaneously otherwise insufficient in power supply.
Absstract of: WO2024208792A1
A methanol plant and a process for the production of methanol is provided. A hydrogen recovery section receives off-gas stream from the methanol synthesis section and outputs a hydrogen-rich stream, which is recycled upstream the methanol synthesis section.
Absstract of: CN120936755A
The present application relates to an electrolytic cell battery cell having a battery layer (1314) comprising an electrochemically active battery region (1350), the battery layer (1314) having a first side (1315a) and a second side (1315b). The cell defines a first fluid flow region (1360) for delivering fuel to the first side (1315a) of the cell layer (1314) and a second fluid flow region (1365) for discharging fluid from the second side (1315b) of the cell layer (1314). A cross-sectional area of the second fluid flow region (1365) is less than a cross-sectional area of the first fluid flow region (1360).
Absstract of: EP4693486A1
The invention relates to an electrocatalytic electrode comprising a coating film on an electrically conductive base substrate that includes a non-stoichiometric mixed oxide dispersed in the film, including a mixture of iron and vanadium, in a metal-organic matrix, the organic part of which includes the mixed oxide dispersed therein. The electrocatalytic electrode can be used for the production of molecular hydrogen.The invention also relates to a method for producing the electrocatalytic electrode and the use of the electrocatalytic electrode for the improved production of molecular hydrogen by means of at least water hydrolysis, alkaline water electrolysis, alkaline electrolysis via ion exchange, as a selective electrode and as an electrode for the oxidation of organic compounds in an aqueous solution.
Absstract of: CN120981421A
A hydrogen production system comprising: a first electrode having an electrocatalyst, a second electrode having an electron donor material comprising a plurality of active sites, the second electrode configured to release electrons from the active sites within a predetermined working potential range below a working potential triggering an oxygen evolution reaction; a first electrolyte in contact with the first and second electrodes, the electrolyte being a source of hydrogen protons; and a power source configured to provide the system with the predetermined operating potential range to release electrons from the second electrode and transfer electrons to the first electrode such that hydrogen protons combine with the electrons to produce hydrogen gas.
Absstract of: EP4692424A1
It is an object of the present invention to provide a steam electrolysis device and a steam electrolysis method, which have high energy efficiency. The present invention relates to: a steam electrolysis device, comprising an anode electrode chamber, a cathode electrode chamber, and an ion conductor disposed between these electrode chambers, wherein steam in an amount more than twice the amount of hydrogen generated is supplied to at least one selected from the anode electrode chamber and the cathode electrode chamber, and 50% or less of the supplied steam is electrolyzed; and a steam electrolysis method using the steam electrolysis device.
Absstract of: CN120898031A
The present invention relates to a composition comprising from about 90% to about 99.99% by weight of one or more non-crosslinked fluorinated sulfonyl fluoride polymers and from about 0.01% to about 10% by weight of one or more noble metal catalysts, based on the total weight of the composition, wherein the one or more noble metal catalysts are uniformly distributed throughout the one or more non-crosslinked fluorinated sulfonyl fluoride polymers. Such compositions may be formed as cation exchange precursors, for example by extrusion, and, after treatment, form cation exchange membranes. The resulting films and membranes have a noble metal catalyst uniformly distributed throughout the layer of the catalyst-containing polymer.
Absstract of: CN120882906A
A porous transport layer for an electrolytic cell or for a fuel cell, the porous transport layer comprising: a first non-woven layer having metal fibers, the first non-woven layer having metal fibers being arranged for contacting a proton exchange membrane, where the first non-woven layer having metal fibers comprises metal fibers having a first equivalent diameter, and the second non-woven layer having metal fibers having a second equivalent diameter; wherein the first non-woven layer having metal fibers has a first surface roughness and a first porosity,-a second non-woven layer having metal fibers wherein the second non-woven layer having metal fibers comprises metal fibers having a second equivalent diameter, wherein the second nonwoven layer having metal fibers has a second surface roughness and a second porosity wherein the first surface has a material ratio of less than 5% material at a height of 5 mu m and greater than 70% material at a depth of-5 mu m, the first equivalent diameter is less than the second equivalent diameter, the first surface roughness is at least 20% less than the second surface roughness, and the second surface roughness is at least 20% less than the second surface roughness. The first porosity is at least 10% less than the second porosity, such as in the range of 20% to 120%, for example, the first porosity is at least 10% less than the second porosity, such as in the range of 10% to 50%, and wherein the first nonwoven layer is metallurgically bo
Absstract of: EP4691992A1
Provided is a method for producing a highly active oxygen carrier at low cost, and a method for producing hydrogen and an apparatus for producing hydrogen using the highly active oxygen carrier.SolutionA method for producing an oxygen carrier of the present invention is a method for producing an oxygen carrier formed of an activated iron titanate containing an alkali titanate and an iron oxide by calcining a mixture of iron titanate particles and an alkali component. The mixture of the iron titanate particles and the alkali component is prepared by any of: physically mixing the iron titanate particles and an alkaline compound; and spraying an aqueous solution of the alkaline compound to the iron titanate particles or impregnating the iron titanate particles with the aqueous solution of the alkaline compound and then drying the sprayed or impregnated iron titanate particles.
Absstract of: CN120752767A
A method of making a catalyst coated ion conducting membrane for use in an electrochemical device, such as a fuel cell or an electrolytic cell, is provided. The method includes providing an electrolyte membrane having a first face and a second face, the first face disposed opposite the second face. A first catalyst ink is deposited onto the first side of the electrolyte membrane to form a first wet catalyst layer, and then dried to form a first catalyst layer on the first surface of the electrolyte membrane. The first catalyst ink comprises a first ionically conductive polymer; a first electrocatalyst; and a first dispersant. Subsequently, a second catalyst ink is deposited onto a second face of the electrolyte membrane to form a second wet catalyst layer and dried to form a second catalyst layer. The second catalyst ink comprises a second ionically conductive polymer; a second electrocatalyst; and a second dispersant. Before depositing the second catalyst ink onto the second side of the electrolyte membrane, the first catalyst layer is subjected to a temperature A of 130 DEG C or more, and the second catalyst layer is subjected to a temperature B lower than the temperature A.
Absstract of: CN120958177A
The invention relates to a membrane electrode assembly (1) having an anode (2), a cathode (3) and a hydrocarbon membrane (4) between the anode (2) and the cathode (3). The membrane electrode assembly (1) further comprises a protective layer (5) arranged between the anode (2) and the hydrocarbon membrane (4) and-or between the cathode (3) and the hydrocarbon membrane (4), where the protective layer (5) comprises at least one ceramic material (6) and a fluorine-containing ionomer (7), where the ceramic material (6) is dispersed in the fluorine-containing ionomer (7).
Absstract of: CN121013925A
The invention relates to a membrane electrode assembly (1) for a water electrolyser, comprising an anode (2), a cathode (3) and a hydrocarbon membrane (4) located between the anode (2) and the cathode (3), further comprising a first gas recombination layer (5) arranged between the anode (2) and the hydrocarbon membrane (4) wherein the first gas recombination layer (5) comprises a noble metal (6), a ceramic material (7) and a proton conducting polymer (8), and wherein the volume fraction of the proton-conducting polymer (8) is 24 to 84 vol%, in particular 35 to 75 vol%, and in particular 46 to 65 vol%, based on the total volume of the gas recombination layer (5).
Absstract of: CN121013921A
The invention provides a porous transport layer for an electrolytic cell or for a fuel cell, the porous transport layer comprising:-a first non-woven layer having metal fibres, the first non-woven layer having metal fibres being arranged for contacting a proton exchange membrane, wherein the first non-woven layer having metal fibers comprises metal fibers having a first equivalent diameter, and wherein the first non-woven layer having metal fibers has a first surface roughness and a first porosity; -a second non-woven layer having metal fibers, where the second non-woven layer having metal fibers comprises metal fibers having a second equivalent diameter, where the second non-woven layer having metal fibers has a second surface roughness and a second porosity, where the first surface roughness is less than 10 mu m, and the second surface roughness is less than 10 mu m. The first equivalent diameter is less than the second equivalent diameter, the first surface roughness is at least 20% less than the second surface roughness, e.g. In the range of 20% to 120%, where the first porosity is at least 10% less than the second porosity, e.g. In the range of 10% to 50%, and where the first nonwoven layer is metallurgically bonded to the second nonwoven layer.
Absstract of: EP4691970A1
The invention relates to a process for producing a hydrogen product (3) from a feedstock stream (4), said process comprising the following steps:- providing an ammonia stream (8);- sending the ammonia stream (8) to a vaporizer (6) configured to receive said ammonia stream (8) and to vaporize said ammonia stream (8) so as to obtain a vaporized ammonia stream (10); and- controlling the temperature of the vaporized ammonia stream (10) by injecting a cooling medium (16) into the vaporized ammonia stream (10) thereby obtaining a temperature-controlled ammonia stream (18).
Absstract of: CN121496442A
本发明公开了一种基于飞秒激光诱导合成高熵析氧催化剂的方法及其在光电化学水分解中的应用，属于析氧催化剂技术领域。本发明方法包括如下步骤：（1）选取含有光电极半导体材料的光电极半导体基底；（2）将高熵金属元素材料负载于光电极半导体基底表面，形成复合基底；（3）将飞秒激光引导至复合基底表面，诱导表面重构，形成高熵金属氧化物‑半导体产物，得到高熵析氧催化剂。本工艺利用飞秒激光导表面重构，使高熵金属氧化物的紧密附着并形成特定结构，实现了高熵金属元素的均匀分布，具有具有步骤简捷、适用性广的优势。高熵析氧催化剂克服了现有技术存在的电荷分离弱、稳定性差等技术问题，在光电化学水分解具有广阔的应用前景。
Absstract of: CN121497449A
本发明公开了一种电解制氢氧高压燃烧的热电联产储能系统及方法，涉及氢储能领域。电解槽制取高压氢气与氧气后，分别储存于氢/氧储罐中，系统可在氢/氧模式下运行，其中氧模式运行：氢气与来自氧储罐和氢/氧蒸压缩机的氧气蒸汽混合气在高压燃烧室内进行燃烧并生成过热水蒸气，随后进入膨胀透平做功；由于氧气过量，做功后的乏汽经气液分离器后分离成两股工质，即气体进入冷却器降温再经氢/氧蒸压缩机返回燃烧室，液体进入供热换热器后产生的排水经水泵加压后进入高温燃烧室，从而实现氢能的清洁利用与工质的循环再生。本发明可实现高发电效率和优良的环保性能，适用于需要稳定消纳波动性可再生能源以及需要电力与热力供应等地区。
Absstract of: JP2026020880A
【課題】少なくとも特定の箇所において電極性能に関連する状態のばらつきが少ない水電解用電極を製造する観点から有利な水電解用電極の製造方法を提供する。【解決手段】水電解用電極の製造方法は、下記（Ｉ）、（II）、及び（III）を含んでいる。（Ｉ）少なくとも１つの導電性基材２１上に水電解用電極を形成させるための原料溶液Ｌ１を少なくとも１つの導電性基材２１が配設された容器１１を経由して循環させる。（II）原料溶液Ｌ１が少なくとも１つの流路１４を通過する。（III）原料溶液Ｌ１の流れの下流における流路１４の流路断面積が原料溶液Ｌ１の流れの上流における流路１４の流路断面積よりも小さい状態で原料溶液Ｌ１の流れを生じさせる。【選択図】図１
Absstract of: CN121490213A
本发明公开了一种高安全性家用智能氢氧治疗机及工作方法，该设备包括壳体、电解槽、气液分离装置、控制模块、电源模块以及集成的安全监测系统、闭环控制系统和人机交互系统；安全监测系统通过水流、差压、水质、水位、温度等多重传感器实时监控设备状态，确保运行安全；闭环控制系统根据电解槽实时电流、电压及输出差压反馈，精确调节电源功率，保证产气稳定可靠；人机互系统通过触摸显示屏和语音交互模块提供丰富的状态信息和直观的故障指导，本发明从根本上解决了现有家用氢氧治疗机在安全性、可靠性及交互体验方面不足的问题，特别适用于家庭保健环境。
Absstract of: CN121496458A
本发明属于电催化二氧化碳还原反应技术领域，具体公开了Ni‑Co双单原子催化剂及其制备方法和应用，催化剂包括碳载体，原子级分散的Ni单原子，以Ni‑N4构型锚定于碳载体；原子级分散的Co单原子，以Co‑N4构型锚定于碳载体，催化剂中无金属‑金属键。本发明采用上述的Ni‑Co双单原子催化剂及其制备方法和应用，通过Ni‑N4和Co‑N4双活性位点分别独立调控CO2‑to‑CO转化和析氢反应（HER），实现CO/H2比例在0.3:1‑2.5:1范围内精确可调；利用Ni单原子位点调控界面水氢键网络刚性，平衡CO2和H2O的活化动力学，抑制工业级电流密度下的副反应。
Absstract of: CN119491243A
The invention relates to the technical field of household appliances, and provides a hydrogen peroxide generating device and application thereof. The hydrogen peroxide generating device comprises a shell, a liquid inlet and a liquid outlet, the liquid inlet and the liquid outlet are formed in the shell, the liquid inlet is used for being connected with a water supply component, a cathode piece and an anode piece which are used for electrolyzing water to generate a hydrogen peroxide solution are arranged in the shell, and the liquid outlet is used for discharging the generated hydrogen peroxide solution. According to the hydrogen peroxide generating device provided by the invention, water entering the shell through the liquid inlet can be electrolyzed to generate the hydrogen peroxide solution, and the generated hydrogen peroxide solution is discharged through the liquid outlet; the hydrogen peroxide generating device can be applied to household appliances such as clothes washing equipment, clothes processing equipment, an air conditioner, a dehumidifier, a refrigerator and a dish washing machine, can play a good role in cleaning, odor removal, disinfection, sterilization and the like, reduces the use of detergent, and improves the use experience of a user.
Absstract of: CN121496477A
本申请公开了一种制氢系统及其温度控制方法、装置、存储介质与程序产品。该制氢系统的温度控制方法包括：获取预设时域内的电解槽的功率指令及设备属性参数；其中，预设时域包括连续的多个预设时段，功率指令包括与各预设时段对应的子功率指令；将各子功率指令输入优化温度控制模型，以最小化预设时域内电解槽温度与目标温度之间的偏差为目标，根据设备属性参数计算各预设时段对应的阀门开度指令；将预设时域内的阀门开度指令下发至制氢设备，以基于功率指令和阀门开度指令，控制制氢设备在预设时域内运行。本申请实施例的技术方案可减小电解槽温度与目标温度之间的偏差，提高制氢设备的产氢效率。
Absstract of: CN121496476A
本申请提供了一种电解槽的温度控制方法，根据当前周期内电解槽的工作电流值和上一周期内电解槽的工作电流值，确定当前周期和上一周期相比电解槽的入口温度理论变化值，进而结合上一周期的电解槽入口温度目标值，确定当前周期的电解槽入口温度目标值，再结合当前周期的电解槽入口温度实测值，调节冷水阀阀门开度。相比于常规的PID反馈调节系统，本方案根据每个周期内电流的变化量，在本周期内重新计算电解槽的入口温度目标值，然后使得冷却水流量阀的阀门开度快速变化，缩小电解槽入口碱液温度过程值与其目标值之间的误差，使电解槽出口碱液温度控制更加准确，保持温度在最佳产氢温度上，提高了制氢效率。
Absstract of: CN121496491A
本发明涉及电解水制氢技术领域，尤其涉及一种制氢系统连通管控制方法，包括以下步骤：同步采集氢分离器和氧分离器的液位数据、氢气中的氧气浓度数据和氧气中的氢气浓度数据；基于采集的液位数据计算液位差，并对气体浓度数据进行信号预处理；将液位差和预处理后的气体浓度数据输入控制模型进行处理；通过控制模型将液位差与液位差阈值进行比对，将气体浓度数据与对应的气体浓度阈值进行比对。本发明中，通过引入气体纯度参数与液位差的多阈值耦合判断机制，进而根据超标等级触发分级控制指令，从而改善了传统方法大都采用单一液位平衡控制，由于缺乏对氢中氧和氧中氢扩散的主动阻断机制，从而造成气体纯度失控风险高的问题。
Absstract of: US20260035242A1
A hydrogen generation system with controlled water distribution is disclosed. The system comprises a reaction chamber containing a hydrogen-producing fuel, a liquid distribution mechanism, and a control system. The liquid distribution mechanism includes a rotating arm with liquid injection ports that move vertically through the fuel chamber. This allows for precise and efficient liquid delivery to unreacted fuel, optimizing hydrogen production. A proprietary fuel blend utilizes chemicals that store significant amounts of hydrogen in a solid-state form. A feature of the device is the arm's controlled vertical movement, achieved through a screw mechanism that adjusts the arm's height as it rotates, creating a spiral liquid distribution pattern. The control system regulates liquid injection rates, arm rotation speed, and vertical movement to optimize hydrogen production based on demand. The system can also operate at low pressures and be scaled to different sizes in a safer, more efficient, on-demand manner.
Absstract of: CN121496443A
本发明公开了一种新型酸性电解水析氧反应电催化剂及其制备方法，所述电催化剂为一种以泡沫镍为基底的新型材料，该材料的制备方法是将预处理后的泡沫镍浸渍在RuCl3水溶液中，一定时间后取出再浸渍在高锰酸钾和盐酸多巴胺的氨水溶液中反应，最后在惰性气氛下焙烧制得。本发明提供了酸性电解水析氧反应电催化剂的方法，Ru在泡沫镍基底分散均匀，负载量低，在0.5M H2SO4酸性电解水析氧反应中，在10mA cm‑2电流密度下，过电位仅为174mv，稳定性超过44h。本发明解决了酸性电解质电解水制氢过程中OER催化剂活性较差、稳定性差、成本高的问题。
Absstract of: CN121496494A
本发明涉及分离技术领域，公开了一种碱性电解水制氢气液分离装置，包括保护外壳，所述保护外壳的内部固定连接有气相出口，所述气相出口的外部固定连接有法兰环，所述气相出口的底端固定连接有套筒，所述套筒的外部固定连接在保护外壳的内部，所述气相出口的内部固定连接有支撑板，所述支撑板的内部设置有泄压组件，所述泄压组件的外部滑动连接在气相出口的内部，所述泄压组件包括浮球，所述浮球的底端滑动连接在支撑板的内部，所述浮球的外部滑动连接在气相出口的内部。通过气相出口支撑支撑板进行固定，从而可以实现自动、智能地调整浮球的位置和密封方式的效果，极大地提升了装置在各种工况下的运行安全性和可靠性。
Absstract of: CN121496460A
本发明公开了一种硒掺杂二氧化钌及其制备方法与应用，通过将三氯化钌和亚硒酸钠溶解在醇类溶剂后置于油浴锅中反应，再将反应后的样品洗涤、负载、烘干、煅烧，最终成功制得了硒掺杂的二氧化钌。制得的二氧化钌呈现多孔簇状形貌，能够暴漏更多活性位点，利用硒掺杂调控电子转移，诱导反应机制转变提升了二氧化钌的活性和稳定性，将其作为催化剂用于电解水制氢时表现出了优异的析氧性能，在电催化领域具有应用前景。
Absstract of: CN121491326A
本申请涉及无机材料合成技术领域，具体涉及一种具有纳米孪晶结构的铂纳米片及其合成方法、应用。该铂纳米片包括多个铂纳米晶粒；在铂纳米片的非边缘区域，孪晶畴内的晶格应变分布为：畴结构上部区域的面间角度小于无应变铂晶体面间角度的理想值，呈现压缩应变特征，畴结构下部区域的面间角度大于无应变铂晶体面间角度的理想值，呈现拉伸应变特征；在铂纳米片的边缘区域，畴结构上部区域的面间角度减小至65.6°，畴结构下部区域的面间角度增加至74.2°。该铂纳米片具有纳米孪晶结构，其孪晶畴内存在的晶格应变现象能够提高铂纳米片的吸附能力，进而显著增强铂纳米片的催化活性。
Absstract of: CN121493905A
本发明公开了一种通过氧化镍晶面调控吸附磷化氢制备电催化剂的方法，属于电催化材料制备技术领域；其包括：以镍源为原料，通过溶剂热法或水热法合成具有特定晶面暴露的形貌可控氧化镍颗粒，对氧化镍颗粒进行热处理得到前驱体，再将前驱体置于磷化氢氛围中进行磷化处理，最终制备得到含NixPy的电催化材料；其中，特定晶面包括（111）晶面和（110）晶面。本发明探究了不同形貌氧化镍对磷化氢吸附性能的差异，在实现高效脱除尾气中磷化氢的同时合成了电催化剂所形成的电催化剂材料，实现了环保治理与资源利用的双重目标。
Absstract of: WO2025002798A1
The invention relates to a reactor (2) for generating hydrogen and at least one other product from at least one reactant, the reactor comprising a tubular reactor vessel (4) which contains a catalyst (6) in the form of a ceramic bed. Improved corrosion resistance against a variety of media and thus an increased service life of the reactor (2) is achieved by forming the reactor vessel (4) from silicon-infiltrated silicon carbide (SiSiC).
Absstract of: CN121496480A
本申请实施例提供一种启动方法、装置、电子设备、存储介质及程序产品。该方法包括：获取电解水制氢系统的多个电解槽的运行参数和效能参数；基于多个电解槽的运行参数，确定各电解槽是否达到启动条件；在存在电解槽未达到启动条件时，生成至少一个电解槽对应的告警提示信息，并停止启动；在多个电解槽达到启动条件时，获取电解水制氢系统的电源的可用功率容量，并结合电源的可用功率容量，启动电解水制氢系统的多个电解槽。在上述方法中，通过自动采集多个电解槽的运行参数与效能参数，基于运行参数自动判定各电解槽是否达到启动条件，无需人工逐台检查运行参数，大幅减少了大规模PEM电解水制氢系统在启动阶段的耗时。
Absstract of: CN121493880A
本发明公开了一种含非界面Ni空位的NiS/NiSe2异质结的制备方法，包括前驱体制备、原位硒化处理步骤。本发明还公开一种含非界面Ni空位的NiS/NiSe2异质结，其采用如上所述的方法制备而成。
Absstract of: CN121496493A
本发明公开了一种制氢加氢自动化控制方法，它包括如下步骤：步骤S1、系统上电初始化，然后进行系统自检；步骤S2、根据不同的使用场景选择对应的氢气生产控制模式，进行制氢加氢操作，所述氢气生产控制模式包括电解制氢加氢模式、高压钢瓶加氢模式和制氢充固态储氢模式。本发明提供一种制氢加氢自动化控制方法及系统，从而提升制氢加氢一体机的可靠性、灵活性和多样性。
Absstract of: CN121496432A
本发明属于质子交换膜（PEM）电解水制氢技术领域，具体涉及一种PEM电解水制氢膜电极涂布方法。该方法包括：步骤1：涂布浆料动态预处理；步骤2：质子交换膜张力稳定输送；步骤3：双面同步狭缝涂布；步骤4：涂布过程第一次OCT在线检测；步骤5：三阶段梯度干燥固化；步骤6：干燥后进行第二次OCT实时检测与闭环调整；步骤7：涂布成品收卷。解决了传统涂布工艺“单面离散效率低、厚度不均、缺陷检测滞后、转运褶皱”等问题。
Absstract of: CN121496462A
本发明属于材料合成及电催化技术领域，具体涉及一种金属离子掺杂的镍磷化物催化剂及其制备方法和催化应用，将含有金属离子的盐、镍源、有机配体、溶剂充分混合后，加入载体，进行水热反应，得到金属离子掺杂的Ni‑有机配体前驱体；再将金属离子掺杂的Ni‑有机配体前驱体进行磷化处理，得到金属离子掺杂的镍磷化物。本发明材料的制备方法简单，制备的材料同时具有碱性氢析出反应（HER）和尿素氧化反应（UOR）催化活性，相较于传统Pt、Ru基催化剂而言，减少了Ru的用量，降低了成本，且拥有更高的HER和UOR活性和稳定性。通过HER耦合UOR产氢，从热力学上解决了全解水能耗高的问题，具有更高的工业应用价值。
Absstract of: CN121496492A
本申请公开了一种电解海水制氢系统健康状态检测方法、装置及设备，涉及设备状态检测领域，该方法包括：获取电解海水制氢系统的多模态数据集；根据多模态数据集对神经网络模型进行训练，得到预训练神经网络模型；神经网络模型包括多个单模态特征提取模块、特征融合模块、投影模块及预测模块；根据无标签多模态运行数据，采用自监督对比学习方法对预训练神经网络模型进行优化，得到优化后的预训练神经网络模型；根据电解海水制氢系统的实时多模态运行数据，采用优化后的预训练神经网络模型确定电解海水制氢系统的实时健康状态。本申请实现了在仅有少量标注数据甚至无异常样本条件下，对电解海水制氢系统全生命周期内健康状态的精准评估。
Absstract of: CN121496429A
本发明公开了一种中板、电极室组件及电解制氢装置，中板包括本体和循环板，所述本体由金属板一体冲压制备而成，所述本体表面周边冲压有截面为S型的环形密封槽道，所述环形密封槽道内侧的本体的两个表面上分别冲压有若干第一凸起和第二凸起；所述循环板倾斜设置并与第一凸起固定连接，所述循环板设置在环形密封槽道内且顶边与本体表面的间距小于底边与本体表面的间距；电极室组件运用上述中板组装而成，电解制氢装置则运用上述的电极室组件。本发明具有良好的密封效果，阴阳极室中板合二为一的冲压结构有效减少泄露点，降低外漏风险；而且减少点焊接工艺，降低内部接触电阻，从而降低电解槽能耗，上述结构配置合理，安装方便。
Absstract of: CN121496445A
本发明涉及电解水制氢的技术领域，提供一种PEM电解水的阳极催化剂浆料的制备方法及浆料及催化层，所述制备方法包括：S1、将阳极催化剂、第一离聚物、第一溶剂混合，分散，得到第一催化剂浆料；S2、将消氢催化剂、第二离聚物、第二溶剂混合，分散，得到第二催化剂浆料；所述消氢催化剂为碳载贵金属催化剂；S3、将第一催化剂浆料和第二催化剂浆料混合，进行均质化处理，得到阳极催化剂浆料。优点：通过消氢添加剂的添加、浆料制备工艺步骤等的配合设置，同时实现提高均匀性、改善传质和降低氧中氢的效果，提升了膜电极性能和安全性。
Absstract of: CN121496455A
本发明公开了一种质子交换膜水电解池的阳极结构的制备方法，所述质子交换膜水电解池的阳极结构包括锗掺杂二氧化钌片状聚集体阳极催化剂，所述锗掺杂二氧化钌片状聚集体阳极催化剂的制备方法包括如下步骤：将固体无机钌盐、有机锗配合物和聚乙烯吡咯烷酮溶于溶剂中，室温搅拌，得到原液；获得的原液进行静电纺丝，干燥得到纳米纤维前驱体；对前驱体进行热处理，得到所述锗掺杂二氧化钌片状聚集体阳极催化剂。本发明还公开了上述制备得到催化剂及其在酸性溶液中，电解水析氧反应和在质子交换膜PEM电解水制氢反应中的应用。该催化剂应用于PEM电解水制氢反应和电解水氧化反应中均展现出优异的电催化活性，且长期工作下仍具有较好稳定性。
Absstract of: AU2024304508A1
According to the invention, electrodes are arranged on two opposite surfaces of a separator. Each electrode consists of an open-pore metal structure, in particular a metal foam made of at least one of the chemical elements Ni, Al, Mo, Fe, Mn, Co, Zn, La, Ce, or an alloy of at least two of said chemical elements or an intermetallic compound of at least two of said chemical elements. A continuously decreasing catalytic activity is provided from the surface facing a separator or the respective other electrode of each electrochemical cell to the opposite surface of the respective electrode, and/or a continuously increasing porosity and/or pore size and/or a continuously decreasing specific surface area is provided from the surface facing a separator or the respective other electrode of each electrochemical cell to the opposite surface of the respective electrode.
Absstract of: CN121490785A
ZIS/CdS/CQDs三元复合光催化剂的制备方法及应用，涉及光催化材料领域，要解决现有光催化产氢催化剂的光催化产氢的效率较低的问题。方法：一、将金属硫化物CdS加入到甲醇溶液中，然后依次加入二水合醋酸锌、四水合氯化铟和硫代乙酰胺，超声处理，加入Na2CO3，得到混合液；二、将混合液转置于反应釜中反应，冷却，洗涤，干燥，得到ZIS/CdS；三、将ZIS/CdS和CQDs粉末混合反应，冷却，洗涤，干燥，得到ZIS/CdS/CQDs。本发明中ZnInS与CdS复合，显著增强光催化活性。CQDs的宽光谱吸收能力可拓展复合材料的可见光响应范围，与CdS的窄带隙协同提升光捕获效率。本发明用于光催化产氢。
Absstract of: CN121490749A
本发明涉及光催化技术领域，具体涉及一种锶铋钒氧化物光催化剂及其制备方法与应用，光催化剂的化学式为Sr3.59Bi19.41V4O42，其晶体结构属于正交晶系，空间群为Immm，是一种由阳离子三重板层构成的独特层状结构；光催化剂通过熔盐法合成，在可见光下表现出光催化分解水产氧活性。本发明通过将SrO、Bi2O3和V₂O₅前驱体与熔盐介质混合研磨后，经程序升温煅烧合成目标产物；该方法所制备的催化剂具有高结晶度、缺陷少、形貌规整的特点，其光催化产氧性能显著优于传统固相法合成的同组分样品，可在波长≥420 nm的可见光照射下，以硝酸银、硝酸铁、氯化铁或者铁氰化钾水溶液为牺牲剂体系实现光催化分解水产氧。
Absstract of: CN121496466A
本发明公开了一种RE‑NiFeLDH双功能催化材料及其制备方法与应用。该催化剂包括镍铁水滑石（NiFeLDH）主体和插层于其层间的稀土元素（RE），同时具备析氢反应和析氧反应双功能催化活性。其制备方法为：将镍盐、铁盐、稀土盐、尿素和氟化铵溶于水中形成混合溶液，将预处理后的基材浸入混合溶液，在100~160℃下水热反应6~24小时，产物经抽滤、洗涤、烘干后获得催化剂。本发明通过稀土元素调控NiFeLDH的层间距和电子结构，增加比表面积、暴露更多活性位点，提升催化活性和电子传输效率；制备方法简单可控、成本低廉，催化剂在碱性电解液及模拟海水中均表现出优异的双功能催化性能，具有广阔的工程应用前景。
Absstract of: CN121496463A
本发明涉及析氢催化剂技术领域，尤其涉及一种基于缺陷工程的钌基碱性析氢催化剂及其制备方法。制备方法包括以下步骤：将钛源、无水乙醇、聚乙二醇200、硼酸的混合体系凝胶老化得到第一前驱体；所述第一前驱体于空气氛围、200～800℃下煅烧5～20h，得到第二前驱体；所述第二前驱体与钌盐和还原剂混合后洗涤干燥，得到所述催化剂。这种催化剂包括电子耦合的载体和Ru活性成分，所述载体为B替位取代Ti的TiO2载体。本发明通过B替位取代Ti，局部引入晶格应力和畸变，实现了快速的水解离，为Ru提供了更多、更强的锚定位点，增强了Ru与载体TiO2之间的电子耦合，至少从强水解能力、优化Ru的氢吸附能两个方面提高催化HER的活性。
Absstract of: CN121496481A
本申请提供一种电解槽的停机方法、装置、设备、存储介质及程序产品。涉及电解制氢技术领域。该方法包括：确定与多个电解槽连接的分离装置的目标压力和多个电解槽的氢气生成速率，分离装置包括氧气分离装置和氢气分离装置；根据氢气生成速率，确定惰性气体待注入的第一总量；根据目标压力和惰性气体对应的注入压力，控制氧气分离装置和氢气分离装置的气体释放；在分离装置的当前压力达到注入压力时，控制多个电解槽停机；根据第一总量，向氧气分离装置和氢气分离装置注入惰性气体，提高了电解槽的停机的安全性。
Absstract of: AU2024303309A1
The present invention provides a method of controlling an electrolyser cell stack within a system having a fluid temperature control system, a current control system, a voltage monitoring system, monitoring/control systems for the temperatures of the fluid inlet and outlet, by controlling the current to a fixed value, calculating a temperature delta between the fluid inlet and outlet, and adjusting the fluid input temperature if the delta is greater than a threshold value. The present invention also provides a method of determining a stack operating condition is the temperature delta as measured above is lower than a threshold value. The present invention also provides a control device and computer program capable of executing the method as outlined above.
Absstract of: CN121285539A
The invention relates to a method for preparing methanol. The method comprises the following steps: (a) preparing a hydrogen raw material through electrolysis; (b) providing a carbon oxide feedstock during the electrolysis operation in step (a); (c) mixing at least part of the hydrogen feed and a carbon oxide source consisting of a carbon monoxide and/or carbon dioxide feed to obtain methanol syngas; (d) adjusting the molar content of hydrogen, carbon monoxide and/or carbon dioxide in step (c) to a modulus M of 1.9 to 2.2, said modulus M being (H2-CO2)/(CO2 + CO); (e) converting the methanol syngas to methanol in one or more boiling water reactors; during the electrolysis inoperation in step (a): (f) interrupting the conversion of methanol syngas by heat exchange with boiling water in one or more boiling water reactors, in which step (f) the one or more boiling water reactors are heated by one or more auxiliary heaters to maintain boiling of water in the one or more boiling water reactors.
Absstract of: JP2026020881A
【課題】従来よりも電極性能に関連する状態のばらつきが少ない水電解用電極を製造する観点から有利な水電解用電極の製造方法を提供する。【解決手段】水電解用電極の製造方法は、第１の設置状態及び第２の設置状態において少なくとも１つの導電性基材２１上に水電解用電極を形成させるための原料溶液Ｌ１を少なくとも１つの導電性基材２１が配置された容器１１を経由して循環させる。第２の設置状態における少なくとも１つの導電性基材２１の向きは、第１の設置状態における少なくとも１つの導電性基材２１を、所定の直線を回転軸として半回転させたときの少なくとも１つの導電性基材２１の向きと一致する。所定の直線は、少なくとも１つの導電性基材２１の主面上の直線又は少なくとも１つの導電性基材の主面と交差する直線である。【選択図】図５
Absstract of: CN121499362A
本发明提供一种用于碱性电解水制氢电极催化剂结合力与均匀性的测试方法，包括实验设备搭建和实验操作两个过程，其中，实验设备搭建包括制备测试溶液A、制备测试溶液B、制备防腐支撑板、制备样品和组装测试设备，然后，接通电源进行测试并记录数据。本发明提出了一种能够模拟电极失效的测试方法，相较于传统的测试方法，本发明的测试时间更短，测试方法更加灵活，尤其能够更加直观方便的反应催化剂与电极基材结合能力的强弱。相较于一般的测试方法，本方法具有更加灵活、快速、便捷、时间人力成本更低等特点。
Absstract of: CN121496456A
本发明涉及电催化剂合成领域，公开了一种中熵固溶体氧化物的制备方法：将固体无机锰盐、锡盐、铱盐和氯化钠进行研磨，混合后获得金属盐混合物；将金属盐混合物在空气中进行高能球磨处理，形成高度均质化的前驱体；将球磨后的前驱体进行热处理，获得含有氯化钠的固溶体氧化物催化剂；将含有氯化钠的固溶体氧化物催化剂进行水洗处理，获得中熵固溶体氧化物电催化剂。本发明还公开了上述制备得到催化剂及其在酸性溶液中电解水析氧反应和在质子交换膜PEM电解水制氢反应中的应用。该催化剂应用于PEM电解水制氢反应和电解水氧化反应中均展现出优异的电催化活性，且长期工作下仍具有较好稳定性。
Absstract of: CN121496439A
本申请提出一种在水基乳液中进行电沉积过程，制备催化电极的技术方法，属于催化电极制备技术领域，公开了催化电极及其制备方法。所述催化电极的制备方法具体包括：将二硫化钼分散液与聚乳酸的三氯甲烷溶液进行混合处理，得到皮克林乳液；将多孔金属基体在含有所述皮克林乳液电沉积液中进行电化学沉积处理，经过清洗干燥后，得到所述催化电极。该催化电极的制备方法简单可靠，易于工业实施，所制备的催化电极具有较高的催化活性，适合于电解水制氢、制氧等电化学装置中应用。
Absstract of: AU2024281599A1
A multi-tier integrated power-to-ammonia system includes a converter for generating ammonia and heat through a reaction involving a compressed mixture of hydrogen and nitrogen gases. The system includes a steam generator that can generate steam using the heat from the reaction, and a reversible solid-oxide system in fluid communication with the steam generator that can separate the steam into oxygen gas and hydrogen gas.
Absstract of: CN121497514A
本发明公开了一种基于发动机尾气余热的等离子体氨分解制氢装置，包括发动机、液氨瓶、等离子体氨分解反应器、温度传感器、氢气罐及等离子体电源。发动机运行时，液氨经汽化器汽化为气态氨，一部分进入发动机燃烧，另一部分与发动机尾气换热后进入反应器。同时，温度传感器实时监测尾气温度并反馈至ECU，ECU根据尾气温度输出控制信号到等离子体电源。尾气温度高于700 K时，关闭等离子体电源，依靠热催化实现氨气分解；当尾气温度低于700 K时，触发等离子体电源并进入动态调节模式，采用分阶段上电策略，先低功率预放电保证放电稳定性，再根据需求逐步提升功率。反应器内氨气分解生成氢气和氮气，产物混合气部分储存，部分作为发动机燃料使用。
Absstract of: CN121496425A
本申请实施例提供一种电解水制氢系统及其设备。该电解水制氢系统包括电解槽、气液分离装置、换热器、第一管路、第二管路、第三管路、控制器和第一温度传感器，其中：电解槽通过第一管路与气液分离装置连接，电解槽还通过第二管路与换热器连接；气液分离装置通过第三管路与换热器连接；第三管路上包括旁通的第四管路，第四管路与电解槽连接；第一温度传感器设于第一管路；换热器用于对气液分离装置输出的电解液进行降温；气液分离装置用于对电解槽输出的电解液进行气液分离；控制器用于基于第一温度传感器检测电解槽输出的电解液的第一温度，并在第一温度小于或等于第一阈值时，控制气液分离装置分离的电解液通过第四管路向电解槽传输。
Absstract of: CN121496424A
本发明涉及氢气制备技术领域，公开了一种高效制氢空分一体化设备，包括用于存储电解液的蓄液组件和储气组件，蓄液组件内部设置有用于对电解液电解的电解模块，蓄液组件内部设置有用于对电解液充分搅拌的搅拌组件，蓄液组件一侧设置有用于放置储气组件并带动储气组件升降的顶升机构，磁力耦合传动组件有效减少了磨损，并使设备运行更加稳定，氢气通过氢气传输机构输送至储气组件进行储存，而空分过滤组件则进一步提纯氢气，去除氧气和氮气，确保氢气的高纯度，顶升机构和支撑组件提高了设备的操作灵活性和稳定性，该设备的设计有效地提高了氢气生产的效率和安全性，同时减少了设备的维护成本，并增强了其在中小型应用场景中的适应性。
Absstract of: CN121496478A
本发明公开了一种用于电解水制氢系统运行稳定性的控制方法，所述系统包括电解槽、电源、气液分离器、冷却器、循环泵以及检测与执行机构，包括以下步骤：S1：实时监测所述系统的运行状态参数，所述运行状态参数至少包括电解槽温度、电解槽压力、输入电流密度、氢侧与氧侧差压、循环碱液流量或去离子水电阻率；S2：基于所述运行状态参数，通过预设的系统稳定性评估模型。本发明克服了传统单回路控制的局限与干扰问题，使系统面对内外扰动时能整体做出前瞻、平稳且经济的协同响应，不仅在稳态运行时维持全局最优稳定性与能效，更在瞬态与异常工况下通过智能容错与运行点自适应迁移，显著提升系统的鲁棒性、安全性与全生命周期适应能力。
Absstract of: CN121496444A
本申请涉及金属催化技术领域，具体涉及一种复合配位单原子催化剂及其制备方法和应用。本申请实施例催化剂包括载体和金属中心，载体包括辅助配位原子，至少两个辅助配位原子与金属中心耦合形成催化活性中心；其中，金属中心包括单原子金属中心，辅助配位原子包括C、N、P、S、Cr中的至少两种。该复合配位单原子催化剂通过金属中心和辅助配位原子间的协同作用降低H2O的解离能垒，提高H2O解离和质子产生速率，极大提高了复合配位单原子催化剂在碱性析氢反应中的催化效率。该复合配位单原子催化剂还通过辅助配位原子耦合锚定金属中心形成催化活性中心从而提高了复合配位单原子催化剂的稳定性和耐久性。
Absstract of: CN121490747A
本发明涉及材料制备领域，具体为一种原位刻蚀生长嵌套式SrTiO3/TiO2异质结光催化材料的制备方法，解决了现有制备方法无法原位合成嵌套式SrTiO3/TiO2异质结构的问题。具体为将SrCl2·6H2O的水溶液与LiOH·H2O的水溶液混合，搅拌得到溶液A，将TiCl4加入1,2‑丙二醇的溶液中，搅拌得到溶液B；将溶液A和溶液B混合搅拌并水热反应一段时间，得到十八面体形状SrTiO3；盐酸水热刻蚀后，SrTiO3内部也会被部分刻蚀，并在其(001)晶面生长出锥形小颗粒，形成SrTiO3与TiO2内外嵌套结构；经过冷却、离心、清洗及干燥后，即可得到原位刻蚀生长嵌套式SrTiO3/TiO2异质结光催化材料。本发明在一般水热条件下即可进行，操作简单、成本低廉、具有较高的产率和纯度，且光催化活性较高，具备实际应用的潜力。
Absstract of: CN121499980A
一种基于高频阻抗分析的电解槽在线故障检测方法及系统。通过实验测定AEM电解槽液位的上限、安全工作温度对应的高频阻抗范围以及高频安全阻抗阈值范围；实时计算AEM电解槽的高频阻抗值，与安全工作温度对应的高频阻抗范围进行对比；当高频阻抗值处于安全工作温度对应的高频阻抗范围内，则判定AEM电解槽工作在安全环境中；否则，进入故障诊断流程；在故障诊断流程中，将高频阻抗值与高频安全阻抗阈值范围进行对比；区分上限对比结果与下限对比结果，判定AEM电解槽的故障类型并执行对应的处理措施。本申请方法实现了对AEM电解槽的实时监测、故障诊断和动态调控，确保电解槽的稳定、安全运行。
Absstract of: CN121496482A
本发明提供了一种风光制氢智能控制系统，涉及电力技术领域，包括：能量输入模块，用于实时采集获取制氢功率预测序列；控制指令模块，用于利用最大消纳算法通过制氢功率预测序列，得到最大消纳电解槽状态预测表；利用最小动作算法通过制氢功率预测序列，得到最小动作电解槽状态预测表；通过最大消纳预期收益和最小动作预期收益得到性能指标；通过性能指标将最大消纳电解槽状态预测表或最小动作电解槽状态预测表作为目标电解槽状态预测表；能量转化存储模块，用于根据目标电解槽状态预测表控制氢气转化存储。本发明实现了在提高负荷分配效率的同时实现风光制氢统一调度机制。
Absstract of: AU2023449815A1
A system and method of making hydrogen from water. A cylindrical reaction vessel is provided with an outer shell, a central shaft, and one or more concentric inner tubes separated by annular spaces. Water is delivered to the annular spaces by a water pump through an inlet defined in the reaction vessel. The water courses along a tortuous flow path. That path begins at an inner annular space around a central shaft. It ends at an outer annular space. The water emerges from the reaction vessel through an outlet associated with a manifold. A high-frequency vibratory stimulus is applied to the reaction vessel and water. Water molecules are dissociated into hydrogen molecules and oxygen atoms. These reaction products are delivered through the manifold along an effluent flow path to a receiving pressure vessel before deployment to a sub-assembly for harnessing clean energy.
Absstract of: CN121496430A
本发明公开了一种兆瓦级大幅面AEM电解槽流场板，包括基板，所述基板的中央位置设有阳极进口、阳极出口一、阳极出口二，所述阳极出口一、阳极进口和阳极出口二依次呈直线排列，所述阳极出口一、阳极进口和阳极出口二形成的直线阵列位于所述基板的中央位置，所述阳极出口一、阳极进口和阳极出口二所形成的直线阵列将基板分为左基板和右基板，左右基板共设有四分区。本发明一种兆瓦级大幅面AEM电解槽流场板四分区结构，将大幅面流场进行划分，能够有效提升反应物的分布均匀性，提升活性面积利用率，减少局部过热的情况，同时通过分割为四个分区，大大减小单个流场的面积，有效解决电解槽压降较大的问题，可适用功率相对较小的泵体，降低能耗。
Absstract of: CN121490788A
本发明公开了一种S型异质结Bi12O17Cl2/CeO2光催化剂及其制备方法和应用。该制备方法包括：将CeO2粉末分散在水中得到悬浮液；将BiCl3溶解在乙醇中，滴加NaOH溶液至形成沉淀得到含BiOCl的混合液；将CeO2悬浮液加入含BiOCl的混合液中反应；离心、洗涤、干燥后煅烧，得到S型异质结Bi12O17Cl2/CeO2光催化剂。本发明的S型异质结Bi12O17Cl2/CeO2光催化剂具有优异的光催化性能，既可用于高效降解难降解的抗生素类污染物环丙沙星，也可用于光催化分解水产生氢气这一清洁能源，实现了环境污染治理和清洁能源生产的双重应用功能，为解决环境污染和能源短缺问题提供了一种有效的技术途径。
Absstract of: CN121496410A
本申请属于氢能源制备领域，具体公开了一种萃取辅助无膜电解水制氢方法及装置，包括：S1将电解液注入无膜电解槽内，S2执行电解制氢，S3收集析氢电极上析出的氢气，监测电解电压，在其上升幅度超过设定值时，中断制氢，S4将有机液相注入到电解液中，以促进有机液相萃取溴/碘单质，后将全部有机液相和部分电解液一起回收至第一容器中，S5重新开启外界电源以重启电解制氢，向第一容器中加入抗坏血酸，用于还原溴/碘单质，同时获得脱氢抗坏血酸，S6持续电解制氢同时，将第一容器的电解液重新回流至电解槽中。本发明同时提供了实现以上方法的装置。本发明方法解决了现有技术中无膜电解水制氢工艺连续循环性不足和制氢效率不足的问题。
Absstract of: CN121496465A
本发明公开了一种Co2P/Fe2P异质结纳米片阵列材料及其制备方法和应用，属于电催化材料技术领域。本发明提供的制备方法包括：将预处理后的泡沫镍置于含钴盐、铁盐、尿素和氟化铵的前驱体溶液中，通过水热反应在其表面生长CoFe‑LDH纳米片阵列前驱体；随后在惰性气氛下进行低温磷化处理，将前驱体转化为Co2P/Fe2P异质结，最终得到生长于泡沫镍上的Co2P/Fe2P异质结纳米片阵列材料。该材料在碱性电解质中表现出优异的双功能电催化活性与稳定性，用于全水分解时仅需1.50V的低槽压即可驱动20 mA cm‑2的电流密度。本发明工艺简单、成本低廉，为高效、稳定的非贵金属水分解催化电极的制备提供了新方案。
Absstract of: CN121490828A
本发明公开了一种单原子‑钛氧簇协同催化剂及其制备方法与应用，该复合催化材料，包括：钛氧多核团簇结构单元；以及以单原子形式通过配位键锚定在所述钛氧多核团簇结构单元上的金属活性中心；其中，所述金属活性中心与钛氧多核团簇之间形成电子协同，增强光生电荷分离与传输。所述钛氧多核团簇为Ti6O6、Ti8O8、由NH2‑MIL‑125(Ti)热解衍生的钛氧簇单元、经有机配体修饰的MOF材料，或通过多羧酸配体调控尺寸的钛氧簇中的至少一种；所述金属活性中心选自Cu、Pt、Ru、Pd、Co中的至少一种。本发明能够实现催化剂的克级制造，具有良好的重复性与稳定性，并且实现钛氧簇与单金属原子的协同光催化水产氢。
Absstract of: JP2026021217A
【課題】水素の製造効率が良く、水酸化マグネシウムの産業廃棄物を産出しない、水から水素を製造する方法を提供する。【解決手段】水素化マグネシウムとクエン酸やグルコン酸などのハイドロオキシカルボン酸を水酸化マグネシウムの１．２モル比倍以上加えた塩化マグネシウム水溶液から製造したクロロマグネシウムプラズマで水から水素を製造する方法である。【選択図】なし
Absstract of: CN121496453A
本发明公开了一种镍钒铁基自支撑电极及其制备方法与应用。本发明以偏钒酸钠和氯化镍分别作为钒源和镍源，在泡沫镍基底上通过水热反应合成了由片状结构组成的类球形前驱体，再以无水次磷酸钠和硝酸铁为磷源和铁源，通过磷化处理和浸泡处理最终形成NiO‑VO‑FeP@NF自支撑电极。本发明得到的电极无需添加粘合剂，简化了制备过程并降低了生产成本，而且催化材料与基底的结合紧密，防止了催化剂脱落，这种无缝接触为电荷地快速转移提供了条件，使得催化剂活性得到了明显改善。本发明得到的电极具有优异的析氧反应活性和稳定性，在高电流密度下，其析氧反应活性超越商业RuO2电极，显示出良好的产业化应用前景。
Absstract of: JP2026020857A
【課題】Ｉｒを含有しなくても、十分な触媒性能および十分な耐久性を有する新規な水電解陽極触媒を提供する。【解決手段】第四周期以上第六周期以下の第ＩＶ、Ｖ、ＶＩ族元素および第二周期以上第六周期以下のＸＩＶ族元素からなる群から選択される少なくとも一種の元素、を含む炭化物、窒化物、およびホウ化物からなる群から選択される少なくとも一種の化合物、を含む水電解陽極触媒。【選択図】なし
Absstract of: CN121490765A
本发明适用于制氢技术领域，提供了一种MOF衍生多层碳材料催化剂的制备方法及其应用，所述催化剂以钴基MOF为前驱体，经高温焙烧后，再通过特定条件的DBD等离子体处理制得。DBD处理能有效减小催化剂粒径，增加活性位点暴露，提高钴物种分散度。将所得催化剂用于氨硼烷甲醇分解制氢反应，在温和条件下即可实现高效产氢，其催化活性与部分贵金属催化剂相当。本发明制备工艺简单、能耗低、环境友好，为非贵金属催化剂的开发及氨硼烷储氢材料的应用提供了新途径。
Absstract of: TW202446996A
The present disclosure relates to an electrolysis cell comprising a porous transport layer which comprises at least one metallic support layer and at least one macroporous layer which comprises titanium particles deposited on the at least one support layer so that the titanium particles are at least partly covered with at least one conductive titanium suboxide surface layer.
Absstract of: KR20260020050A
본 발명은 우수한 성능을 지닌 광활성 재료용 복합체, 이를 포함하는 산소 발생 반응용 광전극, 및 이의 제조방법 등에 관한 것으로, 본 발명의 여러 구현예를 통하여 궁극적으로 우수한 성능으로 광전기화학적 물 분해를 통한 녹색 수소 생산을 달성할 수 있다.
Absstract of: CN121496489A
本发明涉及氢能安全监测技术领域，具体地说，涉及一种基于光纤原位监测内部状态的电解槽。包括阴极端板和阳极端板，阳极端板位于阴极端板的一侧，阴极端板的侧壁固定连接有阴极垫片，阴极垫片远离阴极端板的一端固定连接有阴极极板，阴极极板的侧壁固定连接有阴极衬垫，阴极衬垫远离阴极极板的一端固定连接有阳极衬垫，阳极衬垫和阴极衬垫的内表面固定连接有膜电极，通过在阴极极板、阳极极板分别开设主沟槽、副沟槽，嵌入集成温度型和应变型FBG传感器的主光纤、副光纤，直接将监测点布置于反应核心区域贴近膜电极及流场，可实时捕捉流场方向上的温度梯度、机械应力变化等关键信息。
Absstract of: CN121496433A
本发明公开了一种制备高性能AEM电解水制氢膜电极的方法，分别制备AEM电解水制氢阳极和AEM电解水制氢膜阴极，然后将AEM电解水制氢阳极与AEM电解水制氢阴极置于阴离子交换膜两侧并封边，制得AEM电解水制氢膜电极，且制备阳极或阴极时，先将催化剂粉末于溶剂混合制备成催化剂预制浆料后，采用分批次加入阴离子交换树脂溶液后，并加入疏水性粘结剂，制得催化剂浆料，将该浆料涂于疏水改性的扩散层表面制得，最后在扩散层表面涂覆阴离子交换树脂溶液，并浸泡于有机溶剂，经冲洗即可。本发明制备的AEM电解水制氢膜电极能够实现减少氧气气泡滞留的基础上，提升稳定性的同时，提升膜电极的活性。
Absstract of: CN121496483A
本发明提供了质子交换膜电解水制氢的智能调控方法、装置和系统，包括：在不增加上机前器件制备工艺和成本的前提下，实现改善使用寿命的目标；可在线实时进行状态监测，并利用监测数据研判状态，避免人为经验误判；可采集长时间PEMWE电解槽器件的电化学信息，助推其老化机制的解析；当面对外部环境变化时，可快速识别并进行响应，避免因无人值守等情况造成不必要的性能损失。
Absstract of: CN121496447A
本发明公开了一种面向酸性电解水的钴基高密度单原子催化剂及其制备方法、应用，属于催化剂技术领域。所述的钴基高密度单原子催化剂包括：纳米四氧化三钴载体和负载在该载体上的单分散的铱单原子；所述铱单原子的负载量在6wt%以上，所述铱单原子的密度为4个/nm2以上。本发明公开了上述单原子催化剂在电催化分解水反应中的应用；通过提高单原子的利用率和负载密度，其在电催化分解水反应中具有高活性和高稳定性。此外，所述钴基高密度单原子催化剂合成便捷，成本低廉，在产业化应用中有巨大潜力。
Absstract of: CN121496427A
本发明涉及综合能源技术领域的一种新能源储能制氢系统，包含用于提供电能的新能源发电单元，用于利用电能电解水制取氢气并在运行过程中产生废热的电解制氢单元，用于以热能形式存储能量的热储能单元，以及包括热力网和协调控制器的络热管理与协调控制子系统；热力网络将电解制氢单元的废热出口、热储能单元的热交换接口以及电解制氢单元的进料预热需求端流体连接；协调控制器能够实现热能在电解制氢单元与热储能单元之间的协同管理与优化利用；该系统通过智能化的热管理与协调控制，实现系统内热能的高效回收、储存与再利用，提升整体能效与经济性。
Absstract of: JP2026020879A
【課題】電極性能に関連する状態のばらつきが少ない水電解用電極を製造する観点から有利な水電解用電極の製造方法を提供する。【解決手段】水電解用電極の製造方法は、下記（Ｉ）及び（II）を含んでいる。（Ｉ）少なくとも１つの導電性基材２１上に水電解用電極を形成させるための原料溶液Ｌ１を少なくとも１つの導電性基材２１が配設された容器１１を経由して循環させる。（II）容器１１の内部における原料溶液Ｌ１の流れの向きを反転させる。【選択図】図１
Absstract of: CN121496490A
本发明公开了一种氢能系统碱性电解槽的安全故障预测方法，涉及电解槽安全预测技术领域，解决了现有技术中，析氢异常监测无法捕捉电解液浓度微小动态波动、未建立浓度变化与气泡动力学关联的问题，具体为安全故障预测方法全面覆盖析氢异常、热疲劳裂纹、绝缘性能劣化三大核心安全风险，通过多源传感器数据融合、特征参数精准提取、耦合关联模型构建和全生命周期监测，实现了安全故障的早期识别、精准定位和分级预警；为管理员提供可操作的干预策略，有效降低安全故障发生率，延长设备使用寿命，保障氢能系统稳定可靠运行。
Absstract of: CN121490346A
本发明公开了一种用于肺功能训练的腹式呼吸训练装置，腹式呼吸训练装置通过定位板、储存气囊、气体发生装置、收集气囊、气泵、输出管道、发声器和控制组件的协同，使得使用者在吸气时腹部顶推储存气囊、控制组件随之动作并同步放大发声器音量，呼气时气囊回弹音量减弱，形成直观的听觉反馈，引导使用者自然采用腹式呼吸；同时气体发生装置按需向两个储存室供氧或供氢，气泵实现氢气循环，输出管道将氧气直接送达口鼻，既保证呼吸训练所需气体持续充足，又通过氢气回收避免浪费与风险，从而提升训练安全性、舒适性与有效性。
Absstract of: CN121496440A
本发明属于电催化材料与电解制氢技术领域，具体涉及一种复合电催化剂及其制备方法与应用。本发明所述基于高铷高硅锂矿石基为载体的Ni单活性中心复合电催化剂的制备方法，通过对高铷高硅锂矿石进行预处理、酸蚀活化、锂化调控、Ni活性溶液配制、溶剂热负载、焙烧定型等步骤，实现Ni单活性中心在矿石载体上的均匀负载与高效活化。该催化剂应用于尿素电解制氢时，展现出低起始电位、低过电位、高稳定性的优势。
Absstract of: CN121496316A
本发明属于催化剂领域，具体涉及一种钼合金表面负载碳化钼的制备方法及其应用。其制备方法包括取钼合金置于密闭容器中进行加热；向所述密闭容器中通入甲烷，使所述钼合金在甲烷气氛中高温碳化，碳化完成后即得所述钼合金表面负载碳化钼。有益效果是：制备钼合金表面负载碳化钼的过程快速高效；具有优异的电化学性能，具有高电催化活性和稳定性；无需催化剂或有机溶剂，工艺简单环保；通过调节甲烷流量可精准控制钼合金片的碳化时间，可以满足工业化生产的需求。
Absstract of: CN121493877A
本发明提供了一种MoS2(1‑x)Se2x纳米片阵列的方法及其制备方法。该制备方法包括如下步骤：将原料和衬底放置在密闭环境中，所述衬底位于所述原料的上方；其中所述原料为硫单质、硒单质、三氧化钼；在所述密闭环境中施加磁场，使所述原料置于所述磁场中；反应持续预定时间后，停止加载磁场；降温后则可得到原位生长的所述MoS2(1‑x)Se2x纳米片阵列，所述MoS2(1‑x)Se2x纳米片阵列位于所述衬底表面。与现有技术相比，本发明所使用的设备更为简单，反应时间显著缩短，制备效率高。
Absstract of: CN121496474A
本发明公开了一种高韧性碱性电解水制氢复合隔膜及其制备方法，属于电解水制氢复合隔膜的技术领域，所述复合隔膜包括聚砜、软链段单体、催化剂、1wt%~5wt%致孔剂和基于硅烷偶联剂改性的无机纳米氧化物颗粒，所述聚砜与硅烷偶联剂改性的无机纳米氧化物颗粒的质量比为1：3~8；所述无机纳米氧化物颗粒为二氧化硅、二氧化钛、二氧化锆中的任意一种或者多种，且颗粒中位粒径为D50=0.2μm~1μm。本发明通过体系内接枝柔软链段构建互穿网络结构，从而显著提升隔膜的韧性，使其在液氮极端低温环境下仍能保持抗脆断性能，为隔膜在寒冷地区的应用提供了潜在解决方案，具有较好的实用性。
Absstract of: KR20260018302A
산소발생반응용 전기 촉매를 개시한다. 어븀 산화물 나노 클러스터(nano cluster); 및 상기 어븀 산화물 나노 클러스터 상에 배치되어 상기 어븀 산화물 나노 클러스터와 이종계면을 형성하는 철 산화물 나노 입자를 포함한다.
Absstract of: CN120882907A
A system and method for generating hydrogen from a liquid source comprising water is disclosed. The system comprises: a high fluid velocity electrolysis cell comprising an inlet and an outlet, the inlet of the high fluid velocity electrolysis cell being fluidly connected to a liquid source; and a gas fractionation system fluidly connected to the outlet of the high fluid velocity electrolysis cell.
Nº publicación: KR20260018245A 09/02/2026
Applicant:
주지필로스
Absstract of: KR20260018245A
본 발명의 일 태양에 따르면, 수전해 스택에 공급되는 전해액의 유량을 개별 제어하기 위한 수전해 시스템으로서, 복수의 수전해 스택, 상기 복수의 수전해 스택과 일대일 대응으로 연결되어 전해액을 공급하는 복수의 전해액 공급 펌프, 및 상기 복수의 수전해 스택으로부터 배출되는 수소 가스 또는 산소 가스의 온도와 상기 복수의 수전해 스택에 대하여 설정되는 타겟 온도를 참조하여 상기 복수의 전해액 공급 펌프의 유량을 개별 제어하는 유량 제어부를 포함하는 수전해 시스템이 제공된다.
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